ES2175498T3 - Un procedimiento para la preparacion de un reactivo organico de zinc. - Google Patents
Un procedimiento para la preparacion de un reactivo organico de zinc.Info
- Publication number
- ES2175498T3 ES2175498T3 ES97950253T ES97950253T ES2175498T3 ES 2175498 T3 ES2175498 T3 ES 2175498T3 ES 97950253 T ES97950253 T ES 97950253T ES 97950253 T ES97950253 T ES 97950253T ES 2175498 T3 ES2175498 T3 ES 2175498T3
- Authority
- ES
- Spain
- Prior art keywords
- metal
- preparation
- organozinc
- halide salt
- hydrocarbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title abstract 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title 1
- 239000003153 chemical reaction reagent Substances 0.000 title 1
- 239000011701 zinc Substances 0.000 title 1
- 229910052725 zinc Inorganic materials 0.000 title 1
- 150000001875 compounds Chemical class 0.000 abstract 5
- 239000002184 metal Substances 0.000 abstract 4
- 229910052751 metal Inorganic materials 0.000 abstract 4
- 239000004215 Carbon black (E152) Substances 0.000 abstract 3
- -1 halide salt Chemical class 0.000 abstract 3
- 229930195733 hydrocarbon Natural products 0.000 abstract 3
- 150000002430 hydrocarbons Chemical class 0.000 abstract 3
- 125000003118 aryl group Chemical group 0.000 abstract 2
- 239000007795 chemical reaction product Substances 0.000 abstract 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 abstract 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 abstract 1
- VNDYJBBGRKZCSX-UHFFFAOYSA-L Zinc bromide Inorganic materials Br[Zn]Br VNDYJBBGRKZCSX-UHFFFAOYSA-L 0.000 abstract 1
- UAYWVJHJZHQCIE-UHFFFAOYSA-L Zinc iodide Inorganic materials I[Zn]I UAYWVJHJZHQCIE-UHFFFAOYSA-L 0.000 abstract 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 150000002902 organometallic compounds Chemical class 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
- 229940102001 zinc bromide Drugs 0.000 abstract 1
- 235000005074 zinc chloride Nutrition 0.000 abstract 1
- 239000011592 zinc chloride Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D213/28—Radicals substituted by singly-bound oxygen or sulphur atoms
- C07D213/30—Oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B53/00—Asymmetric syntheses
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/36—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions with formation of hydroxy groups, which may occur via intermediates being derivatives of hydroxy, e.g. O-metal
- C07C29/38—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions with formation of hydroxy groups, which may occur via intermediates being derivatives of hydroxy, e.g. O-metal by reaction with aldehydes or ketones
- C07C29/40—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions with formation of hydroxy groups, which may occur via intermediates being derivatives of hydroxy, e.g. O-metal by reaction with aldehydes or ketones with compounds containing carbon-to-metal bonds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
- C07F3/06—Zinc compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B2200/00—Indexing scheme relating to specific properties of organic compounds
- C07B2200/07—Optical isomers
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Compounds Of Unknown Constitution (AREA)
- Steroid Compounds (AREA)
- Measuring Or Testing Involving Enzymes Or Micro-Organisms (AREA)
- Catalysts (AREA)
Abstract
