ES2574812T3 - Material compuesto reforzado con fibras - Google Patents
Material compuesto reforzado con fibras Download PDFInfo
- Publication number
- ES2574812T3 ES2574812T3 ES09752459.9T ES09752459T ES2574812T3 ES 2574812 T3 ES2574812 T3 ES 2574812T3 ES 09752459 T ES09752459 T ES 09752459T ES 2574812 T3 ES2574812 T3 ES 2574812T3
- Authority
- ES
- Spain
- Prior art keywords
- layers
- fibers
- support
- layer
- fiber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 239000000463 material Substances 0.000 title description 10
- 239000003733 fiber-reinforced composite Substances 0.000 title 1
- 239000000835 fiber Substances 0.000 abstract description 21
- 239000011159 matrix material Substances 0.000 abstract description 8
- 239000002131 composite material Substances 0.000 abstract description 4
- 230000003014 reinforcing effect Effects 0.000 abstract description 3
- 238000010348 incorporation Methods 0.000 abstract description 2
- 230000002787 reinforcement Effects 0.000 description 5
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 2
- 230000032798 delamination Effects 0.000 description 2
- 238000003475 lamination Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000012783 reinforcing fiber Substances 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000002313 adhesive film Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/022—Non-woven fabric
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
- B32B27/20—Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/024—Woven fabric
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/026—Knitted fabric
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/12—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer characterised by the relative arrangement of fibres or filaments of different layers, e.g. the fibres or filaments being parallel or perpendicular to each other
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
- B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
- B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03C—SHEDDING MECHANISMS; PATTERN CARDS OR CHAINS; PUNCHING OF CARDS; DESIGNING PATTERNS
- D03C7/00—Leno or similar shedding mechanisms
- D03C7/04—Mechanisms having discs oscillating about a weftwise axis and having apertures for warp threads
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D13/00—Woven fabrics characterised by the special disposition of the warp or weft threads, e.g. with curved weft threads, with discontinuous warp threads, with diagonal warp or weft
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/23907—Pile or nap type surface or component
- Y10T428/23957—Particular shape or structure of pile
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24132—Structurally defined web or sheet [e.g., overall dimension, etc.] including grain, strips, or filamentary elements in different layers or components parallel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Moulding By Coating Moulds (AREA)
- Reinforced Plastic Materials (AREA)
- Braiding, Manufacturing Of Bobbin-Net Or Lace, And Manufacturing Of Nets By Knotting (AREA)
- Nonwoven Fabrics (AREA)
- Woven Fabrics (AREA)
Abstract
Una estructura de capas (32) para incorporación en una estructura compuesta (12) reforzada con fibras continuas, que comprende un material de matriz y una pluralidad de estructuras de refuerzo de capas de fibras, comprendiendo la estructura de capas (32) una lámina de soporte de capas de fibras (22) que comprende una capa bidimensional de fibras primarias y una matriz plana bidimensional de fibras secundarias (20) que se extienden hacia fuera del plano de la lámina en una tercera dimensión de manera generalmente alineada y dispuesta a través de al menos una mayor parte de su superficie, en la que las fibras secundarias (20) se proyectan hacia fuera desde ambos lados de la lámina de soporte (22).
Description
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particulares de la unión. Las áreas 16 son áreas particularmente susceptibles a este respecto. El refuerzo relativamente limitado proporcionado fuera de plano en la tercera dimensión en CRFCs convencionales, que conduce a rotura por delaminación y mecanismos asociados, puede ser un problema particular en estas áreas.
Por consiguiente, se introducen capas de soporte de acuerdo con la invención que llevan fibras secundarias (ver las figuras 2 a 4) o se introducen en mayor proporción en aquellas áreas de alta tensión, donde es probable que la delaminaciòn sea un problema. Por ejemplo, una lámina de 6 mm o 7 mm podría incluir de 60 a 70 capas laminares de capas de fibras en el material de la matriz. Podría ser apropiado incorporar capas de acuerdo con la invención en las 10 capas superiores de tal estructura.
Por lo tanto, en la figura 1 se introducen capas de soporte de acuerdo con la invención que llevan fibras secundarias en las capas 16 dentro de la estructura de unión. También se pueden introducir en la interfaz 17. Adicional o alternativamente, se puede utilizar adhesivo en la interfaz 17. El material de las capas de soporte podría estar también entrelazado, si es necesario, en el revestimiento y/o en partes de detalle de esta configuración o configuraciones de uniones similares.
