ES2270038T3 - Proceso para preparar aceites blancos medicinales y tecnicos. - Google Patents
Proceso para preparar aceites blancos medicinales y tecnicos. Download PDFInfo
- Publication number
- ES2270038T3 ES2270038T3 ES03729994T ES03729994T ES2270038T3 ES 2270038 T3 ES2270038 T3 ES 2270038T3 ES 03729994 T ES03729994 T ES 03729994T ES 03729994 T ES03729994 T ES 03729994T ES 2270038 T3 ES2270038 T3 ES 2270038T3
- Authority
- ES
- Spain
- Prior art keywords
- fischer
- tropsch
- product
- weight
- fraction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims abstract description 30
- 239000003921 oil Substances 0.000 title description 54
- 238000009835 boiling Methods 0.000 claims abstract description 20
- 150000001875 compounds Chemical class 0.000 claims abstract description 20
- 238000004821 distillation Methods 0.000 claims abstract description 20
- 239000002243 precursor Substances 0.000 claims abstract description 15
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 11
- 239000003463 adsorbent Substances 0.000 claims abstract description 10
- 238000004517 catalytic hydrocracking Methods 0.000 claims abstract description 5
- 238000000926 separation method Methods 0.000 claims abstract description 4
- 238000002955 isolation Methods 0.000 claims abstract description 3
- 238000002360 preparation method Methods 0.000 claims abstract description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 36
- 238000001228 spectrum Methods 0.000 claims description 12
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- 238000010521 absorption reaction Methods 0.000 claims description 4
- 238000002211 ultraviolet spectrum Methods 0.000 claims description 4
- 125000004429 atom Chemical group 0.000 claims description 3
- 125000004122 cyclic group Chemical group 0.000 claims description 3
- 239000000047 product Substances 0.000 description 31
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 21
- 239000003054 catalyst Substances 0.000 description 20
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 16
- 239000011230 binding agent Substances 0.000 description 12
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 10
- 239000000377 silicon dioxide Substances 0.000 description 10
- 239000001257 hydrogen Substances 0.000 description 9
- 229910052739 hydrogen Inorganic materials 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- 239000011148 porous material Substances 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 8
- 239000010457 zeolite Substances 0.000 description 8
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 7
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 7
- 230000003197 catalytic effect Effects 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 7
- 238000003786 synthesis reaction Methods 0.000 description 7
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 5
- 238000001035 drying Methods 0.000 description 5
- 229910052697 platinum Inorganic materials 0.000 description 5
- 229910021536 Zeolite Inorganic materials 0.000 description 4
- 238000005984 hydrogenation reaction Methods 0.000 description 4
- 239000002808 molecular sieve Substances 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 238000006356 dehydrogenation reaction Methods 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 229910044991 metal oxide Inorganic materials 0.000 description 3
- 150000004706 metal oxides Chemical class 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229910052763 palladium Inorganic materials 0.000 description 3
- 238000002459 porosimetry Methods 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 229910000323 aluminium silicate Inorganic materials 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 239000012013 faujasite Substances 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 210000000540 fraction c Anatomy 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- YBMRDBCBODYGJE-UHFFFAOYSA-N germanium dioxide Chemical compound O=[Ge]=O YBMRDBCBODYGJE-UHFFFAOYSA-N 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 229910052680 mordenite Inorganic materials 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 229910000510 noble metal Inorganic materials 0.000 description 2
