ES2700151T3 - Procedimiento de purificación de nanohilos metálicos - Google Patents
Procedimiento de purificación de nanohilos metálicos Download PDFInfo
- Publication number
- ES2700151T3 ES2700151T3 ES15732049T ES15732049T ES2700151T3 ES 2700151 T3 ES2700151 T3 ES 2700151T3 ES 15732049 T ES15732049 T ES 15732049T ES 15732049 T ES15732049 T ES 15732049T ES 2700151 T3 ES2700151 T3 ES 2700151T3
- Authority
- ES
- Spain
- Prior art keywords
- nanowires
- mpa
- mixture
- particles
- solvent medium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000002070 nanowire Substances 0.000 title claims abstract description 102
- 238000000746 purification Methods 0.000 title description 9
- 239000002904 solvent Substances 0.000 claims abstract description 64
- 239000002245 particle Substances 0.000 claims abstract description 53
- 238000000034 method Methods 0.000 claims abstract description 40
- 239000000203 mixture Substances 0.000 claims abstract description 33
- 238000003786 synthesis reaction Methods 0.000 claims abstract description 26
- 239000006228 supernatant Substances 0.000 claims abstract description 24
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 23
- 229910052751 metal Inorganic materials 0.000 claims abstract description 21
- 239000002184 metal Substances 0.000 claims abstract description 21
- 238000010908 decantation Methods 0.000 claims abstract description 19
- 239000002244 precipitate Substances 0.000 claims abstract description 14
- 239000011541 reaction mixture Substances 0.000 claims abstract description 14
- 239000000725 suspension Substances 0.000 claims abstract description 14
- 239000010954 inorganic particle Substances 0.000 claims abstract description 12
- 239000006185 dispersion Substances 0.000 claims abstract description 7
- 238000001556 precipitation Methods 0.000 claims abstract description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 39
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 33
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 24
- 230000008569 process Effects 0.000 claims description 16
- 239000002042 Silver nanowire Substances 0.000 claims description 15
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 10
- 239000007769 metal material Substances 0.000 claims description 10
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical group CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 9
- 229910052709 silver Inorganic materials 0.000 claims description 9
- 239000004332 silver Substances 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- 125000004432 carbon atom Chemical group C* 0.000 claims description 5
- 229920005862 polyol Polymers 0.000 claims description 5
- 150000003077 polyols Chemical class 0.000 claims description 5
- 238000005406 washing Methods 0.000 claims description 4
- 150000002009 diols Chemical class 0.000 claims description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- 125000004429 atom Chemical group 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 239000010815 organic waste Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 description 9
- 239000002105 nanoparticle Substances 0.000 description 8
- 239000007810 chemical reaction solvent Substances 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 6
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 6
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 6
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 6
- 238000000926 separation method Methods 0.000 description 6
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 6
- 239000004020 conductor Substances 0.000 description 5
- 238000010306 acid treatment Methods 0.000 description 4
- 238000005119 centrifugation Methods 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 239000006227 byproduct Substances 0.000 description 3
- 150000002576 ketones Chemical class 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 229910001961 silver nitrate Inorganic materials 0.000 description 3
- 239000011780 sodium chloride Substances 0.000 description 3
- 239000012780 transparent material Substances 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000004630 atomic force microscopy Methods 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 230000014509 gene expression Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000012798 spherical particle Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 101710134784 Agnoprotein Proteins 0.000 description 1
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- 229910000570 Cupronickel Inorganic materials 0.000 description 1
- 229910000990 Ni alloy Inorganic materials 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000002981 blocking agent Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000001493 electron microscopy Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- 238000001095 inductively coupled plasma mass spectrometry Methods 0.000 description 1
- 238000002354 inductively-coupled plasma atomic emission spectroscopy Methods 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000002159 nanocrystal Substances 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 238000002663 nebulization Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000005693 optoelectronics Effects 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- -1 rods Substances 0.000 description 1
