ES2612352T3 - Formulations, their use as or for the preparation of dishwashing detergents and their preparation - Google Patents
Formulations, their use as or for the preparation of dishwashing detergents and their preparation Download PDFInfo
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- ES2612352T3 ES2612352T3 ES13717782.0T ES13717782T ES2612352T3 ES 2612352 T3 ES2612352 T3 ES 2612352T3 ES 13717782 T ES13717782 T ES 13717782T ES 2612352 T3 ES2612352 T3 ES 2612352T3
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- 239000000203 mixture Substances 0.000 title abstract description 21
- 238000009472 formulation Methods 0.000 title abstract description 19
- 238000004851 dishwashing Methods 0.000 title description 2
- 239000003599 detergent Substances 0.000 title 1
- 125000004433 nitrogen atom Chemical group N* 0.000 abstract description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 4
- PQHYOGIRXOKOEJ-UHFFFAOYSA-N 2-(1,2-dicarboxyethylamino)butanedioic acid Chemical compound OC(=O)CC(C(O)=O)NC(C(O)=O)CC(O)=O PQHYOGIRXOKOEJ-UHFFFAOYSA-N 0.000 abstract 2
- PDIZYYQQWUOPPK-UHFFFAOYSA-N acetic acid;2-(methylamino)acetic acid Chemical compound CC(O)=O.CC(O)=O.CNCC(O)=O PDIZYYQQWUOPPK-UHFFFAOYSA-N 0.000 abstract 2
- LELOWRISYMNNSU-UHFFFAOYSA-N hydrogen cyanide Chemical compound N#C LELOWRISYMNNSU-UHFFFAOYSA-N 0.000 abstract 2
- 229920000642 polymer Polymers 0.000 abstract 2
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical compound NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 abstract 1
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 abstract 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 abstract 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 abstract 1
- 235000013922 glutamic acid Nutrition 0.000 abstract 1
- 239000004220 glutamic acid Substances 0.000 abstract 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 abstract 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 239000011521 glass Substances 0.000 description 15
- -1 Nchlorosulfamide Chemical compound 0.000 description 8
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 8
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 8
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 6
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 239000007844 bleaching agent Substances 0.000 description 6
- 238000005260 corrosion Methods 0.000 description 6
- 230000007797 corrosion Effects 0.000 description 6
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 6
- 239000005639 Lauric acid Substances 0.000 description 4
- 229920002873 Polyethylenimine Polymers 0.000 description 4
- 238000004061 bleaching Methods 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 4
- 235000019253 formic acid Nutrition 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- 229910017052 cobalt Inorganic materials 0.000 description 3
- 239000010941 cobalt Substances 0.000 description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 3
- 239000003112 inhibitor Substances 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229910052707 ruthenium Inorganic materials 0.000 description 3
- 229940005605 valeric acid Drugs 0.000 description 3
- QDHHCQZDFGDHMP-UHFFFAOYSA-N Chloramine Chemical compound ClN QDHHCQZDFGDHMP-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 2
- 239000012190 activator Substances 0.000 description 2
- 239000002518 antifoaming agent Substances 0.000 description 2
- GGNQRNBDZQJCCN-UHFFFAOYSA-N benzene-1,2,4-triol Chemical compound OC1=CC=C(O)C(O)=C1 GGNQRNBDZQJCCN-UHFFFAOYSA-N 0.000 description 2
- 238000010411 cooking Methods 0.000 description 2
- 238000007306 functionalization reaction Methods 0.000 description 2
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 description 2
- FRPJTGXMTIIFIT-UHFFFAOYSA-N tetraacetylethylenediamine Chemical compound CC(=O)C(N)(C(C)=O)C(N)(C(C)=O)C(C)=O FRPJTGXMTIIFIT-UHFFFAOYSA-N 0.000 description 2
