ES347769A1 - Black oil conversion and desulfurization process - Google Patents
Black oil conversion and desulfurization processInfo
- Publication number
- ES347769A1 ES347769A1 ES347769A ES347769A ES347769A1 ES 347769 A1 ES347769 A1 ES 347769A1 ES 347769 A ES347769 A ES 347769A ES 347769 A ES347769 A ES 347769A ES 347769 A1 ES347769 A1 ES 347769A1
- Authority
- ES
- Spain
- Prior art keywords
- fraction
- vapour stream
- separating
- range
- conversion zone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000006243 chemical reaction Methods 0.000 title abstract 7
- 238000000034 method Methods 0.000 title abstract 2
- 238000006477 desulfuration reaction Methods 0.000 title 1
- 230000023556 desulfurization Effects 0.000 title 1
- 239000000203 mixture Substances 0.000 abstract 5
- 238000000926 separation method Methods 0.000 abstract 4
- 229930195733 hydrocarbon Natural products 0.000 abstract 3
- 150000002430 hydrocarbons Chemical class 0.000 abstract 3
- 239000007788 liquid Substances 0.000 abstract 3
- 239000004215 Carbon black (E152) Substances 0.000 abstract 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 abstract 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 2
- 239000005864 Sulphur Substances 0.000 abstract 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 abstract 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 2
- 238000009835 boiling Methods 0.000 abstract 2
- 230000003197 catalytic effect Effects 0.000 abstract 2
- 239000002131 composite material Substances 0.000 abstract 2
- 238000010438 heat treatment Methods 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 abstract 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 abstract 1
- 241000588731 Hafnia Species 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 abstract 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 abstract 1
- -1 boria Chemical compound 0.000 abstract 1
- YZYDPPZYDIRSJT-UHFFFAOYSA-K boron phosphate Chemical compound [B+3].[O-]P([O-])([O-])=O YZYDPPZYDIRSJT-UHFFFAOYSA-K 0.000 abstract 1
- 229910000149 boron phosphate Inorganic materials 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 239000011651 chromium Substances 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- CJNBYAVZURUTKZ-UHFFFAOYSA-N hafnium(IV) oxide Inorganic materials O=[Hf]=O CJNBYAVZURUTKZ-UHFFFAOYSA-N 0.000 abstract 1
- 150000002431 hydrogen Chemical class 0.000 abstract 1
- 229910052741 iridium Inorganic materials 0.000 abstract 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 239000000395 magnesium oxide Substances 0.000 abstract 1
- 229910052750 molybdenum Inorganic materials 0.000 abstract 1
- 239000011733 molybdenum Substances 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- 229910052762 osmium Inorganic materials 0.000 abstract 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 abstract 1
- 229910052763 palladium Inorganic materials 0.000 abstract 1
- 229910052697 platinum Inorganic materials 0.000 abstract 1
- 229910052703 rhodium Inorganic materials 0.000 abstract 1
- 239000010948 rhodium Substances 0.000 abstract 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 abstract 1
- 229910052707 ruthenium Inorganic materials 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 239000007858 starting material Substances 0.000 abstract 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 abstract 1
- 229910052721 tungsten Inorganic materials 0.000 abstract 1
- 239000010937 tungsten Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
- C10G49/22—Separation of effluents
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
Abstract
A process for the conversion of a hydrocarbon charge stock, of which at least 10% by volume boils above 1050 F., and which contains at least 1À0% by weight sulphur, to a product of which a substantial portion boils below 700 F., and which contains less than 1À0% by weight sulphur, comprises (a) separating said charge stock in a first separation zone to provide a light fraction having an end boiling point within a range of from 650 F. to 850 F., and a heavy fraction having an initial boiling point above 650 F. (b) admixing said heavy fraction with hydrogen, and heating the resulting mixture to a temperature above 700 F. (c) contacting the resulting heating mixture with a catalytic composite in a first conversion zone maintained at a pressure greater than 68 atmospheres gauge (d) separating the resulting conversion zone effluent, in a second separation zone at substantially the same pressure as that of the first conversion zone, and at a temperature above 700 F., to provide a first vapour stream and a first liquid stream (e) further separating at least a portion of said first liquid stream, in a third separation zone at a pressure in a range of from sub-atmospheric to 6À8 atmospheres gauge, and at a temperature within a range of 550 F. to 900 F. to provide a residuum fraction and a second vapour stream (f) combining said second vapour stream, said first vapour stream, and said light fraction, and contacting the resulting mixture with a catalytic composite in a second conversion zone at conditions selected to convert sulphurous compounds into hydrogen sulphide and hydrocarbons and (g) separating the second conversion zone effluent, in a fourth separation zone at a temperature within the range of from 60 F. to 130 F. to provide a hydrogen-rich third vapour stream, and a normally liquid hydrocarbon product. The starting material may be a tar sands crude, a topped or reduced crude, an atmospheric bottoms fraction or a vacuum residuum. The catalyst in both zones may comprise molybdenum, tungsten, chromium. iron, cobalt, nickel, platinum, palladium, osmium, iridium, ruthenium or rhodium or mixtures on alumina, silica, boria, magnesia, zirconia, titania, strontia, or hafnia or mixtures (including silica-alumina boron phosphate).
