ES2873892T3 - Producción de calentamiento usando fluidos de trabajo que comprenden Z-1,1,1,4,4,4-hexafluoro-2-buteno - Google Patents
Producción de calentamiento usando fluidos de trabajo que comprenden Z-1,1,1,4,4,4-hexafluoro-2-buteno Download PDFInfo
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- ES2873892T3 ES2873892T3 ES19169921T ES19169921T ES2873892T3 ES 2873892 T3 ES2873892 T3 ES 2873892T3 ES 19169921 T ES19169921 T ES 19169921T ES 19169921 T ES19169921 T ES 19169921T ES 2873892 T3 ES2873892 T3 ES 2873892T3
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- working fluid
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- 238000010438 heat treatment Methods 0.000 title claims abstract description 76
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 9
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- 238000012546 transfer Methods 0.000 claims description 53
- LVGUZGTVOIAKKC-UHFFFAOYSA-N 1,1,1,2-tetrafluoroethane Chemical compound FCC(F)(F)F LVGUZGTVOIAKKC-UHFFFAOYSA-N 0.000 claims description 16
- WXGNWUVNYMJENI-UHFFFAOYSA-N 1,1,2,2-tetrafluoroethane Chemical compound FC(F)C(F)F WXGNWUVNYMJENI-UHFFFAOYSA-N 0.000 claims description 14
- RWRIWBAIICGTTQ-UHFFFAOYSA-N difluoromethane Chemical compound FCF RWRIWBAIICGTTQ-UHFFFAOYSA-N 0.000 claims description 12
- 238000006073 displacement reaction Methods 0.000 claims description 10
- FXRLMCRCYDHQFW-UHFFFAOYSA-N 2,3,3,3-tetrafluoropropene Chemical compound FC(=C)C(F)(F)F FXRLMCRCYDHQFW-UHFFFAOYSA-N 0.000 claims description 9
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- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/02—Materials undergoing a change of physical state when used
- C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
- C09K5/041—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems
- C09K5/044—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds
- C09K5/045—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds containing only fluorine as halogen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/02—Materials undergoing a change of physical state when used
- C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
- C09K5/041—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems
- C09K5/044—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/02—Materials undergoing a change of physical state when used
- C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D17/00—Arrangements for circulating cooling fluids; Arrangements for circulating gas, e.g. air, within refrigerated spaces
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/10—Components
- C09K2205/12—Hydrocarbons
- C09K2205/122—Halogenated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/10—Components
- C09K2205/12—Hydrocarbons
- C09K2205/126—Unsaturated fluorinated hydrocarbons
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- Organic Chemistry (AREA)
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- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
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| ES12704976T Active ES2734475T3 (es) | 2011-01-31 | 2012-01-31 | Producción de calentamiento usando fluidos de trabajo que comprenden Z-1,1,1,4,4,4-hexafluoro-2-buteno |
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| ES12704976T Active ES2734475T3 (es) | 2011-01-31 | 2012-01-31 | Producción de calentamiento usando fluidos de trabajo que comprenden Z-1,1,1,4,4,4-hexafluoro-2-buteno |
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| EP (2) | EP2670813B1 (enExample) |
| JP (1) | JP6001561B2 (enExample) |