- 229910052723 transition metal Inorganic materials 0.000 description 2
- KEQGZUUPPQEDPF-UHFFFAOYSA-N 1,3-dichloro-5,5-dimethylimidazolidine-2,4-dione Chemical compound CC1(C)N(Cl)C(=O)N(Cl)C1=O KEQGZUUPPQEDPF-UHFFFAOYSA-N 0.000 description 1
- ZGZHWIAQICBGKN-UHFFFAOYSA-N 1-nonanoylpyrrolidine-2,5-dione Chemical compound CCCCCCCCC(=O)N1C(=O)CCC1=O ZGZHWIAQICBGKN-UHFFFAOYSA-N 0.000 description 1
- JSIAIROWMJGMQZ-UHFFFAOYSA-N 2h-triazol-4-amine Chemical class NC1=CNN=N1 JSIAIROWMJGMQZ-UHFFFAOYSA-N 0.000 description 1
- 101100345345 Arabidopsis thaliana MGD1 gene Proteins 0.000 description 1
- ZKQDCIXGCQPQNV-UHFFFAOYSA-N Calcium hypochlorite Chemical compound [Ca+2].Cl[O-].Cl[O-] ZKQDCIXGCQPQNV-UHFFFAOYSA-N 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 1
- 241000238634 Libellulidae Species 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 239000005708 Sodium hypochlorite Substances 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- WFACTXCBWPYESL-UHFFFAOYSA-N acetonitrile;4-methylmorpholine Chemical class CC#N.CN1CCOCC1 WFACTXCBWPYESL-UHFFFAOYSA-N 0.000 description 1
- GHDBLWVVUWTQCG-UHFFFAOYSA-N acetonitrile;n,n-dimethylmethanamine Chemical class CC#N.CN(C)C GHDBLWVVUWTQCG-UHFFFAOYSA-N 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 239000012080 ambient air Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 150000001565 benzotriazoles Chemical class 0.000 description 1
- 239000005388 borosilicate glass Substances 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 150000001879 copper Chemical class 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- FCFDNBCKGVPNOG-UHFFFAOYSA-N cyanomethyl(trimethyl)azanium Chemical class C[N+](C)(C)CC#N FCFDNBCKGVPNOG-UHFFFAOYSA-N 0.000 description 1
- CEJLBZWIKQJOAT-UHFFFAOYSA-N dichloroisocyanuric acid Chemical compound ClN1C(=O)NC(=O)N(Cl)C1=O CEJLBZWIKQJOAT-UHFFFAOYSA-N 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 229940074391 gallic acid Drugs 0.000 description 1
- 235000004515 gallic acid Nutrition 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 239000005355 lead glass Substances 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- YZQBYALVHAANGI-UHFFFAOYSA-N magnesium;dihypochlorite Chemical compound [Mg+2].Cl[O-].Cl[O-] YZQBYALVHAANGI-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 150000002751 molybdenum Chemical class 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- QCDYQQDYXPDABM-UHFFFAOYSA-N phloroglucinol Chemical compound OC1=CC(O)=CC(O)=C1 QCDYQQDYXPDABM-UHFFFAOYSA-N 0.000 description 1
- 150000003009 phosphonic acids Chemical class 0.000 description 1
- SATVIFGJTRRDQU-UHFFFAOYSA-N potassium hypochlorite Chemical compound [K+].Cl[O-] SATVIFGJTRRDQU-UHFFFAOYSA-N 0.000 description 1
- IFIDXBCRSWOUSB-UHFFFAOYSA-N potassium;1,3-dichloro-1,3,5-triazinane-2,4,6-trione Chemical compound [K+].ClN1C(=O)NC(=O)N(Cl)C1=O IFIDXBCRSWOUSB-UHFFFAOYSA-N 0.000 description 1
- 229940079877 pyrogallol Drugs 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
- OHOTVSOGTVKXEL-UHFFFAOYSA-K trisodium;2-[bis(carboxylatomethyl)amino]propanoate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C(C)N(CC([O-])=O)CC([O-])=O OHOTVSOGTVKXEL-UHFFFAOYSA-K 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3723—Polyamines or polyalkyleneimines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3788—Graft polymers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/02—Preparation in the form of powder by spray drying
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
