ES2533072T3 - Procedimiento para la preparación de compuestos complejos de manganeso puenteados del triazaciclononano - Google Patents
Procedimiento para la preparación de compuestos complejos de manganeso puenteados del triazaciclononano Download PDFInfo
- Publication number
- ES2533072T3 ES2533072T3 ES10760913.3T ES10760913T ES2533072T3 ES 2533072 T3 ES2533072 T3 ES 2533072T3 ES 10760913 T ES10760913 T ES 10760913T ES 2533072 T3 ES2533072 T3 ES 2533072T3
- Authority
- ES
- Spain
- Prior art keywords
- manganese
- ion
- divalent
- metal
- salt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000011572 manganese Substances 0.000 title abstract description 6
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 title abstract 4
- 150000001875 compounds Chemical class 0.000 title abstract 4
- 229910052748 manganese Inorganic materials 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 3
- 150000003839 salts Chemical class 0.000 abstract description 7
- 239000003446 ligand Substances 0.000 abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052751 metal Inorganic materials 0.000 abstract 6
- 239000002184 metal Substances 0.000 abstract 6
- 230000003647 oxidation Effects 0.000 abstract 4
- 238000007254 oxidation reaction Methods 0.000 abstract 4
- 150000002500 ions Chemical class 0.000 abstract 3
- 150000002739 metals Chemical class 0.000 abstract 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- -1 hexafluorophosphate Chemical compound 0.000 abstract 2
- 150000004679 hydroxides Chemical class 0.000 abstract 2
- 229910000000 metal hydroxide Inorganic materials 0.000 abstract 2
- 229910044991 metal oxide Inorganic materials 0.000 abstract 2
- 150000004706 metal oxides Chemical class 0.000 abstract 2
- 239000011541 reaction mixture Substances 0.000 abstract 2
- 238000000926 separation method Methods 0.000 abstract 2
- 239000000126 substance Substances 0.000 abstract 2
- WLDGDTPNAKWAIR-UHFFFAOYSA-N 1,4,7-trimethyl-1,4,7-triazonane Chemical compound CN1CCN(C)CCN(C)CC1 WLDGDTPNAKWAIR-UHFFFAOYSA-N 0.000 abstract 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- 229910001413 alkali metal ion Inorganic materials 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 229910052742 iron Chemical group 0.000 abstract 1
- 159000000014 iron salts Chemical class 0.000 abstract 1
- 150000002696 manganese Chemical class 0.000 abstract 1
- 150000002697 manganese compounds Chemical class 0.000 abstract 1
- 239000007800 oxidant agent Substances 0.000 abstract 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 abstract 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 230000009466 transformation Effects 0.000 abstract 1
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
- 229910021135 KPF6 Inorganic materials 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F13/00—Compounds containing elements of Groups 7 or 17 of the Periodic Table
- C07F13/005—Compounds without a metal-carbon linkage
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
- B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
- B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
- B01J31/182—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine comprising aliphatic or saturated rings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0213—Complexes without C-metal linkages
- B01J2531/0216—Bi- or polynuclear complexes, i.e. comprising two or more metal coordination centres, without metal-metal bonds, e.g. Cp(Lx)Zr-imidazole-Zr(Lx)Cp
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP09290713 | 2009-09-18 | ||
| EP09290713 | 2009-09-18 | ||
| PCT/EP2010/005569 WO2011032666A1 (de) | 2009-09-18 | 2010-09-10 | Verfahren zur herstellung von verbrückten mangan-komplexen des triazacyclononans |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2533072T3 true ES2533072T3 (es) | 2015-04-07 |
Family
ID=41682826
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES10760913.3T Active ES2533072T3 (es) | 2009-09-18 | 2010-09-10 | Procedimiento para la preparación de compuestos complejos de manganeso puenteados del triazaciclononano |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US9012630B2 (https=) |
| EP (1) | EP2477740B1 (https=) |
| JP (1) | JP5688413B2 (https=) |
| CN (1) | CN102510774B (https=) |
| ES (1) | ES2533072T3 (https=) |
| PL (1) | PL2477740T3 (https=) |
