ES2404159T3 - Procedimiento continuo para la preparación de ésteres de ácidos carboxílicos aromáticos - Google Patents
Procedimiento continuo para la preparación de ésteres de ácidos carboxílicos aromáticos Download PDFInfo
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- ES2404159T3 ES2404159T3 ES10723943T ES10723943T ES2404159T3 ES 2404159 T3 ES2404159 T3 ES 2404159T3 ES 10723943 T ES10723943 T ES 10723943T ES 10723943 T ES10723943 T ES 10723943T ES 2404159 T3 ES2404159 T3 ES 2404159T3
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- acid
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- atoms
- cavity resonator
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- -1 aromatic carboxylic acids Chemical class 0.000 title claims abstract description 65
- 150000002148 esters Chemical class 0.000 title claims abstract description 27
- 238000002360 preparation method Methods 0.000 title claims abstract description 22
- 238000010924 continuous production Methods 0.000 title claims abstract description 8
- 238000006243 chemical reaction Methods 0.000 claims abstract description 159
- 239000011541 reaction mixture Substances 0.000 claims abstract description 59
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- 239000003054 catalyst Substances 0.000 claims abstract description 29
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 27
- 230000032050 esterification Effects 0.000 claims abstract description 25
- 238000005886 esterification reaction Methods 0.000 claims abstract description 25
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- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical class OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 150000005840 aryl radicals Chemical class 0.000 claims abstract description 8
- 125000004429 atom Chemical group 0.000 claims abstract description 6
- 238000000034 method Methods 0.000 claims description 75
- 230000008569 process Effects 0.000 claims description 44
- 239000000463 material Substances 0.000 claims description 32
- 239000002253 acid Substances 0.000 claims description 28
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 17
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 15
- 125000003118 aryl group Chemical group 0.000 claims description 13
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 13
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- QMKYBPDZANOJGF-UHFFFAOYSA-N benzene-1,3,5-tricarboxylic acid Chemical compound OC(=O)C1=CC(C(O)=O)=CC(C(O)=O)=C1 QMKYBPDZANOJGF-UHFFFAOYSA-N 0.000 claims description 4
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- ATZHGRNFEFVDDJ-UHFFFAOYSA-N 4-propylbenzoic acid Chemical compound CCCC1=CC=C(C(O)=O)C=C1 ATZHGRNFEFVDDJ-UHFFFAOYSA-N 0.000 claims description 2
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- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
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- ZEYHEAKUIGZSGI-UHFFFAOYSA-N 4-methoxybenzoic acid Chemical class COC1=CC=C(C(O)=O)C=C1 ZEYHEAKUIGZSGI-UHFFFAOYSA-N 0.000 claims 1
- 125000002877 alkyl aryl group Chemical group 0.000 claims 1
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- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J19/12—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electromagnetic waves
- B01J19/122—Incoherent waves
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J19/12—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electromagnetic waves
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- C07C67/00—Preparation of carboxylic acid esters
- C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/76—Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/76—Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring
- C07C69/80—Phthalic acid esters
- C07C69/82—Terephthalic acid esters
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D213/79—Acids; Esters
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B6/00—Heating by electric, magnetic or electromagnetic fields
- H05B6/64—Heating using microwaves
- H05B6/70—Feed lines
- H05B6/701—Feed lines using microwave applicators
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B6/00—Heating by electric, magnetic or electromagnetic fields
- H05B6/64—Heating using microwaves
- H05B6/80—Apparatus for specific applications
- H05B6/806—Apparatus for specific applications for laboratory use
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J2219/12—Processes employing electromagnetic waves
- B01J2219/1203—Incoherent waves
- B01J2219/1206—Microwaves
