ES2203121T3 - Analizador para la medicion continua del h2s contenido en un gas y dispositivo que lo incluye para la regulacion del flujo de aire inyectado en un reactor de oxidacion de h2 a azufre. - Google Patents
Analizador para la medicion continua del h2s contenido en un gas y dispositivo que lo incluye para la regulacion del flujo de aire inyectado en un reactor de oxidacion de h2 a azufre.Info
- Publication number
- ES2203121T3 ES2203121T3 ES99918035T ES99918035T ES2203121T3 ES 2203121 T3 ES2203121 T3 ES 2203121T3 ES 99918035 T ES99918035 T ES 99918035T ES 99918035 T ES99918035 T ES 99918035T ES 2203121 T3 ES2203121 T3 ES 2203121T3
- Authority
- ES
- Spain
- Prior art keywords
- analyzer
- conduit
- duct
- gas
- flow meter
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 230000003647 oxidation Effects 0.000 title claims abstract description 52
- 238000007254 oxidation reaction Methods 0.000 title claims abstract description 52
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title claims abstract description 23
- 229910052717 sulfur Inorganic materials 0.000 title claims abstract description 23
- 239000011593 sulfur Substances 0.000 title claims abstract description 23
- 238000005259 measurement Methods 0.000 title claims description 10
- 238000001035 drying Methods 0.000 claims abstract description 10
- 230000001105 regulatory effect Effects 0.000 claims abstract description 10
- 238000010790 dilution Methods 0.000 claims abstract description 5
- 239000012895 dilution Substances 0.000 claims abstract description 5
- 238000005070 sampling Methods 0.000 claims abstract description 5
- 239000007789 gas Substances 0.000 claims description 45
- 238000002347 injection Methods 0.000 claims description 18
- 239000007924 injection Substances 0.000 claims description 18
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 14
- 229910052760 oxygen Inorganic materials 0.000 claims description 14
- 239000001301 oxygen Substances 0.000 claims description 14
- 238000011144 upstream manufacturing Methods 0.000 claims description 14
- 239000012528 membrane Substances 0.000 claims description 10
- 238000006243 chemical reaction Methods 0.000 claims description 8
- 238000005984 hydrogenation reaction Methods 0.000 claims description 4
- 230000007062 hydrolysis Effects 0.000 claims description 4
- 238000006460 hydrolysis reaction Methods 0.000 claims description 4
- 239000002912 waste gas Substances 0.000 claims description 4
- 238000005485 electric heating Methods 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 239000011248 coating agent Substances 0.000 claims description 2
- 238000000576 coating method Methods 0.000 claims description 2
- 239000012530 fluid Substances 0.000 claims description 2
- 230000001276 controlling effect Effects 0.000 claims 1
- 150000003464 sulfur compounds Chemical class 0.000 claims 1
- 239000000523 sample Substances 0.000 description 29
- 150000001875 compounds Chemical class 0.000 description 7
- 239000003054 catalyst Substances 0.000 description 6
- 238000004458 analytical method Methods 0.000 description 3
- 239000003792 electrolyte Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000004587 chromatography analysis Methods 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 239000012470 diluted sample Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 230000035945 sensitivity Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000004611 spectroscopical analysis Methods 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/0004—Gaseous mixtures, e.g. polluted air
- G01N33/0009—General constructional details of gas analysers, e.g. portable test equipment
- G01N33/0027—General constructional details of gas analysers, e.g. portable test equipment concerning the detector
