ES2954295T3 - Composición detergente libre de fosfatos para lavavajillas automático - Google Patents
Composición detergente libre de fosfatos para lavavajillas automático Download PDFInfo
- Publication number
- ES2954295T3 ES2954295T3 ES18723012T ES18723012T ES2954295T3 ES 2954295 T3 ES2954295 T3 ES 2954295T3 ES 18723012 T ES18723012 T ES 18723012T ES 18723012 T ES18723012 T ES 18723012T ES 2954295 T3 ES2954295 T3 ES 2954295T3
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- Prior art keywords
- weight
- adjuvant
- detergent composition
- citrate
- carbonate
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 128
- 239000003599 detergent Substances 0.000 title claims abstract description 107
- 239000002671 adjuvant Substances 0.000 claims abstract description 88
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims abstract description 44
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims abstract description 42
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 35
- 229920000578 graft copolymer Polymers 0.000 claims abstract description 34
- 150000004676 glycans Chemical class 0.000 claims abstract description 19
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229920001577 copolymer Polymers 0.000 claims abstract description 17
- 238000004061 bleaching Methods 0.000 claims abstract description 14
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229920001282 polysaccharide Polymers 0.000 claims abstract description 11
- 239000005017 polysaccharide Substances 0.000 claims abstract description 11
- RGHNJXZEOKUKBD-SQOUGZDYSA-M D-gluconate Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O RGHNJXZEOKUKBD-SQOUGZDYSA-M 0.000 claims abstract description 10
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims abstract description 10
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- 238000001556 precipitation Methods 0.000 claims abstract description 10
- 229940095064 tartrate Drugs 0.000 claims abstract description 10
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- 239000002253 acid Substances 0.000 claims description 27
- -1 gums Polymers 0.000 claims description 22
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- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 6
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- 230000009919 sequestration Effects 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 6
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 6
- 239000005913 Maltodextrin Substances 0.000 claims description 5
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 5
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- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 5
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- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 4
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical group [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 claims description 4
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 claims description 3
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 claims description 3
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- 235000021317 phosphate Nutrition 0.000 description 8
- 102000035195 Peptidases Human genes 0.000 description 6
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 6
- 125000000129 anionic group Chemical group 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
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- 239000004094 surface-active agent Substances 0.000 description 6
- CIEZZGWIJBXOTE-UHFFFAOYSA-N 2-[bis(carboxymethyl)amino]propanoic acid Chemical compound OC(=O)C(C)N(CC(O)=O)CC(O)=O CIEZZGWIJBXOTE-UHFFFAOYSA-N 0.000 description 5
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- 229940024999 proteolytic enzymes for treatment of wounds and ulcers Drugs 0.000 description 5
- 239000002689 soil Substances 0.000 description 5
- 238000010998 test method Methods 0.000 description 5
- PQHYOGIRXOKOEJ-UHFFFAOYSA-N 2-(1,2-dicarboxyethylamino)butanedioic acid Chemical compound OC(=O)CC(C(O)=O)NC(C(O)=O)CC(O)=O PQHYOGIRXOKOEJ-UHFFFAOYSA-N 0.000 description 4
- XHZPRMZZQOIPDS-UHFFFAOYSA-N 2-Methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid Chemical compound OS(=O)(=O)CC(C)(C)NC(=O)C=C XHZPRMZZQOIPDS-UHFFFAOYSA-N 0.000 description 4
- 229920002245 Dextrose equivalent Polymers 0.000 description 4
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 230000003625 amylolytic effect Effects 0.000 description 4
- 150000007942 carboxylates Chemical class 0.000 description 4
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
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- 230000001590 oxidative effect Effects 0.000 description 4
- 150000002978 peroxides Chemical class 0.000 description 4
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 4
- 229940045872 sodium percarbonate Drugs 0.000 description 4
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 3
- 239000004382 Amylase Substances 0.000 description 3
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- 125000001931 aliphatic group Chemical group 0.000 description 3
- 229910000288 alkali metal carbonate Inorganic materials 0.000 description 3
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- 125000000217 alkyl group Chemical group 0.000 description 3
- 150000003863 ammonium salts Chemical class 0.000 description 3
