ES2200624A1 - Sintesis en medio alcalino de la zeolita itq.-16 - Google Patents
Sintesis en medio alcalino de la zeolita itq.-16Info
- Publication number
- ES2200624A1 ES2200624A1 ES200100385A ES200100385A ES2200624A1 ES 2200624 A1 ES2200624 A1 ES 2200624A1 ES 200100385 A ES200100385 A ES 200100385A ES 200100385 A ES200100385 A ES 200100385A ES 2200624 A1 ES2200624 A1 ES 2200624A1
- Authority
- ES
- Spain
- Prior art keywords
- zeolite
- itq
- family
- different
- synthesis
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000010457 zeolite Substances 0.000 title abstract 6
- 229910021536 Zeolite Inorganic materials 0.000 title abstract 5
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 title abstract 5
- 230000015572 biosynthetic process Effects 0.000 title 1
- 238000003786 synthesis reaction Methods 0.000 title 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- 230000003647 oxidation Effects 0.000 abstract 2
- 238000007254 oxidation reaction Methods 0.000 abstract 2
- 238000002441 X-ray diffraction Methods 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 150000001767 cationic compounds Chemical class 0.000 abstract 1
- 229910052681 coesite Inorganic materials 0.000 abstract 1
- 229910052906 cristobalite Inorganic materials 0.000 abstract 1
- 150000002222 fluorine compounds Chemical class 0.000 abstract 1
- 229910001411 inorganic cation Inorganic materials 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 229910052682 stishovite Inorganic materials 0.000 abstract 1
- 229910052905 tridymite Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
- C10G11/04—Oxides
- C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
- C01B37/005—Silicates, i.e. so-called metallosilicalites or metallozeosilites
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/023—Preparation of physical mixtures or intergrowth products of zeolites chosen from group C01B39/04 or two or more of groups C01B39/14 - C01B39/48
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
- C01B39/08—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the aluminium atoms being wholly replaced
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
- C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
- C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
- C10G47/12—Inorganic carriers
- C10G47/16—Crystalline alumino-silicate carriers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S423/00—Chemistry of inorganic compounds
- Y10S423/27—Beta, e.g. NU-2
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inorganic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Abstract
Síntesis en medio alcalino de la zeolita ITQ-16. La presente invención se refiere a un procedimiento de síntesis en medio OH- y en ausencia de fluoruros de una familia de materiales zeolíticos que se engloban dentro de la denominación ITQ-16, y a sus aplicaciones catalíticas. Esta familia de materiales, zeolita ITQ-16, se caracteriza por tener relaciones diferentes de los distintos polimorfos A, B y C descritos como posibles intercrecimientos en la zeolita Beta, y que por consiguiente presenta patrones de difracción de rayos X diferentes al descrito para la zeolita Beta. La zeolita ITQ-16 en su forma calcinada tiene la siguiente fórmula empírica: x (MX02) : tT02: gGeO2 : (1- g)Si02 donde T es uno o varios elementos con estado de oxidación +4 distintos de Ge y Si; X es uno o varios elementos con estado de oxidación +3 y M puede ser H+ o uno o varios cationes inorgánicos de carga +n.
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ES200100385A ES2200624B1 (es) | 2001-02-09 | 2001-02-09 | Sintesis en medio alcalino de la zeolita itq.-16. |
PCT/ES2002/000057 WO2002064503A1 (es) | 2001-02-09 | 2002-02-08 | Sintesis en medio alcalino de la zeolita itq-16 |
CA002437132A CA2437132A1 (en) | 2001-02-09 | 2002-02-08 | Synthesis of zeolite itq-16 in an alkaline medium |
EP02710892A EP1364913A1 (en) | 2001-02-09 | 2002-02-08 | Synthesis of zeolite itq-16 in an alkaline medium |
JP2002564441A JP2004523457A (ja) | 2001-02-09 | 2002-02-08 | アルカリ性媒体中でのゼオライトitq−16の合成 |
US10/632,535 US7056489B2 (en) | 2001-02-09 | 2003-08-01 | Synthesis of zeolite ITQ-16 in an alkaline medium |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ES200100385A ES2200624B1 (es) | 2001-02-09 | 2001-02-09 | Sintesis en medio alcalino de la zeolita itq.-16. |