- 238000005292 vacuum distillation Methods 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 238000004438 BET method Methods 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- MXRIRQGCELJRSN-UHFFFAOYSA-N O.O.O.[Al] Chemical compound O.O.O.[Al] MXRIRQGCELJRSN-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical group [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- -1 ZSM-5 Substances 0.000 description 1
- 238000002835 absorbance Methods 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- SNAAJJQQZSMGQD-UHFFFAOYSA-N aluminum magnesium Chemical compound [Mg].[Al] SNAAJJQQZSMGQD-UHFFFAOYSA-N 0.000 description 1
- IXWIAFSBWGYQOE-UHFFFAOYSA-M aluminum;magnesium;oxygen(2-);silicon(4+);hydroxide;tetrahydrate Chemical compound O.O.O.O.[OH-].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Mg+2].[Al+3].[Si+4].[Si+4].[Si+4].[Si+4] IXWIAFSBWGYQOE-UHFFFAOYSA-M 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 230000001174 ascending effect Effects 0.000 description 1
- 239000002199 base oil Substances 0.000 description 1
- 229910052790 beryllium Inorganic materials 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000011362 coarse particle Substances 0.000 description 1
- 238000013016 damping Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 238000011066 ex-situ storage Methods 0.000 description 1
- 229910001657 ferrierite group Inorganic materials 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229940104869 fluorosilicate Drugs 0.000 description 1
- 229940119177 germanium dioxide Drugs 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000003102 growth factor Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 239000003870 refractory metal Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/14—White oil, eating oil
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Fats And Perfumes (AREA)
- Liquid Carbonaceous Fuels (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Medicinal Preparation (AREA)
- Lubricants (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP02291563 | 2002-06-24 | ||
| EP02291563 | 2002-06-24 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2270038T3 true ES2270038T3 (es) | 2007-04-01 |
Family
ID=29797324
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES03729994T Expired - Lifetime ES2270038T3 (es) | 2002-06-24 | 2003-05-07 | Proceso para preparar aceites blancos medicinales y tecnicos. |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US20050258074A1 (https=) |
| EP (1) | EP1516038B1 (https=) |
| JP (1) | JP4344826B2 (https=) |
| CN (1) | CN100419048C (https=) |
| AT (1) | ATE335063T1 (https=) |
| AU (1) | AU2003240612A1 (https=) |
| DE (1) | DE60307274T2 (https=) |
| ES (1) | ES2270038T3 (https=) |
| WO (1) | WO2004000975A1 (https=) |
| ZA (1) | ZA200409056B (https=) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7214307B2 (en) * | 2004-07-22 | 2007-05-08 | Chevron U.S.A. Inc. | White oil from waxy feed using highly selective and active wax hydroisomerization catalyst |
| US7402236B2 (en) * | 2004-07-22 | 2008-07-22 | Chevron Usa | Process to make white oil from waxy feed using highly selective and active wax hydroisomerization catalyst |
| JP5254009B2 (ja) * | 2005-05-20 | 2013-08-07 | シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ | 食品と接触する用途へのフィッシャー・トロプシュ誘導ホワイトオイルの使用法含有する組成物 |
| CN101175813A (zh) * | 2005-05-20 | 2008-05-07 | 国际壳牌研究有限公司 | 含有费-托法得到的白油的聚苯乙烯组合物 |
| US20090036546A1 (en) * | 2007-07-31 | 2009-02-05 | Chevron U.S.A. Inc. | Medicinal Oil Compositions, Preparations, and Applications Thereof |
