ES8506573A1 - Procedimiento para oxidar grupos alquilo a acidos carboxilicos - Google Patents
Procedimiento para oxidar grupos alquilo a acidos carboxilicosInfo
- Publication number
- ES8506573A1 ES8506573A1 ES531657A ES531657A ES8506573A1 ES 8506573 A1 ES8506573 A1 ES 8506573A1 ES 531657 A ES531657 A ES 531657A ES 531657 A ES531657 A ES 531657A ES 8506573 A1 ES8506573 A1 ES 8506573A1
- Authority
- ES
- Spain
- Prior art keywords
- alkyl groups
- carboxylic acids
- basic conditions
- under basic
- acids under
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B33/00—Oxidation in general
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D213/79—Acids; Esters
- C07D213/803—Processes of preparation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D215/00—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems
- C07D215/02—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen atoms or carbon atoms directly attached to the ring nitrogen atom
- C07D215/16—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen atoms or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D215/48—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen
- C07D215/54—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen attached in position 3
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Pyridine Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Quinoline Compounds (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Catalysts (AREA)
Abstract
PROCEDIMIENTO PARA LA PREPARACION DE ACIDOS CARBOXILICOS A PARTIR DE GRUPOS ALQUILO, BAJO CONDICIONES BASICAS, UTILIZANDO OXIDOS DE COBRE, COBALTO Y PLATA.CONSISTE EN HACER REACCIONAR OXIDANTES DE FORMULA GENERAL (I), EN LA QUE X ES COBRE, COBALTO O PLATA; Y ES OXIGENO; M ES UN ENTERO 1 O 2; N ES UN ENTERO DE 2 A 6; Y NIM, CON UN COMPUESTO DE FORMULA GENERAL (II), EN LA QUE R ES ALQUILO, ARILALQUILO O HETEROARILALQUILO, A TEMPERATURAS COMPRENDIDAS ENTRE 25 Y 95 GRADOS Y BAJO CONDICIONES BASICAS. EL COMPUESTO DE FORMULA GENERAL (II) SE MEZCLA CON UN ESTADO DE OXIDACION ELEVADO DE COBRE, COBALTO O PLATA Y A UN PH SUPERIOR A 9.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/485,769 US4623726A (en) | 1983-04-18 | 1983-04-18 | Method for oxidizing alkyl groups on pyridine, quinoline and benzene ring compounds to carboxylic acids under basic conditions |
Publications (2)
Publication Number | Publication Date |
---|---|
ES531657A0 ES531657A0 (es) | 1985-08-01 |
ES8506573A1 true ES8506573A1 (es) | 1985-08-01 |
Family
ID=23929381
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES531657A Expired ES8506573A1 (es) | 1983-04-18 | 1984-04-16 | Procedimiento para oxidar grupos alquilo a acidos carboxilicos |
Country Status (16)
Country | Link |
---|---|
US (2) | US4623726A (es) |
EP (1) | EP0126893B1 (es) |
JP (1) | JPS59199637A (es) |
KR (2) | KR920003836B1 (es) |
AR (1) | AR240910A1 (es) |
AU (1) | AU566449B2 (es) |
BR (1) | BR8401813A (es) |
CA (1) | CA1261845A (es) |
DE (1) | DE3478742D1 (es) |
DK (3) | DK168211B1 (es) |
ES (1) | ES8506573A1 (es) |
HU (1) | HU200980B (es) |
IE (1) | IE57308B1 (es) |
IL (1) | IL71466A (es) |
IN (1) | IN162865B (es) |
ZA (1) | ZA842889B (es) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4816588A (en) * | 1986-09-12 | 1989-03-28 | American Cyanamid Company | Method for the preparation of pyridine-2,3-dicarboxylic acids |
DE3706792A1 (de) * | 1987-03-03 | 1988-09-15 | Basf Ag | Verfahren zur herstellung von 7-chlor-chinolin-8-carbonsaeure |
JP2743473B2 (ja) * | 1988-07-04 | 1998-04-22 | 日産化学工業株式会社 | ピラゾールカルボン酸類の製造方法 |
US5202442A (en) * | 1988-07-04 | 1993-04-13 | Nissan Chemical Industries, Ltd. | Process for preparing pyrazolecarboxylic acid compounds |