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US597935A US3364134A (en) | 1966-11-30 | 1966-11-30 | Black oil conversion and desulfurization process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES347769A1 true ES347769A1 (en) | 1969-02-16 |
Family
ID=24393546
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES347769A Expired ES347769A1 (en) | 1966-11-30 | 1967-11-29 | Black oil conversion and desulfurization process |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US3364134A (en) |
| JP (1) | JPS503323B1 (en) |
| AT (1) | AT276601B (en) |
| BE (1) | BE707236A (en) |
| CH (1) | CH519017A (en) |
| DE (1) | DE1645826B1 (en) |
| ES (1) | ES347769A1 (en) |
| GB (1) | GB1196017A (en) |
| GR (1) | GR37030B (en) |
| NL (1) | NL153597B (en) |
| OA (1) | OA02543A (en) |
| SE (1) | SE342828B (en) |
| YU (1) | YU33884B (en) |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3480540A (en) * | 1967-03-16 | 1969-11-25 | Exxon Research Engineering Co | Process for hydrofining bitumen derived from tar sands |
| US3445377A (en) * | 1967-09-26 | 1969-05-20 | Universal Oil Prod Co | Desulfurization and conversion of black oils to maximize gasoline production |
| US4159935A (en) * | 1978-08-30 | 1979-07-03 | Uop Inc. | Conversion of hydrocarbonaceous black oils |
| US4159937A (en) * | 1978-08-30 | 1979-07-03 | Uop Inc. | Mixed-phase reaction product effluent separation process |
| US4695369A (en) * | 1986-08-11 | 1987-09-22 | Air Products And Chemicals, Inc. | Catalytic hydroconversion of heavy oil using two metal catalyst |
| GB8629477D0 (en) * | 1986-12-10 | 1987-01-21 | Shell Int Research | Manufacture of kerosene/gas oils |
| US5536391A (en) * | 1995-01-17 | 1996-07-16 | Howley; Paul A. | Production of clean distillate fuels from heavy cycle oils |
| US5958218A (en) * | 1996-01-22 | 1999-09-28 | The M. W. Kellogg Company | Two-stage hydroprocessing reaction scheme with series recycle gas flow |
| US6224747B1 (en) | 1998-03-14 | 2001-05-01 | Chevron U.S.A. Inc. | Hydrocracking and hydrotreating |
| US6096190A (en) * | 1998-03-14 | 2000-08-01 | Chevron U.S.A. Inc. | Hydrocracking/hydrotreating process without intermediate product removal |
| DK1064343T3 (en) * | 1998-03-14 | 2004-06-21 | Chevron Usa Inc | Integrated Hydroforming Process with Hydrogen Counterflow |
| US6200462B1 (en) | 1998-04-28 | 2001-03-13 | Chevron U.S.A. Inc. | Process for reverse gas flow in hydroprocessing reactor systems |
| EP1342774A1 (en) * | 2002-03-06 | 2003-09-10 | ExxonMobil Chemical Patents Inc. | A process for the production of hydrocarbon fluids |
| CA2478195C (en) * | 2002-03-06 | 2011-08-30 | Exxonmobil Chemical Patents Inc. | Improved hydrocarbon fluids |
| US9284494B2 (en) * | 2008-11-15 | 2016-03-15 | Uop Llc | Solids management in slurry hydroprocessing |
| US10435339B2 (en) * | 2017-05-12 | 2019-10-08 | Marathon Petroleum Company Lp | FCC feed additive for propylene/butylene maximization |
| US10696906B2 (en) | 2017-09-29 | 2020-06-30 | Marathon Petroleum Company Lp | Tower bottoms coke catching device |
| US12000720B2 (en) | 2018-09-10 | 2024-06-04 | Marathon Petroleum Company Lp | Product inventory monitoring |
| US12031676B2 (en) | 2019-03-25 | 2024-07-09 | Marathon Petroleum Company Lp | Insulation securement system and associated methods |
