ES2608681T3 - Procedimiento para la preparación de hidratos de parawolframato de amonio y parawolframato de amonio decahidrato - Google Patents
Procedimiento para la preparación de hidratos de parawolframato de amonio y parawolframato de amonio decahidrato Download PDFInfo
- Publication number
- ES2608681T3 ES2608681T3 ES08708312.7T ES08708312T ES2608681T3 ES 2608681 T3 ES2608681 T3 ES 2608681T3 ES 08708312 T ES08708312 T ES 08708312T ES 2608681 T3 ES2608681 T3 ES 2608681T3
- Authority
- ES
- Spain
- Prior art keywords
- mixer
- ammonium
- phase
- organic phase
- tungsten
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000000034 method Methods 0.000 title claims abstract description 55
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 title claims abstract description 29
- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- 150000004691 decahydrates Chemical class 0.000 title claims description 19
- 150000004677 hydrates Chemical class 0.000 title description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 110
- 239000012074 organic phase Substances 0.000 claims abstract description 62
- 238000000605 extraction Methods 0.000 claims abstract description 38
- 229910000069 nitrogen hydride Inorganic materials 0.000 claims abstract description 32
- 229910021529 ammonia Inorganic materials 0.000 claims abstract description 22
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims abstract description 21
- 229910052721 tungsten Inorganic materials 0.000 claims abstract description 20
- 239000010937 tungsten Substances 0.000 claims abstract description 20
- 239000007864 aqueous solution Substances 0.000 claims abstract description 13
- 238000004062 sedimentation Methods 0.000 claims abstract description 5
- 239000012071 phase Substances 0.000 claims description 28
- 230000008569 process Effects 0.000 claims description 23
- 239000008346 aqueous phase Substances 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 14
- 238000005191 phase separation Methods 0.000 claims description 11
- 239000007787 solid Substances 0.000 claims description 10
- 239000013078 crystal Substances 0.000 claims description 8
- 239000012452 mother liquor Substances 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- 238000000926 separation method Methods 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-O azanium;hydron;hydroxide Chemical compound [NH4+].O VHUUQVKOLVNVRT-UHFFFAOYSA-O 0.000 claims 1
- 239000000243 solution Substances 0.000 description 44
- 239000000047 product Substances 0.000 description 35
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 22
- 238000002425 crystallisation Methods 0.000 description 17
- 230000008025 crystallization Effects 0.000 description 17
- 230000015572 biosynthetic process Effects 0.000 description 12
- 239000012535 impurity Substances 0.000 description 11
- 239000002243 precursor Substances 0.000 description 9
- ZGRBQKWGELDHSV-UHFFFAOYSA-N N.[W+4] Chemical compound N.[W+4] ZGRBQKWGELDHSV-UHFFFAOYSA-N 0.000 description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- 239000012141 concentrate Substances 0.000 description 6
- 238000001704 evaporation Methods 0.000 description 6
- 230000008020 evaporation Effects 0.000 description 6
- 230000009467 reduction Effects 0.000 description 6
- 230000001105 regulatory effect Effects 0.000 description 6
- 238000000622 liquid--liquid extraction Methods 0.000 description 5
- 238000000638 solvent extraction Methods 0.000 description 5
- 238000013019 agitation Methods 0.000 description 4
- 150000001412 amines Chemical class 0.000 description 4
- 230000007246 mechanism Effects 0.000 description 4
- PLLBRTOLHQQAQQ-UHFFFAOYSA-N 8-methylnonan-1-ol Chemical compound CC(C)CCCCCCCO PLLBRTOLHQQAQQ-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 230000005526 G1 to G0 transition Effects 0.000 description 3
- DKMFARWRZBQGDG-UHFFFAOYSA-N [NH4+].O.O.O.O.O.O.O.O.O.[OH-] Chemical compound [NH4+].O.O.O.O.O.O.O.O.O.[OH-] DKMFARWRZBQGDG-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 238000009434 installation Methods 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 238000000746 purification Methods 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 150000004685 tetrahydrates Chemical class 0.000 description 3
- ZNOKGRXACCSDPY-UHFFFAOYSA-N tungsten(VI) oxide Inorganic materials O=[W](=O)=O ZNOKGRXACCSDPY-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 2