| DE102007042548A1 (de) * | 2007-08-30 | 2009-03-05 | Riepe, Angelika | Flüssiges Trennmittel |
| EP2075314A1 (en) | 2007-12-11 | 2009-07-01 | Shell Internationale Research Maatschappij B.V. | Grease formulations |
| CN101998986B (zh) | 2007-12-20 | 2014-12-10 | 国际壳牌研究有限公司 | 燃料组合物 |
| WO2009080681A2 (en) * | 2007-12-20 | 2009-07-02 | Shell Internationale Research Maatschappij B.V. | Process to prepare a gas oil fraction and a residual base oil |
| WO2009080672A1 (en) | 2007-12-20 | 2009-07-02 | Shell Internationale Research Maatschappij B.V. | Fuel compositions |
| KR100921062B1 (ko) | 2008-05-21 | 2009-10-08 | 현대자동차주식회사 | 액티브 후드 시스템의 리프트 장치 |
| EP2864456B1 (en) | 2012-06-21 | 2018-10-31 | Shell International Research Maatschappij B.V. | Lubricating oil compositions comprising heavy fischer-tropsch derived base oils and alkylated aromatic base oil |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB815264A (en) * | 1955-10-17 | 1959-06-24 | Forsch Patentverwertung Ges | The production of white oil from used oils |
| US4574043A (en) * | 1984-11-19 | 1986-03-04 | Mobil Oil Corporation | Catalytic process for manufacture of low pour lubricating oils |
| US4859311A (en) * | 1985-06-28 | 1989-08-22 | Chevron Research Company | Catalytic dewaxing process using a silicoaluminophosphate molecular sieve |
| US5157191A (en) * | 1986-01-03 | 1992-10-20 | Mobil Oil Corp. | Modified crystalline aluminosilicate zeolite catalyst and its use in the production of lubes of high viscosity index |
| US5252527A (en) * | 1988-03-23 | 1993-10-12 | Chevron Research And Technology Company | Zeolite SSZ-32 |
| US5053373A (en) * | 1988-03-23 | 1991-10-01 | Chevron Research Company | Zeolite SSZ-32 |
| US5082986A (en) * | 1989-02-17 | 1992-01-21 | Chevron Research Company | Process for producing lube oil from olefins by isomerization over a silicoaluminophosphate catalyst |
| EP0736079B1 (en) * | 1993-12-20 | 2000-05-10 | Mobil Oil Corporation | Hydrogenation process |
| US6179994B1 (en) * | 1998-09-04 | 2001-01-30 | Exxon Research And Engineering Company | Isoparaffinic base stocks by dewaxing fischer-tropsch wax hydroisomerate over Pt/H-mordenite |
| US6332974B1 (en) * | 1998-09-11 | 2001-12-25 | Exxon Research And Engineering Co. | Wide-cut synthetic isoparaffinic lubricating oils |
| CN1075547C (zh) * | 1998-09-28 | 2001-11-28 | 中国石油化工集团公司 | 一段加氢法生产工业白油 |
| US6468417B1 (en) * | 1999-06-11 | 2002-10-22 | Chevron U.S.A. Inc. | Filtering lubricating oils to remove haze precursors |
-
2003
- 2003-05-07 AT AT03729994T patent/ATE335063T1/de not_active IP Right Cessation
- 2003-05-07 JP JP2004514632A patent/JP4344826B2/ja not_active Expired - Fee Related
- 2003-05-07 DE DE60307274T patent/DE60307274T2/de not_active Expired - Lifetime
- 2003-05-07 EP EP03729994A patent/EP1516038B1/en not_active Expired - Lifetime
- 2003-05-07 US US10/519,250 patent/US20050258074A1/en not_active Abandoned
- 2003-05-07 WO PCT/EP2003/004853 patent/WO2004000975A1/en not_active Ceased
- 2003-05-07 ES ES03729994T patent/ES2270038T3/es not_active Expired - Lifetime
- 2003-05-07 CN CNB038146940A patent/CN100419048C/zh not_active Expired - Fee Related
- 2003-05-07 AU AU2003240612A patent/AU2003240612A1/en not_active Abandoned
-
2004
- 2004-11-09 ZA ZA200409056A patent/ZA200409056B/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| ATE335063T1 (de) | 2006-08-15 |
| DE60307274T2 (de) | 2007-10-18 |
| CN100419048C (zh) | 2008-09-17 |
| JP4344826B2 (ja) | 2009-10-14 |
| JP2005536578A (ja) | 2005-12-02 |
| EP1516038B1 (en) | 2006-08-02 |
| ZA200409056B (en) | 2005-05-09 |
| AU2003240612A1 (en) | 2004-01-06 |
| EP1516038A1 (en) | 2005-03-23 |
| WO2004000975A1 (en) | 2003-12-31 |
| DE60307274D1 (de) | 2006-09-14 |
| US20050258074A1 (en) | 2005-11-24 |
| CN1662632A (zh) | 2005-08-31 |
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