ES2681346T3 - Microgeles de polisacáridos para la eliminación del agua de petróleo, productos derivados de petróleo y metales, y metodos para la aplicacion de estos materiales (variantes) - Google Patents
Microgeles de polisacáridos para la eliminación del agua de petróleo, productos derivados de petróleo y metales, y metodos para la aplicacion de estos materiales (variantes) Download PDFInfo
- Publication number
- ES2681346T3 ES2681346T3 ES13806672.5T ES13806672T ES2681346T3 ES 2681346 T3 ES2681346 T3 ES 2681346T3 ES 13806672 T ES13806672 T ES 13806672T ES 2681346 T3 ES2681346 T3 ES 2681346T3
- Authority
- ES
- Spain
- Prior art keywords
- petroleum
- solution
- oil
- microgel
- microgels
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 150000004676 glycans Chemical class 0.000 title claims abstract description 66
- 229920001282 polysaccharide Polymers 0.000 title claims abstract description 66
- 239000005017 polysaccharide Substances 0.000 title claims abstract description 66
- 239000003209 petroleum derivative Substances 0.000 title claims abstract description 60
- 239000003208 petroleum Substances 0.000 title claims abstract description 36
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims description 76
- 238000000034 method Methods 0.000 title claims description 55
- 239000000463 material Substances 0.000 title description 42
- 229910052751 metal Inorganic materials 0.000 title description 6
- 239000002184 metal Substances 0.000 title description 6
- 150000002739 metals Chemical class 0.000 title description 3
- 239000000243 solution Substances 0.000 claims abstract description 79
- 239000002245 particle Substances 0.000 claims abstract description 50
- 239000007864 aqueous solution Substances 0.000 claims abstract description 20
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 7
- 229910021645 metal ion Inorganic materials 0.000 claims abstract description 6
- 239000010409 thin film Substances 0.000 claims abstract description 5
- 238000005345 coagulation Methods 0.000 claims description 30
- 230000015271 coagulation Effects 0.000 claims description 30
- 229920001661 Chitosan Polymers 0.000 claims description 14
- 239000007788 liquid Substances 0.000 claims description 9
- 239000001814 pectin Substances 0.000 claims description 9
- 235000010987 pectin Nutrition 0.000 claims description 9
- 229920001277 pectin Polymers 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 238000000746 purification Methods 0.000 claims description 4
- 229920000168 Microcrystalline cellulose Polymers 0.000 claims description 3
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 3
- 235000019813 microcrystalline cellulose Nutrition 0.000 claims description 3
- 239000008108 microcrystalline cellulose Substances 0.000 claims description 3
- 229940016286 microcrystalline cellulose Drugs 0.000 claims description 3
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 3
- 238000013019 agitation Methods 0.000 claims 1
- 239000003921 oil Substances 0.000 description 93
- 239000000203 mixture Substances 0.000 description 38
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 36
- 239000010410 layer Substances 0.000 description 19
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 16
- 238000000926 separation method Methods 0.000 description 16
- 239000002594 sorbent Substances 0.000 description 16
- 239000000047 product Substances 0.000 description 12
- 238000001914 filtration Methods 0.000 description 11
- 239000012530 fluid Substances 0.000 description 9
- 239000010779 crude oil Substances 0.000 description 8
- 239000000839 emulsion Substances 0.000 description 8
- 239000000725 suspension Substances 0.000 description 8
- 239000004744 fabric Substances 0.000 description 7
- 238000002156 mixing Methods 0.000 description 7
- 239000011148 porous material Substances 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- 229920000742 Cotton Polymers 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 6
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 5
- 230000008030 elimination Effects 0.000 description 5
