ES2786499T3 - Método de síntesis de partículas asimétricas (partículas de Janus) por electroquímica bipolar - Google Patents
Método de síntesis de partículas asimétricas (partículas de Janus) por electroquímica bipolar Download PDFInfo
- Publication number
- ES2786499T3 ES2786499T3 ES11817348T ES11817348T ES2786499T3 ES 2786499 T3 ES2786499 T3 ES 2786499T3 ES 11817348 T ES11817348 T ES 11817348T ES 11817348 T ES11817348 T ES 11817348T ES 2786499 T3 ES2786499 T3 ES 2786499T3
- Authority
- ES
- Spain
- Prior art keywords
- substrates
- electrically conductive
- electrodes
- electrodeposition
- janus particles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000013283 Janus particle Substances 0.000 title claims abstract description 35
- 239000002245 particle Substances 0.000 title description 19
- 230000005518 electrochemistry Effects 0.000 title description 5
- 238000001308 synthesis method Methods 0.000 title description 2
- 239000000463 material Substances 0.000 claims abstract description 45
- 238000004070 electrodeposition Methods 0.000 claims abstract description 43
- 239000000758 substrate Substances 0.000 claims abstract description 39
- 239000008151 electrolyte solution Substances 0.000 claims abstract description 22
- 230000005684 electric field Effects 0.000 claims abstract description 18
- 239000012429 reaction media Substances 0.000 claims abstract description 6
- 238000002848 electrochemical method Methods 0.000 claims abstract 2
- 238000000034 method Methods 0.000 claims description 45
- 230000015572 biosynthetic process Effects 0.000 claims description 17
- 239000010949 copper Substances 0.000 claims description 16
- 125000006850 spacer group Chemical group 0.000 claims description 16
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 15
- 229910052802 copper Inorganic materials 0.000 claims description 15
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 claims description 12
- 238000003786 synthesis reaction Methods 0.000 claims description 12
- 229910052751 metal Inorganic materials 0.000 claims description 9
- 239000002184 metal Substances 0.000 claims description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- 150000003839 salts Chemical class 0.000 claims description 8
- 239000010931 gold Substances 0.000 claims description 7
- 239000002243 precursor Substances 0.000 claims description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 6
- 239000004020 conductor Substances 0.000 claims description 6
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 6
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 5
- 229910052737 gold Inorganic materials 0.000 claims description 5
- 229910021645 metal ion Inorganic materials 0.000 claims description 5
- 239000000178 monomer Substances 0.000 claims description 5
- 239000004065 semiconductor Substances 0.000 claims description 5
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 claims description 4
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 4
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 claims description 4
- BFXIKLCIZHOAAZ-UHFFFAOYSA-N methyltrimethoxysilane Chemical compound CO[Si](C)(OC)OC BFXIKLCIZHOAAZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 claims description 4
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 229910052759 nickel Inorganic materials 0.000 claims description 3
- 239000003973 paint Substances 0.000 claims description 3
- 229910052697 platinum Inorganic materials 0.000 claims description 3
- 229910052709 silver Inorganic materials 0.000 claims description 3
- 239000004332 silver Substances 0.000 claims description 3
- 229910052725 zinc Inorganic materials 0.000 claims description 3
- 239000011701 zinc Substances 0.000 claims description 3
- JJQZDUKDJDQPMQ-UHFFFAOYSA-N dimethoxy(dimethyl)silane Chemical compound CO[Si](C)(C)OC JJQZDUKDJDQPMQ-UHFFFAOYSA-N 0.000 claims description 2
- 229930192474 thiophene Natural products 0.000 claims description 2
- 230000000155 isotopic effect Effects 0.000 claims 1
- 230000002194 synthesizing effect Effects 0.000 abstract description 2
- 230000008569 process Effects 0.000 description 15
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 11
- 239000011324 bead Substances 0.000 description 11
- 229910052799 carbon Inorganic materials 0.000 description 10
- 239000012528 membrane Substances 0.000 description 10
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 9
- 238000004626 scanning electron microscopy Methods 0.000 description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
- 239000011521 glass Substances 0.000 description 6
- 239000010410 layer Substances 0.000 description 6
- 238000007254 oxidation reaction Methods 0.000 description 6
- 238000010586 diagram Methods 0.000 description 5
- 229910021397 glassy carbon Inorganic materials 0.000 description 5