DK0388619T3 (da) * | 1989-03-22 | 1994-10-03 | American Cyanamid Co | Fremgangsmåde til fremstilling af substituerede 2,3-pyridindicarboxylsyrer ved sekvensvis oxidation af substituerede quinoliner |
US5002641A (en) * | 1990-06-28 | 1991-03-26 | Reilly Industries, Inc. | Electrochemical synthesis of niacin and other N-heterocyclic compounds |
EP0743279A1 (en) * | 1995-05-16 | 1996-11-20 | The Procter & Gamble Company | Process for the manufacture of hypochlorite bleaching compositions |
US5928559A (en) * | 1995-05-16 | 1999-07-27 | The Procter & Gamble Company | Process for the manufacture of hypochlorite bleaching compositions |
PL236815B1 (pl) * | 2015-11-09 | 2021-02-22 | Wojciech Bukowski | Zastosowanie preparatu antybakteryjnego i antygrzybicznego |
EP3782985A1 (en) | 2019-08-19 | 2021-02-24 | BASF Agrochemical Products B.V. | Process for manufacturing 5-methoxymethylpyridine-2,3-dicarboxylic acid derivatives |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4450055A (en) * | 1983-03-30 | 1984-05-22 | Celanese Corporation | Electrogenerative partial oxidation of organic compounds |
US4496440A (en) * | 1984-06-04 | 1985-01-29 | The Dow Chemical Company | Oxidation of hydrophobic --CH2 OH compounds at oxidized nickel anodes |
-
1983
- 1983-04-18 US US06/485,769 patent/US4623726A/en not_active Expired - Lifetime
-
1984
- 1984-03-28 DE DE8484103414T patent/DE3478742D1/de not_active Expired
- 1984-03-28 EP EP84103414A patent/EP0126893B1/en not_active Expired
- 1984-03-30 IN IN211/CAL/84A patent/IN162865B/en unknown
- 1984-04-08 IL IL71466A patent/IL71466A/xx not_active IP Right Cessation
- 1984-04-16 CA CA000452079A patent/CA1261845A/en not_active Expired
- 1984-04-16 ES ES531657A patent/ES8506573A1/es not_active Expired
- 1984-04-17 ZA ZA842889A patent/ZA842889B/xx unknown
- 1984-04-17 AR AR296332A patent/AR240910A1/es active
- 1984-04-17 AU AU26897/84A patent/AU566449B2/en not_active Expired
- 1984-04-17 IE IE946/84A patent/IE57308B1/en not_active IP Right Cessation
- 1984-04-17 JP JP59075903A patent/JPS59199637A/ja active Granted
- 1984-04-17 DK DK198084A patent/DK168211B1/da not_active IP Right Cessation
- 1984-04-17 BR BR8401813A patent/BR8401813A/pt not_active IP Right Cessation
- 1984-04-17 KR KR1019840002011A patent/KR920003836B1/ko not_active IP Right Cessation
- 1984-04-18 HU HU841499A patent/HU200980B/hu unknown
-
1986
- 1986-08-25 US US06/900,462 patent/US4750978A/en not_active Expired - Lifetime
-
1991
- 1991-10-11 KR KR1019910017899A patent/KR920000693B1/ko not_active IP Right Cessation
-
1993
- 1993-06-22 DK DK074193A patent/DK170154B1/da not_active IP Right Cessation
- 1993-06-22 DK DK074093A patent/DK168623B1/da not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
HUT36771A (en) | 1985-10-28 |
ZA842889B (en) | 1984-11-28 |
EP0126893B1 (en) | 1989-06-21 |
AU566449B2 (en) | 1987-10-22 |
IN162865B (es) | 1988-07-16 |
IE840946L (en) | 1984-10-18 |
IL71466A0 (en) | 1984-07-31 |
DE3478742D1 (en) | 1989-07-27 |
HU200980B (en) | 1990-09-28 |
ES531657A0 (es) | 1985-08-01 |
DK170154B1 (da) | 1995-06-06 |
DK198084D0 (da) | 1984-04-17 |
KR920003836B1 (ko) | 1992-05-15 |
JPS59199637A (ja) | 1984-11-12 |
DK74093A (da) | 1993-06-22 |
EP0126893A1 (en) | 1984-12-05 |
KR920000693B1 (ko) | 1992-01-20 |
JPH0582372B2 (es) | 1993-11-18 |
AU2689784A (en) | 1984-10-25 |
DK168211B1 (da) | 1994-02-28 |
DK74193A (da) | 1993-06-22 |
US4623726A (en) | 1986-11-18 |
US4750978A (en) | 1988-06-14 |
AR240910A1 (es) | 1991-03-27 |
DK198084A (da) | 1984-10-19 |
DK74093D0 (da) | 1993-06-22 |
IE57308B1 (en) | 1992-07-15 |
KR840008460A (ko) | 1984-12-15 |
BR8401813A (pt) | 1984-11-27 |
IL71466A (en) | 1989-12-15 |
DK74193D0 (da) | 1993-06-22 |
DK168623B1 (da) | 1994-05-09 |
AR240910A2 (es) | 1991-03-27 |
CA1261845A (en) | 1989-09-26 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FD1A | Patent lapsed |
Effective date: 20040226 |