ES2526253T3 - Materiales para dispositivos oftálmicos y otorrinolaringológicos - Google Patents

Materiales para dispositivos oftálmicos y otorrinolaringológicos Download PDF

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ES2526253T3
ES2526253T3 ES10749550.9T ES10749550T ES2526253T3 ES 2526253 T3 ES2526253 T3 ES 2526253T3 ES 10749550 T ES10749550 T ES 10749550T ES 2526253 T3 ES2526253 T3 ES 2526253T3
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Walter R. Laredo
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Novartis AG
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    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
    • G02B1/041—Lenses
    • G02B1/043—Contact lenses
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
    • C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
    • C08F290/06—Polymers provided for in subclass C08G
    • C08F290/062—Polyethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10—Esters
    • C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
    • C08F222/102—Esters of polyhydric alcohols or polyhydric phenols of dialcohols, e.g. ethylene glycol di(meth)acrylate or 1,4-butanediol dimethacrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10—Esters
    • C08F222/12—Esters of phenols or saturated alcohols
    • C08F222/14—Esters having no free carboxylic acid groups, e.g. dialkyl maleates or fumarates
    • C08F222/145—Esters having no free carboxylic acid groups, e.g. dialkyl maleates or fumarates the ester chains containing seven or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10—Esters
    • C08F222/12—Esters of phenols or saturated alcohols
    • C08F222/20—Esters containing oxygen in addition to the carboxy oxygen
    • C08F222/205—Esters containing oxygen in addition to the carboxy oxygen the ester chains containing seven or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/10—Homopolymers or copolymers of methacrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/10—Homopolymers or copolymers of methacrylic acid esters
    • C08L33/12—Homopolymers or copolymers of methyl methacrylate
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S525/91—Polymer from ethylenic monomers only, having terminal unsaturation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S525/937—Utility as body contact e.g. implant, contact lens or I.U.D.