- 230000003647 oxidation Effects 0.000 description 5
- 229920000128 polypyrrole Polymers 0.000 description 5
- 239000000725 suspension Substances 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000000017 hydrogel Substances 0.000 description 4
- 230000010287 polarization Effects 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- 238000001878 scanning electron micrograph Methods 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 229920001817 Agar Polymers 0.000 description 3
- 241000206672 Gelidium Species 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 235000010419 agar Nutrition 0.000 description 3
- 238000013459 approach Methods 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000499 gel Substances 0.000 description 3
- FDWREHZXQUYJFJ-UHFFFAOYSA-M gold monochloride Chemical compound [Cl-].[Au+] FDWREHZXQUYJFJ-UHFFFAOYSA-M 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000011810 insulating material Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 238000006479 redox reaction Methods 0.000 description 3
- 229920005372 Plexiglas® Polymers 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- UHYPYGJEEGLRJD-UHFFFAOYSA-N cadmium(2+);selenium(2-) Chemical compound [Se-2].[Cd+2] UHYPYGJEEGLRJD-UHFFFAOYSA-N 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 238000007306 functionalization reaction Methods 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- AHADSRNLHOHMQK-UHFFFAOYSA-N methylidenecopper Chemical compound [Cu].[C] AHADSRNLHOHMQK-UHFFFAOYSA-N 0.000 description 2
- 239000002105 nanoparticle Substances 0.000 description 2
- 239000002071 nanotube Substances 0.000 description 2
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 101710134784 Agnoprotein Proteins 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 238000005251 capillar electrophoresis Methods 0.000 description 1
- 150000001721 carbon Chemical class 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000002800 charge carrier Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 238000013213 extrapolation Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 238000000879 optical micrograph Methods 0.000 description 1
- 238000000399 optical microscopy Methods 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000003071 parasitic effect Effects 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 150000003057 platinum Chemical class 0.000 description 1
- CLSUSRZJUQMOHH-UHFFFAOYSA-L platinum dichloride Chemical compound Cl[Pt]Cl CLSUSRZJUQMOHH-UHFFFAOYSA-L 0.000 description 1
- 229920000767 polyaniline Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920000123 polythiophene Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 229910001961 silver nitrate Inorganic materials 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 229940071240 tetrachloroaurate Drugs 0.000 description 1
- 230000001225 therapeutic effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D13/00—Electrophoretic coating characterised by the process
- C25D13/12—Electrophoretic coating characterised by the process characterised by the article coated
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/04—Making microcapsules or microballoons by physical processes, e.g. drying, spraying
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/02—Electroplating of selected surface areas
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2991—Coated
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Engineering & Computer Science (AREA)
- Dispersion Chemistry (AREA)
- Electrolytic Production Of Metals (AREA)
- Electroplating Methods And Accessories (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Carbon And Carbon Compounds (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1061031A FR2969508B1 (fr) | 2010-12-22 | 2010-12-22 | Particules dissymetriques (particules de janus) et leur procede de synthese par electrochimie bipolaire. |
| PCT/FR2011/053001 WO2012085399A1 (fr) | 2010-12-22 | 2011-12-15 | Particules dissymetriques (particules de janus) et leur procede de synthese par electrochimie bipolaire |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2786499T3 true ES2786499T3 (es) | 2020-10-13 |
Family
ID=44351666
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES11817348T Active ES2786499T3 (es) | 2010-12-22 | 2011-12-15 | Método de síntesis de partículas asimétricas (partículas de Janus) por electroquímica bipolar |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US20140030527A1 (enExample) |
| EP (1) | EP2663394B1 (enExample) |
| JP (1) | JP6063390B2 (enExample) |
| CA (1) | CA2822779C (enExample) |
| ES (1) | ES2786499T3 (enExample) |
| FR (1) | FR2969508B1 (enExample) |
| WO (1) | WO2012085399A1 (enExample) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2969508B1 (fr) | 2010-12-22 | 2015-11-13 | Univ Bordeaux 1 | Particules dissymetriques (particules de janus) et leur procede de synthese par electrochimie bipolaire. |