La figura 2 ilustra una sección a través de una capa de fibras de refuerzo que comprende una configuración de capa de soporte de acuerdo con la invención y adecuada para incorporación en una estructura compuesta, tal como la ilustrada en la figura 1, que comprende un material de matriz, por ejemplo de una composición de resina endurecible, y una pluralidad de capas de refuerzo de fibras para formar un material compuesto reforzado con fibras continuas. Una capa de soporte como se ilustra en la figura 2 es adecuada para uso en tal material, de tal manera que al término del procesamiento se incorpora en el laminado procesado o la interfaz de la unión en la que la capa de fibras de la figura 2 contribuye al refuerzo fuera de plano de la capa en una tercera dimensión.
La capa de soporte ilustrada en la figura 2 comprende un material de soporte de capas de fibras 22. En la forma de realización ilustrada, el material de soporte es un cañamazo de soporte de material de fibras de peso ligero que tiene como su finalidad principal la provisión de una estructura de soporte que soporta las fibras secundarias de la manera vertical generalmente alineada deseada. Se pueden contemplar materiales de soporte alternativos, tales como materiales que son capas de refuerzo adicionalmente totalmente en plano, o capas que son capas adhesivas de película, opcionalmente con una capa de soporte de fibras asociada.
A través de la capa de fibras de la capa de soporte se infiltran fibras secundarias en una pluralidad de matrices de manera generalmente alineada para extenderse generalmente perpendiculares a la lámina 22 a través de una mayorparte de su extensión de una manera espaciada generalmente uniforme. Éstas pueden infiltrarse, por ejemplo, por un proceso de pulverización. La tecnología de pulverización es capaz de producir una disposición de las fibras alineada adecuada. Podrían considerarse otros procesos capaces de producir una disposición de las fibras similar generalmente alineadas.
La figura 3 ilustra en sección transversal cómo se podría incorporar un material, como se ilustra en la figura 2, en una estructura aminada de CFRC, por ejemplo en la etapa de fabricación, con el fin de proporcionar un refuerzo fuera de plano, por ejemplo en una interfaz de unión, tal como se ilustra en la figura 1.
Se extiende una estructura que comprende múltiples capas de laminación parcial de capas 30 de material de capas / matriz de fibras de CFRC convencional, que comprende, por ejemplo, una pluralidad de capas de prepreg de material compuesto de fibras y material de matriz de película endurecible. Mediante entrelazado con éstas, al menos en una zona a reforzar, se proporciona una pluralidad de capas de refuerzo 32 que llevan fibras de refuerzo secundarias fuera del plano general del laminado de la manera ilustrada en la figura 3a. Detalles específicos de esto se ilustra en el recuadro de la figura 3b.
A medida que este material es procesado de una manera convencional adecuada, por ejemplo endureciendo el material de la matriz, se con solida el refuerzo secundario en el laminado procesado para mejorar propiedades fuera de plano mediante proyección dentro del material de la matriz interlaminar.
La estructura laminada procesada resultante se ilustra esquemáticamente en la figura 4. La estructura de la figura 4 podría ser adecuada, en particular, por ejemplo para uso en áreas de alta tensión de laminación en una interfaz de unión, tal como se ilustra en la figura 1.
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Claims (1)
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imagen1 imagen2
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB0821134 | 2008-11-19 | ||
GB0821134A GB0821134D0 (en) | 2008-11-19 | 2008-11-19 | Fibre reinforced composite |
EP08275075 | 2008-11-19 | ||
EP08275075A EP2189277A1 (en) | 2008-11-19 | 2008-11-19 | Fibre reinforced composite |
PCT/GB2009/051503 WO2010058196A1 (en) | 2008-11-19 | 2009-11-10 | Fibre reinforced composite |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2574812T3 true ES2574812T3 (es) | 2016-06-22 |
Family
ID=41606567
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES09752459.9T Active ES2574812T3 (es) | 2008-11-19 | 2009-11-10 | Material compuesto reforzado con fibras |