LA INVENCION SE REFIERE A UN PROCEDIMIENTO DE PREPARACION DE UN COMPUESTO AROMATICO DE ORGANOZINC. DICHO PROCEDIMIENTO CONSISTE EN HACER REACCIONAR UN CLORURO, BROMURO O IODURO DE ZINC Y UN COMPUESTO ORGANOMETALICO DE OTRO METAL QUE COMPRENDE UNA FRACCION AROMATICA, Y PRODUCIR UN PRODUCTO DE REACCION QUE COMPRENDE UN COMPUESTO DE ORGANOZINC Y UNA SAL DE HALURO DEL OTRO METAL. DICHO PRODUCTO DE REACCION SE HACE REACCIONAR A CONTINUACION CON UN HIDROCARBURO LIQUIDO, EN EL CUAL ES SOLUBLE EL COMPUESTO DE ORGANOZINC Y LA SAL DE HALURO DEL OTRO METAL ES DEBILMENTE SOLUBLE. LA SAL DE HALURO DEL OTRO METAL SE SEPARA DEL HIDROCARBURO, Y EL COMPUESTO DE ORGANOZINC SE PUEDE RECUPERAR A PARTIR DE DICHO HIDROCARBURO. LOS COMPUESTOS DE ORGANOZINC OBTENIDOS MEDIANTE DICHO PROCEDIMIENTO SE PUEDEN EMPLEAR PARA GENERAR CENTROS QUIRALES EN SUSTRATOS ADECUADOS.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GBGB9626635.8A GB9626635D0 (en) | 1996-12-21 | 1996-12-21 | Zinc reagent and synthesis |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2175498T3 true ES2175498T3 (es) | 2002-11-16 |
Family
ID=10804854
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES97950253T Expired - Lifetime ES2175498T3 (es) | 1996-12-21 | 1997-12-15 | Un procedimiento para la preparacion de un reactivo organico de zinc. |
Country Status (12)
Country | Link |
---|---|
US (1) | US6258967B1 (es) |
EP (1) | EP0946570B1 (es) |
JP (1) | JP2001507348A (es) |
AT (1) | ATE219086T1 (es) |
AU (1) | AU5327998A (es) |
CA (1) | CA2273942C (es) |
DE (1) | DE69713385T2 (es) |
DK (1) | DK0946570T3 (es) |
ES (1) | ES2175498T3 (es) |
GB (1) | GB9626635D0 (es) |
PT (1) | PT946570E (es) |
WO (1) | WO1998028306A1 (es) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2826963B1 (fr) * | 2001-07-04 | 2006-01-27 | Rhodia Chimie Sa | Preparation d'organozinciques aromatiques et composition pour ce faire |
US8089904B2 (en) | 2006-08-01 | 2012-01-03 | Opnet Technologies, Inc. | Link inference in large networks based on incomplete data |
EP2155759A4 (en) | 2007-05-07 | 2012-10-17 | Valorisation Rech Soc En Commandite | METHODS FOR THE PREPARATION OF DIORGANOZINC COMPOUNDS |
JP5488786B2 (ja) * | 2009-03-31 | 2014-05-14 | 宇部興産株式会社 | アザボラシクロペンテン化合物の製造方法及びその合成中間体 |
JP5423212B2 (ja) * | 2009-07-30 | 2014-02-19 | 宇部興産株式会社 | アミノアザボラシクロペンテン化合物の製造方法 |
WO2011115963A1 (en) * | 2010-03-16 | 2011-09-22 | Rieke Metals Inc. | Stabilized organometallic reagents |
JP6157358B2 (ja) * | 2010-12-22 | 2017-07-05 | ルートヴィヒ‐マクシミリアン‐ユニバーシタット ミュンヘン | 有機亜鉛錯体ならびに有機亜鉛錯体を作製および使用するための方法 |
WO2012147897A1 (ja) * | 2011-04-25 | 2012-11-01 | 住友化学株式会社 | アミン化合物の製造方法 |
CN103272645B (zh) * | 2013-06-19 | 2014-11-05 | 罗梅 | 一种手性锌配合物的用途 |
JP6505115B2 (ja) * | 2014-01-03 | 2019-04-24 | アルベマール ジャーマニー ゲゼルシャフト ミット ベシュレンクテル ハフツングAlbemarle Germany GmbH | 臭化亜鉛および臭化リチウムを含む非プロトン性溶液の製造方法 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB9012974D0 (en) * | 1990-06-11 | 1990-08-01 | Ici Plc | Chemical process |
-
1996
- 1996-12-21 GB GBGB9626635.8A patent/GB9626635D0/en active Pending
-
1997
- 1997-12-15 DK DK97950253T patent/DK0946570T3/da active
- 1997-12-15 CA CA002273942A patent/CA2273942C/en not_active Expired - Fee Related
- 1997-12-15 WO PCT/GB1997/003443 patent/WO1998028306A1/en active IP Right Grant
- 1997-12-15 PT PT97950253T patent/PT946570E/pt unknown
- 1997-12-15 AU AU53279/98A patent/AU5327998A/en not_active Abandoned
- 1997-12-15 AT AT97950253T patent/ATE219086T1/de not_active IP Right Cessation
- 1997-12-15 EP EP97950253A patent/EP0946570B1/en not_active Expired - Lifetime
- 1997-12-15 DE DE69713385T patent/DE69713385T2/de not_active Expired - Fee Related
- 1997-12-15 JP JP52851398A patent/JP2001507348A/ja not_active Withdrawn
- 1997-12-15 ES ES97950253T patent/ES2175498T3/es not_active Expired - Lifetime
- 1997-12-15 US US09/331,451 patent/US6258967B1/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
WO1998028306A1 (en) | 1998-07-02 |
CA2273942A1 (en) | 1998-07-02 |
US6258967B1 (en) | 2001-07-10 |
DE69713385D1 (de) | 2002-07-18 |
JP2001507348A (ja) | 2001-06-05 |
CA2273942C (en) | 2007-04-17 |
AU5327998A (en) | 1998-07-17 |
EP0946570A1 (en) | 1999-10-06 |
EP0946570B1 (en) | 2002-06-12 |
DK0946570T3 (da) | 2002-10-07 |
GB9626635D0 (en) | 1997-02-12 |
DE69713385T2 (de) | 2003-02-06 |
PT946570E (pt) | 2002-10-31 |
ATE219086T1 (de) | 2002-06-15 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
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