ES347426A1 - Process for the Manufacture of vinyl Acetate - Google Patents
Process for the Manufacture of vinyl AcetateInfo
- Publication number
- ES347426A1 ES347426A1 ES347426A ES347426A ES347426A1 ES 347426 A1 ES347426 A1 ES 347426A1 ES 347426 A ES347426 A ES 347426A ES 347426 A ES347426 A ES 347426A ES 347426 A1 ES347426 A1 ES 347426A1
- Authority
- ES
- Spain
- Prior art keywords
- carbon dioxide
- gas
- reaction
- vinyl acetate
- unreacted
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/48—Silver or gold
- B01J23/52—Gold
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
- C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
- C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Vinyl acetate is prepared by reacting ethylene, acetic acid and molecular oxygen in the gas phase, at temperatures between 120 and 250 C., under a pressure of between 1 and 10 atmospheres absolute, in the presence of a carrier catalyst containing metallic palladium and metallic gold, and in which the reaction is carried out continuously in the presence of a cycle gas containing 5 to 60% by volume carbon dioxide. The vinyl acetate, water, and unreacted acetic acid are then liberated and isolated in the vapour form by a process which comprises condensing the said compounds under pressure, continuously recycling, as a cycle gas to the reaction zone, the residual reaction gas formed substantially of unreacted ethylene, unreacted oxygen and carbon dioxide, allowing the carbon dioxide content of the cycle gas, which increases during each passage through the reaction zone, to increase to a predetermined value between 5 and 60% by volume, and continuously freeing the reaction gas and/or residual reaction gas from carbon dioxide in excess of that predetermined value.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEK60768A DE1277249B (en) | 1966-11-23 | 1966-11-23 | Process for the production of vinyl acetate |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES347426A1 true ES347426A1 (en) | 1969-01-16 |
Family
ID=7229752
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES347426A Expired ES347426A1 (en) | 1966-11-23 | 1967-11-21 | Process for the Manufacture of vinyl Acetate |
Country Status (15)
| Country | Link |
|---|---|
| JP (1) | JPS5245690B1 (en) |
| AT (1) | AT272293B (en) |
| BE (1) | BE706919A (en) |
| BR (1) | BR6794939D0 (en) |
| CH (1) | CH502296A (en) |
| DE (1) | DE1277249B (en) |
| DK (1) | DK122224B (en) |
| ES (1) | ES347426A1 (en) |
| FR (1) | FR1554792A (en) |
| GB (1) | GB1163850A (en) |
| LU (1) | LU54893A1 (en) |
| NL (1) | NL164018C (en) |
| NO (1) | NO119740B (en) |
| SE (1) | SE341179B (en) |
| YU (1) | YU32281B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS53139994U (en) * | 1977-04-12 | 1978-11-06 | ||
| DE2811115A1 (en) * | 1978-03-15 | 1979-09-27 | Hoechst Ag | CARRIER CATALYST FOR THE PRODUCTION OF VINYL ACETATE FROM ETHYLENE, ACETIC ACID AND OXYGEN IN THE GAS PHASE |
| DE102007047430A1 (en) * | 2007-10-04 | 2009-04-09 | Evonik Degussa Gmbh | catalyst |
| DE102014223246A1 (en) * | 2014-11-14 | 2016-05-19 | Wacker Chemie Ag | Process for the preparation of vinyl acetate |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE246766C (en) * | ||||
| BE638489A (en) * | 1962-10-11 |
-
1966
- 1966-11-23 DE DEK60768A patent/DE1277249B/en active Pending
-
1967
- 1967-11-16 LU LU54893D patent/LU54893A1/xx unknown
- 1967-11-17 CH CH1535667A patent/CH502296A/en not_active IP Right Cessation
- 1967-11-21 SE SE1598867A patent/SE341179B/xx unknown
- 1967-11-21 AT AT1048567A patent/AT272293B/en active
- 1967-11-21 DK DK582267A patent/DK122224B/en unknown
- 1967-11-21 ES ES347426A patent/ES347426A1/en not_active Expired
- 1967-11-21 YU YU227067A patent/YU32281B/en unknown
- 1967-11-22 NL NL6715862A patent/NL164018C/en not_active IP Right Cessation
- 1967-11-22 NO NO17063767A patent/NO119740B/no unknown
- 1967-11-22 BE BE706919D patent/BE706919A/xx unknown
- 1967-11-23 GB GB5333967A patent/GB1163850A/en not_active Expired
- 1967-11-23 FR FR1554792D patent/FR1554792A/fr not_active Expired
- 1967-11-23 BR BR19493967A patent/BR6794939D0/en unknown
- 1967-11-24 JP JP7521567A patent/JPS5245690B1/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| NL6715862A (en) | 1968-05-24 |
| BE706919A (en) | 1968-05-22 |
| JPS5245690B1 (en) | 1977-11-17 |
| SE341179B (en) | 1971-12-20 |
| NO119740B (en) | 1970-06-29 |
| BR6794939D0 (en) | 1973-04-10 |
| CH502296A (en) | 1971-01-31 |
| NL164018C (en) | 1980-11-17 |
| LU54893A1 (en) | 1968-06-17 |
| GB1163850A (en) | 1969-09-10 |
| DE1277249B (en) | 1968-09-12 |
| FR1554792A (en) | 1969-01-24 |
| YU32281B (en) | 1974-08-31 |
| DK122224B (en) | 1972-02-07 |
| NL164018B (en) | 1980-06-16 |
| AT272293B (en) | 1969-07-10 |
| YU227067A (en) | 1974-02-28 |
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