ES466474A1 - Multicomponent membranes - Google Patents

Multicomponent membranes

Info

Publication number
ES466474A1
ES466474A1 ES466474A ES466474A ES466474A1 ES 466474 A1 ES466474 A1 ES 466474A1 ES 466474 A ES466474 A ES 466474A ES 466474 A ES466474 A ES 466474A ES 466474 A1 ES466474 A1 ES 466474A1
Authority
ES
Spain
Prior art keywords
gas
membrane
permeation
mixture
gas mixture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES466474A
Other languages
Spanish (es)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Monsanto Co
Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/832,481 external-priority patent/US4230463A/en
Application filed by Monsanto Co filed Critical Monsanto Co
Publication of ES466474A1 publication Critical patent/ES466474A1/en
Expired legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D69/00Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/12Composite membranes; Ultra-thin membranes
    • B01D69/1212Coextruded layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D67/00Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0081After-treatment of organic or inorganic membranes
    • B01D67/0088Physical treatment with compounds, e.g. swelling, coating or impregnation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • B01D53/228Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion characterised by specific membranes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D69/00Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/08Hollow fibre membranes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D69/00Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/12Composite membranes; Ultra-thin membranes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D71/00Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06Organic material
    • B01D71/66Polymers having sulfur in the main chain, with or without nitrogen, oxygen or carbon only
    • B01D71/68Polysulfones; Polyethersulfones
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D71/00Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06Organic material
    • B01D71/76Macromolecular material not specifically provided for in a single one of groups B01D71/08 - B01D71/74

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

A method for separating at least one gas in a gas mixture from at least one other gas in said gas mixture by selective permeation and providing a product that has been subjected to permeation containing at least one permeation gas, which comprises at least one in contact the gas mixture with a surface of a membrane, which membrane exhibits, with respect to at least a pair of gases of said gas mixture, a selective permeation of a gas of said gas pair over that of the remaining gas of said gas. Of gases, maintain the opposite surface of the membrane at a lower chemical potential for at least said permeation gas than the chemical potential on said surface, cause at least said permeation gas to pass through the membrane, and separate from the proximity of said opposite surface a product that has been subjected to permeation having a different proportion of said gas from said gas mixture with respect to said other gas of said mixture gaseous gas that ratio in said gas mixture of at least one gas relative to said other gas, characterized in that the membrane is a membrane of multiple components comprising a coating in occlusion contact with a porous separation membrane having a volume of holes important and comprising material, said material exhibiting a selective permeation of at least one gas of the gaseous mixture over that of one or more remaining gases of the gas mixture, wherein with respect to at least one pair of gases of said gas mixture, the material of the porous separation membrane exhibits a determined intrinsic separation factor of the coating material and the multi-component membrane exhibits a separation factor significantly greater than the determined intrinsic separation factor of the coating material and greater than the separation factor exhibited by the porous separation membrane. (Machine-translation by Google Translate, not legally binding)
ES466474A 1976-11-15 1978-01-30 Multicomponent membranes Expired ES466474A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US74215976A 1976-11-15 1976-11-15
US05/832,481 US4230463A (en) 1977-09-13 1977-09-13 Multicomponent membranes for gas separations

Publications (1)

Publication Number Publication Date
ES466474A1 true ES466474A1 (en) 1979-06-01

Family

ID=27113975

Family Applications (3)

Application Number Title Priority Date Filing Date
ES464048A Expired ES464048A1 (en) 1976-11-15 1977-11-11 Multicomponent membranes
ES466474A Expired ES466474A1 (en) 1976-11-15 1978-01-30 Multicomponent membranes
ES475666A Expired ES475666A1 (en) 1976-11-15 1978-12-01 Multicomponent membranes

Family Applications Before (1)

Application Number Title Priority Date Filing Date
ES464048A Expired ES464048A1 (en) 1976-11-15 1977-11-11 Multicomponent membranes

Family Applications After (1)

Application Number Title Priority Date Filing Date
ES475666A Expired ES475666A1 (en) 1976-11-15 1978-12-01 Multicomponent membranes

Country Status (28)

Country Link
JP (1) JPS5951321B2 (en)
AR (1) AR224102A1 (en)
AT (1) AT374375B (en)
AU (1) AU504016B2 (en)
BE (1) BE860811A (en)
BR (1) BR7707583A (en)
CA (1) CA1107203A (en)
CS (1) CS257751B2 (en)
DD (1) DD133298A5 (en)
DE (1) DE2750874C2 (en)
DK (1) DK148735C (en)
EG (1) EG13082A (en)
ES (3) ES464048A1 (en)
FI (1) FI61636C (en)
FR (1) FR2410501A1 (en)
GB (1) GB1590813A (en)
IL (1) IL53379A (en)
IT (1) IT1089058B (en)
MX (2) MX148173A (en)
NL (1) NL175387C (en)
NO (1) NO149019C (en)
PH (1) PH14682A (en)
PL (1) PL125022B1 (en)
PT (1) PT67269B (en)
RO (1) RO76391A (en)
SE (1) SE440744B (en)
TR (1) TR19886A (en)
YU (1) YU41572B (en)