- 229910052785 arsenic Inorganic materials 0.000 description 2
- 238000004108 freeze drying Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 238000004626 scanning electron microscopy Methods 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- UNHKSXOTUHOTAB-UHFFFAOYSA-N sodium;sulfane Chemical compound [Na].S UNHKSXOTUHOTAB-UHFFFAOYSA-N 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- -1 tungsten carbides Chemical class 0.000 description 2
- YOFPVMWVLDSWKR-UHFFFAOYSA-N 11-methyl-n-(11-methyldodecyl)dodecan-1-amine Chemical compound CC(C)CCCCCCCCCCNCCCCCCCCCCC(C)C YOFPVMWVLDSWKR-UHFFFAOYSA-N 0.000 description 1
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 150000003973 alkyl amines Chemical group 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 244000309464 bull Species 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- XAYGUHUYDMLJJV-UHFFFAOYSA-Z decaazanium;dioxido(dioxo)tungsten;hydron;trioxotungsten Chemical compound [H+].[H+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O XAYGUHUYDMLJJV-UHFFFAOYSA-Z 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- VVRQVWSVLMGPRN-UHFFFAOYSA-N oxotungsten Chemical class [W]=O VVRQVWSVLMGPRN-UHFFFAOYSA-N 0.000 description 1
- 230000020477 pH reduction Effects 0.000 description 1
- 230000003071 parasitic effect Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 150000003658 tungsten compounds Chemical class 0.000 description 1
- 229910001930 tungsten oxide Inorganic materials 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G41/00—Compounds of tungsten
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G41/00—Compounds of tungsten
- C01G41/003—Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/01—Crystal-structural characteristics depicted by a TEM-image
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/60—Compounds characterised by their crystallite size
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/03—Particle morphology depicted by an image obtained by SEM
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/54—Particles characterised by their aspect ratio, i.e. the ratio of sizes in the longest to the shortest dimension
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/10—Solid density
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/11—Powder tap density
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102007005286 | 2007-02-02 | ||
| DE102007005286A DE102007005286B4 (de) | 2007-02-02 | 2007-02-02 | Verfahren zur Herstellung von Ammoniumparawolframathydraten und Ammoniumparawolframatdekahydrat |
| PCT/EP2008/050995 WO2008092837A1 (de) | 2007-02-02 | 2008-01-29 | Verfahren zur herstellung von ammoniumparawolframathydraten und ammoniumparawolframatdekahydrat |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2608681T3 true ES2608681T3 (es) | 2017-04-12 |
Family
ID=39400947
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES08708312.7T Active ES2608681T3 (es) | 2007-02-02 | 2008-01-29 | Procedimiento para la preparación de hidratos de parawolframato de amonio y parawolframato de amonio decahidrato |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US8216533B2 (enExample) |
| EP (1) | EP2118017B1 (enExample) |
| JP (1) | JP5424897B2 (enExample) |
| CN (1) | CN101600654B (enExample) |
| DE (2) | DE102007005286B4 (enExample) |
| ES (1) | ES2608681T3 (enExample) |
| PT (1) | PT2118017T (enExample) |
| WO (1) | WO2008092837A1 (enExample) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102007005285B4 (de) * | 2007-02-02 | 2009-06-25 | H.C. Starck Gmbh | Verfahren zur Herstellung von Ammoniumheptamolybdat |
| DE102007005287B4 (de) * | 2007-02-02 | 2009-10-01 | H.C. Starck Gmbh | Verfahren zur Herstellung von Ammoniumparawolframattetrahydrat und hochreines Ammoniumparawolframattetrahydrat |
| JP4797099B2 (ja) * | 2009-10-01 | 2011-10-19 | Ｊｘ日鉱日石金属株式会社 | 高純度タングステン粉末の製造方法 |
| CN203085734U (zh) | 2010-05-19 | 2013-07-24 | 法国圣戈班玻璃厂 | 混合天线构造 |
| DE212012000003U1 (de) | 2011-02-16 | 2012-09-06 | Saint-Gobain Glass France | Transparente Scheibe mit elektrischer Heizschicht |
| US9751498B2 (en) | 2011-03-22 | 2017-09-05 | Saint-Gobain Glass France | Method and arrangement for de-icing a transparent window using an electric heating device |
| CN110790312B (zh) * | 2019-11-13 | 2022-05-17 | 厦门钨业股份有限公司 | 利用含钨废料制备仲钨酸铵的方法 |
| CN111689520B (zh) * | 2020-06-17 | 2023-04-18 | 赣州有色冶金研究所有限公司 | 一种二段真空制备十水合仲钨酸铵的方法 |
| CN113816429B (zh) * | 2021-11-12 | 2023-04-18 | 江西钨业股份有限公司 | 仲钨酸铵的颗粒粗化方法 |