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- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
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- 239000001509 sodium citrate Substances 0.000 description 3
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 3
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- SZHQPBJEOCHCKM-UHFFFAOYSA-N 2-phosphonobutane-1,2,4-tricarboxylic acid Chemical compound OC(=O)CCC(P(O)(O)=O)(C(O)=O)CC(O)=O SZHQPBJEOCHCKM-UHFFFAOYSA-N 0.000 description 2
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- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 2
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
- C11D1/721—End blocked ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/08—Silicates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3788—Graft polymers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP17170802 | 2017-05-12 | ||
| PCT/EP2018/062286 WO2018206812A1 (en) | 2017-05-12 | 2018-05-14 | Phosphate-free automatic dishwashing detergent composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2954295T3 true ES2954295T3 (es) | 2023-11-21 |
Family
ID=58707383
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES18723012T Active ES2954295T3 (es) | 2017-05-12 | 2018-05-14 | Composición detergente libre de fosfatos para lavavajillas automático |
Country Status (3)
| Country | Link |
|---|---|
| EP (1) | EP3622049B1 (de) |
| ES (1) | ES2954295T3 (de) |
| WO (1) | WO2018206812A1 (de) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9113892B2 (en) | 2013-01-08 | 2015-08-25 | Covidien Lp | Surgical clip applier |
| US20230106979A1 (en) | 2020-02-28 | 2023-04-06 | Conopco Inc., D/B/A Unilever | Dishwash detergent product |
| WO2022243533A1 (en) | 2021-05-20 | 2022-11-24 | Nouryon Chemicals International B.V. | Manufactured polymers having altered oligosaccharide or polysaccharide functionality or narrowed oligosaccharide distribution, processes for preparing them, compositions containing them, and methods of using them |
| WO2022253565A1 (en) * | 2021-06-03 | 2022-12-08 | Unilever Ip Holdings B.V. | Machine dishwash detergent |
| CN120905663B (zh) * | 2025-10-09 | 2026-02-06 | 洛阳强龙实业有限公司 | 一种循环水无磷清洗预膜剂及其制备方法 |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4751015A (en) | 1987-03-17 | 1988-06-14 | Lever Brothers Company | Quaternary ammonium or phosphonium substituted peroxy carbonic acid precursors and their use in detergent bleach compositions |
| US5047163A (en) | 1990-03-16 | 1991-09-10 | Lever Brothers Company, Division Of Conopco, Inc. | Activation of bleach precursors with sulfonimines |
| US5041232A (en) | 1990-03-16 | 1991-08-20 | Lever Brothers Company, Division Of Conopco, Inc. | Sulfonimines as bleach catalysts |
| ES2100925T3 (es) | 1990-05-21 | 1997-07-01 | Unilever Nv | Activacion de blanqueador. |
| US5898025A (en) | 1992-09-25 | 1999-04-27 | Henkel Kommanditgesellschaft Auf Aktien | Mildly alkaline dishwashing detergents |
| DE59405259D1 (de) | 1993-05-08 | 1998-03-19 | Henkel Kgaa | Silberkorrosionsschutzmittel i |
| ES2134944T3 (es) | 1993-05-08 | 1999-10-16 | Henkel Kgaa | Agente anticorrosivo de plata ii. |
| BR9407809A (pt) | 1993-10-14 | 1997-05-06 | Unilever Nv | Composição detergente alvejante processo para lavar um artigo de prata ou revestido de prata e uso de um composto |
| DE19503116A1 (de) | 1995-02-01 | 1996-08-08 | Basf Ag | Verwendung von wasserlöslichen gepfropften Naturstoffen als Additiv für Geschirrspülmittel |
| US20110028371A1 (en) | 2009-07-31 | 2011-02-03 | Akzo Nobel N.V. | Hybrid copolymers |
| US7666963B2 (en) | 2005-07-21 | 2010-02-23 | Akzo Nobel N.V. | Hybrid copolymers |
| NO20073834L (no) | 2006-07-21 | 2008-01-22 | Akzo Nobel Chemicals Int Bv | Sulfonerte podede kopolymerer |
| US7781387B2 (en) | 2008-01-22 | 2010-08-24 | Access Business Group International, Llc. | Automatic phosphate-free dishwashing detergent providing improved spotting and filming performance |
| EP2138560B2 (de) | 2008-06-24 | 2015-04-01 | Cognis IP Management GmbH | Reinigungsmittel enthaltend Pfropfcopolymere |
| DE102008063801A1 (de) | 2008-12-19 | 2010-06-24 | Henkel Ag & Co. Kgaa | Maschinelles Geschirrspülmittel |
| JP5645937B2 (ja) | 2009-07-31 | 2014-12-24 | アクゾ ノーベル ナムローゼ フェンノートシャップＡｋｚｏ Ｎｏｂｅｌ Ｎ．Ｖ． | パーソナルケア用途のためのハイブリッドコポリマー組成物 |
| US8945314B2 (en) | 2012-07-30 | 2015-02-03 | Ecolab Usa Inc. | Biodegradable stability binding agent for a solid detergent |
| DE102014208509A1 (de) | 2014-05-07 | 2015-11-12 | Henkel Ag & Co. Kgaa | Reinigungsmittel |
| JP6628749B2 (ja) | 2014-06-23 | 2020-01-15 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 配合物、その製造及び使用、並びに適した構成成分 |
| RU2687255C2 (ru) | 2014-06-23 | 2019-05-08 | Басф Се | Композиции, их применение в качестве или для получения средств для мытья посуды и их получение |
| ES2962909T3 (es) | 2017-05-12 | 2024-03-21 | Unilever Ip Holdings B V | Composición detergente para lavavajillas automático |
-
2018
- 2018-05-14 EP EP18723012.3A patent/EP3622049B1/de not_active Revoked
- 2018-05-14 WO PCT/EP2018/062286 patent/WO2018206812A1/en not_active Ceased
- 2018-05-14 ES ES18723012T patent/ES2954295T3/es active Active
Also Published As
| Publication number | Publication date |
|---|---|
| WO2018206812A1 (en) | 2018-11-15 |
| EP3622049A1 (de) | 2020-03-18 |
| EP3622049B1 (de) | 2023-08-16 |
| EP3622049C0 (de) | 2023-08-16 |
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