ES2319052A1 - Transportador de oxigeno de nio/ai2o3, procedimiento de obtencion del mismo y sus aplicaciones - Google Patents

Transportador de oxigeno de nio/ai2o3, procedimiento de obtencion del mismo y sus aplicaciones Download PDF

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Publication number
ES2319052A1
ES2319052A1 ES200702104A ES200702104A ES2319052A1 ES 2319052 A1 ES2319052 A1 ES 2319052A1 ES 200702104 A ES200702104 A ES 200702104A ES 200702104 A ES200702104 A ES 200702104A ES 2319052 A1 ES2319052 A1 ES 2319052A1
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ES
Spain
Prior art keywords
nio
al2o3
obtaining
oxygen transporter
oxygen carrier
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
ES200702104A
Other languages
English (en)
Other versions
ES2319052B1 (es
Inventor
Elorza Juan Adanez
Diego Poza Luis Francisco De
Labiano Francisco Garcia
Sanz Pilar Gayan
Secades Alberto Abad
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Consejo Superior de Investigaciones Cientificas CSIC
Original Assignee
Consejo Superior de Investigaciones Cientificas CSIC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Consejo Superior de Investigaciones Cientificas CSIC filed Critical Consejo Superior de Investigaciones Cientificas CSIC
Priority to ES200702104A priority Critical patent/ES2319052B1/es
Priority to PCT/ES2008/070146 priority patent/WO2009022046A1/es
Publication of ES2319052A1 publication Critical patent/ES2319052A1/es
Application granted granted Critical
Publication of ES2319052B1 publication Critical patent/ES2319052B1/es
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C99/00—Subject-matter not provided for in other groups of this subclass
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0207—Pretreatment of the support
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/36—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using oxygen or mixtures containing oxygen as gasifying agents
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C10/00—Fluidised bed combustion apparatus
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/042—Purification by adsorption on solids
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0475—Composition of the impurity the impurity being carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1241—Natural gas or methane
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00—Combustion technologies with mitigation potential
    • Y02E20/34—Indirect CO2mitigation, i.e. by acting on non CO2directly related matters of the process, e.g. pre-heating or heat recovery
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Catalysts (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Abstract

Transportador de oxigeno de NiO/Al{sub,2}O{sub,3}, procedimiento de obtención del mismo y sus aplicaciones. La presente invención describe un transportador de oxígeno que obtenido por impregnación comprende un óxido de níquel sobre un soporte de gamma-alúmina comercial (Al{sub,2}O{sub,3}) modificada térmicamente, así como el procedimiento de obtención. Este transportador de oxígeno de la invención puede ser utilizado para la combustión indirecta de gas (metano, H{sub,2}, CO, H{sub,2}/CO) en lecho fluidizado para la producción de energía sin emisión de CO{sub,2} ("Chemical Looping combustion", CLC), y para la producción de gas de síntesis (H{sub,2}+CO) o H{sub,2} por oxidación parcial de metano con captura inherente de CO{sub,2} en lecho fluidizado ("Chemical Looping Reforming", CLR).
ES200702104A 2007-07-27 2007-07-27 Transportador de oxigeno de nio/al2o3, procedimiento de obtencion del mismo y sus aplicaciones. Expired - Fee Related ES2319052B1 (es)

Priority Applications (2)

Application Number Priority Date Filing Date Title
ES200702104A ES2319052B1 (es) 2007-07-27 2007-07-27 Transportador de oxigeno de nio/al2o3, procedimiento de obtencion del mismo y sus aplicaciones.
PCT/ES2008/070146 WO2009022046A1 (es) 2007-07-27 2008-07-24 Transportador de oxígeno de nio/al2o3, procedimiento de obtención del mismo y sus aplicaciones.

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ES200702104A ES2319052B1 (es) 2007-07-27 2007-07-27 Transportador de oxigeno de nio/al2o3, procedimiento de obtencion del mismo y sus aplicaciones.