Formulación que contiene (A) en total en el intervalo del 1 % al 50 % en peso al menos de un aminocarboxilato, seleccionado de diacetato de metilglicina (MGDA), ácido iminodisuccínico (IDS) y diacetato de ácido glutámico (GLDA) así como sus sales, (B) en total en el intervalo 5 del 0,001 % al 5 % en peso al menos de un polímero de alquilenimina, que está modificado de manera covalente con al menos un ácido carboxílico o al menos un derivado de un ácido carboxílico o al menos un derivado de ácido carbónico, habiendo reaccionado hasta como máximo el 75 % en moles de los átomos de nitrógeno de los grupos amino primarios y secundarios del polímero de alquilenimina con ácido carboxílico o bien derivado de ácido carboxílico o bien ácido carbónico o con ácido cianhídrico y formaldehído, con respecto en cada caso al contenido de sólidos de la respectiva formulación.Formulation containing (A) in total in the range of 1% to 50% by weight at least of one aminocarboxylate, selected from methylglycine diacetate (MGDA), iminodisuccinic acid (IDS) and glutamic acid diacetate (GLDA) as well as its salts, (B) in total in the range 5 from 0.001% to 5% by weight of at least one alkyleneimine polymer, which is covalently modified with at least one carboxylic acid or at least one derivative of a carboxylic acid or at less a derivative of carbonic acid, having reacted up to a maximum of 75 mol% of the nitrogen atoms of the primary and secondary amino groups of the alkyleneimine polymer with carboxylic acid or derived from carboxylic acid or carbonic acid or with hydrocyanic acid and formaldehyde, with respect in each case to the solids content of the respective formulation.
Description
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Las formulaciones de acuerdo con la invención pueden contener además de agentes blanqueadores (D) uno o varios agentes blanqueadores que contienen cloro. The formulations according to the invention may contain in addition to bleaching agents (D) one or more bleaching agents containing chlorine.
Los agentes blanqueadores que contienen cloro adecuados son por ejemplo 1,3-dicloro-5,5-dimetilhidantoína, Nclorosulfamida, cloroamina T, cloroamina B, hipoclorito de sodio, hipoclorito de calcio, hipoclorito de magnesio, hipoclorito de potasio, dicloroisocianurato de potasio y dicloroisocianurato de sodio. Suitable chlorine-containing bleaching agents are, for example, 1,3-dichloro-5,5-dimethylhydantoin, Nchlorosulfamide, chloroamine T, chloroamine B, sodium hypochlorite, calcium hypochlorite, magnesium hypochlorite, potassium hypochlorite, potassium dichloroisocyanurate and sodium dichloroisocyanurate.
Las formulaciones de acuerdo con la invención pueden contener agentes blanqueadores que contienen cloro por ejemplo en el intervalo del 3 % al 10 % en peso. The formulations according to the invention may contain bleaching agents containing chlorine, for example in the range of 3% to 10% by weight.
Las formulaciones de acuerdo con la invención pueden contener uno o varios catalizadores de blanqueo. Los catalizadores de blanqueo pueden seleccionarse de sales de metales de transición o complejos de metales de transición que refuerzan el blanqueo, tales como por ejemplo complejos de carbonilo o complejos de sales de manganeso, hierro, cobalto, rutenio o molibdeno. Pueden usarse como catalizadores de blanqueo también complejos de manganeso, hierro, cobalto, rutenio, molibdeno, titanio, vanadio y cobre con ligandos tipo trípode que contienen nitrógeno así como complejos de amino de cobalto, hierro, cobre y rutenio. The formulations according to the invention may contain one or more bleaching catalysts. The bleaching catalysts can be selected from transition metal salts or transition metal complexes that reinforce bleaching, such as for example carbonyl complexes or complexes of manganese, iron, cobalt, ruthenium or molybdenum salts. Manganese, iron, cobalt, ruthenium, molybdenum, titanium, vanadium and copper complexes with nitrogen-containing tripod ligands as well as cobalt, iron, copper and ruthenium amino complexes can also be used as bleaching catalysts.
