ES2193909T3 - Procedimiento para la preparacion de esteres de acidos fosfinicos. - Google Patents

Procedimiento para la preparacion de esteres de acidos fosfinicos.

Info

Publication number
ES2193909T3
ES2193909T3 ES00109475T ES00109475T ES2193909T3 ES 2193909 T3 ES2193909 T3 ES 2193909T3 ES 00109475 T ES00109475 T ES 00109475T ES 00109475 T ES00109475 T ES 00109475T ES 2193909 T3 ES2193909 T3 ES 2193909T3
Authority
ES
Spain
Prior art keywords
esters
preparation
procedure
phosphinic acids
phosphorous
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES00109475T
Other languages
English (en)
Inventor
Sebastian Dr Horold
Norbert Dr Weferling
Heinz-Peter Breuer
Martin Dr Sicken
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Clariant Produkte Deutschland GmbH
Original Assignee
Clariant GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Clariant GmbH filed Critical Clariant GmbH
Application granted granted Critical
Publication of ES2193909T3 publication Critical patent/ES2193909T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/48—Phosphonous acids [RP(OH)2] including [RHP(=O)(OH)]; Thiophosphonous acids including [RP(SH)2], [RHP(=S)(SH)]; Derivatives thereof
    • C07F9/4808—Phosphonous acids [RP(OH)2] including [RHP(=O)(OH)]; Thiophosphonous acids including [RP(SH)2], [RHP(=S)(SH)]; Derivatives thereof the acid moiety containing a substituent or structure which is considered as characteristic
    • C07F9/4816—Acyclic saturated acids or derivatices which can have further substituents on alkyl
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/30—Phosphinic acids [R2P(=O)(OH)]; Thiophosphinic acids ; [R2P(=X1)(X2H) (X1, X2 are each independently O, S or Se)]
    • C07F9/32—Esters thereof
    • C07F9/3205—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
    • C07F9/3211—Esters of acyclic saturated acids which can have further substituents on alkyl

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Fireproofing Substances (AREA)

Abstract

Procedimiento para la preparación de ésteres de ácido fosfínico, caracterizado porque a) se hace reaccionar fósforo amarillo elemental con agentes de alquilación en presencia de una base para formar una mezcla, que como constituyentes principales contiene las sales (metálicas) de los ácidos alquil- fosfonosos, fosforoso hipofosforoso, b) los constituyentes principales de la mezcla procedente de a) se esterifican para formar una mezcla de ésteres, c) se aísla el éster de un ácido alquil-fosfonoso a partir de la mezcla de ésteres, d) el éster de un ácido alquil-fosfonoso, así obtenido, se hace reaccionar por adición con una olefina que tiene un grupo funcional.
ES00109475T 1999-05-25 2000-05-04 Procedimiento para la preparacion de esteres de acidos fosfinicos. Expired - Lifetime ES2193909T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19923617A DE19923617C2 (de) 1999-05-25 1999-05-25 Verfahren zur Herstellung von Phosphinsäureestern

Publications (1)

Publication Number Publication Date
ES2193909T3 true ES2193909T3 (es) 2003-11-16

Family

ID=7908918

Family Applications (1)

Application Number Title Priority Date Filing Date
ES00109475T Expired - Lifetime ES2193909T3 (es) 1999-05-25 2000-05-04 Procedimiento para la preparacion de esteres de acidos fosfinicos.

Country Status (6)