- 238000003379 elimination reaction Methods 0.000 description 5
- 239000000835 fiber Substances 0.000 description 5
- 230000005484 gravity Effects 0.000 description 5
- 230000035699 permeability Effects 0.000 description 5
- 239000013049 sediment Substances 0.000 description 5
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 4
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 4
- 239000001768 carboxy methyl cellulose Substances 0.000 description 4
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 4
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 4
- 238000007667 floating Methods 0.000 description 4
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 4
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 4
- 239000000416 hydrocolloid Substances 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 239000010802 sludge Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- 235000010980 cellulose Nutrition 0.000 description 3
- 230000007547 defect Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000010408 film Substances 0.000 description 3
- 239000000499 gel Substances 0.000 description 3
- 108010025899 gelatin film Proteins 0.000 description 3
- 230000005661 hydrophobic surface Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 239000007764 o/w emulsion Substances 0.000 description 3
- 239000003305 oil spill Substances 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 2
- 235000021314 Palmitic acid Nutrition 0.000 description 2
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 description 2
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 2
- -1 aliphatic amines Chemical class 0.000 description 2
- 239000008346 aqueous phase Substances 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- WGQKYBSKWIADBV-UHFFFAOYSA-N benzylamine Chemical compound NCC1=CC=CC=C1 WGQKYBSKWIADBV-UHFFFAOYSA-N 0.000 description 2
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 238000010382 chemical cross-linking Methods 0.000 description 2
- FOCAUTSVDIKZOP-UHFFFAOYSA-N chloroacetic acid Chemical compound OC(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-N 0.000 description 2
- 229940106681 chloroacetic acid Drugs 0.000 description 2
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 description 2
- 239000000701 coagulant Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 230000006196 deacetylation Effects 0.000 description 2
- 238000003381 deacetylation reaction Methods 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 239000010840 domestic wastewater Substances 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 238000005538 encapsulation Methods 0.000 description 2
- 239000013505 freshwater Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000010842 industrial wastewater Substances 0.000 description 2
- 239000010954 inorganic particle Substances 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 239000000523 sample Substances 0.000 description 2
- 150000003384 small molecules Chemical class 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- ADFXKUOMJKEIND-UHFFFAOYSA-N 1,3-dicyclohexylurea Chemical compound C1CCCCC1NC(=O)NC1CCCCC1 ADFXKUOMJKEIND-UHFFFAOYSA-N 0.000 description 1
- 229920006051 Capron® Polymers 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- QOSSAOTZNIDXMA-UHFFFAOYSA-N Dicylcohexylcarbodiimide Chemical compound C1CCCCC1N=C=NC1CCCCC1 QOSSAOTZNIDXMA-UHFFFAOYSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- NQTADLQHYWFPDB-UHFFFAOYSA-N N-Hydroxysuccinimide Chemical compound ON1C(=O)CCC1=O NQTADLQHYWFPDB-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- CSCPPACGZOOCGX-UHFFFAOYSA-N acetone Substances CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000005903 acid hydrolysis reaction Methods 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000029936 alkylation Effects 0.000 description 1
- 238000005804 alkylation reaction Methods 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- XKXHCNPAFAXVRZ-UHFFFAOYSA-N benzylazanium;chloride Chemical compound [Cl-].[NH3+]CC1=CC=CC=C1 XKXHCNPAFAXVRZ-UHFFFAOYSA-N 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 239000002775 capsule Substances 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 230000001112 coagulating effect Effects 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 239000012043 crude product Substances 0.000 description 1