| CN103611945A (zh) * | 2013-12-04 | 2014-03-05 | 桂林理工大学 | 利用液/液界面反应一步制备双亲性Janus金纳米粒子的方法 |
| CN103846067B (zh) * | 2014-03-19 | 2016-04-20 | 中国科学技术大学 | 一种粒径和形貌均可控的磁性异性Janus微球及其制备方法和所用的微流体控制装置 |
| CN103846068B (zh) * | 2014-03-19 | 2016-04-20 | 中国科学技术大学 | 一种粒径和形貌可控的单分散极性异性Janus微球及其制备方法和所用的微流体控制装置 |
| CN103920434B (zh) * | 2014-04-21 | 2015-11-18 | 中国科学技术大学 | 一种粒径与形貌可控的具有电荷与光学异性特征的炭黑/聚四氟乙烯Janus微球及其制备方法 |
| CN105420761B (zh) * | 2015-11-05 | 2017-05-03 | 上海应用技术学院 | 一种在氧化铝模板上自还原制备多种金属Janus颗粒的方法 |
| CN105414541B (zh) * | 2015-11-26 | 2017-07-28 | 哈尔滨工业大学 | 一种双金属Janus结构纳米粒子的制备方法 |
| WO2018014052A1 (en) * | 2016-07-11 | 2018-01-18 | Csir | Composite activated carbon and conductive polymer adsorption media |
| CN108530582B (zh) * | 2017-03-03 | 2019-08-09 | 中国科学院化学研究所 | 多组分的Janus复合纳米材料及其制备方法 |
| US10221288B1 (en) | 2017-08-08 | 2019-03-05 | International Business Machines Corporation | Matrix bonding abrasion resistant CNTs (MBARCs) and employing same in fiber reinforced polymer composites |
| US10670964B2 (en) | 2017-11-21 | 2020-06-02 | International Business Machines Corporation | Ruggedized solder mask material |
| CN107987279A (zh) * | 2017-11-29 | 2018-05-04 | 湘潭大学 | 利用离子液体双极性电化学合成花瓣状金属有机框架物ZIF-8的Janus微球的方法 |
| CN108822302B (zh) * | 2018-06-20 | 2020-08-14 | 同济大学 | 一种Janus纳米颗粒及其制备方法与应用 |
| CN112805083B (zh) * | 2018-08-02 | 2024-01-05 | 南洋理工大学 | 通过两相界面组装的janus颗粒制备 |
| CN110449150B (zh) * | 2019-07-04 | 2020-11-06 | 中山大学 | 一种内嵌纳米金属的中空炭管阵列催化剂及其制备方法和应用 |
| CN110508224B (zh) * | 2019-08-16 | 2021-09-24 | 中科广化（重庆）新材料研究院有限公司 | 一种无机半导体/共轭聚合物Janus微球及其制备方法 |
| CN111663167A (zh) * | 2020-06-16 | 2020-09-15 | 合肥工业大学 | 一种基于bpe技术的金属线制备方法 |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5819752B2 (ja) * | 1974-03-30 | 1983-04-19 | カガクギジユツチヨウ キンゾクザイリヨウギジユツケンキユウシヨチヨウ | ドウデンカイホウ |
| US4699700A (en) * | 1986-05-19 | 1987-10-13 | Delphi Research, Inc. | Method for hydrogen production and metal winning, and a catalyst/cocatalyst composition useful therefor |
| US6214210B1 (en) * | 1994-11-08 | 2001-04-10 | Rockwell Technologies, Llc | Electrochemical surface analysis using deoxygenated gel electrolyte |
| AU3201699A (en) * | 1998-03-24 | 1999-10-18 | Drexel University | Process of making bipolar electrodeposited catalysts and catalysts so made |
| US6080282A (en) * | 1998-04-22 | 2000-06-27 | Mitsubishi Chemical Corporation | Electrolytic solution for use as gel electrolyte and process for making the same |
| JP2002069689A (ja) * | 2000-08-28 | 2002-03-08 | Yuken Industry Co Ltd | 粉末の電気めっき方法 |
| FR2846572B1 (fr) * | 2002-11-05 | 2004-12-31 | Centre Nat Rech Scient | Particules dissymetriques de taille nanometrique ou mesoscopique, et leur procede de preparation |
| WO2005042810A2 (en) * | 2003-10-31 | 2005-05-12 | E.I Du Pont De Nemours And Company | Membrane -mediated electropolishing |
| GB0408805D0 (en) * | 2004-04-08 | 2004-05-26 | Accentus Plc | Precious metal recovery |
| US20080213593A1 (en) * | 2005-01-21 | 2008-09-04 | President And Fellows Of Harvard College | Systems And Methods For Forming Fluidic Droplets Encapsulated In Particles Such As Colloidal Particles |
| DK2227322T3 (da) * | 2007-12-13 | 2012-05-14 | Sven Oscarsson | Partiel derivatisering af partikler |
| US8906218B2 (en) * | 2010-05-05 | 2014-12-09 | Solexel, Inc. | Apparatus and methods for uniformly forming porous semiconductor on a substrate |
| TWI523976B (zh) * | 2010-05-19 | 2016-03-01 | 諾菲勒斯系統公司 | 利用具有雙態抑制劑的電解液之矽穿孔填充 |
| FR2969508B1 (fr) | 2010-12-22 | 2015-11-13 | Univ Bordeaux 1 | Particules dissymetriques (particules de janus) et leur procede de synthese par electrochimie bipolaire. |
-
2010
- 2010-12-22 FR FR1061031A patent/FR2969508B1/fr not_active Expired - Fee Related
-
2011
- 2011-12-15 JP JP2013545463A patent/JP6063390B2/ja not_active Expired - Fee Related
- 2011-12-15 ES ES11817348T patent/ES2786499T3/es active Active
- 2011-12-15 US US13/996,783 patent/US20140030527A1/en not_active Abandoned
- 2011-12-15 CA CA2822779A patent/CA2822779C/fr active Active
- 2011-12-15 EP EP11817348.3A patent/EP2663394B1/fr active Active
- 2011-12-15 WO PCT/FR2011/053001 patent/WO2012085399A1/fr not_active Ceased
-
2016
- 2016-09-16 US US15/267,538 patent/US10745821B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CA2822779A1 (fr) | 2012-06-28 |
| US20140030527A1 (en) | 2014-01-30 |
| JP2014508215A (ja) | 2014-04-03 |
| FR2969508B1 (fr) | 2015-11-13 |
| FR2969508A1 (fr) | 2012-06-29 |
| EP2663394B1 (fr) | 2020-02-05 |
| JP6063390B2 (ja) | 2017-01-18 |
| CA2822779C (fr) | 2020-06-30 |
| WO2012085399A1 (fr) | 2012-06-28 |
| US20170130356A1 (en) | 2017-05-11 |
| US10745821B2 (en) | 2020-08-18 |
| EP2663394A1 (fr) | 2013-11-20 |
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