| CN117401715A (zh) * | 2023-11-01 | 2024-01-16 | 中南大学 | 一种从粗钨酸钠溶液制备偏钨酸铵与仲钨酸铵的方法 |
| WO2025168426A1 (en) | 2024-02-09 | 2025-08-14 | Saint-Gobain Sekurit France | Windshield with heating layer and optimized arrangement of an integrated temperature sensor |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE150962C (enExample) | ||||
| US3052516A (en) * | 1959-02-10 | 1962-09-04 | Gen Mills Inc | Process for recovering tungsten values from solution |
| DE1150962B (de) | 1959-02-10 | 1963-07-04 | Gen Mills Inc | Verfahren zur Abtrennung von Wolframverbindungen aus waessrigen, wolframhaltigen Loesungen |
| US3158438A (en) * | 1962-09-19 | 1964-11-24 | Union Carbide Corp | Solvent extraction process for recovering tungsten values from contaminated aqueous solutions |
| DE1244141B (de) | 1962-10-26 | 1967-07-13 | Blair Burwell | Verfahren zur Herstellung von hochreinem Ammoniumparawolframat |
| US4092400A (en) | 1977-04-11 | 1978-05-30 | Engelhard Minerals & Chemicals Corp. | Process for recovering high purity tungsten compositions from wolframite ores |
| US4175109A (en) * | 1978-08-03 | 1979-11-20 | Gte Sylvania Incorporated | Process for extracting tungsten from alkali metal tungstate solutions |
| US4279869A (en) * | 1979-12-13 | 1981-07-21 | Kerr-Mcgee Corporation | Process for recovering concentrated, purified tungsten values from brine |
| US4450144A (en) * | 1981-01-19 | 1984-05-22 | Amax Inc. | Ammonium hydroxide stripping of tungsten from organic solvents |
| US4346061A (en) * | 1981-03-31 | 1982-08-24 | Union Carbide Corporation | Purification of ammonium tungstate solutions |
| US4508701A (en) * | 1983-03-31 | 1985-04-02 | Union Carbide Corporation | Extraction of tungsten from spent or scrap catalyst materials |
| US4448755A (en) * | 1983-12-01 | 1984-05-15 | Gte Products Corporation | Method for removal of tin from ammonium tungstates |
| US4613182A (en) * | 1984-08-27 | 1986-09-23 | Stone Jack C | Side panel assembly |
| US4624844A (en) * | 1985-02-04 | 1986-11-25 | Gte Products Corporation | Process for producing ammonium paratungstate |
| US4612183A (en) * | 1985-02-25 | 1986-09-16 | Gte Products Corporation | Method of producing crystalline ammonium metatungstate |
| US4623534A (en) * | 1985-03-21 | 1986-11-18 | Gte Products Corporation | Method for producing ammonium paratungstate |
| US4882131A (en) * | 1987-04-30 | 1989-11-21 | Gte Products Corporation | Process for recovering tungsten from organic solutions |
| US4963336A (en) * | 1989-09-25 | 1990-10-16 | Amax Inc. | Purification of APT |
| US5417945A (en) * | 1990-08-22 | 1995-05-23 | Gte Products Corporation | Process for recovering tungsten as an ammoniacal tungstate compound in which ammoniacal tungstate liquors are reclaimed |
| DE102007005287B4 (de) | 2007-02-02 | 2009-10-01 | H.C. Starck Gmbh | Verfahren zur Herstellung von Ammoniumparawolframattetrahydrat und hochreines Ammoniumparawolframattetrahydrat |
| DE102007005285B4 (de) | 2007-02-02 | 2009-06-25 | H.C. Starck Gmbh | Verfahren zur Herstellung von Ammoniumheptamolybdat |
-
2007
- 2007-02-02 DE DE102007005286A patent/DE102007005286B4/de active Active
- 2007-02-02 DE DE102007063691A patent/DE102007063691B4/de not_active Expired - Fee Related
-
2008
- 2008-01-29 CN CN2008800039606A patent/CN101600654B/zh active Active
- 2008-01-29 EP EP08708312.7A patent/EP2118017B1/de active Active
- 2008-01-29 US US12/524,957 patent/US8216533B2/en active Active
- 2008-01-29 JP JP2009547657A patent/JP5424897B2/ja active Active
- 2008-01-29 WO PCT/EP2008/050995 patent/WO2008092837A1/de not_active Ceased
- 2008-01-29 PT PT87083127T patent/PT2118017T/pt unknown
- 2008-01-29 ES ES08708312.7T patent/ES2608681T3/es active Active
-
2012
- 2012-05-29 US US13/482,075 patent/US8440161B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| DE102007005286B4 (de) | 2009-08-27 |
| WO2008092837A1 (de) | 2008-08-07 |
| US20100098619A1 (en) | 2010-04-22 |
| JP2010517902A (ja) | 2010-05-27 |
| US20130029153A1 (en) | 2013-01-31 |
| PT2118017T (pt) | 2016-12-14 |
| DE102007063691B4 (de) | 2011-01-13 |
| US8440161B2 (en) | 2013-05-14 |
| DE102007005286A8 (de) | 2008-12-24 |
| JP5424897B2 (ja) | 2014-02-26 |
| EP2118017A1 (de) | 2009-11-18 |
| CN101600654B (zh) | 2013-05-29 |
| CN101600654A (zh) | 2009-12-09 |
| US8216533B2 (en) | 2012-07-10 |
| EP2118017B1 (de) | 2016-10-12 |
| DE102007005286A1 (de) | 2008-08-07 |
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