ES2177916T3 - Procedimiento de produccion de isobuteno de alta pureza combinando una destilacion asociada a reaccion de hidroisomerizacion, una destilacion y una isomerizacion estructurada. - Google Patents

Procedimiento de produccion de isobuteno de alta pureza combinando una destilacion asociada a reaccion de hidroisomerizacion, una destilacion y una isomerizacion estructurada.

Info

Publication number
ES2177916T3
ES2177916T3 ES97403049T ES97403049T ES2177916T3 ES 2177916 T3 ES2177916 T3 ES 2177916T3 ES 97403049 T ES97403049 T ES 97403049T ES 97403049 T ES97403049 T ES 97403049T ES 2177916 T3 ES2177916 T3 ES 2177916T3
Authority
ES
Spain
Prior art keywords
distillation
area
effluent
isomerization
structured
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES97403049T
Other languages
English (en)
Inventor
Michel Dorbon
Jean-Alain Chodorge
Jean Cosyns
Jean-Charles Viltard
Blaise Didillon
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Application granted granted Critical
Publication of ES2177916T3 publication Critical patent/ES2177916T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/08—Alkenes with four carbon atoms
    • C07C11/09—Isobutene
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G7/00—Distillation of hydrocarbon oils
    • C10G7/08—Azeotropic or extractive distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2767—Changing the number of side-chains
    • C07C5/277—Catalytic processes
    • C07C5/2791—Catalytic processes with metals
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/42—Platinum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/44—Palladium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/46—Ruthenium, rhodium, osmium or iridium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/755—Nickel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1088—Olefins
    • C10G2300/1092—C2-C4 olefins
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S203/00—Distillation: processes, separatory
    • Y10S203/06—Reactor-distillation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

LA INVENCION SE REFIERE A UN METODO DE PRODUCCION DE ISOBUTENO DE ELEVADA PUREZA A PARTIR DE UNA FRACCION DE HIDROCARBUROS FORMADA ESENCIALMENTE POR HIDROCARBUROS OLEFINICOS DE 4 ATOMOS DE CARBONO POR MOLECULA E ISOBUTENO, ADEMAS DE BUTENO - 1 Y BUTENOS - 2 EN RELACION EQUIVALENTE EN ESENCIA AL EQUILIBRIO TERMODINAMICO; DICHO METODO COMPRENDE EL PASO DE LA MENCIONADA FRACCION A UNA ZONA (3) DE DESTILACION ASOCIADA CON UNA ZONA DE REACCION DE HIDROISOMERIZACION; EL FONDO DE LA ZONA DE DESTILACION QUE CONTIENE LOS BUTENOS - 2 SE PASA A UNA SEGUNDA ZONA DE DESTILACION (4), PREFERIBLEMENTE EXTRACTIVA, QUE PERMITE OBTENER UN PRIMER EFLUENTE FORMADO EN SU MAYOR PARTE POR BUTENOS - 2 Y UN SEGUNDO EFLUENTE FORMADO EN SU MAYOR PARTE POR BUTANO NORMAL; DICHO PRIMER EFLUENTE PASA EN SU MAYOR PARTE A UNA ZONA DE ISOMERIZACION ESTRUCTURAL (2) DONDE LOS BUTENOS LINEALES SE ISOMERIZAN, AL MENOS PARCIALMENTE, EN ISOBUTENO; EL EFLUENTE PRINCIPAL DE LA ZONA DE ISOMERIZACION ESTRUCTURAL SE RECICLA AL MENOS ENPARTE HACIA LA ENTRADA A LA ZONA DE DESTILACION REACTIVA.
ES97403049T 1996-12-23 1997-12-15 Procedimiento de produccion de isobuteno de alta pureza combinando una destilacion asociada a reaccion de hidroisomerizacion, una destilacion y una isomerizacion estructurada. Expired - Lifetime ES2177916T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9616022A FR2757505B1 (fr) 1996-12-23 1996-12-23 Procede de production d'isobutene de haute purete combinant une distillation reactive d'hydroisomerisation, une distillation et une isomerisation squelettale

Publications (1)

Publication Number Publication Date
ES2177916T3 true ES2177916T3 (es) 2002-12-16

Family

ID=9499143

Family Applications (1)

Application Number Title Priority Date Filing Date
ES97403049T Expired - Lifetime ES2177916T3 (es) 1996-12-23 1997-12-15 Procedimiento de produccion de isobuteno de alta pureza combinando una destilacion asociada a reaccion de hidroisomerizacion, una destilacion y una isomerizacion estructurada.

