ES2654614T3 - Dispersión inversa que comprende un polímero catiónico y un agente de estabilización - Google Patents
Dispersión inversa que comprende un polímero catiónico y un agente de estabilización Download PDFInfo
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- ES2654614T3 ES2654614T3 ES13719540.0T ES13719540T ES2654614T3 ES 2654614 T3 ES2654614 T3 ES 2654614T3 ES 13719540 T ES13719540 T ES 13719540T ES 2654614 T3 ES2654614 T3 ES 2654614T3
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000003094 microcapsule Substances 0.000 description 1
- ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical compound C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 description 1
- ZBJVLWIYKOAYQH-UHFFFAOYSA-N naphthalen-2-yl 2-hydroxybenzoate Chemical compound OC1=CC=CC=C1C(=O)OC1=CC=C(C=CC=C2)C2=C1 ZBJVLWIYKOAYQH-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- XNTUJOTWIMFEQS-UHFFFAOYSA-N octadecanoyl octadecaneperoxoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCCCCCCCC XNTUJOTWIMFEQS-UHFFFAOYSA-N 0.000 description 1
- HMZGPNHSPWNGEP-UHFFFAOYSA-N octadecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C(C)=C HMZGPNHSPWNGEP-UHFFFAOYSA-N 0.000 description 1
- CXQXSVUQTKDNFP-UHFFFAOYSA-N octamethyltrisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C CXQXSVUQTKDNFP-UHFFFAOYSA-N 0.000 description 1
- 239000004533 oil dispersion Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 125000005375 organosiloxane group Chemical group 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- DCKVFVYPWDKYDN-UHFFFAOYSA-L oxygen(2-);titanium(4+);sulfate Chemical compound [O-2].[Ti+4].[O-]S([O-])(=O)=O DCKVFVYPWDKYDN-UHFFFAOYSA-L 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 125000005385 peroxodisulfate group Chemical group 0.000 description 1
- 125000000864 peroxy group Chemical group O(O*)* 0.000 description 1
- XCRBXWCUXJNEFX-UHFFFAOYSA-N peroxybenzoic acid Chemical compound OOC(=O)C1=CC=CC=C1 XCRBXWCUXJNEFX-UHFFFAOYSA-N 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 238000004987 plasma desorption mass spectroscopy Methods 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 229920000867 polyelectrolyte Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 1
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- VSVCAMGKPRPGQR-UHFFFAOYSA-N propan-2-one;sulfurous acid Chemical compound CC(C)=O.OS(O)=O VSVCAMGKPRPGQR-UHFFFAOYSA-N 0.000 description 1
- BWJUFXUULUEGMA-UHFFFAOYSA-N propan-2-yl propan-2-yloxycarbonyloxy carbonate Chemical compound CC(C)OC(=O)OOC(=O)OC(C)C BWJUFXUULUEGMA-UHFFFAOYSA-N 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- XWGJFPHUCFXLBL-UHFFFAOYSA-M rongalite Chemical compound [Na+].OCS([O-])=O XWGJFPHUCFXLBL-UHFFFAOYSA-M 0.000 description 1
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 1
- 229910001379 sodium hypophosphite Inorganic materials 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 229940001584 sodium metabisulfite Drugs 0.000 description 1
- 235000010262 sodium metabisulphite Nutrition 0.000 description 1