- 238000004626 scanning electron microscopy Methods 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 238000004627 transmission electron microscopy Methods 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F9/00—Making metallic powder or suspensions thereof
- B22F9/16—Making metallic powder or suspensions thereof using chemical processes
- B22F9/18—Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds
- B22F9/24—Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds starting from liquid metal compounds, e.g. solutions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D21/00—Separation of suspended solid particles from liquids by sedimentation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
- B22F1/05—Metallic powder characterised by the size or surface area of the particles
- B22F1/054—Nanosized particles
- B22F1/0545—Dispersions or suspensions of nanosized particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
- B22F1/05—Metallic powder characterised by the size or surface area of the particles
- B22F1/054—Nanosized particles
- B22F1/0547—Nanofibres or nanotubes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Nanotechnology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Composite Materials (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Manufacture Of Metal Powder And Suspensions Thereof (AREA)
- Powder Metallurgy (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1454515A FR3021230B1 (fr) | 2014-05-20 | 2014-05-20 | Procede de purification de nanofils metalliques |
| PCT/IB2015/053672 WO2015177717A1 (fr) | 2014-05-20 | 2015-05-19 | Procede de purification de nanofils metalliques. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2700151T3 true ES2700151T3 (es) | 2019-02-14 |
Family
ID=51225763
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES15732049T Active ES2700151T3 (es) | 2014-05-20 | 2015-05-19 | Procedimiento de purificación de nanohilos metálicos |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US10576546B2 (https=) |
| EP (1) | EP3145661B1 (https=) |
| JP (1) | JP6587192B2 (https=) |
| DK (1) | DK3145661T3 (https=) |
| ES (1) | ES2700151T3 (https=) |
| FR (1) | FR3021230B1 (https=) |
| WO (1) | WO2015177717A1 (https=) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9975178B2 (en) * | 2016-07-15 | 2018-05-22 | Lawrence Livermore National Security, Llc | Cross-phase separation of nanowires and nanoparticles |
| US12263529B2 (en) * | 2019-04-03 | 2025-04-01 | Pine Castle Investments Limited | Conductive nanostructure purification |
| FR3098134B1 (fr) * | 2019-07-02 | 2021-07-02 | Commissariat Energie Atomique | Procédé de purification de nanofils métalliques |
| FR3101806B1 (fr) | 2019-10-09 | 2021-09-17 | Commissariat Energie Atomique | Materiau composite pour impression 3d et procede d’impression 3d |
| FR3114514A1 (fr) | 2020-09-29 | 2022-04-01 | Commissariat A L Energie Atomique Et Aux Energies Alternatives | Utilisation d’aérogel à base de nanofils métalliques en tant que matériau filtrant pour le traitement de l’air, Cartouche à électrodes associée, Système de traitement de l’air associé. |
| CN118106499B (zh) * | 2024-01-09 | 2024-08-09 | 西湖大学 | 一种溶剂排除法将超细金纳米线和颗粒分离的纯化方法 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI543873B (zh) | 2009-08-24 | 2016-08-01 | 坎畢歐科技公司 | 用於改良由金屬奈米結構所製得透明導體之濁度的金屬奈米結構純化 |
| JP2011065944A (ja) * | 2009-09-18 | 2011-03-31 | Fujifilm Corp | 導電膜形成用感光材料、導電性材料、表示素子及び太陽電池 |
| DE102010017706B4 (de) * | 2010-07-02 | 2012-05-24 | Rent-A-Scientist Gmbh | Verfahren zur Herstellung von Silber-Nanodrähten |
| CN103338882B (zh) * | 2010-12-07 | 2017-03-08 | 罗地亚管理公司 | 导电纳米结构体、制备该纳米结构体的方法、包括该纳米结构体的导电聚合物膜以及包括该膜的电子装置 |
| FR2991342B1 (fr) | 2012-06-05 | 2014-07-04 | Commissariat Energie Atomique | Procede d'amelioration des performances electriques et optiques d'un materiau conducteur electrique et transparent a base de nanofils d'argent |
| US10130992B2 (en) * | 2013-12-31 | 2018-11-20 | Rhodia Operations | Processes for making silver nanostructures |
| JP6321566B2 (ja) * | 2014-03-07 | 2018-05-09 | Ｄｏｗａホールディングス株式会社 | 銀ナノワイヤの製造方法並びに銀ナノワイヤおよびそれを用いたインク |
-
2014
- 2014-05-20 FR FR1454515A patent/FR3021230B1/fr active Active
-
2015
- 2015-05-19 DK DK15732049.0T patent/DK3145661T3/da active
- 2015-05-19 WO PCT/IB2015/053672 patent/WO2015177717A1/fr not_active Ceased
- 2015-05-19 JP JP2016568651A patent/JP6587192B2/ja active Active
- 2015-05-19 EP EP15732049.0A patent/EP3145661B1/fr active Active
- 2015-05-19 US US15/313,038 patent/US10576546B2/en active Active
- 2015-05-19 ES ES15732049T patent/ES2700151T3/es active Active
Also Published As
| Publication number | Publication date |
|---|---|
| US10576546B2 (en) | 2020-03-03 |
| FR3021230A1 (fr) | 2015-11-27 |
| EP3145661A1 (fr) | 2017-03-29 |
| WO2015177717A1 (fr) | 2015-11-26 |
| JP6587192B2 (ja) | 2019-10-09 |
| EP3145661B1 (fr) | 2018-08-29 |
| US20170120341A1 (en) | 2017-05-04 |
| DK3145661T3 (da) | 2019-01-02 |
| JP2017521554A (ja) | 2017-08-03 |
| FR3021230B1 (fr) | 2016-06-24 |
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