Las formulaciones de acuerdo con la invención pueden contener uno o varios activadores de blanqueo, por ejemplo sales de N-metilmorfolinio-acetonitrilo (“sales de MMA”), sales de trimetilamonioacetonitrilo, N-acilimidas tales como por ejemplo N-nonanoilsuccinimida, 1,5-diacetil-2,2-dioxo-hexahidro-1,3,5-triazina (“DADHT”) o nitrilquats (sales de trimetilamonioacetonitrilo). The formulations according to the invention may contain one or more bleach activators, for example N-methylmorpholinium-acetonitrile salts ("MMA salts"), trimethylammonioacetonitrile salts, N-acylimides such as for example N-nonanoylsuccinimide, 1, 5-diacetyl-2,2-dioxo-hexahydro-1,3,5-triazine ("DADHT") or nitrilquats (trimethylammonium acetonitrile salts).
Otros ejemplos de activadores de blanqueo adecuados son tetraacetiletilendiamina (TAED) y tetraacetilhexilendiamina. Other examples of suitable bleach activators are tetraacetylethylenediamine (TAED) and tetraacetylhexylenediamine.
Las formulaciones de acuerdo con la invención pueden contener uno o varios inhibidores de la corrosión. Por esto ha de entenderse en el presente caso aquellos compuestos que inhiben la corrosión de metal. Ejemplos de inhibidores de la corrosión adecuados son triazoles, en particular benzotriazoles, bisbenzotriazoles, aminotriazoles, alquilaminotriazoles, además derivados de fenol tales como por ejemplo hidroquinona, brenzcatequina, hidroxihidroquinona, ácido gálico, floroglucina o pirogalol. The formulations according to the invention may contain one or more corrosion inhibitors. This is to be understood in the present case those compounds that inhibit metal corrosion. Examples of suitable corrosion inhibitors are triazoles, in particular benzotriazoles, bisbenzotriazoles, aminotriazoles, alkylaminotriazoles, in addition to phenol derivatives such as for example hydroquinone, brenzcatechin, hydroxyhydroquinone, gallic acid, floroglucin or pyrogallol.
En una forma de realización de la presente invención, las formulaciones de acuerdo con la invención contienen inhibidores de la corrosión en total en el intervalo del 0,1 % al 1,5 % en peso. In one embodiment of the present invention, the formulations according to the invention contain corrosion inhibitors in total in the range of 0.1% to 1.5% by weight.
Las formulaciones de acuerdo con la invención pueden contener una o varias sustancias soporte, por ejemplo sulfato de sodio. The formulations according to the invention may contain one or more support substances, for example sodium sulfate.
Las formulaciones de acuerdo con la invención pueden contener uno o varios agentes desespumantes, seleccionados por ejemplo de aceites de silicona y aceites de parafina. The formulations according to the invention may contain one or more defoaming agents, selected for example from silicone oils and paraffin oils.
En una forma de realización de la presente invención, las formulaciones de acuerdo con la invención contienen agentes desespumantes en total en el intervalo del 0,05 % al 0,5 % en peso. In one embodiment of the present invention, the formulations according to the invention contain defoaming agents in total in the range of 0.05% to 0.5% by weight.
Las formulaciones de acuerdo con la invención pueden contener ácido fosfónico o uno o varios derivados de ácido fosfónico, por ejemplo ácido hidroxietano-1,1-difosfónico. The formulations according to the invention may contain phosphonic acid or one or more derivatives of phosphonic acid, for example hydroxyethane-1,1-diphosphonic acid.