Country Status (10)
Country | Link |
---|---|
US (1) | US10035333B2 (es) |
EP (1) | EP2358521B1 (es) |
JP (1) | JP5405584B2 (es) |
KR (1) | KR101318312B1 (es) |
AU (1) | AU2009316988B2 (es) |
BR (1) | BRPI0921312A2 (es) |
CA (1) | CA2744069C (es) |
ES (1) | ES2574812T3 (es) |
IL (1) | IL212965A (es) |
WO (1) | WO2010058196A1 (es) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8523524B2 (en) * | 2010-03-25 | 2013-09-03 | General Electric Company | Airfoil cooling hole flag region |
KR101727470B1 (ko) | 2015-11-13 | 2017-04-17 | 경상대학교산학협력단 | z-방향 섬유로 보강된 복합재료 스티칭 구조 |
CN110753611A (zh) * | 2017-06-19 | 2020-02-04 | 维特尔有限公司 | 用于制造可充气的起重垫的方法以及起重垫 |
US11376812B2 (en) | 2020-02-11 | 2022-07-05 | Helicoid Industries Inc. | Shock and impact resistant structures |
WO2022256022A1 (en) | 2021-06-01 | 2022-12-08 | Helicoid Industries Inc. | Containers and methods for protecting pressure vessels |
US11852297B2 (en) | 2021-06-01 | 2023-12-26 | Helicoid Industries Inc. | Containers and methods for protecting pressure vessels |
US11952103B2 (en) | 2022-06-27 | 2024-04-09 | Helicoid Industries Inc. | High impact-resistant, reinforced fiber for leading edge protection of aerodynamic structures |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2368706A (en) * | 1943-08-07 | 1945-02-06 | United Merchants & Mfg | Multicolor flock printed fabric |
US4218276A (en) * | 1972-03-31 | 1980-08-19 | Avco Corporation | Method for making 3-D structures |
GB2066308A (en) | 1979-12-11 | 1981-07-08 | Cambridge Consultants | Three-dimensional woven structure |
DE3246803A1 (de) * | 1982-12-17 | 1984-06-20 | Messerschmitt-Bölkow-Blohm GmbH, 8000 München | Verfahren zum herstellen von bauteilen aus lagen von faserverstaerktem kunststoff |
JPH08103960A (ja) * | 1994-10-06 | 1996-04-23 | Fuji Heavy Ind Ltd | 3次元繊維強化複合材 |
BE1010775A3 (nl) | 1996-11-29 | 1999-01-05 | Dsm Nv | Velvormig voortbrengsel van een thermohardbaar harsmengsel en vezelvormig materiaal. |
NL1007281C2 (nl) * | 1997-10-15 | 1999-04-19 | Syncoglas Sa Nv | Driedimensionaal versterkingsmateriaal. |
ATE448346T1 (de) * | 2001-01-24 | 2009-11-15 | Univ Auburn | Stossabsorbierendes material |
JP2003039429A (ja) * | 2001-08-02 | 2003-02-13 | Mitsubishi Heavy Ind Ltd | 複合材料用繊維基材 |
AU2003304187A1 (en) * | 2002-09-10 | 2005-01-04 | Tex Tech Industries, Inc. | Enhanced energy absorbing materials |
US7981495B2 (en) * | 2006-10-31 | 2011-07-19 | Invensys Systems, Inc. | Materials methodology to improve the delamination strength of laminar composites |
US9511571B2 (en) | 2007-01-23 | 2016-12-06 | The Boeing Company | Composite laminate having a damping interlayer and method of making the same |
US20120177870A1 (en) * | 2007-03-05 | 2012-07-12 | Phra Douglas Lyle | Ballistic materials |
-
2009
- 2009-11-10 BR BRPI0921312A patent/BRPI0921312A2/pt not_active Application Discontinuation
- 2009-11-10 AU AU2009316988A patent/AU2009316988B2/en not_active Ceased
- 2009-11-10 WO PCT/GB2009/051503 patent/WO2010058196A1/en active Application Filing
- 2009-11-10 JP JP2011536949A patent/JP5405584B2/ja active Active
- 2009-11-10 CA CA 2744069 patent/CA2744069C/en not_active Expired - Fee Related
- 2009-11-10 EP EP09752459.9A patent/EP2358521B1/en active Active
- 2009-11-10 KR KR1020117013170A patent/KR101318312B1/ko not_active IP Right Cessation
- 2009-11-10 US US13/130,165 patent/US10035333B2/en active Active
- 2009-11-10 ES ES09752459.9T patent/ES2574812T3/es active Active
-
2011
- 2011-05-17 IL IL212965A patent/IL212965A/en not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
CA2744069C (en) | 2013-08-06 |
JP2012509414A (ja) | 2012-04-19 |
WO2010058196A1 (en) | 2010-05-27 |
US20110236620A1 (en) | 2011-09-29 |
KR20110083728A (ko) | 2011-07-20 |
BRPI0921312A2 (pt) | 2015-12-29 |
EP2358521B1 (en) | 2016-05-04 |
AU2009316988A2 (en) | 2011-08-04 |
KR101318312B1 (ko) | 2013-10-15 |
US10035333B2 (en) | 2018-07-31 |
IL212965A0 (en) | 2011-07-31 |
EP2358521A1 (en) | 2011-08-24 |
AU2009316988B2 (en) | 2013-09-05 |
JP5405584B2 (ja) | 2014-02-05 |
IL212965A (en) | 2012-12-31 |
CA2744069A1 (en) | 2010-05-27 |
AU2009316988A1 (en) | 2010-05-27 |
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