ES485527A1 - Procedimiento para la preparacion de acetaldehido - Google Patents
Procedimiento para la preparacion de acetaldehidoInfo
- Publication number
- ES485527A1 ES485527A1 ES485527A ES485527A ES485527A1 ES 485527 A1 ES485527 A1 ES 485527A1 ES 485527 A ES485527 A ES 485527A ES 485527 A ES485527 A ES 485527A ES 485527 A1 ES485527 A1 ES 485527A1
- Authority
- ES
- Spain
- Prior art keywords
- gram
- halogen
- ionic iodide
- cobalt
- ions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
- Saccharide Compounds (AREA)
Abstract
Procedimiento para la preparación del acetaldehído, medio reacción sobre metanol de una mezcla que comprende hidrógeno y monóxido de carbono, representando el hidrógeno al menos un 25% en moles, a una temperatura mínima de 165ºC y en presencia de una cantidad eficaz de cobalto, caracterizado porque la citada reacción se lleva a cabo en presencia de un yoduro iónico por lo menos y cuando menos un halogenuro covalente, eligiéndose el catión del yoduro iónico entre el grupo que está constituido por los cationes de metales alcalinos, cationes de metales alcalinotérreos, cationes de amonio, cationes de amonio cuaternario, cationes fosfonio y cationes fosfonio cuaternario, siendo mayor o igual a 5 la relación I- /Co (en átomos-grano) y estando comprendida entre el 0,1 y 10 % la relación X/I- (en átomos-grano) donde X representa un átomo de halógeno procedente del halogenuro covalente.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7831634A FR2441603A1 (fr) | 1978-10-31 | 1978-10-31 | Procede de preparation de l'acetaldehyde |
Publications (1)
Publication Number | Publication Date |
---|---|
ES485527A1 true ES485527A1 (es) | 1980-05-16 |
Family
ID=9214627
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES485527A Expired ES485527A1 (es) | 1978-10-31 | 1979-10-30 | Procedimiento para la preparacion de acetaldehido |
Country Status (10)
Country | Link |
---|---|
US (1) | US4293718A (es) |
EP (1) | EP0011042B2 (es) |
JP (1) | JPS5564539A (es) |
AT (1) | ATE199T1 (es) |
BR (1) | BR7907034A (es) |
CA (1) | CA1125311A (es) |
DD (1) | DD146943A5 (es) |
DE (1) | DE2960788D1 (es) |
ES (1) | ES485527A1 (es) |
FR (1) | FR2441603A1 (es) |
Families Citing this family (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2460284A1 (fr) * | 1979-07-04 | 1981-01-23 | Rhone Poulenc Ind | Procede de preparation de l'acetaldehyde |
US4320230A (en) * | 1979-09-24 | 1982-03-16 | Exxon Research & Engineering Co. | Methanol homologation using iron-cobalt carbonyl cluster catalyst |
CA1155458A (en) * | 1980-04-09 | 1983-10-18 | Union Carbide Corporation | Process for the selective hydroformylation of methanol to acetaldehyde |
JPS579733A (en) * | 1980-06-18 | 1982-01-19 | Mitsubishi Gas Chem Co Inc | Preparation of acetaldehyde |
DE3031558C2 (de) * | 1980-08-21 | 1984-04-26 | Union Rheinische Braunkohlen Kraftstoff AG, 5000 Köln | Verfahren zur Herstellung von Acetaldehyd und Ethanol |
US4361707A (en) * | 1981-08-03 | 1982-11-30 | Gulf Research & Development Company | Process for producing aldehydes |
US4361706A (en) * | 1981-08-03 | 1982-11-30 | Gulf Research & Development Company | Process for preparing aldehydes |
EP0098689B1 (en) * | 1982-06-05 | 1986-12-17 | BP Chemicals Limited | Process for the production of monocarboxylic acid anhydrides |
GB8326986D0 (en) * | 1983-10-08 | 1983-11-09 | British Petroleum Co Plc | Production of ethanol |