Otro objeto de la presente invención es el uso de formulaciones de acuerdo con la invención para la limpieza a máquina de la vajilla y utensilios de cocina. Como utensilios de cocina han de mencionarse en el contexto de la presente invención por ejemplo ollas, sartenes, cacerolas, además objetos metálicos tales como por ejemplo espumaderas, espátulas y prensaajos. Another object of the present invention is the use of formulations according to the invention for the machine cleaning of crockery and kitchen utensils. As cooking utensils, in the context of the present invention, for example, pots, pans, pans, and also metal objects such as skimmers, spatulas and grommets should be mentioned.
Se prefiere el uso de formulaciones de acuerdo con la invención para la limpieza a máquina de objetos que presentan al menos una superficie de vidrio, que puede estar decorada o no decorada. A este respecto ha de entenderse por una superficie de vidrio en el contexto de la presente invención que el objeto en cuestión presenta al menos una pieza de vidrio, que entra en contacto con el aire ambiente y puede ensuciarse con el uso del objeto. Así, en el caso de los objetos en cuestión puede tratarse de aquéllos que esencialmente son vidriosos, tales como vasos The use of formulations according to the invention for machine cleaning of objects having at least one glass surface, which may be decorated or not decorated, is preferred. In this regard, it should be understood by a glass surface in the context of the present invention that the object in question has at least one piece of glass, which comes into contact with the ambient air and can become dirty with the use of the object. Thus, in the case of the objects in question, they may be those that are essentially glassy, such as vessels
o cuencos de vidrio. Sin embargo puede tratarse también por ejemplo de tapaderas, que presentan componentes individuales de otro material, por ejemplo tapaderas de olla con borde y asa de metal. or glass bowls. However, it can also be covers, for example, which have individual components of another material, for example pot covers with a metal edge and handle.
La superficie de vidrio puede estar decorada, por ejemplo coloreada o impresa, o no decorada. The glass surface may be decorated, for example colored or printed, or not decorated.
Por el término “vidrio” se subsuma cualquier vidrio, por ejemplo vidrio de plomo y en particular vidrio de cal y sosa, vidrio de cristal y vidrios de borosilicato. By the term "glass" any glass is subsumed, for example lead glass and in particular lime and soda glass, glass glass and borosilicate glasses.
Preferentemente, en el caso de la limpieza a máquina se trata de un lavado con una máquina lavavajillas (inglés: “automatic dishwashing”). Preferably, in the case of machine cleaning it is a washing with a dishwasher (English: "automatic dishwashing").
En una forma de realización de la presente invención se usa al menos una formulación de acuerdo con la invención para la limpieza a máquina de vasos, jarrones de vidrio y recipientes de vidrio para cocinar. In one embodiment of the present invention at least one formulation according to the invention is used for the machine cleaning of glasses, glass vases and glass cooking containers.
