ES3053761T3 - Hydrogenation of dienals or dienones with rhodium complexes under carbon monoxide free atmosphere - Google Patents

Hydrogenation of dienals or dienones with rhodium complexes under carbon monoxide free atmosphere

Info

Publication number
ES3053761T3
ES3053761T3 ES22718233T ES22718233T ES3053761T3 ES 3053761 T3 ES3053761 T3 ES 3053761T3 ES 22718233 T ES22718233 T ES 22718233T ES 22718233 T ES22718233 T ES 22718233T ES 3053761 T3 ES3053761 T3 ES 3053761T3
Authority
ES
Spain
Prior art keywords
group
optionally substituted
hydrogen atom
represent
formula
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
ES22718233T
Other languages
English (en)
Spanish (es)
Inventor
Lionel Saudan
Julie Quintaine
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Firmenich SA
Original Assignee
Firmenich SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Firmenich SA filed Critical Firmenich SA
Application granted granted Critical
Publication of ES3053761T3 publication Critical patent/ES3053761T3/es
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/20—Unsaturated compounds containing keto groups bound to acyclic carbon atoms
    • C07C49/213—Unsaturated compounds containing keto groups bound to acyclic carbon atoms containing six-membered aromatic rings
    • C07C49/217—Unsaturated compounds containing keto groups bound to acyclic carbon atoms containing six-membered aromatic rings having unsaturation outside the aromatic rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2495—Ligands comprising a phosphine-P atom and one or more further complexing phosphorus atoms covered by groups B01J31/1845 - B01J31/1885, e.g. phosphine/phosphinate or phospholyl/phosphonate ligands
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/62—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by hydrogenation of carbon-to-carbon double or triple bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/20—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms
    • C07C47/228—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms containing six-membered aromatic rings, e.g. phenylacetaldehyde
    • C07C47/232—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms containing six-membered aromatic rings, e.g. phenylacetaldehyde having unsaturation outside the aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/20—Unsaturated compounds containing keto groups bound to acyclic carbon atoms
    • C07C49/203—Unsaturated compounds containing keto groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/20—Unsaturated compounds containing keto groups bound to acyclic carbon atoms
    • C07C49/21—Unsaturated compounds containing keto groups bound to acyclic carbon atoms containing rings other than six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/20—Unsaturated compounds containing keto groups bound to acyclic carbon atoms
    • C07C49/213—Unsaturated compounds containing keto groups bound to acyclic carbon atoms containing six-membered aromatic rings
    • C07C49/217—Unsaturated compounds containing keto groups bound to acyclic carbon atoms containing six-membered aromatic rings having unsaturation outside the aromatic rings
    • C07C49/223—Unsaturated compounds containing keto groups bound to acyclic carbon atoms containing six-membered aromatic rings having unsaturation outside the aromatic rings polycyclic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/643—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of R2C=O or R2C=NR (R= C, H)
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/24—Phosphines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/06—Systems containing only non-condensed rings with a five-membered ring
    • C07C2601/08—Systems containing only non-condensed rings with a five-membered ring the ring being saturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/06—Systems containing only non-condensed rings with a five-membered ring
    • C07C2601/10—Systems containing only non-condensed rings with a five-membered ring the ring being unsaturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
ES22718233T 2021-04-19 2022-04-12 Hydrogenation of dienals or dienones with rhodium complexes under carbon monoxide free atmosphere Active ES3053761T3 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP21169049 2021-04-19
PCT/EP2022/059703 WO2022223363A1 (en) 2021-04-19 2022-04-12 Hydrogenation of dienals or dienones with rhodium complexes under carbon monoxide free atmosphere

Publications (1)

Publication Number Publication Date
ES3053761T3 true ES3053761T3 (en) 2026-01-26

Family

ID=75581418

Family Applications (1)

Application Number Title Priority Date Filing Date
ES22718233T Active ES3053761T3 (en) 2021-04-19 2022-04-12 Hydrogenation of dienals or dienones with rhodium complexes under carbon monoxide free atmosphere

Country Status (6)