Publications (2)
Publication Number | Publication Date |
---|---|
ES2200624A1 true ES2200624A1 (es) | 2004-03-01 |
ES2200624B1 ES2200624B1 (es) | 2005-05-01 |
Family
ID=8496800
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES200100385A Expired - Fee Related ES2200624B1 (es) | 2001-02-09 | 2001-02-09 | Sintesis en medio alcalino de la zeolita itq.-16. |
Country Status (6)
Country | Link |
---|---|
US (1) | US7056489B2 (es) |
EP (1) | EP1364913A1 (es) |
JP (1) | JP2004523457A (es) |
CA (1) | CA2437132A1 (es) |
ES (1) | ES2200624B1 (es) |
WO (1) | WO2002064503A1 (es) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2196963B1 (es) * | 2001-07-03 | 2005-02-16 | Universidad Politecnica De Valencia | Sintesis de itq-17 en ausencia de iones fluoruro. |
JP2004010537A (ja) * | 2002-06-06 | 2004-01-15 | Mitsubishi Chemicals Corp | 水熱合成用テンプレート、ケイ素含有層状化合物の製造方法及びケイ素含有層状化合物 |
FR2860224B1 (fr) * | 2003-09-26 | 2006-06-02 | Inst Francais Du Petrole | Solide cristallise im-12 et son procede de preparation |
CA2631560C (en) * | 2005-12-20 | 2014-08-12 | Exxonmobil Research And Engineering Company | Itq-26, new crystalline microporous material |
CA2584876A1 (en) * | 2007-02-02 | 2008-08-02 | Albemarle Netherlands Bv | A crystalline microporous material of zeolitic nature |
WO2009134534A2 (en) * | 2008-05-02 | 2009-11-05 | Exxonmobil Chemical Patents Inc. | Treatment of small pore molecular sieves and their use in the conversion of oxygenates to olefins |
US8865121B2 (en) * | 2009-06-18 | 2014-10-21 | Basf Se | Organotemplate-free synthetic process for the production of a zeolitic material |
ES2462872B1 (es) | 2012-10-25 | 2015-03-10 | Consejo Superior Investigacion | Catalizador y proceso catalítico para la eterificación/reducción de furfuril derivados a tetrahidro-furfuril éteres |
CN104692407B (zh) * | 2015-02-28 | 2016-08-31 | 中国石油天然气股份有限公司 | 一种ith结构稀土硅铝分子筛及其合成方法 |
CN105905921A (zh) * | 2016-06-29 | 2016-08-31 | 北京化工大学 | 一种itq-16分子筛的合成方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1995022507A1 (en) * | 1994-02-18 | 1995-08-24 | Chevron U.S.A. Inc. | Zeolite ssz-42 |
WO1998029338A1 (en) * | 1996-12-31 | 1998-07-09 | Chevron U.S.A. Inc. | Zeolite ssz-45 |
ES2128961A1 (es) * | 1996-12-18 | 1999-05-16 | Univ Politecnica De Valencia C | Zeolitaitq-4. |
ES2152143A1 (es) * | 1998-02-06 | 2001-01-16 | Univ Valencia Politecnica | Sintesis de zeolitas y zeotipos de poro grande. |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
USRE28341E (en) | 1964-05-01 | 1975-02-18 | Marshall dann | |
US6787124B2 (en) * | 2002-03-15 | 2004-09-07 | Exxonmobil Research And Engineering Company | Synthetic porous crystalline material, EMM-1, its synthesis and use |
US6733742B1 (en) * | 2002-12-26 | 2004-05-11 | Chevron U.S.A. Inc. | Molecular sieve SSZ-63 composition of matter and synthesis thereof |
-
2001
- 2001-02-09 ES ES200100385A patent/ES2200624B1/es not_active Expired - Fee Related
-
2002
- 2002-02-08 EP EP02710892A patent/EP1364913A1/en not_active Withdrawn
- 2002-02-08 CA CA002437132A patent/CA2437132A1/en not_active Abandoned
- 2002-02-08 JP JP2002564441A patent/JP2004523457A/ja not_active Ceased
- 2002-02-08 WO PCT/ES2002/000057 patent/WO2002064503A1/es active Application Filing
-
2003
- 2003-08-01 US US10/632,535 patent/US7056489B2/en not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1995022507A1 (en) * | 1994-02-18 | 1995-08-24 | Chevron U.S.A. Inc. | Zeolite ssz-42 |
ES2128961A1 (es) * | 1996-12-18 | 1999-05-16 | Univ Politecnica De Valencia C | Zeolitaitq-4. |
WO1998029338A1 (en) * | 1996-12-31 | 1998-07-09 | Chevron U.S.A. Inc. | Zeolite ssz-45 |
ES2152143A1 (es) * | 1998-02-06 | 2001-01-16 | Univ Valencia Politecnica | Sintesis de zeolitas y zeotipos de poro grande. |
Also Published As
Publication number | Publication date |
---|---|
US20040089587A1 (en) | 2004-05-13 |
CA2437132A1 (en) | 2002-08-22 |
ES2200624B1 (es) | 2005-05-01 |
US7056489B2 (en) | 2006-06-06 |
EP1364913A1 (en) | 2003-11-26 |
WO2002064503A1 (es) | 2002-08-22 |
JP2004523457A (ja) | 2004-08-05 |
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Legal Events
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