9 9
Tabla 2: polietileniminas modificadas Table 2: modified polyethyleneimines
- Abreviatura Abbreviation
- Mw (g/mol) Modificación con Funcionalización (% en mol) Densidad de carga catiónica (meq/g) Mw (g / mol) Modification with Functionalization (% in mol) Cationic charge density (meq / g)
- B.1.1.1 B.1.1.1
- 800 ácido acrílico 5 15 800 acrylic acid 5 fifteen
- B.1.1.2 B.1.1.2
- 800 ácido acrílico 20 11 800 acrylic acid twenty eleven
- B.1.1.3 B.1.1.3
- 800 ácido acrílico 40 7 800 acrylic acid 40 7
- B.1.2.1 B.1.2.1
- 2000 ácido acrílico 15 12 2000 acrylic acid fifteen 12
- B.1.3.1 B.1.3.1
- 5000 ácido acrílico 15 13 5000 acrylic acid fifteen 13
- B.1.4.1 B.1.4.1
- 50.000 ácido acrílico 15 11,5 50,000 acrylic acid fifteen 11.5
- B.2.1.1 B.2.1.1
- 800 nitrilo de ácido fórmico 20 12 800 formic acid nitrile twenty 12
- B.2.2.2 B.2.2.2
- 2000 nitrilo de ácido fórmico 15 11 2000 formic acid nitrile fifteen eleven
- B.2.3.3 B.2.3.3
- 5000 nitrilo de ácido fórmico 25 9 5000 formic acid nitrile 25 9
- B.2.4.4 B.2.4.4
- 50.000 nitrilo de ácido fórmico 10 14 50,000 formic acid nitrile 10 14
- B.3.1.1 B.3.1.1
- 800 ácido valérico 10 16 800 valeric acid 10 16
- B.3.2.2 B.3.2.2
- 2000 ácido valérico 40 9 2000 valeric acid 40 9
- B.3.3.3 B.3.3.3
- 5000 ácido valérico 15 14 5000 valeric acid fifteen 14
- B.4.1.1 B.4.1.1
- 800 ácido láurico 5 18 800 lauric acid 5 18
- B.4.1.2 B.4.1.2
- 800 ácido láurico 15 14,5 800 lauric acid fifteen 14.5
- B.4.2.3 B.4.2.3
- 2000 ácido láurico 20 12,5 2000 lauric acid twenty 12.5
- B.4.3.3 B.4.3.3
- 5000 ácido láurico 20 12 5000 lauric acid twenty 12
- B.5.1.1 B.5.1.1
- 800 carbonato de etileno 10 16 800 ethylene carbonate 10 16
- B.5.1.2 B.5.1.2
- 800 carbonato de etileno 20 13 800 ethylene carbonate twenty 13
- B.5.1.3 B.5.1.3
- 800 carbonato de etileno 50 9 800 ethylene carbonate fifty 9
- B.5.2.4 B.5.2.4
- 2000 carbonato de etileno 15 11,5 2000 ethylene carbonate fifteen 11.5
- B.5.3.2 B.5.3.2
- 5000 carbonato de etileno 20 12,5 5000 ethylene carbonate twenty 12.5
- B.5.4.1 B.5.4.1
- 50.000 carbonato de etileno 10 14,5 50,000 ethylene carbonate 10 14.5
El peso molar Mw se determinó en las polietileniminas subyacentes, o sea en cada caso antes de la modificación. La funcionalización se refiere a la suma de los átomos de N primarios y secundarios en la respectiva polietilenimina. The molar weight Mw was determined in the underlying polyethyleneimines, that is in each case before the modification. Functionalization refers to the sum of the primary and secondary N atoms in the respective polyethyleneimine.
5 Modo de proceder: 5 Procedure:
En un vaso de precipitados de 100 ml se dispusieron 20 ml de agua destilada y se añadió polietilenimina modificada 20 ml of distilled water were placed in a 100 ml beaker and modified polyethyleneimine was added
(B) de acuerdo con las tablas 2 y 3 con agitación. Entonces se agitó durante 10 minutos. A continuación se añadió sal de trisodio de MGDA (A.1), disuelta en 30 ml de agua, de acuerdo con la tabla 3. Se obtuvo una disolución clara transparente. Después se añadió la mezcla base de acuerdo con la tabla 3, se agitó de nuevo y se evaporó el agua. (B) according to tables 2 and 3 with agitation. Then it was stirred for 10 minutes. Next, MGDA trisodium salt (A.1), dissolved in 30 ml of water, was added according to Table 3. A clear clear solution was obtained. The base mixture was then added according to table 3, stirred again and the water evaporated.