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| AR (1) | AR085045A1 (enExample) |
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| US8463441B2 (en) | 2002-12-09 | 2013-06-11 | Hudson Technologies, Inc. | Method and apparatus for optimizing refrigeration systems |
| CN103228757B (zh) | 2010-11-25 | 2016-02-17 | 阿克马法国公司 | 氯三氟丙烯和六氟丁烯的组合物 |
| FR2968009B1 (fr) | 2010-11-25 | 2012-11-16 | Arkema France | Fluides frigorigenes contenant du (e)-1,1,1,4,4,4-hexafluorobut-2-ene |
| FR2968310B1 (fr) | 2010-12-03 | 2012-12-07 | Arkema France | Compositions a base de 1,1,1,4,4,4-hexafluorobut-2-ene et de 3,3,4,4,4-pentafluorobut-1-ene |
| FR2977256B1 (fr) | 2011-07-01 | 2013-06-21 | Arkema France | Compositions de 2,4,4,4-tetrafluorobut-1-ene et de cis-1,1,1,4,4,4-hexafluorobut-2-ene |
| FR2989084B1 (fr) | 2012-04-04 | 2015-04-10 | Arkema France | Compositions a base de 2,3,3,4,4,4-hexafluorobut-1-ene |
| JP2016514187A (ja) * | 2013-03-15 | 2016-05-19 | ハネウェル・インターナショナル・インコーポレーテッド | 冷却のための組成物および方法 |
| US9234123B2 (en) * | 2013-03-21 | 2016-01-12 | Hsi Fire & Safety Group, Llc | Compositions for totally non-flammable aerosol dusters |
| DE102013211084A1 (de) * | 2013-06-14 | 2014-12-18 | Siemens Aktiengesellschaft | Verfahren zum Betrieb einer Wärmepumpe und Wärmepumpe |
| KR20210104183A (ko) * | 2014-02-07 | 2021-08-24 | 더 케무어스 컴퍼니 에프씨, 엘엘씨 | Z-1,1,1,4,4,4-헥사플루오로-2-부텐의 생산을 위한 통합 공정 |
| WO2016010634A1 (en) * | 2014-07-18 | 2016-01-21 | The Chemours Company Fc, Llc | Use of 1,1,2,2-tetrafluoroethane in high temperature heat pumps |
| WO2016048613A1 (en) | 2014-09-23 | 2016-03-31 | The Chemours Company Fc, Llc | Use of (2e)-1,1,1,4,5,5,5-heptafluoro-4-(trifluoromethyl)pent-2-ene in high temperature heat pumps |
| ES2923647T3 (es) * | 2015-02-06 | 2022-09-29 | Chemours Co Fc Llc | Composiciones que comprenden Z-1,1,1,4,4,4-hexafluoro-2-buteno y usos del mismo |
| WO2016140187A1 (ja) * | 2015-03-02 | 2016-09-09 | Ｊｘエネルギー株式会社 | 冷凍機油及び冷凍機用作動流体組成物 |
| CN115638555A (zh) * | 2017-06-21 | 2023-01-24 | 霍尼韦尔国际公司 | 制冷系统和方法 |
| CN107328128A (zh) * | 2017-08-18 | 2017-11-07 | 广东高而美制冷设备有限公司 | 一种高温空调热泵系统及其工作方式 |
| AU2019202101A1 (en) | 2018-05-10 | 2019-11-28 | Eavor Technologies Inc | Fluid for use in power production environments |
| CN110964485B (zh) * | 2019-11-18 | 2021-02-05 | 珠海格力电器股份有限公司 | 一种混合制冷剂 |
| WO2023205374A1 (en) * | 2022-04-22 | 2023-10-26 | The Chemours Company Fc, Llc | Compositions comprising tetrafluoropropene and hexafluorobutene |
| US20250066654A1 (en) * | 2023-08-24 | 2025-02-27 | Carbon Ventures, Llc | Sterically hindered hydrofluoroolefins with dipole moment and their blends with sterically hindered-olefins as refrigerants for high temperature heat pumps and working fluid for organic rankine cycles |
| KR102893236B1 (ko) * | 2024-11-20 | 2025-12-03 | 주식회사 귀뚜라미 냉동기계 | 고온용 히트펌프용 R-245fa 및 R-1336mzz(Z)의 대체 혼합냉매 조성물 |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1578933A (en) | 1977-05-24 | 1980-11-12 | Ici Ltd | Manufacture of halogenated hydrocarbons |
| EP0127365A3 (en) * | 1983-05-20 | 1988-03-16 | Imperial Chemical Industries Plc | Heat pumps |
| US6274781B1 (en) | 1993-11-01 | 2001-08-14 | E. I. Du Pont De Nemours And Company | Production of dihalomethanes containing fluorine and azeotropes of dihalomethanes containing chlorine with HF |
| DE10056606A1 (de) | 2000-11-15 | 2002-05-23 | Solvay Fluor & Derivate | Verwendung von Gemischen,die 1,1,1,3,3-Pentafluorbutan enthalten, als Kältemittel oder Wärmerträger |