Country Status (7)

Country Link
US (1) US5969203A (es)
EP (1) EP0850904B1 (es)
JP (1) JP4235924B2 (es)
KR (1) KR100530714B1 (es)
DE (1) DE69713048T2 (es)
ES (1) ES2177916T3 (es)
FR (1) FR2757505B1 (es)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2752236B1 (fr) * 1996-08-08 1998-09-11 Inst Francais Du Petrole Procede de production d'isobutene de haute purete a partir d'une coupe c4 contenant de l'isobutene et du butene-1
EP0938926B1 (fr) * 1998-02-26 2003-08-13 Institut Francais Du Petrole Catalyseur comprenant une zéolithe choise dans le groupe formé par les zéolithes NU-85, NU-86 et NU-87 et son utilisation en hydroconversion de charges pétrolières hydrocarbonées
FR2779072B1 (fr) * 1998-05-28 2000-07-13 Inst Francais Du Petrole Catalyseur comprenant une zeolithe choisie dans le groupe forme par les zeolithes nu-85, nu-86 et nu-87, un element du groupe vb et son utilisation en hydroconversion de charges petrolieres hydrocarbonees
US6242661B1 (en) * 1999-07-16 2001-06-05 Catalytic Distillation Technologies Process for the separation of isobutene from normal butenes
US6500309B1 (en) * 1999-12-11 2002-12-31 Peter Tung Dimensions in reactive distillation technology
ES2219482T3 (es) 2000-08-29 2004-12-01 Bp Koln Gmbh Procedimiento para la preparacion selectiva de di-isobutileno a partir de una corriente de c4 que contiene i-buteno.
DE10056685A1 (de) * 2000-11-15 2002-06-06 Max Planck Gesellschaft Verfahren zur Abtrennung von mindestens einer reaktiven Komponente aus flüssigen Stoffgemischen und Vorrichtung zur Durchführung dieses Verfahrens
US20060235255A1 (en) * 2005-04-15 2006-10-19 Gartside Robert J Double bond hydroisomerization process
US20060235254A1 (en) * 2005-04-15 2006-10-19 Gartside Robert J Double bond hydroisomerization process
US7576251B2 (en) * 2005-04-15 2009-08-18 Abb Lummus Global Inc. Process for the double bond hydroisomerization of butenes
US7888541B2 (en) * 2005-04-15 2011-02-15 Catalytic Distillation Technologies Double bond hydroisomerization of butenes
US7982086B2 (en) * 2009-02-03 2011-07-19 Catalytic Distillation Technologies Deisobutenizer
KR101658545B1 (ko) * 2014-08-22 2016-09-21 대림산업 주식회사 폴리부텐의 제조방법
EP3604261A1 (de) * 2018-08-02 2020-02-05 Omv Refining & Marketing Gmbh Verfahren zur aufreinigung von isobuten aus einem c4-strom und verfahrenstechnische anlage dafür
CN114478161A (zh) * 2020-10-23 2022-05-13 中国石油化工股份有限公司 混合c4物流选择加氢的装置和方法

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3758604A (en) * 1971-03-19 1973-09-11 Exxon Research Engineering Co Isomerization-fractionation process
US4104321A (en) * 1977-03-18 1978-08-01 Uop Inc. Process for the separation of olefins
US4236027A (en) * 1977-10-17 1980-11-25 American Cyanamid Company Novel 11-alkoxy-9-keto (or hydroxy)-prostenoic acid derivatives and method for preparing same
US4255605A (en) * 1980-01-02 1981-03-10 Philliphs Petroleum Company Diisopropyl from butenes
JPS5920232A (ja) * 1982-07-26 1984-02-01 Japan Synthetic Rubber Co Ltd ｎ−ブテンの製造方法
JPS6118732A (ja) * 1984-07-06 1986-01-27 Mitsui Petrochem Ind Ltd Ｃ４炭化水素中のイソブチレンの濃縮方法
JPS6461434A (en) * 1987-08-31 1989-03-08 Tonen Sekiyukagaku Kk Method for isomerizing butene-1 contained in isobutylene to butene-2
US5621150A (en) * 1994-02-25 1997-04-15 Uop Process for the production of ethyl tert.-alkyl ethers
GB9404368D0 (en) * 1994-03-07 1994-04-20 Bp Chem Int Ltd Production of polyisobutenes
KR0175697B1 (ko) * 1995-08-03 1999-05-15 서곤 n-부텐으로부터 이소부텐으로의 전환방법
US5689015A (en) * 1996-03-08 1997-11-18 Phillips Petroleum Company Method for the production of ether and alkylate from a paraffin feedstock

Also Published As

Publication number Publication date
JP4235924B2 (ja) 2009-03-11
FR2757505B1 (fr) 1999-02-19
EP0850904B1 (fr) 2002-06-05
KR19980064502A (ko) 1998-10-07
KR100530714B1 (ko) 2006-02-28
US5969203A (en) 1999-10-19
JPH10182507A (ja) 1998-07-07
DE69713048T2 (de) 2002-09-19
DE69713048D1 (de) 2002-07-11
FR2757505A1 (fr) 1998-06-26
EP0850904A1 (fr) 1998-07-01

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