- G01N33/0036—General constructional details of gas analysers, e.g. portable test equipment concerning the detector specially adapted to detect a particular component
- G01N33/0044—Sulphides, e.g. H2S
-
- G—PHYSICS
- G05—CONTROLLING; REGULATING
- G05D—SYSTEMS FOR CONTROLLING OR REGULATING NON-ELECTRIC VARIABLES
- G05D11/00—Control of flow ratio
- G05D11/02—Controlling ratio of two or more flows of fluid or fluent material
- G05D11/13—Controlling ratio of two or more flows of fluid or fluent material characterised by the use of electric means
- G05D11/135—Controlling ratio of two or more flows of fluid or fluent material characterised by the use of electric means by sensing at least one property of the mixture
- G05D11/138—Controlling ratio of two or more flows of fluid or fluent material characterised by the use of electric means by sensing at least one property of the mixture by sensing the concentration of the mixture, e.g. measuring pH value
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Physics & Mathematics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Food Science & Technology (AREA)
- Combustion & Propulsion (AREA)
- Automation & Control Theory (AREA)
- Medicinal Chemistry (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Sampling And Sample Adjustment (AREA)
- Other Investigation Or Analysis Of Materials By Electrical Means (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9805937A FR2778743B1 (fr) | 1998-05-12 | 1998-05-12 | Analyseur pour la mesure en continu de l'h2s contenu dans un gaz et dispositif l'incluant pour la regulation du debit d'air injecte dans un reacteur d'oxydation d'h2s en soufre |
| FR9805937 | 1998-05-12 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2203121T3 true ES2203121T3 (es) | 2004-04-01 |
Family
ID=9526239
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES99918035T Expired - Lifetime ES2203121T3 (es) | 1998-05-12 | 1999-05-10 | Analizador para la medicion continua del h2s contenido en un gas y dispositivo que lo incluye para la regulacion del flujo de aire inyectado en un reactor de oxidacion de h2 a azufre. |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US6355150B1 (enExample) |
| EP (1) | EP1000334B1 (enExample) |
| JP (1) | JP4317324B2 (enExample) |
| CA (1) | CA2296709C (enExample) |
| DE (1) | DE69909939T2 (enExample) |
| DK (1) | DK1000334T3 (enExample) |
| EA (1) | EA002070B1 (enExample) |
| ES (1) | ES2203121T3 (enExample) |
| FR (1) | FR2778743B1 (enExample) |
| NO (1) | NO319485B1 (enExample) |
| WO (1) | WO1999058950A1 (enExample) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3339724B2 (ja) * | 1992-09-29 | 2002-10-28 | 株式会社リコー | インクジェット記録方法及びその装置 |
| US7404882B2 (en) * | 1999-11-19 | 2008-07-29 | Perkinelmer Las, Inc. | Film-type solid polymer ionomer sensor and sensor cell |
| US6932941B2 (en) * | 1999-11-19 | 2005-08-23 | Perkinelmer Instruments Llc | Method and apparatus for improved gas detection |
| US7013707B2 (en) * | 1999-11-19 | 2006-03-21 | Perkinelmer Las, Inc | Method and apparatus for enhanced detection of a specie using a gas chromatograph |
| US6929735B2 (en) * | 1999-11-19 | 2005-08-16 | Perkin Elmer Instruments Llc | Electrochemical sensor having improved response time |
| US6682638B1 (en) | 1999-11-19 | 2004-01-27 | Perkin Elmer Llc | Film type solid polymer ionomer sensor and sensor cell |
| US6830730B2 (en) | 2001-09-11 | 2004-12-14 | Spectrolanalytical Instruments | Method and apparatus for the on-stream analysis of total sulfur and/or nitrogen in petroleum products |
| AU2002349692A1 (en) * | 2001-12-06 | 2003-06-17 | Mitsubishi Chemical Corporation | Oxidation reactor, method for producing (meth)acrylic acid or the like, and method for analyzing easily polymerizable compound |