Country Link
US (1) US6278012B1 (es)
EP (1) EP1055677B1 (es)
JP (1) JP2001026596A (es)
AT (1) ATE233775T1 (es)
DE (2) DE19923617C2 (es)
ES (1) ES2193909T3 (es)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MX210830B (es) * 1998-09-01 2002-10-11 Clariant Finance Bvi Ltd Proceso para la produccion de compuestos organicos de fosforo
DE19912920C2 (de) 1999-03-22 2001-06-21 Clariant Gmbh Polymere Phosphinsäuren und deren Salze
DE19923615C1 (de) * 1999-05-25 2000-12-14 Clariant Gmbh Verfahren zur Herstellung von Alkylphosphonigsäureestern
DE19923743C2 (de) * 1999-05-25 2002-03-07 Clariant Gmbh Verfahren zur Herstellung von (Metall)salzen von Alkylphosphonigen Säuren II
DE19923830C1 (de) * 1999-05-25 2001-02-01 Clariant Gmbh Verfahren zur Herstellung von Metallsalzen von Alkylphosphonigen Säuren I
DE10065051A1 (de) * 2000-12-23 2002-07-04 Clariant Gmbh Verfahren zur Herstellung von Ethanbis(alkylphosphinsäuren)
DE10153780C1 (de) * 2001-11-02 2002-11-28 Clariant Gmbh Verfahren zur Herstellung von Carboxyethylmethylphosphinsäureglykolester und ihre Verwendung
US6781011B2 (en) 2002-12-13 2004-08-24 Texas Christian University Bis-H-phosphinic acid derivatives as precursors to therapeutic bisphosphonates and uses thereof
CN1732155A (zh) * 2002-12-27 2006-02-08 三共农业株式会社 4－氨基－5－甲基吡唑衍生物及其制备方法
DE102006010361A1 (de) * 2006-03-07 2007-09-13 Clariant International Limited Mischungen aus Mono-Carboxylfunktionalisierten Dialkylphosphinsäureestern und weiteren Komponenten
DE102007032669A1 (de) * 2007-07-13 2009-01-15 Clariant International Limited Alkylphosphonigsäuren, -salze und -ester, Verfahren zu deren Herstellung und ihre Verwendung
DE102008056235A1 (de) * 2008-11-06 2010-05-12 Clariant International Limited Verfahren zur Herstellung von monovinylfunktionalisierten Dialkylphosphinsäuren, deren Salze und Ester und ihre Verwendung
DE102008056341A1 (de) * 2008-11-07 2010-05-12 Clariant International Limited Verfahren zur Herstellung von monoaminofunktionalisierten Dialkylphosphinsäuren, -estern und -salzen mittels Acrylnitrilen und ihre Verwendung
DE102008060035A1 (de) * 2008-12-02 2010-06-10 Clariant International Limited Verfahren zur Herstellung von mono-hydroxyfunktionalisierten Dialkylphosphinsäuren, -estern und -salzen mittels Vinylester einer Carbonsäure und ihre Verwendung
US9181487B2 (en) * 2008-12-18 2015-11-10 Clariant Finance (Bvi) Limited Process for preparing ethylenedialkylphosphinic acids, esters and salts by means of acetylene and use thereof
DE102008063668A1 (de) * 2008-12-18 2010-07-01 Clariant International Limited Verfahren zur Herstellung von Alkylphosponsäuren, -estern und -salzen mittels Oxidation von Alkylphosphonigsäuren und ihre Verwendung
DE102008064003A1 (de) * 2008-12-19 2010-06-24 Clariant International Limited Verfahren zur Herstellung von mono-funktionalisierten Dialkylphosphinsäuren, -estern und -salzen und ihre Verwendung
WO2013045965A1 (en) 2011-09-28 2013-04-04 Italmatch Chemicals S.P.A. Halogen-free flame retardant polyesters composition
ES2577178T3 (es) 2011-09-28 2016-07-13 Italmatch Chemicals S.P.A. Composición de poliamida ignífuga libre de halógeno
ES2656960T3 (es) 2013-12-12 2018-03-01 Italmatch Chemicals S.P.A Composiciones de moldeo de poliamida retardante a las llamas libres de halógeno con una resistencia incrementada al hilo incandescente y al fuego
CU20160168A7 (es) * 2014-05-13 2017-06-05 Bayer Cropscience Ag Proceso para preparar cianhidrinas que contienen fósforo
US10188573B2 (en) 2014-11-05 2019-01-29 Allen Medical Systems, Inc. Boot stirrup
WO2017047096A1 (ja) * 2015-09-18 2017-03-23 片山化学工業株式会社 単純付加反応
KR102675718B1 (ko) 2018-12-03 2024-06-14 이탈마치 케미칼스 에스피에이 무기 하이포아인산 금속염을 포함하는 폴리올레핀 무할로겐 난연 성형 조성물
WO2020201811A1 (en) 2019-04-02 2020-10-08 Italmatch Chemicals S.P.A. Non-flammable hypophosphite metal salt based powders and their use as flame retardant ingredients
CN113620989B (zh) * 2021-08-23 2023-05-19 河北威远生物化工有限公司 一种甲基亚膦酸酯的合成方法

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2957931A (en) * 1949-07-28 1960-10-25 Socony Mobil Oil Co Inc Synthesis of compounds having a carbonphosphorus linkage
DE2540283C3 (de) 1975-09-10 1981-10-01 Hoechst Ag, 6000 Frankfurt Verfahren zur Herstellung von carboxylgruppenhaltigen organischen Phosphorverbindungen
DE2652007A1 (de) 1976-11-15 1978-05-18 Hoechst Ag Neue, phosphorhaltige epoxidharze, verfahren zu ihrer herstellung und ihre verwendung zur flammfestausruestung
DE2849003A1 (de) 1978-11-11 1980-08-21 Hoechst Ag Phosphorhaltige cyanhydrinderivate und verfahren zu ihrer herstellung
US5399428A (en) 1994-03-11 1995-03-21 Monsanto Company Flame retardant polyester copolymers
DE19752736A1 (de) * 1997-11-28 1999-08-19 Clariant Gmbh Verfahren zur Alkylierung von gelbem Phosphor
DE19828863C1 (de) * 1998-06-29 1999-09-02 Clariant Gmbh Verfahren zur Herstellung von Phosphinsäureestern und deren Verwendung
DE19828861C1 (de) * 1998-06-29 1999-12-02 Clariant Gmbh Verfahren zur Herstellung von Phosphonigsäureestern und deren Verwendung

Also Published As

Publication number Publication date
JP2001026596A (ja) 2001-01-30
EP1055677B1 (de) 2003-03-05
EP1055677A3 (de) 2001-03-14
DE19923617C2 (de) 2001-10-31
EP1055677A2 (de) 2000-11-29
US6278012B1 (en) 2001-08-21
DE50001357D1 (de) 2003-04-10
DE19923617A1 (de) 2000-11-30
ATE233775T1 (de) 2003-03-15

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