10 Cuando se dosificaron durante el ensayo las correspondientes proporciones de la mezcla base separadas de la disolución acuosa de (A.1), (B), (C.1) o (D.1), se obtuvieron los mismos resultados que cuando se sometió a prueba la formulación secada con las mismas cantidades de principios activos. Por tanto no depende del orden de la 10 When the corresponding proportions of the base mixture separated from the aqueous solution of (A.1), (B), (C.1) or (D.1) were dosed during the test, the same results were obtained as when tested the dried formulation with the same amounts of active ingredients. Therefore it does not depend on the order of the
12 12
II.3 Resultados Los resultados están resumidos en las tablas 2 y 3. Pudo determinarse en los ejemplos de acuerdo con la invención sólo baja o incluso ninguna corrosión de vidrio. Si en lugar de agua se usó agua dura con 2 ºdH para los ensayos, entonces las formulaciones de acuerdo con la II.3 Results The results are summarized in Tables 2 and 3. It can be determined in the examples according to the invention only low or even no glass corrosion. If, instead of water, hard water with 2dH was used for the tests, then the formulations according to the
invención eran igualmente siempre superiores a las correspondientes formulaciones de comparación, en cuanto a la inhibición de la corrosión de vidrio. The invention was also always superior to the corresponding comparison formulations, in terms of glass corrosion inhibition.
14 14
15 fifteen
Claims (1)
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| Application Number | Priority Date | Filing Date | Title |
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| EP12165550 | 2012-04-25 | ||
| EP12165550 | 2012-04-25 | ||
| EP12168038 | 2012-05-15 | ||
| EP12168038 | 2012-05-15 | ||
| PCT/EP2013/058311 WO2013160259A1 (en) | 2012-04-25 | 2013-04-22 | Formulations, use thereof as or for production of dishwashing detergents and production thereof |
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| ES2612352T3 true ES2612352T3 (en) | 2017-05-16 |
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| EP (1) | EP2841548B1 (en) |
| JP (1) | JP6162791B2 (en) |
| KR (1) | KR20150013590A (en) |
| CN (1) | CN104284971B (en) |
| BR (1) | BR112014026564A2 (en) |
| CA (1) | CA2870785A1 (en) |
| ES (1) | ES2612352T3 (en) |
| MX (1) | MX2014013010A (en) |
| PL (1) | PL2841548T3 (en) |
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| WO (1) | WO2013160259A1 (en) |
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| PL2989192T3 (en) * | 2013-04-23 | 2019-01-31 | Basf Se | Formulations, use of same as or for manufacture of dish-washing agents and their manufacture |
| GB201409632D0 (en) * | 2014-05-30 | 2014-07-16 | Reckitt Benckiser Brands Ltd | Improved detergent composition |
| ES2670687T3 (en) * | 2014-06-23 | 2018-05-31 | Basf Se | Formulations, their use as or for the preparation of dishwashing agents and their preparation |
| EP3026103B1 (en) * | 2014-11-26 | 2018-07-25 | The Procter and Gamble Company | Cleaning pouch |
| MX2017006900A (en) * | 2014-11-26 | 2018-06-06 | Basf Se | Aqueous solution containing combination of complexing agents. |
| BR112018000250A2 (en) * | 2015-07-09 | 2018-09-04 | Basf Se | process for cleaning greasy soiled dishes, and formulating |
| CN109477065A (en) | 2016-07-14 | 2019-03-15 | 巴斯夫欧洲公司 | Fermentation medium comprising chelating agent |
| CN116583584A (en) * | 2020-12-07 | 2023-08-11 | 联合利华知识产权控股有限公司 | Detergent composition |