| WO (1) | WO2011032666A1 (https=) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2103604A1 (de) | 2008-03-17 | 2009-09-23 | Evonik Degussa GmbH | Verfahren zur Herstellung von Epichlorhydrin |
| WO2011106906A1 (en) | 2010-03-03 | 2011-09-09 | Unilever Plc | Preparation of bleaching catalysts |
| ES2683005T3 (es) | 2011-09-08 | 2018-09-24 | Catexel Technologies Limited | Catalizadores |
| US9624119B2 (en) | 2014-06-13 | 2017-04-18 | Ecolab Usa Inc. | Enhanced catalyst stability in activated peroxygen and/or alkaline detergent formulations |
| CN107652436B (zh) * | 2016-07-23 | 2020-12-11 | 金华职业技术学院 | 一种不同价双核锰(ii、iii)一维双带状配位聚合物及其制备方法 |
| CN114599772A (zh) * | 2019-10-17 | 2022-06-07 | 罗地亚经营管理公司 | 金属络合物及其用途 |
| CN110963558A (zh) * | 2019-11-29 | 2020-04-07 | 常熟市化创化学技术有限公司 | 类芬顿试剂及其在有机废水处理中的应用 |
| CN120005219B (zh) * | 2025-04-22 | 2025-08-29 | 天津科技大学 | 具有氧化酶特性的锰金属有机框架材料及其制备方法与应用 |
| CN121698848A (zh) * | 2026-02-09 | 2026-03-20 | 浙江大学衢州研究院 | 一种具有三氮杂环壬烷大环骨架的铁配合物及其制备方法和应用 |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2100925T3 (es) | 1990-05-21 | 1997-07-01 | Unilever Nv | Activacion de blanqueador. |
| EP0522817A1 (en) | 1991-07-11 | 1993-01-13 | Unilever Plc | Process for preparing manganese complexes |
| GB9118242D0 (en) | 1991-08-23 | 1991-10-09 | Unilever Plc | Machine dishwashing composition |
| US5153161A (en) * | 1991-11-26 | 1992-10-06 | Lever Brothers Company, Division Of Conopco, Inc. | Synthesis of manganese oxidation catalyst |
| US5256779A (en) * | 1992-06-18 | 1993-10-26 | Lever Brothers Company, Division Of Conopco, Inc. | Synthesis of manganese oxidation catalyst |
| US5329024A (en) | 1993-03-30 | 1994-07-12 | National Starch And Chemical Investment Holding Corporation | Epoxidation of olefins via certain manganese complexes |
| US5385893A (en) * | 1993-05-06 | 1995-01-31 | The Dow Chemical Company | Tricyclopolyazamacrocyclophosphonic acids, complexes and derivatives thereof, for use as contrast agents |
| WO1995030733A1 (en) * | 1994-05-09 | 1995-11-16 | Unilever N.V. | Bleach catalyst composition |
| WO1996006145A1 (en) | 1994-08-19 | 1996-02-29 | Akzo Nobel N.V. | Liquid-crystalline polyethers |
| WO1996006154A1 (en) | 1994-08-19 | 1996-02-29 | Unilever N.V. | Detergent bleach composition |
| DE19620241A1 (de) | 1996-05-20 | 1997-11-27 | Patt R Prof Dr | Verfahren zum Delignifizieren von Zellstoffen und Verwendung eines Katalysators |
| US6689733B1 (en) * | 1999-03-08 | 2004-02-10 | Ciba Specialty Chemicals Corporation | Manganese complexes of salen ligands and the use thereof |
| GB9930422D0 (en) | 1999-12-22 | 2000-02-16 | Unilever Plc | Bleach catalysts |
| DE10051317A1 (de) | 2000-10-17 | 2002-04-18 | Degussa | Übergangsmetallkomplexe mit Polydentaten Liganden zur Verstärkung der Bleich- und Delignifizierungswirkung von Persauerstoffverbindungen |
| BR0206673A (pt) * | 2001-01-26 | 2004-01-13 | Ciba Sc Holding Ag | Processo para a preparação de partìculas ou gr nulos solúveis em água de complexos de manganês do tipo saldimine |
| JP2004525986A (ja) | 2001-04-27 | 2004-08-26 | ロンザ ア−ゲ− | ケトンの製造方法 |
| BR0312694B1 (pt) * | 2002-07-11 | 2013-11-05 | Uso de compostos de complexo de metal como catalisadores de oxidação, compostos de complexo de metal, agente de lavagem, limpeza, desinfecção ou alvejamento, bem como preparação sólida | |
| ATE428818T1 (de) | 2005-10-12 | 2009-05-15 | Unilever Nv | Verfahren zum bleichen von substraten |
| US7976582B2 (en) | 2007-01-16 | 2011-07-12 | Conopco, Inc. | Bleaching of substrates |
-
2010
- 2010-09-10 ES ES10760913.3T patent/ES2533072T3/es active Active
- 2010-09-10 JP JP2012529144A patent/JP5688413B2/ja active Active
- 2010-09-10 PL PL10760913T patent/PL2477740T3/pl unknown
- 2010-09-10 CN CN201080041259.0A patent/CN102510774B/zh active Active
- 2010-09-10 WO PCT/EP2010/005569 patent/WO2011032666A1/de not_active Ceased
- 2010-09-10 US US13/394,968 patent/US9012630B2/en active Active
- 2010-09-10 EP EP10760913.3A patent/EP2477740B1/de active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN102510774A (zh) | 2012-06-20 |
| CN102510774B (zh) | 2014-07-23 |
| JP5688413B2 (ja) | 2015-03-25 |
| EP2477740B1 (de) | 2015-01-21 |
| WO2011032666A1 (de) | 2011-03-24 |
| US9012630B2 (en) | 2015-04-21 |
| PL2477740T3 (pl) | 2015-06-30 |
| US20120202990A1 (en) | 2012-08-09 |
| EP2477740A1 (de) | 2012-07-25 |
| JP2013505206A (ja) | 2013-02-14 |
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