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 235000011150 stannous chloride Nutrition 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- LPBNNQBYFCZCTA-UHFFFAOYSA-N sulfuric acid;1-tridecoxytridecane Chemical class OS(O)(=O)=O.CCCCCCCCCCCCCOCCCCCCCCCCCCC LPBNNQBYFCZCTA-UHFFFAOYSA-N 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- SWAXTRYEYUTSAP-UHFFFAOYSA-N tert-butyl ethaneperoxoate Chemical compound CC(=O)OOC(C)(C)C SWAXTRYEYUTSAP-UHFFFAOYSA-N 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- IUTCEZPPWBHGIX-UHFFFAOYSA-N tin(2+) Chemical class [Sn+2] IUTCEZPPWBHGIX-UHFFFAOYSA-N 0.000 description 1
- AXZWODMDQAVCJE-UHFFFAOYSA-L tin(II) chloride (anhydrous) Chemical compound [Cl-].[Cl-].[Sn+2] AXZWODMDQAVCJE-UHFFFAOYSA-L 0.000 description 1
- 229910000348 titanium sulfate Inorganic materials 0.000 description 1
- CMWCOKOTCLFJOP-UHFFFAOYSA-N titanium(3+) Chemical class [Ti+3] CMWCOKOTCLFJOP-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- FVJLCPJDDAGIJE-UHFFFAOYSA-N tris(2-hydroxyethyl)-methylazanium Chemical compound OCC[N+](C)(CCO)CCO FVJLCPJDDAGIJE-UHFFFAOYSA-N 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/32—Polymerisation in water-in-oil emulsions
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/14—Organic medium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/34—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F226/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/911—Emulsifying agents
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Dispersion Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Cosmetics (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP12168760 | 2012-05-21 | ||
| EP12168760 | 2012-05-21 | ||
| PCT/EP2013/058874 WO2013174622A1 (en) | 2012-05-21 | 2013-04-29 | Inverse dispersion comprising a cationic polymer and a stabilizing agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2654614T3 true ES2654614T3 (es) | 2018-02-14 |
Family
ID=48227287
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES13719540.0T Active ES2654614T3 (es) | 2012-05-21 | 2013-04-29 | Dispersión inversa que comprende un polímero catiónico y un agente de estabilización |
Country Status (12)
| Country | Link |
|---|---|
| EP (1) | EP2852622B1 (enExample) |
| JP (1) | JP6211070B2 (enExample) |
| KR (1) | KR101975179B1 (enExample) |
| CN (1) | CN104334586B (enExample) |
| BR (1) | BR112014028776B1 (enExample) |
| CA (1) | CA2870653A1 (enExample) |
| ES (1) | ES2654614T3 (enExample) |
| MX (1) | MX2014014249A (enExample) |
| PH (1) | PH12014502611A1 (enExample) |
| PL (1) | PL2852622T3 (enExample) |
| RU (1) | RU2630309C2 (enExample) |
| WO (1) | WO2013174622A1 (enExample) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3172243A1 (en) * | 2014-07-23 | 2017-05-31 | Basf Se | Inverse dispersion comprising a cationic polymer, a stabilizing agent and a trifunctional and/or polyfunctional crosslinker |
| US10920001B2 (en) | 2016-01-25 | 2021-02-16 | Basf Se | Process for obtaining a cationic polymer with an at least bimodal molecular weight distribution |
| WO2017129435A1 (en) * | 2016-01-25 | 2017-08-03 | Basf Se | Cationic polymer with an at least bimodal molecular weight distribution |
| JP2019507879A (ja) * | 2016-03-07 | 2019-03-22 | アドヴァンスド ポリマー モニタリング テクノロジーズ インコーポレイテッドＡｄｖａｎｃｅｄ Ｐｏｌｙｍｅｒ Ｍｏｎｉｔｏｒｉｎｇ Ｔｅｃｈｎｏｌｏｇｉｅｓ， Ｉｎｃ． | ポリマーの固有粘度及び非ニュートン挙動を同時特定する装置及び方法 |
| CN107286302A (zh) * | 2017-06-28 | 2017-10-24 | 常州市瑞泰物资有限公司 | 一种纸用柔软剂及其制备方法 |
| US10781413B2 (en) | 2018-01-29 | 2020-09-22 | The Procter & Gamble Company | Dryer sheets comprising branched polyester polymers |
