ES468467A1 - Un procedimiento mejorado de preparacion de anhidrido malei-co - Google Patents

Un procedimiento mejorado de preparacion de anhidrido malei-co

Info

Publication number
ES468467A1
ES468467A1 ES468467A ES468467A ES468467A1 ES 468467 A1 ES468467 A1 ES 468467A1 ES 468467 A ES468467 A ES 468467A ES 468467 A ES468467 A ES 468467A ES 468467 A1 ES468467 A1 ES 468467A1
Authority
ES
Spain
Prior art keywords
molybdenum
maleic anhydride
catalyst
group
butadiene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES468467A
Other languages
English (en)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Standard Oil Co
Original Assignee
Standard Oil Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Standard Oil Co filed Critical Standard Oil Co
Publication of ES468467A1 publication Critical patent/ES468467A1/es
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/30—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8877—Vanadium, tantalum, niobium or polonium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/31—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting
    • C07C51/313—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting with molecular oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Furan Compounds (AREA)

Abstract

Un procedimiento mejorado de preparación de anhídrido maleico, que comprende poner en contacto una mezcla de un compuesto orgánico insaturado seleccionado del grupo que consta de n-butilenos, 1,3-butadieno, aldehido crotónico y furano, y un gas que contiene oxígeno, con un catalizador, a una temperatura comprendida entre aproximadamente 0,07 y 35 kg/cm2, y en donde la proporción molar de oxígeno respecto al compuesto orgánico está comprendida entre 2:1 y 40:1, comprendiendo la mejora: usar como catalizador un catalizador un catalizador de fórmula AaEcMoeSbfOx en la que A es por lo menos un elemento seleccionado del grupo que consta de niobio, zirconio, titanio y tántalo; E es un miembro seleccionado del grupo que consta de hidrato de hidracina, un metal finamente dividido de molibdeno, wolframio, magnesio, aluminio o níquel; y en donde a es un número de 0,01 a 6; c es un número de 0 a 0,2 e y f son números de 1 a 9; x es un número que satisface los requisitos de valencia de los otros elementos presentes; y en donde por lo menos parte del molibdeno en el catalizador se mantiene en un estado de valencia inferior a +6; conteniendo facultativamente dicho catalizador uno o más elementos seleccionados del grupo que consta de litio, plata, cerio, cadmio, cobalto, arsénico, silicio, zinc, germanio, bismuto, rutenio, platino y uranio.
ES468467A 1977-04-04 1978-04-01 Un procedimiento mejorado de preparacion de anhidrido malei-co Expired ES468467A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/784,003 US4155920A (en) 1977-04-04 1977-04-04 Synthesis of maleic anhydride

Publications (1)

Publication Number Publication Date
ES468467A1 true ES468467A1 (es) 1979-01-01

Family

ID=25131062

Family Applications (2)

Application Number Title Priority Date Filing Date
ES468467A Expired ES468467A1 (es) 1977-04-04 1978-04-01 Un procedimiento mejorado de preparacion de anhidrido malei-co
ES469556A Expired ES469556A1 (es) 1977-04-04 1978-05-08 Un procedimiento mejorado de preparacion de anhidrido malei-co.

Family Applications After (1)

Application Number Title Priority Date Filing Date
ES469556A Expired ES469556A1 (es) 1977-04-04 1978-05-08 Un procedimiento mejorado de preparacion de anhidrido malei-co.

Country Status (19)

Country Link
US (1) US4155920A (es)
JP (1) JPS53124217A (es)
AT (1) ATA220278A (es)
BE (1) BE865379A (es)
BR (1) BR7802105A (es)
CA (1) CA1117930A (es)
CS (1) CS209892B2 (es)
DD (1) DD138209A5 (es)
DE (1) DE2813424A1 (es)
EG (1) EG13335A (es)
ES (2) ES468467A1 (es)
FR (1) FR2386536A1 (es)
GB (2) GB1595363A (es)
IN (1) IN149044B (es)
IT (1) IT1093993B (es)
MX (1) MX147707A (es)
NL (1) NL7803459A (es)
NO (1) NO781154L (es)
PT (1) PT67837B (es)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4473707A (en) * 1981-01-16 1984-09-25 The Standard Oil Company Oxidative dehydrogenation of carboxylic acids with mixed metal phosphorus oxide coated catalysts
US4364856A (en) * 1981-01-16 1982-12-21 The Standard Oil Company Mixed metal phosphorus oxide coated catalysts for the oxidative dehydrogenation of carboxylic acids
US4358601A (en) * 1981-07-02 1982-11-09 National Distillers & Chemical Corp. Process for preparing 2-butenolide
US4599430A (en) * 1981-12-21 1986-07-08 The Standard Oil Company Nitrogenation of hydrocarbons, including the production of maleimide
DE10137534A1 (de) * 2001-08-01 2003-02-13 Basf Ag Verfahren zur Herstellung von Maleinsäureanhydrid
WO2020130802A1 (en) 2018-12-21 2020-06-25 Nederlandse Organisatie Voor Toegepast- Natuurwetenschappelijk Onderzoek Tno Oxidative preparation of maleic acid

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1160630A (fr) * 1955-12-15 1958-07-22 Du Pont Nouvelles compositions adhésives
GB1157117A (en) * 1966-07-04 1969-07-02 Ici Ltd Production of Maleic Anhydride
BE759434A (fr) * 1969-11-25 1971-04-30 Power Gas Ltd Oxydation catalytique
BE787647A (fr) * 1971-09-01 1973-02-19 Standard Oil Co Procede de preparation d'anhydride maleique et catalyseur utilisable dans ce procede
FR2252123B1 (es) * 1973-11-22 1980-08-08 Rhone Progil
DE2425287A1 (de) * 1974-05-24 1975-12-11 Celamerck Gmbh & Co Kg Triazinderivate

Also Published As

Publication number Publication date
DD138209A5 (de) 1979-10-17
BE865379A (fr) 1978-07-17
IN149044B (es) 1981-08-22
PT67837A (en) 1978-04-01
CA1117930A (en) 1982-02-09
FR2386536B1 (es) 1983-05-27
PT67837B (en) 1979-09-28
US4155920A (en) 1979-05-22
CS209892B2 (en) 1981-12-31
IT7821893A0 (it) 1978-03-31
ES469556A1 (es) 1978-12-01
BR7802105A (pt) 1979-04-03
IT1093993B (it) 1985-07-26
MX147707A (es) 1983-01-06
EG13335A (en) 1981-03-31
DE2813424A1 (de) 1978-10-12
JPS53124217A (en) 1978-10-30
FR2386536A1 (fr) 1978-11-03
NO781154L (no) 1978-10-05
GB1595364A (en) 1981-08-12
NL7803459A (nl) 1978-10-06
ATA220278A (de) 1981-12-15
GB1595363A (en) 1981-08-12

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