ES2617228T3 - Componentes catalizadores para la polimerización de olefinas - Google Patents

Componentes catalizadores para la polimerización de olefinas Download PDF

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Publication number
ES2617228T3
ES2617228T3 ES12770490.6T ES12770490T ES2617228T3 ES 2617228 T3 ES2617228 T3 ES 2617228T3 ES 12770490 T ES12770490 T ES 12770490T ES 2617228 T3 ES2617228 T3 ES 2617228T3
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ES
Spain
Prior art keywords
polymerization
olefins
groups
catalyst components
bicyclo
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
ES12770490.6T
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English (en)
Inventor
Ilya Nifant'ev
Alessandro Mignogna
Vladimir Bagrov
Simona Esposito
Simona Guidotti
Giampiero Morini
Joachim T. M. Pater
Fabrizio Piemontesi
Sophia A. Toloraya
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Poliolefine Italia SRL
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Basell Poliolefine Italia SRL
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Publication date
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Publication of ES2617228T3 publication Critical patent/ES2617228T3/es
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/647—Catalysts containing a specific non-metal or metal-free compound
    • C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
    • C08F4/6498—Catalysts containing a specific non-metal or metal-free compound organic containing another heteroatom
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

Un componente catalizador sólido para la polimerización de olefinas que comprende Mg, Ti y un compuesto donador de electrones de la siguiente fórmula (I)**Fórmula** donde los grupos R1 a R12, iguales o diferentes entre sí, son hidrógeno, halógeno o grupos hidrocarburo C1-C15 que contienen, opcionalmente, un heteroátomo seleccionado de halógeno, P, S, O, N y Si, los grupos R iguales o diferentes entre sí son grupos hidrocarburo C1-C15 y los grupos carboxilato están en transconfiguración entre sí.

Description

imagen1
imagen2
imagen3
imagen4
imagen5
Tabla 1. Composición y rendimiento de catalizadores ejemplares en la polimerización de propileno
Ej.
Nombre del donador interno Ti % en peso Kilometr aje kg/g XI % en peso MIL g/10 '
% en peso
1
Trans-biciclo[2.2.2]octano-2,3-dicarboxilato de dietilo 9,7 2,6 69 98,4 4,3
2
Trans-biciclo[2.2.2]octano-2,3-dicarboxilato de diisobutilo 15,8 3,3 76 97,8 6,8
3
1-isopropil-4-metill trans-biciclo[2.2.2]octano-2,3-dicarboxilato de dietilo 18,5 3,2 41 96,6 4,2
4
5-isopropil-7-metil trans-biciclo[2.2.2]octano-2,3-dicarboxilato de dietilo 11,0 2,9 53 97,9 3,4
5
5-isopropil-7-metilo trans-biciclo[2.2.2]octano-2,3-dicarboxilato de diisobutilo 14,2 3,1 40 96,9 6,2
6
1,4-dimetil trans-biciclo[2.2.2]octano-2,3-dicarboxilato de dietilo 21,1 2,7 25 97,4 3,2
C1
Cis-biciclo[2.2.2]octano-2,3-di-carboxilato de dietilo 6,3 3,2 9 94,8 12,2
C2
endo-,exo-biciclo[2.2.1]hept-5-eno-2,3-di-carboxilato de dietilo ND 3,4 13 94,7 ND
C3
endo-,endo-biciclo[2.2.1]hept-5-eno-2,3-di-carboxilato de dietilo ND 3,3 14 96,0 ND
C4
endo-,exo-biciclo[2.2.1]heptano-2,3-di-carboxilato de dietilo 13,4 3,2 16 95,3 7,2
C5
endo-,endo-biciclo[2.2.1]heptano-2,3-di-carboxilato de dietilo 4,6 3,4 27 95,6 1,3
N.D. sin datos
Tabla 2. Composición y rendimiento de catalizadores ejemplares en la polimerización de 1-buteno
Ej.
Nombre del donador interno Ti % en peso Kilometraje kg/g XI % en peso IV dL/g
% en peso
7
trans-biciclo[2.2.2]octano-2,3-dicarboxilato de dietilo 9,7 2,6 42 98,1 1,82
7