Publications (2)

Publication Number Publication Date
ES2319052A1 true ES2319052A1 (es) 2009-05-01
ES2319052B1 ES2319052B1 (es) 2010-02-15

Family

ID=40350423

Family Applications (1)

Application Number Title Priority Date Filing Date
ES200702104A Expired - Fee Related ES2319052B1 (es) 2007-07-27 2007-07-27 Transportador de oxigeno de nio/al2o3, procedimiento de obtencion del mismo y sus aplicaciones.

Country Status (2)

Country Link
ES (1) ES2319052B1 (es)
WO (1) WO2009022046A1 (es)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2324852A1 (es) * 2008-02-15 2009-08-17 Consejo Superior De Investigaciones Cientificas Transportador solido de oxigeno de ni0/al203 util para el reformado demetano, procedimiento de obtencion y sus aplicaciones.

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2930733B1 (fr) * 2008-04-30 2014-04-11 Inst Francais Du Petrole Masse active d'oxydo-reduction et procede de combustion en boucle chimique.
FR2937030B1 (fr) * 2008-10-10 2012-04-13 Inst Francais Du Petrole MASSES OXYDO-REDUCTRICES A STRUCTURE DE TYPE SPINELLE AxA'x'ByB'y'O4 ET UTILISATION DANS UN PROCEDE D'OXYDO-REDUCTION EN BOUCLE CHIMIQUE
AT507917B1 (de) * 2009-03-02 2014-02-15 Univ Wien Tech Verfahren zur herstellung von kohlendioxid und wasserstoff
CN102183014B (zh) * 2011-03-10 2012-05-02 东南大学 一种煤加压高密度循环流化床化学链燃烧分离co2方法
CN102618349B (zh) * 2012-03-31 2014-07-02 昆明理工大学 一种甲烷化学链燃烧的氧载体及其制备方法
CN103552983A (zh) * 2013-10-25 2014-02-05 西南石油大学 一种CaO引导的甲烷蒸汽重整化学链燃烧制氢工艺
CN104061568B (zh) * 2014-06-26 2017-09-26 东南大学 一种Cu/Ca基化合物联合循环捕捉CO2的方法及装置
CN104930518B (zh) * 2015-05-18 2017-09-29 华中科技大学 一种低碳处理固体垃圾并抑制二噁英生成的方法
CN110094722B (zh) * 2019-04-19 2020-08-18 南京师范大学 一种流化床载氧体辅助富氧燃烧系统及方法

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
ABAD, A. et al. "Mapping of the range of operational conditions for Cu-, Fe- and Ni-based oxygen carriers in chemical-looping combustion" Chemical Engineering Science. 14.09.2006 Vol. 62 Páginas 533-549; apartados 1-2. *
MATISSON T. et al. "The use of NiO as an oxygen carrier in chemical-looping combustion" Fuel. 09.09.2005 Vol. 85 Páginas 736-747; apartado 3.1 *
READMAN J.E. et al. "Chemical Looping Combustion Usinng NiO/ NiAl2O4: Mechanisms and Kinetics of Redcution-Oxidation (Red-OX) Reactions from In Situ Powder X-ray Diffraction and Thermogravimetry Experiments" Energy & Fuel 20.05.2006 Vol. 20 Páginas 1382-1387; apartados Introduction, Experimental. *
VILLA, R. et al. "Ni based mixed oxide materials for CH4 oxidation under redox cycle conditions" Journal Of Molecular Catalysis A: Chemical 15.09.2003 Vol. 204-205 Páginas 637-646; apartados 1-3. *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2324852A1 (es) * 2008-02-15 2009-08-17 Consejo Superior De Investigaciones Cientificas Transportador solido de oxigeno de ni0/al203 util para el reformado demetano, procedimiento de obtencion y sus aplicaciones.

Also Published As

Publication number Publication date
WO2009022046A1 (es) 2009-02-19
ES2319052B1 (es) 2010-02-15

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