ES2191402T3 - Procedimiento para la produccion de monoxido de carbono. - Google Patents

Procedimiento para la produccion de monoxido de carbono.

Info

Publication number
ES2191402T3
ES2191402T3 ES99401543T ES99401543T ES2191402T3 ES 2191402 T3 ES2191402 T3 ES 2191402T3 ES 99401543 T ES99401543 T ES 99401543T ES 99401543 T ES99401543 T ES 99401543T ES 2191402 T3 ES2191402 T3 ES 2191402T3
Authority
ES
Spain
Prior art keywords
column
carbon monoxide
sent
gas
methane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES99401543T
Other languages
English (en)
Inventor
Jean Billy
Francois Fuentes
Nathalie Sosson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Air Liquide SA
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Original Assignee
Air Liquide SA
LAir Liquide SA a Directoire et Conseil de Surveillance pour lEtude et lExploitation des Procedes Georges Claude
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Air Liquide SA, LAir Liquide SA a Directoire et Conseil de Surveillance pour lEtude et lExploitation des Procedes Georges Claude filed Critical Air Liquide SA
Application granted granted Critical
Publication of ES2191402T3 publication Critical patent/ES2191402T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/40Carbon monoxide
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0228Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
    • F25J3/0261Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of carbon monoxide
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/506Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification at low temperatures
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0204Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the feed stream
    • F25J3/0223H2/CO mixtures, i.e. synthesis gas; Water gas or shifted synthesis gas
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0228Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
    • F25J3/0252Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of hydrogen
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465Composition of the impurity
    • C01B2203/047Composition of the impurity the impurity being carbon monoxide
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465Composition of the impurity
    • C01B2203/048Composition of the impurity the impurity being an organic compound
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2200/00Processes or apparatus using separation by rectification
    • F25J2200/40Features relating to the provision of boil-up in the bottom of a column
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2200/00Processes or apparatus using separation by rectification
    • F25J2200/70Refluxing the column with a condensed part of the feed stream, i.e. fractionator top is stripped or self-rectified
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2205/00Processes or apparatus using other separation and/or other processing means
    • F25J2205/02Processes or apparatus using other separation and/or other processing means using simple phase separation in a vessel or drum
    • F25J2205/04Processes or apparatus using other separation and/or other processing means using simple phase separation in a vessel or drum in the feed line, i.e. upstream of the fractionation step
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2205/00Processes or apparatus using other separation and/or other processing means
    • F25J2205/40Processes or apparatus using other separation and/or other processing means using hybrid system, i.e. combining cryogenic and non-cryogenic separation techniques
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2205/00Processes or apparatus using other separation and/or other processing means
    • F25J2205/60Processes or apparatus using other separation and/or other processing means using adsorption on solid adsorbents, e.g. by temperature-swing adsorption [TSA] at the hot or cold end
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2205/00Processes or apparatus using other separation and/or other processing means
    • F25J2205/80Processes or apparatus using other separation and/or other processing means using membrane, i.e. including a permeation step
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2210/00Processes characterised by the type or other details of the feed stream
    • F25J2210/04Mixing or blending of fluids with the feed stream
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2245/00Processes or apparatus involving steps for recycling of process streams
    • F25J2245/02Recycle of a stream in general, e.g. a by-pass stream
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2270/00Refrigeration techniques used
    • F25J2270/04Internal refrigeration with work-producing gas expansion loop
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S62/00Refrigeration
    • Y10S62/92Carbon monoxide

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Separation By Low-Temperature Treatments (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Abstract

Producción de monóxido de carbono e hidrógeno a partir de una mezcla gaseosa que también contiene metano. El proceso está simplificado y el número de elementos del equipo reducido, mientras que se mantiene un alto rendimiento y pureza de hidrógeno. Hay menos columnas de separación y se han eliminado la columna lavadora y la columna de destilación para separar el monóxido de carbono y el metano. La instalación para este procedimiento solo requiere dos columnas lavadoras y dos separadores de fase. La mezcla se refrigera, se condensa parcialmente y se envía a un separador de fases (A). El condensado va a una columna lavadora (B) para proporcionar hidrógeno gaseoso (H{sub,2}) por cabeza y un líquido que contiene metano y monóxido de carbono (CO) por cola. El gas se condensa parcialmente en un cambiador de calor (K) y se separa en un separador e fases (H) en H{sub,2} y un condensado. El condensado se envía a un columna lavadora (I) dando un H{sub,2} gaseoso rico por cabeza y un COlíquido rico por cola. El gas se calienta y se recicla a la mezcla para ser tratado. La fracción líquida de la primera columna puede enviarse a una columna de purificación (C) para producir monóxido de carbono puro por cabeza y un líquido rico en metano por cola. El gas de la primera columna y del primer separador se envían a una unidad de permeación o adsorción o se recicla al principio del proceso. La energía de separación se suministra mediante una expansión de Joule Thomson de la mezcla existente o mediante intercambio de calor con un líquido criogénico o mediante inyección de un líquido criogénico en una de las columnas.
ES99401543T 1998-06-26 1999-06-22 Procedimiento para la produccion de monoxido de carbono. Expired - Lifetime ES2191402T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9808139A FR2780391B1 (fr) 1998-06-26 1998-06-26 Procede de production de monoxyde de carbone

Publications (1)

Publication Number Publication Date
ES2191402T3 true ES2191402T3 (es) 2003-09-01

Family

ID=9527913

Family Applications (1)

Application Number Title Priority Date Filing Date
ES99401543T Expired - Lifetime ES2191402T3 (es) 1998-06-26 1999-06-22 Procedimiento para la produccion de monoxido de carbono.