- XYZMOVWWVXBHDP-UHFFFAOYSA-N cyclohexyl isocyanide Chemical compound [C-]#[N+]C1CCCCC1 XYZMOVWWVXBHDP-UHFFFAOYSA-N 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 125000005442 diisocyanate group Chemical group 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 238000005188 flotation Methods 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- VANNPISTIUFMLH-UHFFFAOYSA-N glutaric anhydride Chemical compound O=C1CCCC(=O)O1 VANNPISTIUFMLH-UHFFFAOYSA-N 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 230000005660 hydrophilic surface Effects 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 238000011089 mechanical engineering Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- 229920006173 natural rubber latex Polymers 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 150000007530 organic bases Chemical class 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920005594 polymer fiber Polymers 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 239000010801 sewage sludge Substances 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 239000010455 vermiculite Substances 0.000 description 1
- 229910052902 vermiculite Inorganic materials 0.000 description 1
- 235000019354 vermiculite Nutrition 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/286—Treatment of water, waste water, or sewage by sorption using natural organic sorbents or derivatives thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D17/00—Separation of liquids, not provided for elsewhere, e.g. by thermal diffusion
- B01D17/02—Separation of non-miscible liquids
- B01D17/0202—Separation of non-miscible liquids by ab- or adsorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D17/00—Separation of liquids, not provided for elsewhere, e.g. by thermal diffusion
- B01D17/02—Separation of non-miscible liquids
- B01D17/04—Breaking emulsions
- B01D17/047—Breaking emulsions with separation aids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
- B01J20/24—Naturally occurring macromolecular compounds, e.g. humic acids or their derivatives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
- B01J20/28004—Sorbent size or size distribution, e.g. particle size
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
- B01J20/28047—Gels
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/001—Processes for the treatment of water whereby the filtration technique is of importance
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/285—Treatment of water, waste water, or sewage by sorption using synthetic organic sorbents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/5272—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using specific organic precipitants
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/54—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
- C02F1/56—Macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/68—Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water
- C02F1/681—Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water by addition of solid materials for removing an oily layer on water
-
- E—FIXED CONSTRUCTIONS
- E02—HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
- E02B—HYDRAULIC ENGINEERING
- E02B15/00—Cleaning or keeping clear the surface of open water; Apparatus therefor
- E02B15/04—Devices for cleaning or keeping clear the surface of open water from oil or like floating materials by separating or removing these materials
- E02B15/041—Devices for distributing materials, e.g. absorbed or magnetic particles over a surface of open water to remove the oil, with or without means for picking up the treated oil
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/38—Treatment of water, waste water, or sewage by centrifugal separation
- C02F1/385—Treatment of water, waste water, or sewage by centrifugal separation by centrifuging suspensions
