ES451697A1 - Method for the preparation of 2-alkyl indanes - Google Patents

Method for the preparation of 2-alkyl indanes

Info

Publication number
ES451697A1
ES451697A1 ES451697A ES451697A ES451697A1 ES 451697 A1 ES451697 A1 ES 451697A1 ES 451697 A ES451697 A ES 451697A ES 451697 A ES451697 A ES 451697A ES 451697 A1 ES451697 A1 ES 451697A1
Authority
ES
Spain
Prior art keywords
formula
obtaining
same meaning
view
see formula
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES451697A
Other languages
Spanish (es)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hexachimie SA
Original Assignee
Hexachimie SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hexachimie SA filed Critical Hexachimie SA
Publication of ES451697A1 publication Critical patent/ES451697A1/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/76Ketones containing a keto group bound to a six-membered aromatic ring
    • C07C49/82Ketones containing a keto group bound to a six-membered aromatic ring containing hydroxy groups
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/22Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by reduction
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C07C13/28Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
    • C07C13/32Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
    • C07C13/45Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with a bicyclo ring system containing nine carbon atoms
    • C07C13/465Indenes; Completely or partially hydrogenated indenes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/65Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by splitting-off hydrogen atoms or functional groups; by hydrogenolysis of functional groups
    • C07C45/66Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by splitting-off hydrogen atoms or functional groups; by hydrogenolysis of functional groups by dehydration
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/72Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups
    • C07C45/75Reactions with formaldehyde
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00Systems containing two condensed rings
    • C07C2602/02Systems containing two condensed rings the rings having only two atoms in common
    • C07C2602/04One of the condensed rings being a six-membered aromatic ring
    • C07C2602/08One of the condensed rings being a six-membered aromatic ring the other ring being five-membered, e.g. indane

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Preparation process for 2-alkylindane of formula (IV) ** (See formula) ** wherein R represents a group selected from the linear or branched C1-C5 lower alkyl group and the C3-C7 cycloalkyl group, characterized in that: a) An aromatic ring of formula (I) is condensed: ** (See formula) ** wherein R has the same meaning as above with formaldehyde or a formaldehyde precursor in basic medium and in a polar organic solvent, with a view to obtaining a ketol of formula (II) ** (See formula) ** where R has the same meaning as above, b) the mentioned ketol of formula (I) is cyclized in a strong acid medium with a view to obtaining indanone of formula (III): ** (See formula) ** where R has the same meaning as above, c) the mentioned indanone is reduced with a view to obtaining the desired 2-alkylindane. (Machine-translation by Google Translate, not legally binding)
ES451697A 1975-09-26 1976-09-20 Method for the preparation of 2-alkyl indanes Expired ES451697A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7529658A FR2325625A1 (en) 1975-09-26 1975-09-26 PROCESS FOR PREPARING 2-ALKYL INDANE

Publications (1)

Publication Number Publication Date
ES451697A1 true ES451697A1 (en) 1977-08-16

Family

ID=9160530

Family Applications (1)

Application Number Title Priority Date Filing Date
ES451697A Expired ES451697A1 (en) 1975-09-26 1976-09-20 Method for the preparation of 2-alkyl indanes

Country Status (22)

Country Link
JP (1) JPS5257157A (en)
AR (1) AR210162A1 (en)
AT (1) AT346322B (en)
AU (1) AU497933B2 (en)
BE (1) BE846528A (en)
CA (1) CA1062286A (en)
CH (1) CH595302A5 (en)
CS (1) CS204996B2 (en)
DD (1) DD126332A5 (en)
DE (1) DE2643074A1 (en)
DK (1) DK424676A (en)
ES (1) ES451697A1 (en)
FR (1) FR2325625A1 (en)
GB (1) GB1500229A (en)
GR (1) GR58459B (en)
HU (1) HU172481B (en)
NL (1) NL7610336A (en)
NO (1) NO143703C (en)
PT (1) PT65587B (en)
SE (1) SE417086B (en)
SU (1) SU615847A3 (en)
ZA (1) ZA765536B (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5975133U (en) * 1982-11-12 1984-05-22 金鹿「こて」工業株式会社 power wire brush
FR2784986A1 (en) * 1998-10-26 2000-04-28 Rhodia Chimie Sa Preparation of indanone and thioindanone phytosanitary agents by cyclizing substituted aromatic compound in fluorinated organic sulfonic acid
FR2788764B1 (en) * 1999-01-25 2001-03-02 Rhodia Chimie Sa PROCESS FOR THE PREPARATION OF AN INDANONE OR THIOINDANONE COMPOUND
RU2768714C2 (en) * 2020-05-22 2022-03-24 Федеральное государственное бюджетное образовательное учреждение высшего образования "Санкт-Петербургский государственный лесотехнический университет имени С.М. Кирова" Method for synthesis of 3-arylindan-1-ones by reaction of super-electrophilic aromatic substitution of cinnamic nitriles

Also Published As

Publication number Publication date
SE7610637L (en) 1977-03-27
NL7610336A (en) 1977-03-29
AU497933B2 (en) 1979-01-25
NO143703B (en) 1980-12-22
ATA707376A (en) 1978-03-15
ZA765536B (en) 1977-08-31
JPS5257157A (en) 1977-05-11
BE846528A (en) 1977-01-17
CA1062286A (en) 1979-09-11
AU1787976A (en) 1978-03-23
DE2643074A1 (en) 1977-04-07
AR210162A1 (en) 1977-06-30
FR2325625B1 (en) 1980-08-01
JPS543870B2 (en) 1979-02-27
AT346322B (en) 1978-11-10
SE417086B (en) 1981-02-23
HU172481B (en) 1978-09-28
DD126332A5 (en) 1977-07-13
CS204996B2 (en) 1981-04-30
FR2325625A1 (en) 1977-04-22
NO763272L (en) 1977-03-29
PT65587A (en) 1976-10-01
GR58459B (en) 1977-10-12
PT65587B (en) 1978-03-28
GB1500229A (en) 1978-02-08
DK424676A (en) 1977-03-27
CH595302A5 (en) 1978-02-15
SU615847A3 (en) 1978-07-15
NO143703C (en) 1981-04-08

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