Families Citing this family (41)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5416378A (en) * 1977-07-08 1979-02-06 Asahi Chem Ind Co Ltd Polysulfone semipermeable membrane
CA1127472A (en) * 1977-11-25 1982-07-13 Robert L. Riley Gas separation membranes and process for the preparation thereof
US4181675A (en) * 1978-09-19 1980-01-01 Monsanto Company Process for methanol production
IL59581A0 (en) * 1979-03-28 1980-06-30 Monsanto Co Methods for preparing anisotropic membranes and membranes prepared therefrom
DE3061132D1 (en) * 1979-04-03 1982-12-30 Monsanto Co Gas recovery process
US4238204A (en) * 1979-06-18 1980-12-09 Monsanto Company Selective adsorption process
EP0024718A3 (en) * 1979-09-04 1981-10-14 Friedrich Wolff Device for increasing or decreasing the oxygen content of air, and method of producing and of operating it
DE3006880C2 (en) * 1980-02-23 1986-10-09 Akzo Gmbh, 5600 Wuppertal Plasmaphoresis membrane
FR2478482A1 (en) * 1980-03-21 1981-09-25 Lidorenko Nikolai Supported gas-permeable membranes - for use in blood oxygenator(s)
FR2482468A1 (en) * 1980-05-19 1981-11-20 Bend Res Inc Reverse osmosis composite membrane is hollow fibre - whose inner surface is coated with interfacial salt rejecting membrane
JPS5794304A (en) * 1980-12-03 1982-06-11 Sumitomo Chem Co Ltd Gas separating membrane made of polysulfone hollow fiber and its manufacture
JPS57104007A (en) * 1980-12-19 1982-06-28 Matsushita Electric Ind Co Ltd Oxygen-enriched gas supplying equipment for combustion
US4362613A (en) * 1981-03-13 1982-12-07 Monsanto Company Hydrocracking processes having an enhanced efficiency of hydrogen utilization
US4367135A (en) * 1981-03-12 1983-01-04 Monsanto Company Processes
JPS588514A (en) * 1981-07-08 1983-01-18 Ube Ind Ltd Preparation of composite separation film
JPS58132111A (en) * 1982-01-29 1983-08-06 Asahi Chem Ind Co Ltd Polysulfone hollow fiber
US4428776A (en) * 1982-06-23 1984-01-31 The Standard Oil Company Cellulosic semipermeable membranes containing silicon compounds
JPS59160506A (en) * 1983-02-28 1984-09-11 Kuraray Co Ltd Composite hollow yarn separating membrane and its production
JPS59169509A (en) * 1983-03-14 1984-09-25 Toray Ind Inc Hollow yarn membrane for separating gas and preparation thereof
EP0141793A1 (en) * 1983-06-30 1985-05-15 Monsanto Company Asymmetric gas separation membranes having increased selectivy, and process for their production
US4530703A (en) * 1983-06-30 1985-07-23 Monsanto Company Cross-linked polyarylene oxide membranes
DE3467856D1 (en) * 1983-06-30 1988-01-14 Monsanto Co Amorphous aryl substituted polyarylene oxide membranes
GB2151597B (en) * 1983-12-16 1987-09-30 Petrocarbon Dev Ltd Recovery of carbon dioxide from gas mixtures
US4639257A (en) * 1983-12-16 1987-01-27 Costain Petrocarbon Limited Recovery of carbon dioxide from gas mixture
GB2154600A (en) * 1984-02-23 1985-09-11 British Gas Corp Producing and purifying methane
WO1985004593A1 (en) * 1984-04-11 1985-10-24 Syrinx Research Pty. Ltd. High flux membrane
JPS61408A (en) * 1984-06-11 1986-01-06 Toyobo Co Ltd Hollow yarn composite membrane
DE3567809D1 (en) * 1985-02-14 1989-03-02 Uop Inc Thin-film semipermeable membranes, a method for their preparation and hydrogen-sensing and-separating devices including them
DE3525235C1 (en) * 1985-07-15 1986-11-27 Gkss - Forschungszentrum Geesthacht Gmbh, 2054 Geesthacht Process for producing and increasing the selectivity of an integral asymmetrical membrane
JPH0822373B2 (en) * 1986-02-10 1996-03-06 旭化成工業株式会社 Method for forming polysulfone-based composite membrane
EP0242069A3 (en) * 1986-04-14 1988-08-03 Dow Corning Corporation Semipermeable composite membranes produced from silicone water based emulsions applied to porous substrates
US4894068A (en) * 1988-12-27 1990-01-16 Permea, Inc. Process for capturing nitrogen from air using gas separation membranes
DE4242806A1 (en) * 1992-12-17 1994-06-23 Siemens Ag Sensor hose
US5286280A (en) * 1992-12-31 1994-02-15 Hoechst Celanese Corporation Composite gas separation membrane having a gutter layer comprising a crosslinked polar phenyl-containing - organopolysiloxane, and method for making the same -
US5514413A (en) * 1994-03-31 1996-05-07 Air Products And Chemicals, Inc. Process for producing composite membranes
US5443728A (en) * 1994-04-28 1995-08-22 Praxair Technology, Inc. Method of preparing membranes from blends of polyetherimide and polyimide polymers
US6315968B1 (en) * 1995-01-18 2001-11-13 Air Products And Chemicals, Inc. Process for separating acid gases from gaseous mixtures utilizing composite membranes formed from salt-polymer blends
US6085549A (en) * 1998-04-08 2000-07-11 Messer Griesheim Industries, Inc. Membrane process for producing carbon dioxide
US6128919A (en) * 1998-04-08 2000-10-10 Messer Griesheim Industries, Inc. Process for separating natural gas and carbon dioxide
US20090223229A1 (en) * 2006-12-19 2009-09-10 Hua Wang Method and System for Using Low BTU Fuel Gas in a Gas Turbine
ITUB20159436A1 (en) * 2015-12-28 2017-06-28 Medica S P A USE OF A MEMBRANE FOR BIOGAS PURIFICATION