| ES2199689B1 (es) * | 2002-08-06 | 2005-04-01 | Cespa Gestion De Residuos, S.A. | Dispositivo para controlar la produccion de gases en un reactor. |
| US20050135970A1 (en) * | 2003-12-18 | 2005-06-23 | Mroczynski Shawn A. | Hydrogen sulfide monitoring system |
| CN100334452C (zh) * | 2004-04-15 | 2007-08-29 | 长沙三德实业有限公司 | 一种测定可燃物质含硫量的闭路循环气体分析方法及装置 |
| US7531135B2 (en) * | 2004-07-13 | 2009-05-12 | D Haene Paul E | Process and system for controlling a process gas stream |
| US8048682B2 (en) * | 2007-04-30 | 2011-11-01 | Ut-Battelle, Llc | Device and method for detecting sulfur dioxide at high temperatures |
| CN102230855A (zh) * | 2011-04-08 | 2011-11-02 | 中国石油大学(北京) | 开环式高压天然气管道内粉尘离线采样系统及其采样方法 |
| CN102507295B (zh) * | 2011-10-13 | 2014-12-10 | 北京雪迪龙科技股份有限公司 | 一种无机微滤膜干燥器 |
| FR3032035B1 (fr) | 2015-01-27 | 2022-07-15 | Arkema France | Dispositif transportable de mesure en ligne de la concentration en sulfure d'hydrogene d'un effluent gazeux |
| JP2016223881A (ja) * | 2015-05-29 | 2016-12-28 | 富士電機株式会社 | ガス分析装置 |
| EP3635370B1 (en) | 2017-05-10 | 2024-10-30 | Opsis Ab | Method and system for determining a content of h2s |
| FR3069453A1 (fr) * | 2017-07-27 | 2019-02-01 | Suez Groupe | Dispositif de nettoyage d'un gaz pour analyse en ligne |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2118365A5 (enExample) * | 1970-12-18 | 1972-07-28 | Aquitaine Petrole | |
| US3888109A (en) * | 1973-11-16 | 1975-06-10 | Dresser Ind | Gas dilution unit |
| US4101282A (en) * | 1977-02-18 | 1978-07-18 | Phillips Petroleum Company | Sample conditioner and analyzer |
| US4402910A (en) * | 1981-06-15 | 1983-09-06 | Exlog Smith | Gas sampling system |
| FR2616241B1 (fr) * | 1987-06-02 | 1990-12-07 | Elf Aquitaine | Dispositif de regulation du fonctionnement d'une installation de traitements chimiques, pour ameliorer le rendement par attenuation des variances des parametres de reglage |
| US5637809A (en) * | 1991-11-12 | 1997-06-10 | United Sciences, Inc. | Vacuum extraction sampling system |
| DE4407345A1 (de) * | 1994-03-05 | 1995-09-07 | Testo Gmbh & Co | Verfahren und Vorrichtung zum Messen eines Gasmediums mit einem chemischen Sensor |
| US5473951A (en) * | 1994-06-23 | 1995-12-12 | Tomlin; Robert L. | Differential dilution sampling probe |
-
1998
- 1998-05-12 FR FR9805937A patent/FR2778743B1/fr not_active Expired - Fee Related
-
1999
- 1999-05-10 WO PCT/FR1999/001099 patent/WO1999058950A1/fr not_active Ceased
- 1999-05-10 EP EP99918035A patent/EP1000334B1/fr not_active Expired - Lifetime
- 1999-05-10 JP JP2000548703A patent/JP4317324B2/ja not_active Expired - Lifetime
- 1999-05-10 ES ES99918035T patent/ES2203121T3/es not_active Expired - Lifetime
- 1999-05-10 US US09/462,722 patent/US6355150B1/en not_active Expired - Fee Related
- 1999-05-10 DK DK99918035T patent/DK1000334T3/da active
- 1999-05-10 EA EA200000117A patent/EA002070B1/ru not_active IP Right Cessation
- 1999-05-10 CA CA002296709A patent/CA2296709C/fr not_active Expired - Lifetime
- 1999-05-10 DE DE69909939T patent/DE69909939T2/de not_active Expired - Lifetime
-
2000
- 2000-01-06 NO NO20000059A patent/NO319485B1/no not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| EP1000334A1 (fr) | 2000-05-17 |
| FR2778743B1 (fr) | 2000-06-23 |
| NO20000059L (no) | 2000-03-07 |
| DE69909939D1 (de) | 2003-09-04 |
| EA200000117A1 (ru) | 2000-08-28 |
| EP1000334B1 (fr) | 2003-07-30 |
| JP4317324B2 (ja) | 2009-08-19 |
| US6355150B1 (en) | 2002-03-12 |
| CA2296709C (fr) | 2006-07-11 |
| DE69909939T2 (de) | 2004-04-22 |
| WO1999058950A1 (fr) | 1999-11-18 |
| NO20000059D0 (no) | 2000-01-06 |
| FR2778743A1 (fr) | 1999-11-19 |
| NO319485B1 (no) | 2005-08-22 |
| EA002070B1 (ru) | 2001-12-24 |
| JP2002514751A (ja) | 2002-05-21 |
| DK1000334T3 (da) | 2003-11-10 |
| CA2296709A1 (fr) | 1999-11-18 |
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