- B01J2219/1209—Features relating to the reactor or vessel
- B01J2219/1212—Arrangements of the reactor or the reactors
- B01J2219/1215—Single reactor
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J2219/12—Processes employing electromagnetic waves
- B01J2219/1203—Incoherent waves
- B01J2219/1206—Microwaves
- B01J2219/1209—Features relating to the reactor or vessel
- B01J2219/1221—Features relating to the reactor or vessel the reactor per se
- B01J2219/1224—Form of the reactor
- B01J2219/1227—Reactors comprising tubes with open ends
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J2219/12—Processes employing electromagnetic waves
- B01J2219/1203—Incoherent waves
- B01J2219/1206—Microwaves
- B01J2219/1248—Features relating to the microwave cavity
- B01J2219/1272—Materials of construction
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J2219/12—Processes employing electromagnetic waves
- B01J2219/1203—Incoherent waves
- B01J2219/1206—Microwaves
- B01J2219/1275—Controlling the microwave irradiation variables
- B01J2219/1281—Frequency
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J2219/12—Processes employing electromagnetic waves
- B01J2219/1203—Incoherent waves
- B01J2219/1206—Microwaves
- B01J2219/1275—Controlling the microwave irradiation variables
- B01J2219/1284—Intensity
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- Chemical & Material Sciences (AREA)
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- Physics & Mathematics (AREA)
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- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Clinical Laboratory Science (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Pyridine Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102009031054A DE102009031054A1 (de) | 2009-06-30 | 2009-06-30 | Kontinuierliches Verfahren zur Herstellung von Estern aromatischer Carbonsäuren |
| DE102009031054 | 2009-06-30 | ||
| PCT/EP2010/003447 WO2011000464A2 (de) | 2009-06-30 | 2010-06-09 | Kontinuierliches verfahren zur herstellung von estern aromatischer carbonsäuren |
Publications (1)
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| ES2404159T3 true ES2404159T3 (es) | 2013-05-24 |
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| ES10723943T Active ES2404159T3 (es) | 2009-06-30 | 2010-06-09 | Procedimiento continuo para la preparación de ésteres de ácidos carboxílicos aromáticos |
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| EP (1) | EP2448904B1 (enExample) |
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| DE (1) | DE102009031054A1 (enExample) |
| ES (1) | ES2404159T3 (enExample) |
| WO (1) | WO2011000464A2 (enExample) |
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| DE102006047619B4 (de) * | 2006-10-09 | 2008-11-13 | Clariant International Limited | Verfahren zur Herstellung basischer Fettsäureamide |
| DE102006047617B4 (de) * | 2006-10-09 | 2008-11-27 | Clariant International Limited | Verfahren zur Herstellung basischer (Meth)acrylamide |
| DE102008017215B4 (de) * | 2008-04-04 | 2012-08-09 | Clariant International Ltd. | Kontinuierliches Verfahren zur Herstellung von Amiden ethylenisch ungesättigter Carbonsäuren |
| DE102008017214B4 (de) * | 2008-04-04 | 2012-02-16 | Clariant International Limited | Kontinuierliches Verfahren zur Herstellung von Fettsäurealkanolamiden |
| DE102008017213B4 (de) * | 2008-04-04 | 2012-08-09 | Clariant International Limited | Kontinuierliches Verfahren zur Herstellung von Amiden aliphatischer Hydroxycarbonsäuren |
| DE102008017216B4 (de) * | 2008-04-04 | 2013-08-14 | Clariant International Ltd. | Kontinuierliches Verfahren zur Herstellung von Fettsäureamiden |
| DE102008017218B4 (de) * | 2008-04-04 | 2011-09-22 | Clariant International Ltd. | Kontinuierliches Verfahren zur Herstellung von Amiden niederer aliphatischer Carbonsäuren |
| DE102008017219A1 (de) * | 2008-04-04 | 2009-10-08 | Clariant International Ltd. | Verfahren zur Herstellung von Amiden in Gegenwart von überhitztem Wasser |
| DE102008017217A1 (de) * | 2008-04-04 | 2009-10-08 | Clariant International Ltd. | Kontinuierliches Verfahren zur Herstellung von Amiden aromatischer Carbonsäuren |
| DE102009031059A1 (de) | 2009-06-30 | 2011-01-05 | Clariant International Ltd. | Vorrichtung zur kontinuierlichen Durchführung chemischer Reaktionen bei hohen Temperaturen |
| DE102009042522A1 (de) | 2009-09-22 | 2011-04-07 | Clariant International Ltd. | Kontinuierliches Umesterungsverfahren |