| US7897823B2 (en) | 2004-10-29 | 2011-03-01 | E. I. Du Pont De Nemours And Company | Process for production of azeotrope compositions comprising hydrofluoroolefin and hydrogen fluoride and uses of said azeotrope compositions in separation processes |
| US20060242985A1 (en) * | 2005-03-04 | 2006-11-02 | Leck Thomas J | Refrigeration/air-conditioning apparatus powered by an engine exhaust gas driven turbine |
| US7708903B2 (en) * | 2005-11-01 | 2010-05-04 | E.I. Du Pont De Nemours And Company | Compositions comprising fluoroolefins and uses thereof |
| FR2894014B1 (fr) * | 2005-11-30 | 2008-02-22 | Gerard Llurens | Unite solaire de production frigorifique pour installation de climatisation et procede de controle correspondant |
| US8618339B2 (en) | 2007-04-26 | 2013-12-31 | E I Du Pont De Nemours And Company | High selectivity process to make dihydrofluoroalkenes |
| CN101668566B (zh) | 2007-04-27 | 2012-03-28 | 纳幕尔杜邦公司 | Z-1,1,1,4,4,4-六氟-2-丁烯的共沸和类共沸组合物 |
| CN101688817A (zh) * | 2007-06-21 | 2010-03-31 | 纳幕尔杜邦公司 | 用于热传递系统的渗漏检测的方法 |
| US20110094259A1 (en) * | 2007-10-10 | 2011-04-28 | Alexander Lifson | Multi-stage refrigerant system with different compressor types |
| TW200930801A (en) * | 2007-10-31 | 2009-07-16 | Du Pont | Compositions comprising iodotrifluoromethane and uses thereof |
| WO2009155490A1 (en) * | 2008-06-20 | 2009-12-23 | E. I. Du Pont De Nemours And Company | Azeotropic and azeotrope-like compositions of z-1,1,1,4,4,4-hexafluoro-2-butene |
| AU2009268701A1 (en) | 2008-07-08 | 2010-01-14 | E. I. Du Pont De Nemours And Company | Compositions comprising ionic liquids and fluoroolefins and use thereof in absorption cycle systems |
| FR2948678B1 (fr) | 2009-07-28 | 2011-10-14 | Arkema France | Procede de transfert de chaleur |
| MX365490B (es) | 2009-09-16 | 2019-06-05 | E I Du Pont De Nemours And Company Star | Composicion que comprende cis-1,1,1,4,4,4-hexafluoro-2-buteno y trans-1,2-dicloroetileno, aparato que los contiene y metodos para producir enfriamiento en ellos. |
| ES2581516T3 (es) * | 2009-09-16 | 2016-09-06 | The Chemours Company Fc, Llc | Aparato enfriador que contiene trans-1,1,1,4,4,4-hexafluoro-2-buteno y procedimientos para producir enfriamiento en él |
| US20110144216A1 (en) * | 2009-12-16 | 2011-06-16 | Honeywell International Inc. | Compositions and uses of cis-1,1,1,4,4,4-hexafluoro-2-butene |
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- 2012-01-31 MY MYPI2013002553A patent/MY168776A/en unknown
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| EP2670813A1 (en) | 2013-12-11 |
| JP6001561B2 (ja) | 2016-10-05 |
| SG192215A1 (en) | 2013-09-30 |
| MX355497B (es) | 2018-04-20 |
| JP2014505228A (ja) | 2014-02-27 |
| AR085045A1 (es) | 2013-08-07 |
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| US20130298581A1 (en) | 2013-11-14 |
| EP2670813B1 (en) | 2019-04-24 |
| AU2012212450A1 (en) | 2013-07-18 |
| MY168776A (en) | 2018-12-04 |
| CN103502380A (zh) | 2014-01-08 |
| BR112013018849B1 (pt) | 2021-01-12 |
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| ES2734475T3 (es) | 2019-12-10 |
| EP3533853A1 (en) | 2019-09-04 |
| EP3533853B1 (en) | 2021-03-10 |
| CN103502380B (zh) | 2016-02-17 |
| MX2013008695A (es) | 2013-08-21 |
| WO2012106305A1 (en) | 2012-08-09 |
| CA2824423A1 (en) | 2012-08-09 |
| CA2824423C (en) | 2017-03-21 |
| TW201233965A (en) | 2012-08-16 |
| BR112013018849A2 (pt) | 2016-09-27 |
| AU2012212450B2 (en) | 2015-12-17 |
| DK3533853T3 (da) | 2021-06-07 |
| KR20140015352A (ko) | 2014-02-06 |
| TWI573971B (zh) | 2017-03-11 |
| AU2012212450A2 (en) | 2013-08-01 |
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