JPS6084239A (ja) * | 1983-10-14 | 1985-05-13 | Agency Of Ind Science & Technol | アセトアルデヒドの製造法 |
DE3343519A1 (de) * | 1983-12-01 | 1985-06-13 | Union Rheinische Braunkohlen Kraftstoff AG, 5000 Köln | Selektive herstellung von acetaldehyd |
DE3506714A1 (de) * | 1985-02-26 | 1986-08-28 | Union Rheinische Braunkohlen Kraftstoff AG, 5000 Köln | Verfahren zur kontinuierlichen homologisierung von methanol |
JPH0374007U (es) * | 1989-11-15 | 1991-07-25 | ||
US20050154239A1 (en) * | 2004-01-08 | 2005-07-14 | Windhorst Kenneth A. | Methods for preparing 1,3 butylene glycol |
US9365479B1 (en) | 2014-12-30 | 2016-06-14 | Eastman Chemical Company | Methyl-iodide-free carbonylation of an alcohol to its homologous aldehyde and/or alcohol |
US9714206B2 (en) | 2014-12-30 | 2017-07-25 | Eastman Chemical Company | Methyl-iodide-free carbonylation of an alcohol to its homologous aldehyde and/or alcohol |
US9266806B1 (en) | 2014-12-30 | 2016-02-23 | Eastman Chemical Company | Reductive carbonylation of methanol to acetaldehyde |
US9266807B1 (en) | 2014-12-30 | 2016-02-23 | Eastman Chemical Company | Conversion of alcohols to longer chain aldehydes or alcohols |
US9238606B1 (en) | 2014-12-30 | 2016-01-19 | Eastman Chemical Company | Methyl-Iodide-free carbonylation of methanol to acetaldehyde |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3248432A (en) * | 1961-12-12 | 1966-04-26 | Commercial Solvents Corp | Process for the production of ethyl alcohol |
US3356734A (en) * | 1963-02-28 | 1967-12-05 | Kuraishi Michio | Process for the production of acetaldehyde |
US3285948A (en) * | 1965-01-22 | 1966-11-15 | Commercial Solvents Corp | Halides of ruthenium and osmium in conjunction with cobalt and iodine in the production of ethanol from methanol |
BE842430A (nl) * | 1975-06-09 | 1976-12-01 | Werkwijze ter bereiding van ethanol uit methanol koolmonoxyde en waterstof | |
JPS52133914A (en) * | 1976-04-30 | 1977-11-09 | Mitsubishi Gas Chem Co Inc | Preparation of acetaldehyde |
JPS52136111A (en) * | 1976-05-10 | 1977-11-14 | Mitsubishi Gas Chem Co Inc | Preparation of acetaldehyde |
US4151208A (en) * | 1977-12-23 | 1979-04-24 | Gulf Research & Development Company | Process for the selective preparation of acetaldehyde from methanol and synthesis gas |
-
1978
- 1978-10-31 FR FR7831634A patent/FR2441603A1/fr active Granted
-
1979
- 1979-10-22 DE DE7979420052T patent/DE2960788D1/de not_active Expired
- 1979-10-22 EP EP79420052A patent/EP0011042B2/fr not_active Expired
- 1979-10-22 AT AT79420052T patent/ATE199T1/de active
- 1979-10-23 US US06/087,631 patent/US4293718A/en not_active Expired - Lifetime
- 1979-10-26 JP JP13863179A patent/JPS5564539A/ja active Granted
- 1979-10-30 DD DD79216554A patent/DD146943A5/de unknown
- 1979-10-30 BR BR7907034A patent/BR7907034A/pt unknown
- 1979-10-30 CA CA338,764A patent/CA1125311A/fr not_active Expired
- 1979-10-30 ES ES485527A patent/ES485527A1/es not_active Expired
Also Published As
Publication number | Publication date |
---|---|
CA1125311A (fr) | 1982-06-08 |
JPS5564539A (en) | 1980-05-15 |
EP0011042B1 (fr) | 1981-09-09 |
EP0011042B2 (fr) | 1986-03-26 |
FR2441603A1 (fr) | 1980-06-13 |
JPS6344135B2 (es) | 1988-09-02 |
DD146943A5 (de) | 1981-03-11 |
EP0011042A1 (fr) | 1980-05-14 |
US4293718A (en) | 1981-10-06 |
BR7907034A (pt) | 1980-07-15 |
ATE199T1 (de) | 1981-09-15 |
DE2960788D1 (en) | 1981-11-26 |
FR2441603B1 (es) | 1981-05-29 |
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