ES8506573A1 - Procedimiento para oxidar grupos alquilo a acidos carboxilicos - Google Patents

Procedimiento para oxidar grupos alquilo a acidos carboxilicos

Info

Publication number
ES8506573A1
ES8506573A1 ES531657A ES531657A ES8506573A1 ES 8506573 A1 ES8506573 A1 ES 8506573A1 ES 531657 A ES531657 A ES 531657A ES 531657 A ES531657 A ES 531657A ES 8506573 A1 ES8506573 A1 ES 8506573A1
Authority
ES
Spain
Prior art keywords
alkyl groups
carboxylic acids
basic conditions
under basic
acids under
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES531657A
Other languages
English (en)
Other versions
ES531657A0 (es
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wyeth Holdings LLC
Original Assignee
American Cyanamid Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by American Cyanamid Co filed Critical American Cyanamid Co
Publication of ES8506573A1 publication Critical patent/ES8506573A1/es
Publication of ES531657A0 publication Critical patent/ES531657A0/es
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B33/00—Oxidation in general
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C07D213/79—Acids; Esters
    • C07D213/803—Processes of preparation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D215/00—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems
    • C07D215/02—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen atoms or carbon atoms directly attached to the ring nitrogen atom
    • C07D215/16—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen atoms or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D215/48—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen
    • C07D215/54—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen attached in position 3

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Pyridine Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Quinoline Compounds (AREA)

Abstract

PROCEDIMIENTO PARA LA PREPARACION DE ACIDOS CARBOXILICOS A PARTIR DE GRUPOS ALQUILO, BAJO CONDICIONES BASICAS, UTILIZANDO OXIDOS DE COBRE, COBALTO Y PLATA.CONSISTE EN HACER REACCIONAR OXIDANTES DE FORMULA GENERAL (I), EN LA QUE X ES COBRE, COBALTO O PLATA; Y ES OXIGENO; M ES UN ENTERO 1 O 2; N ES UN ENTERO DE 2 A 6; Y NIM, CON UN COMPUESTO DE FORMULA GENERAL (II), EN LA QUE R ES ALQUILO, ARILALQUILO O HETEROARILALQUILO, A TEMPERATURAS COMPRENDIDAS ENTRE 25 Y 95 GRADOS Y BAJO CONDICIONES BASICAS. EL COMPUESTO DE FORMULA GENERAL (II) SE MEZCLA CON UN ESTADO DE OXIDACION ELEVADO DE COBRE, COBALTO O PLATA Y A UN PH SUPERIOR A 9.
ES531657A 1983-04-18 1984-04-16 Procedimiento para oxidar grupos alquilo a acidos carboxilicos Granted ES531657A0 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US06/485,769 US4623726A (en) 1983-04-18 1983-04-18 Method for oxidizing alkyl groups on pyridine, quinoline and benzene ring compounds to carboxylic acids under basic conditions

Publications (2)

Publication Number Publication Date
ES8506573A1 true ES8506573A1 (es) 1985-08-01
ES531657A0 ES531657A0 (es) 1985-08-01

Family

ID=23929381

Family Applications (1)

Application Number Title Priority Date Filing Date
ES531657A Granted ES531657A0 (es) 1983-04-18 1984-04-16 Procedimiento para oxidar grupos alquilo a acidos carboxilicos

Country Status (16)

Country Link
US (2) US4623726A (es)
EP (1) EP0126893B1 (es)
JP (1) JPS59199637A (es)
KR (2) KR920003836B1 (es)
AR (1) AR240910A1 (es)
AU (1) AU566449B2 (es)
BR (1) BR8401813A (es)
CA (1) CA1261845A (es)
DE (1) DE3478742D1 (es)
DK (3) DK168211B1 (es)
ES (1) ES531657A0 (es)
HU (1) HU200980B (es)
IE (1) IE57308B1 (es)
IL (1) IL71466A (es)
IN (1) IN162865B (es)
ZA (1) ZA842889B (es)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4816588A (en) * 1986-09-12 1989-03-28 American Cyanamid Company Method for the preparation of pyridine-2,3-dicarboxylic acids
DE3706792A1 (de) * 1987-03-03 1988-09-15 Basf Ag Verfahren zur herstellung von 7-chlor-chinolin-8-carbonsaeure
JP2743473B2 (ja) * 1988-07-04 1998-04-22 日産化学工業株式会社 ピラゾールカルボン酸類の製造方法
US5202442A (en) * 1988-07-04 1993-04-13 Nissan Chemical Industries, Ltd. Process for preparing pyrazolecarboxylic acid compounds
ES2058625T3 (es) * 1989-03-22 1994-11-01 American Cyanamid Co Metodo para la oxidacion secuencial de quinolinas sustituidas para producir acidos piridin-2,3-dicarboxilicos sustituidos.
US5002641A (en) * 1990-06-28 1991-03-26 Reilly Industries, Inc. Electrochemical synthesis of niacin and other N-heterocyclic compounds
US5928559A (en) * 1995-05-16 1999-07-27 The Procter & Gamble Company Process for the manufacture of hypochlorite bleaching compositions
EP0743279A1 (en) * 1995-05-16 1996-11-20 The Procter & Gamble Company Process for the manufacture of hypochlorite bleaching compositions
PL236815B1 (pl) * 2015-11-09 2021-02-22 Wojciech Bukowski Zastosowanie preparatu antybakteryjnego i antygrzybicznego
EP3782985A1 (en) 2019-08-19 2021-02-24 BASF Agrochemical Products B.V. Process for manufacturing 5-methoxymethylpyridine-2,3-dicarboxylic acid derivatives

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4450055A (en) * 1983-03-30 1984-05-22 Celanese Corporation Electrogenerative partial oxidation of organic compounds
US4496440A (en) * 1984-06-04 1985-01-29 The Dow Chemical Company Oxidation of hydrophobic --CH2 OH compounds at oxidized nickel anodes

Also Published As

Publication number Publication date
DK170154B1 (da) 1995-06-06
EP0126893B1 (en) 1989-06-21
EP0126893A1 (en) 1984-12-05
US4750978A (en) 1988-06-14
DK168623B1 (da) 1994-05-09
DK74193D0 (da) 1993-06-22
IL71466A (en) 1989-12-15
DK74093D0 (da) 1993-06-22
DK74093A (da) 1993-06-22
JPS59199637A (ja) 1984-11-12
IN162865B (es) 1988-07-16
HU200980B (en) 1990-09-28
IL71466A0 (en) 1984-07-31
DE3478742D1 (en) 1989-07-27
DK198084A (da) 1984-10-19
AU566449B2 (en) 1987-10-22
DK198084D0 (da) 1984-04-17
AR240910A2 (es) 1991-03-27
IE57308B1 (en) 1992-07-15
HUT36771A (en) 1985-10-28
CA1261845A (en) 1989-09-26
JPH0582372B2 (es) 1993-11-18
BR8401813A (pt) 1984-11-27
AU2689784A (en) 1984-10-25
KR920000693B1 (ko) 1992-01-20
KR920003836B1 (ko) 1992-05-15
AR240910A1 (es) 1991-03-27
DK168211B1 (da) 1994-02-28
DK74193A (da) 1993-06-22
KR840008460A (ko) 1984-12-15
US4623726A (en) 1986-11-18
ZA842889B (en) 1984-11-28
IE840946L (en) 1984-10-18
ES531657A0 (es) 1985-08-01

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Legal Events

Date Code Title Description
FD1A Patent lapsed

Effective date: 20040226