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/66—Treatment of water, waste water, or sewage by neutralisation; pH adjustment
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/20—Heavy metals or heavy metal compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/32—Hydrocarbons, e.g. oil
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/007—Contaminated open waterways, rivers, lakes or ponds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/10—Nature of the water, waste water, sewage or sludge to be treated from quarries or from mining activities
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/34—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32
- C02F2103/36—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32 from the manufacture of organic compounds
- C02F2103/365—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32 from the manufacture of organic compounds from petrochemical industry (e.g. refineries)
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/16—Regeneration of sorbents, filters
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/08—Nanoparticles or nanotubes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A20/00—Water conservation; Efficient water supply; Efficient water use
- Y02A20/20—Controlling water pollution; Waste water treatment
- Y02A20/204—Keeping clear the surface of open water from oil spills
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Water Supply & Treatment (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- Thermal Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Mechanical Engineering (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Dispersion Chemistry (AREA)
- Water Treatment By Sorption (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Separation Of Suspended Particles By Flocculating Agents (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Applications Claiming Priority (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| RU2012125534/05A RU2492905C1 (ru) | 2012-06-19 | 2012-06-19 | Способ разделения смесей двух несмешивающихся жидкостей типа масло-в-воде |
| RU2012125534 | 2012-06-19 | ||
| RU2012136757 | 2012-08-27 | ||
| RU2012136757/13A RU2514645C1 (ru) | 2012-08-27 | 2012-08-27 | Способ локализации разливов нефти в водной среде |
| RU2013123536/05A RU2535858C1 (ru) | 2013-05-22 | 2013-05-22 | Коагулянт для очистки воды преимущественно от нефтепродуктов |
| RU2013123536 | 2013-05-22 | ||
| PCT/RU2013/000506 WO2013191590A1 (ru) | 2012-06-19 | 2013-06-18 | Микрогели полисахаридов для очистки воды от нефти и нефтепродуктов и способ их использования (варианты) |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2681346T3 true ES2681346T3 (es) | 2018-09-12 |
Family
ID=49769079
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES13806672.5T Active ES2681346T3 (es) | 2012-06-19 | 2013-06-18 | Microgeles de polisacáridos para la eliminación del agua de petróleo, productos derivados de petróleo y metales, y metodos para la aplicacion de estos materiales (variantes) |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US9718704B2 (enExample) |
| EP (1) | EP2862843B1 (enExample) |
| CN (1) | CN104661969B (enExample) |
| CA (1) | CA2876623C (enExample) |
| DK (1) | DK2862843T3 (enExample) |
| EA (1) | EA029441B1 (enExample) |
| ES (1) | ES2681346T3 (enExample) |
| HR (1) | HRP20181219T1 (enExample) |
| IN (1) | IN2015MN00132A (enExample) |
| LT (1) | LT2862843T (enExample) |
| PL (1) | PL2862843T3 (enExample) |
| PT (1) | PT2862843T (enExample) |
| WO (1) | WO2013191590A1 (enExample) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2550425C1 (ru) * | 2014-06-11 | 2015-05-10 | Общество с ограниченной ответственностью "НПО БиоМикроГели" | Способ сбора нефти или нефтепродуктов с поверхности воды (варианты) |
| RU2596751C1 (ru) * | 2015-05-07 | 2016-09-10 | Общество с ограниченной ответственностью "НПО БиоМикроГели" | Вещество для очистки почвы и твердых поверхностей от масел, в том числе от нефти и нефтепродуктов, и способ его использования (варианты) |