Country Status (11)

Country Link
US (1) US6173585B1 (es)
EP (1) EP0968959B1 (es)
JP (1) JP2000065469A (es)
KR (1) KR100573528B1 (es)
CN (1) CN1131410C (es)
DE (1) DE69905426T2 (es)
ES (1) ES2191402T3 (es)
FR (1) FR2780391B1 (es)
MY (1) MY119591A (es)
SG (1) SG71212A1 (es)
TW (1) TWI220867B (es)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1215458B1 (en) * 2000-12-18 2005-02-09 Air Products And Chemicals, Inc. Process and apparatus for the separation of carbon monoxide and hydrogen from a gaseous mixture thereof
US6568206B2 (en) 2001-07-18 2003-05-27 Air Products And Chemicals, Inc. Cryogenic hydrogen and carbon monoxide production with membrane permeate expander
FR2843447B1 (fr) * 2003-09-30 2009-02-06 Air Liquide Procede et installation de production de monoxyde de carbone par distillation cryogenique
DE102005021530A1 (de) * 2005-05-10 2006-11-23 Linde Ag Verfahren und Vorrichtung zur Gewinnung von Produkten aus Synthesegas
DE102005025651A1 (de) * 2005-06-03 2006-12-07 Linde Ag Verfahren und Vorrichtung zur Gewinnung von Produkten aus Synthesegas
FR2911390B1 (fr) * 2007-01-16 2009-04-17 Air Liquide Procede et appareil de production de monoxyde de carbone par distillation cryogenique
DE102008059716A1 (de) * 2008-11-29 2010-06-02 Linde Ag Prozess zur Minimierung von Rückführgas in einem Kondensationsprozess
US8640495B2 (en) * 2009-03-03 2014-02-04 Ait Products and Chemicals, Inc. Separation of carbon monoxide from gaseous mixtures containing carbon monoxide
CN102288008B (zh) * 2011-08-04 2013-06-12 成都蜀远煤基能源科技有限公司 煤制气来原料气的一氧化碳提取方法
CN102674347A (zh) * 2012-05-17 2012-09-19 四川亚连科技有限责任公司 一种低温蒸馏制备一氧化碳的方法
CN103657133B (zh) * 2013-12-06 2015-07-22 福建恒嘉环保设备有限公司 一种高效节能的冷凝装置
CN104495751B (zh) * 2015-01-12 2017-09-08 上海启元空分技术发展股份有限公司 一种高效分离合成气制取氢气及一氧化碳的方法及装置
DE102015012317A1 (de) * 2015-09-23 2017-03-23 Linde Aktiengesellschaft Verfahren und Anlage zur trenntechnischen Bearbeitung eines Gasgemischs
DE102016012616A1 (de) * 2016-10-20 2018-04-26 Linde Aktiengesellschaft Verfahren und Vorrichtung zur kryogenen Zerlegung von Synthesegas
FR3057942B1 (fr) 2016-10-21 2019-12-27 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Procede et appareil de separation cryogenique d’un gaz de synthese par condensation partielle
CN107490244B (zh) * 2017-07-27 2023-05-30 四川蜀道装备科技股份有限公司 一种低功耗co深冷分离系统及其分离方法
US20210254891A1 (en) * 2020-02-14 2021-08-19 Joseph Michael Schwartz Method for an improved partial condensation carbon monoxide cold box operation
CN111486662A (zh) * 2020-03-31 2020-08-04 北京三泰天洁气体净化技术有限公司 一种低温分离合成气以及制备氨合成气的方法和装置

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4732583B1 (en) * 1984-12-03 1990-05-15 Gas separation
US4589896A (en) * 1985-01-28 1986-05-20 Air Products And Chemicals, Inc. Process for separating CO2 and H2 S from hydrocarbons
US4654047A (en) * 1985-08-23 1987-03-31 Air Products And Chemicals, Inc. Hybrid membrane/cryogenic process for hydrogen purification
FR2636250B1 (fr) * 1988-09-12 1992-01-17 Air Liquide Procede et installation de recuperation d'hydrogene et de monoxyde de carbone
DE4210638A1 (de) * 1991-09-12 1993-03-18 Linde Ag Verfahren zur gewinnung von hochreinem wasserstoff und hochreinem kohlenmonoxid
DE4325513A1 (de) * 1993-06-17 1994-12-22 Linde Ag Verfahren zur Gewinnung eines hochreinen Kohlenmonoxid-Produktstromes und eines Wasserstoff-Produktstromes
FR2718428B1 (fr) * 1994-04-11 1997-10-10 Air Liquide Procédé et installation de production de monoxyde de carbone.
FR2718725B1 (fr) * 1994-04-13 1996-05-24 Air Liquide Procédé et installation de séparation d'un mélange gazeux.
DE4433114A1 (de) * 1994-09-16 1996-03-21 Linde Ag Verfahren zum Gewinnen einer Kohlenmonoxid-Reinfraktion
FR2735990B1 (fr) * 1995-06-30 1997-08-14 Air Liquide Procede et dispositif pour la preparation d'un flux substantiellement epure en l'une au moins des impuretes oxygene et monoxyde de carbone

Also Published As

Publication number Publication date
DE69905426T2 (de) 2003-11-20
FR2780391B1 (fr) 2000-10-20
TWI220867B (en) 2004-09-11
JP2000065469A (ja) 2000-03-03
US6173585B1 (en) 2001-01-16
CN1131410C (zh) 2003-12-17
EP0968959B1 (fr) 2003-02-19
MY119591A (en) 2005-06-30
DE69905426D1 (de) 2003-03-27
FR2780391A1 (fr) 1999-12-31
SG71212A1 (en) 2000-03-21
CN1252517A (zh) 2000-05-10
KR20000006459A (ko) 2000-01-25
KR100573528B1 (ko) 2006-04-26
EP0968959A1 (fr) 2000-01-05

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