Claims (1)

  1. imagen1
ES12770490.6T 2011-10-19 2012-10-11 Componentes catalizadores para la polimerización de olefinas Active ES2617228T3 (es)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201161549127P 2011-10-19 2011-10-19
EP11185721 2011-10-19
EP11185721.5A EP2583983A1 (en) 2011-10-19 2011-10-19 Catalyst component for the polymerization of olefins
US201161549127P 2011-10-19
PCT/EP2012/070136 WO2013057036A1 (en) 2011-10-19 2012-10-11 Catalyst components for the polymerization of olefins

Publications (1)

Publication Number Publication Date
ES2617228T3 true ES2617228T3 (es) 2017-06-15

Family

ID=44862588

Family Applications (1)

Application Number Title Priority Date Filing Date
ES12770490.6T Active ES2617228T3 (es) 2011-10-19 2012-10-11 Componentes catalizadores para la polimerización de olefinas

Country Status (6)

Country Link
US (1) US20140243489A1 (es)
EP (2) EP2583983A1 (es)
CN (1) CN104245750B (es)
BR (1) BR112014008878A2 (es)
ES (1) ES2617228T3 (es)
WO (1) WO2013057036A1 (es)

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DK133012C (da) 1968-11-21 1976-08-09 Montedison Spa Katalysator til polymerisation af alkener
YU35844B (en) 1968-11-25 1981-08-31 Montedison Spa Process for obtaining catalysts for the polymerization of olefines
GB1603724A (en) 1977-05-25 1981-11-25 Montedison Spa Components and catalysts for the polymerisation of alpha-olefins
IT1096661B (it) 1978-06-13 1985-08-26 Montedison Spa Procedimento per la preparazione di prodotti in forma sferoidale solidi a temperatura ambiente
IT1098272B (it) 1978-08-22 1985-09-07 Montedison Spa Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine
US4617284A (en) * 1984-06-04 1986-10-14 Mitsubishi Petrochemical Company, Limited Catalyst component for polymerization of olefins and process for production thereof
IT1230134B (it) 1989-04-28 1991-10-14 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine.
IT1262935B (it) 1992-01-31 1996-07-22 Montecatini Tecnologie Srl Componenti e catalizzatori per la polimerizzazione di olefine
IT1262934B (it) 1992-01-31 1996-07-22 Montecatini Tecnologie Srl Componenti e catalizzatori per la polimerizzazione di olefine
IT1256648B (it) 1992-12-11 1995-12-12 Montecatini Tecnologie Srl Componenti e catalizzatori per la polimerizzazione delle olefine
AUPO591797A0 (en) 1997-03-27 1997-04-24 Commonwealth Scientific And Industrial Research Organisation High avidity polyvalent and polyspecific reagents
AU736901B2 (en) 1997-03-29 2001-08-02 Montell Technology Company B.V. "Magnesium dichloride-alcohol adducts, process for their preparation and catalyst components obtained therefrom"
EP1613670B1 (en) 2003-03-26 2017-05-10 Ineos Technologies USA LLC Olefin polymerisation catalyst component containing a bicyclic cycloakane dicarboxylate as electron donor
TWI315317B (en) 2005-01-19 2009-10-01 Mitsui Chemicals Inc Solid titanium catalyst component, catalyst for polymerization of olefin and process for producing olefin polymer
KR20100066612A (ko) 2008-12-10 2010-06-18 삼성토탈 주식회사 올레핀 중합 또는 공중합용 촉매, 이의 제조 방법 및 이를 이용한 올레핀의 중합 또는 공중합 방법

Also Published As

Publication number Publication date
CN104245750A (zh) 2014-12-24
WO2013057036A1 (en) 2013-04-25
US20140243489A1 (en) 2014-08-28
EP2771371A1 (en) 2014-09-03
EP2771371B1 (en) 2016-12-07
CN104245750B (zh) 2018-02-23
BR112014008878A2 (pt) 2017-06-13
EP2583983A1 (en) 2013-04-24

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