| JP7043626B2 (ja) * | 2018-01-29 | 2022-03-29 | ザ プロクター アンド ギャンブル カンパニー | 粒子状洗濯用柔軟化洗浄添加剤 |
| US10781402B2 (en) | 2018-01-29 | 2020-09-22 | The Procter & Gamble Company | Liquid fabric enhancers comprising branched polyester molecules |
| JP7216116B2 (ja) | 2018-05-30 | 2023-01-31 | ザ プロクター アンド ギャンブル カンパニー | 分岐鎖状ポリエステル分子を含む液体布地増強剤 |
| US11104866B2 (en) | 2018-05-30 | 2021-08-31 | The Procter & Gamble Company | Particulate laundry softening wash additive |
| EP3575339B1 (en) | 2018-05-30 | 2024-05-08 | The Procter & Gamble Company | Dryer sheets comprising branched polyester polymers |
Family Cites Families (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1482515A (en) * | 1974-07-24 | 1977-08-10 | Allied Colloids Ltd | Polymers |
| GB2002400B (en) | 1977-07-12 | 1982-01-20 | Ici Ltd | Block or graft copolymers and their use as surfactants |
| EP0000424B1 (en) * | 1977-07-12 | 1984-02-01 | Imperial Chemical Industries Plc | Linear or branched ester-ether block copolymers and their use as surfactants either alone or in blends with conventional surfactants |
| JPS59136305A (ja) * | 1983-01-26 | 1984-08-04 | Sumitomo Chem Co Ltd | 水溶性球状ポリマ−の製造方法 |
| GB8309275D0 (en) * | 1983-04-06 | 1983-05-11 | Allied Colloids Ltd | Dissolution of water soluble polymers in water |
| EP0172724B1 (en) | 1984-08-15 | 1991-07-24 | Ciba Specialty Chemicals Water Treatments Limited | Polymerisation processes and polymeric compositions |
| DE3584551D1 (de) | 1984-08-15 | 1991-12-05 | Allied Colloids Ltd | Polymerzusammensetzungen. |
| DE3583559D1 (de) | 1984-08-15 | 1991-08-29 | Allied Colloids Ltd | Wasserloesliche polymere. |
| CA1331251C (en) | 1988-05-20 | 1994-08-02 | Peter Flesher | Particulate polymers, their production and uses |
| DE4418156A1 (de) | 1994-05-25 | 1995-11-30 | Basf Ag | Verfahren zur Herstellung von stabilen Wasser-in-Öl-Emulsionen von hydrolysierten Polymerisaten von N-Vinylamiden und ihre Verwendung |
| US5646212A (en) | 1994-09-02 | 1997-07-08 | Ici Americas Inc. | Polyalkylene glycol anhydroxy carboxylic acid dispersant |
| GB9618332D0 (en) | 1996-09-03 | 1996-10-16 | Ici Plc | Polyacrylamide polymerisation |
| IT1293509B1 (it) | 1997-07-30 | 1999-03-01 | 3V Sigma Spa | Addensanti per composizioni acquose acide |
| DE19911170A1 (de) * | 1999-03-12 | 2000-09-14 | Basf Ag | Verfahren zum Herstellen von W/O-Emulsionen |
| FR2797635A1 (fr) | 1999-08-20 | 2001-02-23 | Atofina | Preparation de polymeres hydrophiles par un procede de polymerisation en emulsion inverse |
| JP4312364B2 (ja) | 2000-09-29 | 2009-08-12 | 花王株式会社 | 液体柔軟剤組成物 |
| JP4057423B2 (ja) * | 2001-02-28 | 2008-03-05 | インターベツト・インターナシヨナル・ベー・ベー | 注射用油中水型乳剤 |
| EP1509556A1 (en) | 2002-06-04 | 2005-03-02 | Ciba SC Holding AG | Aqueous polymer formulations |
| KR101014357B1 (ko) * | 2002-11-29 | 2011-02-15 | 시바 홀딩 인코포레이티드 | 동종 중합체 및/또는 공중합체를 포함하는 수성 조성물 |
| US7659238B2 (en) * | 2002-11-29 | 2010-02-09 | Ciba Specialty Chemicals Corp. | Fabric softener compositions comprising homo- and/or copolymers |
| CN1720267A (zh) * | 2002-12-06 | 2006-01-11 | 赫尔克里士公司 | 在反相乳液基质中制备的阳离子或两性共聚物以及它们在制备纤维素纤维组合物中的应用 |
| US7396874B2 (en) * | 2002-12-06 | 2008-07-08 | Hercules Incorporated | Cationic or amphoteric copolymers prepared in an inverse emulsion matrix and their use in preparing cellulosic fiber compositions |