Country Link
US (1) US20240208891A1 (enExample)
EP (1) EP4294783B1 (enExample)
JP (1) JP7787907B2 (enExample)
CN (1) CN117157273A (enExample)
ES (1) ES3053761T3 (enExample)
WO (1) WO2022223363A1 (enExample)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN119212972A (zh) * 2022-01-13 2024-12-27 巴斯夫欧洲公司 用于二烯酮的选择性催化氢化的方法
WO2026032797A1 (en) 2024-08-05 2026-02-12 Firmenich Sa Selective hydrogenation of conjugated dienes
CN120132913B (zh) * 2025-05-15 2025-07-15 北京众智创新科技开发有限公司 一种氢甲酰化合成丁醛的催化剂体系及其应用

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2396735A1 (fr) * 1977-07-04 1979-02-02 Rhone Poulenc Ind Procede de preparation de citronellal optiquement actif
DE102004049631A1 (de) * 2004-10-11 2006-04-20 Basf Ag Verfahren zur Herstellung optisch aktiver Carbonylverbindungen
EP2678304B1 (en) * 2011-02-22 2016-04-20 Firmenich SA Hydrogenation of dienals with rhodium complexes under carbon monoxide free atmosphere
DE102013103563A1 (de) * 2013-04-10 2014-10-16 Basf Se Verfahren zur Herstellung von Citronellal
US9573871B2 (en) * 2014-06-12 2017-02-21 The Florida State University Research Foundation, Inc. Stereo controlled synthesis of (E,Z)-dienals via tandem Rh(I) catalyzed propargyl claisen rearrangement
CN109851486B (zh) * 2018-12-20 2022-03-11 万华化学集团股份有限公司 一种钌络合物选择性氢化二烯酮的方法
CN111871429B (zh) * 2020-08-28 2022-07-12 万华化学集团股份有限公司 一种雷尼催化剂及其制备方法，一种α,γ-二烯酮制备γ-烯酮的方法

Also Published As

Publication number Publication date
JP2024515186A (ja) 2024-04-05
WO2022223363A1 (en) 2022-10-27
CN117157273A (zh) 2023-12-01
EP4294783B1 (en) 2025-10-15
US20240208891A1 (en) 2024-06-27
JP7787907B2 (ja) 2025-12-17
EP4294783A1 (en) 2023-12-27

Similar Documents

Publication Publication Date Title
US7763758B2 (en) Hydrogenation of esters with Ru/bidentate ligands complexes
US8692022B2 (en) Hydrogenation of esters with Ru/bidentate ligands complexes
EP4294783B1 (en) Hydrogenation of dienals or dienones with rhodium complexes under carbon monoxide free atmosphere
US7579295B2 (en) Catalytic hydrogenation processes
US8871982B2 (en) Hydrogenation of dienals with rhodium complexes under carbon monoxide free atmosphere
US10138200B2 (en) Process for preparing polyols
JP6483134B2 (ja) Ｆｅ／三座配位子錯体によるエステルの水素化
JPS5826831A (ja) エタノ−ルの製造方法
US20030149267A1 (en) Valeraldehyde and process for its preparation
WO2013099819A1 (ja) バナジウム錯体を用いたファルネサールの製造方法
WO1999042211A1 (en) Oxidation catalyst system and method of oxidation with the same
CN111051314A (zh) 制备双环烯醇醚的方法
JPH07116133B2 (ja) ビタミンａの調製法
US7601667B2 (en) Sulfonate catalyst and method of producing alcohol compound using the same
EP2922813A1 (en) Hydrocarbonylation or methoxycarbonylation of 1,3-diene derivatives with palladium complex
JP2509393B2 (ja) テルペン系ケトン類の製造方法
JP2009280529A (ja) エステル化合物の製造方法
US5245060A (en) Terpene derivatives and process for preparing the same
WO2022072182A1 (en) Processes of preparing ferrocene ligand mixtures suitable for propylene hydroformylation
JPS5879943A (ja) ビタミンｋ↓３の製法
JP3590980B2 (ja) 光学活性３級ホスフィン化合物、それを配位子とする遷移金属錯体およびその用途
JPH05331076A (ja) シクロドデセンの製造方法
JP5382667B2 (ja) 環状化合物の製法
JPS6023355A (ja) ３−フエニル−２−アミノ−２−メチルプロピオン酸アミド類の製造法
PL175950B1 (pl) Sposób wytwarzania 2,3-dipodstawionych cykloalk-2-enonów