| WO2023285064A1 (en) | 2021-07-14 | 2023-01-19 | Basf Se | Liquid phosphate-free detergent composition for the reduction of microfiber release |
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| EP0892848B1 (en) * | 1996-04-09 | 2002-12-18 | JohnsonDiversey, Inc. | Anti-etch bottle washing solution |
| US5837663A (en) | 1996-12-23 | 1998-11-17 | Lever Brothers Company, Division Of Conopco, Inc. | Machine dishwashing tablets containing a peracid |
| CA2296719A1 (en) * | 1997-07-23 | 1999-02-04 | Joseph Oreste Carnali | Automatic dishwashing compositions containing water soluble cationic or amphoteric polymers |
| DE19819187A1 (en) | 1998-04-30 | 1999-11-11 | Henkel Kgaa | Solid dishwasher detergent with phosphate and crystalline layered silicates |
| JP4015778B2 (en) * | 1999-06-17 | 2007-11-28 | ディバーシー・アイピー・インターナショナル・ビー・ヴイ | Liquid detergent composition for dishwashers |
| AU2000254879A1 (en) | 2000-06-14 | 2001-12-24 | The Procter And Gamble Company | Process for cleaning a surface |
| DE10104469A1 (en) | 2001-02-01 | 2002-08-08 | Basf Ag | Copolymers to prevent glass corrosion |
| JP4005855B2 (en) * | 2002-04-01 | 2007-11-14 | 株式会社日本触媒 | Detergent composition |
| US7196044B2 (en) * | 2003-07-02 | 2007-03-27 | Ecolab, Inc. | Warewashing composition for use in automatic dishwashing machines, comprising a zinc ion and aluminum ion corrosion inhibitor |
| JP4942284B2 (en) * | 2003-09-26 | 2012-05-30 | 株式会社日本触媒 | Polyalkyleneimine derivatives and uses thereof |
| DE102004005010A1 (en) * | 2004-01-30 | 2005-08-18 | Basf Ag | Polymer for the treatment of surfaces |
| EP1769092A4 (en) | 2004-06-29 | 2008-08-06 | Europ Nickel Plc | Improved leaching of base metals |
| JP5025097B2 (en) * | 2005-06-02 | 2012-09-12 | ディバーシー・アイピー・インターナショナル・ビー・ヴイ | Liquid detergent composition for automatic washing machine |
| EP1945746B1 (en) * | 2005-11-09 | 2010-02-10 | Ecolab Inc. | Composition with surface modifying properties |
| JP5213091B2 (en) * | 2006-08-22 | 2013-06-19 | ディバーシー株式会社 | Granular detergent composition for automatic dishwasher, method for producing the same, and method for using the same |
| UA103760C2 (en) * | 2008-01-24 | 2013-11-25 | Юнилевер Н.В. | Machine dishwash detergent composition |
| EP2083067A1 (en) * | 2008-01-25 | 2009-07-29 | Basf Aktiengesellschaft | Use of organic complexing agents and/or polymeric compounds containing carbonic acid groups in a liquid washing or cleaning agent compound |
| WO2010000020A1 (en) | 2008-06-30 | 2010-01-07 | Cathrx Ltd | A catheter |
| GB0815022D0 (en) * | 2008-08-16 | 2008-09-24 | Reckitt Benckiser Nv | Composition |
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- 2013-04-22 KR KR1020147032912A patent/KR20150013590A/en not_active Application Discontinuation
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- 2013-04-22 CN CN201380022145.5A patent/CN104284971B/en not_active Expired - Fee Related
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| KR20150013590A (en) | 2015-02-05 |
| CA2870785A1 (en) | 2013-10-31 |
| MX2014013010A (en) | 2015-08-06 |
| JP2015519428A (en) | 2015-07-09 |
| EP2841548A1 (en) | 2015-03-04 |
| CN104284971B (en) | 2017-08-08 |
| JP6162791B2 (en) | 2017-07-12 |
| EP2841548B1 (en) | 2016-10-26 |
| RU2629112C2 (en) | 2017-08-24 |
| BR112014026564A2 (en) | 2017-06-27 |
| CN104284971A (en) | 2015-01-14 |
| PL2841548T3 (en) | 2017-04-28 |
| RU2014147080A (en) | 2016-06-10 |
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