| DE102009042523B4 (de) | 2009-09-22 | 2012-02-16 | Clariant International Ltd. | Vorrichtung und Verfahren zur kontinuierlichen Durchführung heterogen katalysierter chemischer Reaktionen bei hohen Temperaturen |
| DE102010056564A1 (de) | 2010-12-30 | 2012-07-05 | Clariant International Limited | Hydroxylgruppen und Estergruppen tragende Polymere und Verfahren zu ihrer Herstellung |
| DE102010056565A1 (de) | 2010-12-30 | 2012-07-05 | Clariant International Ltd. | Verfahren zur Modifizierung Hydroxylgruppen tragender Polymere |
| CN102260170B (zh) * | 2011-06-02 | 2014-10-15 | 浙江大学 | 微波管道化生产乙酸正t酯的方法 |
| US8957242B2 (en) * | 2013-03-15 | 2015-02-17 | Renewable Energy Group, Inc. | Dual catalyst esterification |
| CN104710314A (zh) * | 2015-03-25 | 2015-06-17 | 河南师范大学 | 一种水杨酸酯的制备方法 |
| CN104803848B (zh) * | 2015-04-23 | 2016-07-13 | 安徽佳先功能助剂股份有限公司 | 采用含有氯化钠的苯甲酸为原料生产苯甲酸甲酯的方法 |
| CN108476188B (zh) * | 2015-11-02 | 2021-05-25 | 三星电子株式会社 | 在波束形成通信系统中发送或接收参考信号的方法和装置 |
| DE102019006639A1 (de) | 2019-09-20 | 2021-03-25 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Kontinuierliches Verfahren zum Erhitzen von Medien mittels Mikrowellenstrahlung und dafür geeignete Mikrowellenanlage |
| CN119219490B (zh) * | 2024-12-03 | 2025-03-04 | 宿州恒昶生物科技有限公司 | 一种羟苯甲酯的制备工艺 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3461261A (en) * | 1966-10-31 | 1969-08-12 | Du Pont | Heating apparatus |
| DE3060279D1 (en) * | 1979-06-20 | 1982-05-19 | Basf Canada Inc | Use of microwave energy in the production of plasticizer esters |
| JPH01133910A (ja) * | 1987-06-08 | 1989-05-26 | Cil Inc | マイクロ波エネルギ−を使用して発煙硫酸から三酸化硫黄を発生させる方法及び装置 |
| WO1990003840A1 (en) | 1988-10-10 | 1990-04-19 | Commonwealth Scientific And Industrial Research Organisation | Method and apparatus for continuous chemical reactions |
| JP2784789B2 (ja) * | 1989-03-27 | 1998-08-06 | 山本化成株式会社 | ２―アルキルアントラキノンの製造方法 |
| US6020579A (en) * | 1997-01-06 | 2000-02-01 | International Business Machines Corporation | Microwave applicator having a mechanical means for tuning |
| US5114684A (en) * | 1990-12-13 | 1992-05-19 | Serawaste Systems Corporation | In-line electromagnetic energy wave applicator |
| US5471037A (en) * | 1992-08-18 | 1995-11-28 | E. I. Du Pont De Nemours And Company | Process for preparing polymeric material with microwave |
| JPH07330667A (ja) * | 1994-06-10 | 1995-12-19 | Koichi Shinozaki | マイクロ波を加熱に用いるエステル類の製造方法 |
| FR2751830B1 (fr) * | 1996-07-23 | 1998-10-23 | Prolabo Sa | Dispositif pour realiser des reactions chimiques sous micro-ondes sur une grande quantite de produits |
| JP4376627B2 (ja) * | 2001-10-19 | 2009-12-02 | バイオタージ・アクチボラゲット | マイクロ波加熱装置、マイクロ波加熱システム、およびマイクロ波加熱装置またはマイクロ波加熱システムの使用方法 |
| JP2004059517A (ja) * | 2002-07-30 | 2004-02-26 | New Japan Chem Co Ltd | ヒドロキシ安息香酸エステル類の製造方法 |
| US6867400B2 (en) * | 2002-07-31 | 2005-03-15 | Cem Corporation | Method and apparatus for continuous flow microwave-assisted chemistry techniques |
| FR2849343B1 (fr) * | 2002-12-23 | 2009-01-23 | Aldivia | Synthese chimique comportant un traitement thermique par chauffage dielectrique intermittent, combine a un systeme de recirculation |
| JP4759668B2 (ja) * | 2004-05-11 | 2011-08-31 | 株式会社Ｉｄｘ | マイクロ波加熱装置 |
| US20050274065A1 (en) | 2004-06-15 | 2005-12-15 | Carnegie Mellon University | Methods for producing biodiesel |
| JP2006181533A (ja) * | 2004-12-28 | 2006-07-13 | Idx Corp | マイクロ波化学反応装置 |
| JP2006272055A (ja) * | 2005-03-28 | 2006-10-12 | Idx Corp | マイクロ波化学反応装置 |
| JP2007222696A (ja) * | 2005-12-23 | 2007-09-06 | Tokyo Electric Power Co Inc:The | マイクロ波反応用の触媒カラム及びそれを用いた分解処理方法 |
| CN100352793C (zh) * | 2006-01-20 | 2007-12-05 | 杨鸿生 | 用于以天然气制乙烯的槽波导微波化学反应设备及制备方法 |
| PL2013319T3 (pl) | 2006-04-28 | 2019-07-31 | Sk Chemicals Co., Ltd. | Sposób wytwarzania estru alkilowego kwasu tłuszczowego z użyciem destylatu kwasu tłuszczowego |
| EP2079680B1 (de) * | 2006-10-09 | 2015-07-01 | Clariant Finance (BVI) Limited | Verfahren zur herstellung von fettsäurealkanolamiden |
| US8128788B2 (en) * | 2008-09-19 | 2012-03-06 | Rf Thummim Technologies, Inc. | Method and apparatus for treating a process volume with multiple electromagnetic generators |
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| US20120088918A1 (en) | 2012-04-12 |
| CA2766955A1 (en) | 2011-01-06 |
| EP2448904B1 (de) | 2013-04-17 |
| WO2011000464A3 (de) | 2011-03-31 |
| JP2012531384A (ja) | 2012-12-10 |
| DE102009031054A1 (de) | 2011-01-13 |
| EP2448904A2 (de) | 2012-05-09 |
| KR20120027004A (ko) | 2012-03-20 |
| WO2011000464A2 (de) | 2011-01-06 |
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