| US6949500B2 (en) | 2002-12-16 | 2005-09-27 | Colgate-Palmolive Company | Fabric softener compositions containing a mixture of cationic polymers as rheology modifiers |
| JP2005125215A (ja) * | 2003-10-23 | 2005-05-19 | Hymo Corp | 含油有機汚泥の脱水方法 |
| CN1964993A (zh) | 2004-04-06 | 2007-05-16 | 西巴特殊化学制品控股公司 | 液体分散聚合物组合物、其制备及其应用 |
| US7304026B2 (en) | 2004-04-15 | 2007-12-04 | Colgate-Palmolive Company | Fabric care composition comprising polymer encapsulated fabric or skin beneficiating ingredient |
| WO2005103091A1 (en) * | 2004-04-21 | 2005-11-03 | Ciba Specialty Chemicals Water Treatments Limited | Composition and method of preparing high solid emulsions |
| US7485451B2 (en) | 2004-11-18 | 2009-02-03 | Regents Of The University Of California | Storage stable compositions of biological materials |
| FR2879607B1 (fr) * | 2004-12-16 | 2007-03-30 | Seppic Sa | Nouveaux latex inverse concentre, procede pour sa preparation, et utilisation dans l'industrie |
| US20070015684A1 (en) | 2005-07-15 | 2007-01-18 | Marshall Michael L | Viscosity improvement in liquid fabric softeners |
| CA2694212C (en) * | 2007-08-03 | 2016-04-12 | Reinhold Leyrer | Associative thickener dispersion |
| CN100551941C (zh) * | 2007-11-28 | 2009-10-21 | 湖北省化学研究院 | 分散聚合型聚丙烯酰胺乳液及其在油田采出液处理中的应用 |
| JP2009280648A (ja) | 2008-05-20 | 2009-12-03 | Hymo Corp | 粉末からなるイオン性水溶性高分子とその製造方法およびその用途 |
| JP5366301B2 (ja) * | 2008-07-10 | 2013-12-11 | ハイモ株式会社 | 粉末状イオン性水溶性高分子およびその用途 |
| CN102272282B (zh) * | 2009-01-06 | 2014-03-05 | 荷兰联合利华有限公司 | 与织物调理剂相关的改进 |
| CN102482619B (zh) * | 2009-01-06 | 2016-04-20 | S.P.C.M.股份有限公司 | 阳离子聚合物增稠剂 |
| GB0922624D0 (en) | 2009-12-24 | 2010-02-10 | Croda Int Plc | Inverse emulsions |
-
2013
- 2013-04-29 MX MX2014014249A patent/MX2014014249A/es unknown
- 2013-04-29 KR KR1020147035746A patent/KR101975179B1/ko not_active Expired - Fee Related
- 2013-04-29 RU RU2014151609A patent/RU2630309C2/ru active
- 2013-04-29 ES ES13719540.0T patent/ES2654614T3/es active Active
- 2013-04-29 BR BR112014028776-7A patent/BR112014028776B1/pt active IP Right Grant
- 2013-04-29 PL PL13719540T patent/PL2852622T3/pl unknown
- 2013-04-29 CN CN201380026324.6A patent/CN104334586B/zh active Active
- 2013-04-29 CA CA2870653A patent/CA2870653A1/en not_active Abandoned
- 2013-04-29 WO PCT/EP2013/058874 patent/WO2013174622A1/en not_active Ceased
- 2013-04-29 JP JP2015513074A patent/JP6211070B2/ja active Active
- 2013-04-29 EP EP13719540.0A patent/EP2852622B1/en active Active
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2014
- 2014-11-21 PH PH12014502611A patent/PH12014502611A1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CN104334586A (zh) | 2015-02-04 |
| EP2852622A1 (en) | 2015-04-01 |
| WO2013174622A1 (en) | 2013-11-28 |
| EP2852622B1 (en) | 2017-10-18 |
| JP6211070B2 (ja) | 2017-10-11 |
| PL2852622T3 (pl) | 2018-03-30 |
| RU2630309C2 (ru) | 2017-09-07 |
| CN104334586B (zh) | 2017-05-31 |
| KR101975179B1 (ko) | 2019-05-07 |
| JP2015517600A (ja) | 2015-06-22 |
| KR20150013863A (ko) | 2015-02-05 |
| BR112014028776B1 (pt) | 2021-02-09 |
| BR112014028776A2 (pt) | 2017-06-27 |
| CA2870653A1 (en) | 2013-11-28 |
| PH12014502611A1 (en) | 2015-01-21 |
| RU2014151609A (ru) | 2016-07-10 |
| MX2014014249A (es) | 2016-02-05 |
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