| US11975316B2 (en) | 2019-05-09 | 2024-05-07 | Marathon Petroleum Company Lp | Methods and reforming systems for re-dispersing platinum on reforming catalyst |
| US11124714B2 (en) | 2020-02-19 | 2021-09-21 | Marathon Petroleum Company Lp | Low sulfur fuel oil blends for stability enhancement and associated methods |
| US11898109B2 (en) | 2021-02-25 | 2024-02-13 | Marathon Petroleum Company Lp | Assemblies and methods for enhancing control of hydrotreating and fluid catalytic cracking (FCC) processes using spectroscopic analyzers |
| US11905468B2 (en) | 2021-02-25 | 2024-02-20 | Marathon Petroleum Company Lp | Assemblies and methods for enhancing control of fluid catalytic cracking (FCC) processes using spectroscopic analyzers |
| US11702600B2 (en) | 2021-02-25 | 2023-07-18 | Marathon Petroleum Company Lp | Assemblies and methods for enhancing fluid catalytic cracking (FCC) processes during the FCC process using spectroscopic analyzers |
| US20220268694A1 (en) | 2021-02-25 | 2022-08-25 | Marathon Petroleum Company Lp | Methods and assemblies for determining and using standardized spectral responses for calibration of spectroscopic analyzers |
| US11692141B2 (en) | 2021-10-10 | 2023-07-04 | Marathon Petroleum Company Lp | Methods and systems for enhancing processing of hydrocarbons in a fluid catalytic cracking unit using a renewable additive |
| US11802257B2 (en) | 2022-01-31 | 2023-10-31 | Marathon Petroleum Company Lp | Systems and methods for reducing rendered fats pour point |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3118830A (en) * | 1961-03-08 | 1964-01-21 | Texaco Inc | Hydroconversion of hydrocarbons |
| DE1186573B (en) * | 1962-03-31 | 1965-02-04 | Universal Oil Prod Co | Process for converting gasoline-free heavy hydrocarbon oil feed |
| US3260663A (en) * | 1963-07-15 | 1966-07-12 | Union Oil Co | Multi-stage hydrocracking process |
| US3240694A (en) * | 1963-11-26 | 1966-03-15 | Chevron Res | Multi-zone hydrocaracking process |
-
1966
- 1966-11-30 US US597935A patent/US3364134A/en not_active Expired - Lifetime
-
1967
- 1967-11-27 GR GR670137030A patent/GR37030B/en unknown
- 1967-11-28 GB GB54023/67A patent/GB1196017A/en not_active Expired
- 1967-11-28 AT AT1074967A patent/AT276601B/en active
- 1967-11-28 YU YU2348/67A patent/YU33884B/en unknown
- 1967-11-29 OA OA53112A patent/OA02543A/en unknown
- 1967-11-29 SE SE16427/67A patent/SE342828B/xx unknown
- 1967-11-29 ES ES347769A patent/ES347769A1/en not_active Expired
- 1967-11-29 BE BE707236D patent/BE707236A/xx not_active IP Right Cessation
- 1967-11-30 JP JP42076685A patent/JPS503323B1/ja active Pending
- 1967-11-30 NL NL676716296A patent/NL153597B/en not_active IP Right Cessation
- 1967-11-30 DE DE19671645826 patent/DE1645826B1/en not_active Withdrawn
- 1967-11-30 CH CH1684867A patent/CH519017A/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| GR37030B (en) | 1969-04-08 |
| NL153597B (en) | 1977-06-15 |
| YU234867A (en) | 1977-12-31 |
| GB1196017A (en) | 1970-06-24 |
| YU33884B (en) | 1978-06-30 |
| DE1645826B1 (en) | 1972-03-16 |
| AT276601B (en) | 1969-11-25 |
| US3364134A (en) | 1968-01-16 |
| SE342828B (en) | 1972-02-21 |
| BE707236A (en) | 1968-04-01 |
| CH519017A (en) | 1972-02-15 |
| OA02543A (en) | 1970-05-05 |
| JPS503323B1 (en) | 1975-02-03 |
| NL6716296A (en) | 1968-05-31 |
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