| AU2017408169B2 (en) * | 2017-04-03 | 2021-07-22 | Obshestvo S Ogranichennoi Otvetstvennost'u "Biomicrogeli" | Use of polysaccharide microgels in detergents |
| CN109851686B (zh) * | 2018-12-26 | 2021-02-12 | 大连民族大学 | 用于石油凝聚的微生物胞外多糖及其纯化方法 |
| RU2691716C1 (ru) * | 2018-12-28 | 2019-06-17 | федеральное государственное автономное образовательное учреждение высшего образования "Российский государственный университет нефти и газа (национальный исследовательский университет) имени И.М. Губкина" | Способ получения композиции для ликвидации нефтеразливов |
| CN110054323B (zh) * | 2019-05-29 | 2021-11-09 | 江西科技师范大学 | 一种用于处理污水中有机油膜污染物的凝胶材料及其应用方法 |
| CN115212779B (zh) * | 2022-07-05 | 2023-05-26 | 江苏铁锚玻璃股份有限公司 | 双极变色粒子的除碘方法 |
| WO2024232781A1 (ru) * | 2023-05-10 | 2024-11-14 | Олег Ильич ЭПШТЕЙН | Модификатор и способ изменения эксплуатационных свойств нефти и продуктов нефтепереработки |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS53103986A (en) | 1977-02-24 | 1978-09-09 | Agency Of Ind Science & Technol | Manufacture of coagulating agent for flowed-out oil |
| US4285819A (en) * | 1980-01-28 | 1981-08-25 | California Institute Of Technology | Functional magnetic microspheres |
| RU2148425C1 (ru) * | 1999-10-07 | 2000-05-10 | Общество с ограниченной ответственностью "Рютар" | Способ фильтрации |
| FR2829494B1 (fr) * | 2001-07-13 | 2005-10-28 | Rhodia Chimie Sa | Compositions aqueuses comprenant un microgel chimique associe a un polymere pontant, preparation et utilisation |
| GB0130518D0 (en) * | 2001-12-21 | 2002-02-06 | Univ Gent | Pulsed bio-agent delivery systems based on degradable polymer solutions or hydrogels |
| RU2361661C2 (ru) | 2003-08-11 | 2009-07-20 | Владимир Александрович Дегтярев | Сорбирующий материал, способ его изготовления и использования |
| CN1594493A (zh) * | 2004-07-07 | 2005-03-16 | 石油大学(华东) | 亚微米聚合物活性微球调剖驱油剂 |
| RU2279405C2 (ru) * | 2004-08-23 | 2006-07-10 | Институт химии Дальневосточного отделения Российской академии наук (статус государственного учреждения) (Институт химии ДВО РАН) | Способ очистки вод от нефтепродуктов |
| CN100584386C (zh) * | 2005-01-27 | 2010-01-27 | 复旦大学 | 一种纳米微凝胶、其制备方法及应用 |
| NO326276B1 (no) * | 2006-04-11 | 2008-10-27 | Sorbwater Technology As | Fremgangsmate til fjerning av hydrokarboner og partikulaert materiale fra en vaeskestrom |
| BRPI0710141B1 (pt) * | 2006-04-11 | 2018-02-06 | Sorbwater Technology As | Método para remoção de poluentes de uma corrente aquosa contínua, solução apropriada para adição a uma corrente aquosa, uso do método e mistura para adicionar a uma corrente aquosa poluída |
| RU2352388C1 (ru) * | 2007-11-07 | 2009-04-20 | Государственное образовательное учреждение высшего профессионального образования Волгоградский государственный технический университет (ВолгГТУ) | Способ получения сорбента для очистки воды |
| RU73618U1 (ru) * | 2007-11-07 | 2008-05-27 | Государственное образовательное учреждение высшего профессионального образования Волгоградский государственный технический университет (ВолгГТУ) | Сорбент для очистки воды |
| CN101298038B (zh) * | 2008-03-13 | 2011-03-23 | 西南石油大学 | 一种用于废水处理的凝胶吸附剂 |
| US8865632B1 (en) * | 2008-11-10 | 2014-10-21 | Cesi Chemical, Inc. | Drag-reducing copolymer compositions |
| RU2439244C1 (ru) | 2010-07-05 | 2012-01-10 | Институт проблем нефти и газа Сибирского отделения Российской академии наук | Способ сбора разлива нефти в зоне траншейного подводного перехода магистрального нефтепровода |
| JP5812537B2 (ja) * | 2010-11-05 | 2015-11-17 | 江崎グリコ株式会社 | アミノ糖含有グルカン、その製造法および利用 |
| US20120145645A1 (en) * | 2010-12-13 | 2012-06-14 | Halosource, Inc. | Clarification of hydrocarbons and suspended matter from an aqueous medium |
| CN102127189B (zh) * | 2010-12-24 | 2012-07-04 | 北京石大万嘉新材料科技有限公司 | 聚丙烯酰胺微凝胶及其制备方法和应用 |
| RU2471041C2 (ru) | 2011-03-02 | 2012-12-27 | Валерий Владимирович Бодров | Способ очистки поверхностей от нефти и нефтепродуктов |
| RU2479348C1 (ru) | 2011-08-31 | 2013-04-20 | Валентина Евгеньевна Лекторская | Сорбент для сбора нефти и способ его получения |
-
2013
- 2013-06-18 US US14/408,656 patent/US9718704B2/en active Active
- 2013-06-18 EP EP13806672.5A patent/EP2862843B1/en active Active