Abstract

Un material para dispositivo oftálmico u otorrinolaringológico que comprende a) 70 a 98% (p/p) de un monómero de acrilato o metacrilato monofuncional de fórmula [1]: en la que B >= -O(CH2)n-, -(OCH2CH2)n-, -NH(CH2)n-, o -NCH3(CH2)n-; R1 >= H, CH3, CH2CH3, o CH2OH; n >= 0 - 12; A >= C6H5 o OCH2)mC6H5, en la que el grupo C6H5 está opcionalmente substituido con -(CH2)nH, - O(CH2)nH, -CH(CH3)2-, -C6H5, -OC6H5, -CH2C6H5, F, Cl, Br, o I; y m >= 0 - 18; b) 0,5 a 3% (p/p) de un monómero de reticulación de acrilato o metacrilato difuncional de fórmula [2]: en la que R2, R3 independientemente >= H, CH3, CH2CH3, o CH2OH; W, W' independientemente >= O(CH2)d, NH(CH2)d-, NCH3(CH2)d, O(CH2)dC6H4, O(CH2CH2O)dCH2, O(CH2CH2CH2O)dCH2, O(CH2CH2CH2CH2O)dCH2, o nada; J >= CH2)a , O(CH2CH2O)b; O, o nada, a condición de que si W y W' >= nada, entonces J ≠ nada; d >= 0 - 12; a >= 1 - 12; y b >= 1 ≠ 24; y c) 0,5 a 15% (p/p) de un aditivo copolímero de fórmula [3]: en la que para la fórmula [3]: D >= OCH2CH2S, SCH2C>=O, CH3CH(OH)CH2S, SCH2CH(OH)CH2O, S(CH2)11O, S(CH2)10C>=O, S(CH2)14C>=O, S(CH2C>=O, SC6H4CH2O, CH3CH(S)C>=O, S(CH2CH2CH2)O, CH3CH(S)CH(O)CH3, OCH2CH2C(CH3)2S, SCH2CH2C>=O, S(CH2)5 4O, SC6H4CH2C>=O, SC6H4C>=O, S(CH2)11C>=O, CH3CH(O)CH(S)CH3, SC6H4C>=O, S(CH2)6OC6H4CH2O, S(CH2)6O, S(CH2)5C>=O, S(CH2)7C>=O , S(CH2)9O, C(CH3)2C(>=O)NHCH2CH2O, C(CH3)2C(>=NH)NHCH2CH2C>=O, C(CH3C(>=O)NHCH(CH2CH3)(CH2O), C(CH3)2CN, C(CH3)(CN)CH2C(OCH3)(CH3CH3, C(CH3)2C(>=O)NHCH2CH>=CH2, C(CH3)(CN)CH2C(CH3)2(OCH3), C(CH3)(CN)CH2CH(CH3)2, C(CH3)2C(>=O)OCH3, C(CH3)(CN)CH2CH3, C(CN)(CH2)5, C(CH3)2C(>=O)NHCH2CH2CH3, o C(CH3)2C(>=O)NHC6H11; E >= nada, O(CH2)nNH, (OCH2CH2)nNH, O(CH2)nNHC>=O, HN(CH2)nNH, o H; a condición de que si D >= C(CH3)2CN, C(CH3)(CN)CH2C(OCH3)(CH3CH3), C(CH3)2C(>=O)NHCH2CH>=CH2, C(CH3)(CN)CH2C(CH3)2(OCH3), C(CH3)(CN)CH2CH(CH3)2, C(CH3)2C(>=O)OCH3, C(CH3)(CN)CH2CH3, C(CN)(CH2)5, C(CH3)2C(>=O)NHCH2CH2CH2CH3, o C(CH3)2C(O>=)NHC6H11, entonces E >= F >= nada; n >= 1 - 5; si E >= H o OH, entonces F >= nada; si E ≠ H o OH, entonces F >= C(>=O)C(CH3)>=CH2, C(>=O)CH>=CH2, C(>=O)C(CH2CH3)>=CH2, C(>=O)C(CH2OH)>=CH2, C(>=O)NHCH2CH2OC(>=O)C(CH3)>=CH2, o C(>=O)NHC(CH3)2C6H4C(>=CH2)CH3; R4, R5, y R6 independientemente >= H o CH3; t, u, y v representan valores de fracciones molares y t + u + v >= 1; t y u independientemente >= 0 - 0,95; a condición de que t + u >= 0,8 - 0,95; v >= 0,05 - 0,2; W >= H, CH3, C(>=O)C(CH3)>=CH2, C(>=O)CH>=CH2, C(>=O)C(CH2CH3)>=CH2, C(>=O)C(CH2OH)>=CH2, C(>=O)NHCH2CH2OC(>=O)C(CH3)>=CH2, o C(>=O)NHC(CH3)2C6H4(>=CH2)CH3 ; a condición de que si F >= nada, entonces W >= C(>=O)C(CH3)>=CH2, C(>=O)CH>=CH2, C(>=O)C(CH2CH3)>=CH2, C(>=O)C(CH2OH)>=CH2, C(>=O)NHCH2CH2OC(>=O)C(CH3)>=CH2, o C(>=O)NHC(CH3)2C6H4(>=CH2)CH3; y1, y2, e y3 independientemente >= 4 - 200; y x >= 1 - 100.

Description

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Claims (1)

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ES10749550.9T 2009-08-24 2010-08-23 Materiales para dispositivos oftálmicos y otorrinolaringológicos Active ES2526253T3 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US23640209P 2009-08-24 2009-08-24
US236402P 2009-08-24
PCT/US2010/046345 WO2011028480A2 (en) 2009-08-24 2010-08-23 Ophthalmic and otorhinolaryngological device materials

Publications (1)

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ES2526253T3 true ES2526253T3 (es) 2015-01-08