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL236452A (en) * 1958-02-24 1900-01-01
US3350844A (en) * 1964-09-21 1967-11-07 Gen Electric Process for the separation or enrichment of gases
AU412451B1 (en) * 1966-02-21 1971-04-21 E. I. Dupont De Nemours And Company Process and apparatus for separation of fluid mixtures
FR1566272A (en) * 1968-01-19 1969-05-09
NL158087B (en) * 1968-01-30 1978-10-16 Universal Oil Prod Co PROCESS FOR SEPARATING GASES USING A MEMBRANE FROM A CELLULOSE ESTER.
FR2082095A5 (en) * 1970-03-03 1971-12-10 Rhone Poulenc Sa
US3926798A (en) * 1974-10-17 1975-12-16 Us Interior Reverse osmosis membrane
JPS5255719A (en) * 1975-10-31 1977-05-07 Daicel Chem Ind Ltd Hollow fibers having selective gas permeability and production thereof
US3980456A (en) * 1975-03-31 1976-09-14 General Electric Company Method for sealing breaches in multi-layer ultrathin membrane composites

Also Published As

Publication number Publication date
IL53379A0 (en) 1978-01-31
CS257751B2 (en) 1988-06-15
ES475666A1 (en) 1979-05-16
SE440744B (en) 1985-08-19
DK503277A (en) 1978-05-16
AU504016B2 (en) 1979-09-27
DE2750874A1 (en) 1978-05-18
FR2410501A1 (en) 1979-06-29
FI61636C (en) 1982-09-10
SE7712818L (en) 1978-05-16
DK148735C (en) 1986-02-03
PT67269B (en) 1979-04-18
MX172537B (en) 1993-12-17
NL175387C (en) 1984-11-01
FR2410501B1 (en) 1982-12-10
MX148173A (en) 1983-03-24
NO773882L (en) 1978-05-18
AU3060777A (en) 1979-05-24
ES464048A1 (en) 1978-08-01
PT67269A (en) 1977-12-01
ATA812477A (en) 1983-09-15
BE860811A (en) 1978-05-16
IL53379A (en) 1980-05-30
IT1089058B (en) 1985-06-10
PL202124A1 (en) 1979-01-02
AR224102A1 (en) 1981-10-30
PL125022B1 (en) 1983-03-31
AT374375B (en) 1984-04-10
JPS5951321B2 (en) 1984-12-13
DK148735B (en) 1985-09-16
CA1107203A (en) 1981-08-18
YU272277A (en) 1982-10-31
BR7707583A (en) 1978-08-22
NL175387B (en) 1984-06-01
DE2750874C2 (en) 1986-04-30
FI61636B (en) 1982-05-31
FI773439A (en) 1978-05-16
DD133298A5 (en) 1978-12-27
TR19886A (en) 1980-04-09
GB1590813A (en) 1981-06-10
NL7712432A (en) 1978-05-17
YU41572B (en) 1987-10-31
NO149019B (en) 1983-10-24
EG13082A (en) 1980-10-31
PH14682A (en) 1981-11-10
RO76391A (en) 1981-05-30
JPS5386684A (en) 1978-07-31
NO149019C (en) 1984-02-01

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