- 2013-06-18 ES ES13806672.5T patent/ES2681346T3/es active Active
- 2013-06-18 CN CN201380036171.3A patent/CN104661969B/zh active Active
- 2013-06-18 LT LTEP13806672.5T patent/LT2862843T/lt unknown
- 2013-06-18 EA EA201401284A patent/EA029441B1/ru not_active IP Right Cessation
- 2013-06-18 HR HRP20181219TT patent/HRP20181219T1/hr unknown
- 2013-06-18 IN IN132MUN2015 patent/IN2015MN00132A/en unknown
- 2013-06-18 CA CA2876623A patent/CA2876623C/en active Active
- 2013-06-18 DK DK13806672.5T patent/DK2862843T3/en active
- 2013-06-18 PT PT138066725T patent/PT2862843T/pt unknown
- 2013-06-18 WO PCT/RU2013/000506 patent/WO2013191590A1/ru not_active Ceased
- 2013-06-18 PL PL13806672T patent/PL2862843T3/pl unknown
Also Published As
| Publication number | Publication date |
|---|---|
| WO2013191590A1 (ru) | 2013-12-27 |
| PT2862843T (pt) | 2018-08-07 |
| EA201401284A1 (ru) | 2015-03-31 |
| CN104661969B (zh) | 2017-03-01 |
| US20150191368A1 (en) | 2015-07-09 |
| EP2862843A1 (en) | 2015-04-22 |
| IN2015MN00132A (enExample) | 2015-10-16 |
| PL2862843T3 (pl) | 2018-10-31 |
| EP2862843B1 (en) | 2018-05-02 |
| CA2876623C (en) | 2019-09-24 |
| LT2862843T (lt) | 2018-09-10 |
| CA2876623A1 (en) | 2013-12-27 |
| DK2862843T3 (en) | 2018-08-13 |
| CN104661969A (zh) | 2015-05-27 |
| EA029441B1 (ru) | 2018-03-30 |
| HRP20181219T1 (hr) | 2018-10-05 |
| EP2862843A4 (en) | 2015-05-06 |
| US9718704B2 (en) | 2017-08-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP2862843B1 (en) | Polysaccharide microgels for cleaning water of petroleum and petroleum products and method for using same (variants) | |
| Haridharan et al. | Oil spills adsorption and cleanup by polymeric materials: A review | |
| Guo et al. | A robust cotton textile-based material for high-flux oil–water separation | |
| Ceylan et al. | Evaluation of butyl rubber as sorbent material for the removal of oil and polycyclic aromatic hydrocarbons from seawater | |
| Dong et al. | Polydopamine-assisted surface coating of MIL-53 and dodecanethiol on a melamine sponge for oil–water separation | |
| Hubbe et al. | Cellulosic Substrates for Removal of Pollutants from Aqueous Systems: A Review. 3. Spilled Oil and Emulsified Organic Liquids. | |
| KR20120051000A (ko) | 수성 매체로부터 물의 회수 및 현탁된 고형물의 분리를 위한 이중 중합체 시스템 | |
| ES2404140T3 (es) | Procedimiento y dispositivo para la regeneración de las soluciones de lavado contaminadas | |
| Parsaie et al. | Novel approach for rapid oil/water separation through superhydrophobic/superoleophilic zinc stearate coated polyurethane sponges | |
| CN106573185A (zh) | 油水分离装置、排水系统 | |
| CN103958421B (zh) | 用于水处理的方法和设备 | |
| Dong et al. | Facile fabrication of marine algae-based robust superhydrophobic sponges for efficient oil removal from water | |
| Eldin et al. | Development of low-cost chitosan derivatives based on marine waste sources as oil adsorptive materials: I. Preparation and characterization | |
| WO2016178597A1 (ru) | Вещество для очистки почвы и твердых поверхностей от масел, способ его использования (варианты) | |
| Kuimov et al. | Biopolymer-based membranes: green technologies for the separation of oil–water mixtures and the reduction of oil pollution | |
| US20110163037A1 (en) | Filtration of a hydrocarbon from a fluid | |
| Hamimed et al. | Nanocelluloses for removal of heavy metals from wastewater | |
| Kumar | Sustainable approach to oil recovery from oil spills through superhydrophobic jute fabric | |
| Kratochvil et al. | Superhydrophobic polymer multilayers for the filtration‐and absorption‐based separation of oil/water mixtures | |
| RU2492905C1 (ru) | Способ разделения смесей двух несмешивающихся жидкостей типа масло-в-воде | |
| ben Hammouda et al. | Buoyant oleophilic magnetic activated carbon nanoparticles for oil spill cleanup | |
| Banerjee et al. | Overview on natural materials for oil water separation | |
| Kizil et al. | Organogels and hydrogels for oil/water separation | |
| Toteva et al. | Preparation and application of composite material as sorbent for oil spills | |
| RU2275466C1 (ru) | Нефтесорбирующий бон |