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US (1) US9012581B2 (es)
EP (1) EP2470578B1 (es)
JP (1) JP5732462B2 (es)
AU (1) AU2010289896B2 (es)
CA (1) CA2769827C (es)
ES (1) ES2526253T3 (es)
WO (1) WO2011028480A2 (es)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI473823B (zh) 2010-06-21 2015-02-21 Novartis Ag 具有經降低的閃光之高折射率、丙烯酸系眼科裝置材料
MX358329B (es) * 2012-02-15 2018-08-15 Novartis Ag Materiales para dispositivo oftalmico y otorrinolaringologico que contienen un macromero de peg ramificado.
JP5447720B1 (ja) 2012-05-31 2014-03-19 ダイソー株式会社 電池電極用バインダー、およびそれを用いた電極ならびに電池

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5290892A (en) 1990-11-07 1994-03-01 Nestle S.A. Flexible intraocular lenses made from high refractive index polymers
US5331073A (en) 1992-11-09 1994-07-19 Allergan, Inc. Polymeric compositions and intraocular lenses made from same
US5470932A (en) 1993-10-18 1995-11-28 Alcon Laboratories, Inc. Polymerizable yellow dyes and their use in opthalmic lenses
JP3206004B2 (ja) * 1995-06-07 2001-09-04 アルコン ラボラトリーズ， インコーポレイテッド 改良された高屈折率の眼科用レンズ材料
US6353069B1 (en) 1998-04-15 2002-03-05 Alcon Manufacturing, Ltd. High refractive index ophthalmic device materials
CA2315747C (en) * 1998-04-15 2007-06-26 Alcon Laboratories, Inc. High refractive index ophthalmic device materials
US6281319B1 (en) 1999-04-12 2001-08-28 Surgidev Corporation Water plasticized high refractive index polymer for ophthalmic applications
CN1151186C (zh) 1999-09-07 2004-05-26 爱尔康通用有限公司 可折叠的眼科及耳鼻喉科器件材料
AR029901A1 (es) * 2000-03-24 2003-07-23 Novartis Ag Prepolimeros reticulables o polimerizables, y un proceso para la fabricacion de articulos moldeados ''biomedicos'' ''
CN101193929B (zh) * 2005-06-13 2012-02-01 爱尔康公司 眼科和耳鼻喉科装置材料
WO2007149083A1 (en) 2006-06-21 2007-12-27 Bausch & Lomb Incorporated Polymerizable surfactants and their use as device forming comonomers
TW200816966A (en) 2006-07-21 2008-04-16 Alcon Mfg Ltd Low-tack ophthalmic and otorhinolaryngological device materials
TWI399228B (zh) 2006-07-21 2013-06-21 Alcon Inc 低黏性的眼科與耳鼻喉科裝置材料（二）
TW200916130A (en) * 2007-10-02 2009-04-16 Alcon Inc Ophthalmic and otorhinolaryngological device materials containing an alkylphenol ethoxylate
TW200920330A (en) 2007-10-02 2009-05-16 Alcon Inc Ophthalmic and otorhinolaryngological device materials containing an alkyl ethoxylate
TWI426931B (zh) 2007-10-03 2014-02-21 Alcon Inc 眼科與耳鼻喉科裝置材料（一）
TWI461186B (zh) 2007-10-05 2014-11-21 Alcon Inc 眼科與耳鼻喉科裝置材料（二）
TWI426932B (zh) 2007-10-05 2014-02-21 Alcon Inc 眼科與耳鼻喉科裝置材料（三）

Also Published As

Publication number Publication date
AU2010289896B2 (en) 2013-08-29
WO2011028480A3 (en) 2011-05-12
CA2769827C (en) 2016-09-13
WO2011028480A2 (en) 2011-03-10
EP2470578A2 (en) 2012-07-04
JP5732462B2 (ja) 2015-06-10
CA2769827A1 (en) 2011-03-10
EP2470578B1 (en) 2014-11-12
US20110046258A1 (en) 2011-02-24
AU2010289896A1 (en) 2012-03-01
US9012581B2 (en) 2015-04-21
JP2013502302A (ja) 2013-01-24

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