KR910011873A - 가수분해에 대해 안정한 유기포스 파이트의 제조방법 - Google Patents

가수분해에 대해 안정한 유기포스 파이트의 제조방법 Download PDF

Info

Publication number
KR910011873A
KR910011873A KR1019900020650A KR900020650A KR910011873A KR 910011873 A KR910011873 A KR 910011873A KR 1019900020650 A KR1019900020650 A KR 1019900020650A KR 900020650 A KR900020650 A KR 900020650A KR 910011873 A KR910011873 A KR 910011873A
Authority
KR
South Korea
Prior art keywords
process according
radical
amine
acid
carbon atoms
Prior art date
Application number
KR1019900020650A
Other languages
English (en)
Other versions
KR940001061B1 (ko
Inventor
바하만 헬뮤트
번하드펠
파파도기안키스 게오기스
Original Assignee
콘콜, 라이첼트
훽스트 악치엔 게젤샤프트
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 콘콜, 라이첼트, 훽스트 악치엔 게젤샤프트 filed Critical 콘콜, 라이첼트
Publication of KR910011873A publication Critical patent/KR910011873A/ko
Application granted granted Critical
Publication of KR940001061B1 publication Critical patent/KR940001061B1/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
    • C07F9/6574—Esters of oxyacids of phosphorus
    • C07F9/65744—Esters of oxyacids of phosphorus condensed with carbocyclic or heterocyclic rings or ring systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/06—Phosphorus compounds without P—C bonds
    • C07F9/08—Esters of oxyacids of phosphorus
    • C07F9/141—Esters of phosphorous acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
    • C07F9/6574—Esters of oxyacids of phosphorus
    • C07F9/65746—Esters of oxyacids of phosphorus the molecule containing more than one cyclic phosphorus atom

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Lubricants (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Catalysts (AREA)

Abstract

내용 없음

Description

가수분해에 대해 안정한 유기포스 파이트의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 식PX3또는(R3O) PX2(식에서 X는 염소, 브롬 또는 요오드이고 R3는 임의적으로 치환된 지방족, 고리지방족 또는 방향족 탄화수소 라디칼임)의 유기포스파이트 또는 인-할로겐 화합물을 물에 불용성 이고 유기용매에 용해되는 당량 또는 과량의 히도록시 술폰산의 암모늄염과 반응시키는 것으로 이루어지는, 가수분해에 대해 안정한 포스파이트의 제조방법.
  2. 제1항에 있어서, 히드록시술폰산의 암모늄염이 히드록시 술폰산의 수용액 또는 히드록시 술폰산의 수용성염의 산성화된 용액과 수불용성 유기용매내 수불용성아민의 용액과의 반응으로 수득된 생성물 형태로 사용되는 방법.
  3. 제2항에 있어서, 히드록시술폰산 또는 그의 수용성염이 하기식의 화합물인 방법.
    (MO3S)n-Y-(OH)m
    〔상기식에서 Y는 유기라디칼, M은 수소이온, 알칼리 금속이온 또는 식〔NP4〕4(식에서 R은 수소 및/또는 같거나 다른 직쇄 또는 분지쇄 C1-또는 C4-알킬라디칼임)의 암모늄이온 또는 알칼리토금속이온, 납이온 또는 구리이온의 등가물이며, m은 1-3의 정수이고 n은 1-4의 정수이다.
  4. 제2항에서 있어서, 식(MO3S)n-Y-(OH)m에서, Y는 탄소원자수 2-20의 직쇄 또는 분지쇄 포화 지방족 라디칼, 탄소원자수 5∼12의 단핵 또는 2핵 고리지방족 라디칼, 벤젠비페닐, 나프탈렌 또는 비나프틸로부터 유도된 라디칼, 벤질라디칼, 톨루엔, 에티벤젠, 또는 크실렌 이성질체로 부터 유도된 라디칼 또는 포화 또는 불포화질소함유 5-또는 6-원고리, 특히 피리딘으로 부터 유도된 라디칼인 방법.
  5. 제2항 내지 4항중 어느한항에 있어서, 히드록시술폰산의 염의 수용액의 H2SO4, HCL, HNO, H3PO4, HF 또는 HBF4에 의해 산성화되는 방법.
  6. 제2항 내지 5항중 어느한항에 있어서, 술폰산 다량 당 0.8-1.2몰의 아민이 사용되는 방법.
  7. 제1항 내지 6항중 어느 한항에 있어서, 유기용매에 용해되는 암모늄염이 전체 탄소원자수 10-60, 바람직하게는 12-36을 갖는 수불용성 직쇄 또는 분지쇄 지방족 아민으로 부터 유도되는 방법.
  8. 제2항 내지 7항중 어느 한항에 있어서, 톨루엔 또는 케로센형 탄화수소 분획이 아민에 대한 용매로서 사용되는 방법.
  9. 제1 내지 8항중 어느 한항에 있어서, 유기 포스파이트의 반응이 촉매로서 나트륨, 아민, 나트륨 알코올레이트, 알루미늄 클로라이드, 티탄산에스테르 또는 아인산 디알킬 에스테르 존재하에 수행되는 방법.
  10. 제1내지 9항중 어느 한항에 있어서, 트랜스 에스테르화 반응에 의해 유리된 페놀이 박막 증발기를 사용하여 연속적으로 진공 증류 제거되는 방법
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019900020650A 1989-12-23 1990-12-14 가수분해에 대해 안정한 유기포스파이트의 제조방법 KR940001061B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE3942787.0 1989-12-23
DEP3942787.0 1989-12-23
DE3942787A DE3942787A1 (de) 1989-12-23 1989-12-23 Verfahren zur herstellung hydrolysestabiler organischer phosphite

Publications (2)

Publication Number Publication Date
KR910011873A true KR910011873A (ko) 1991-08-07
KR940001061B1 KR940001061B1 (ko) 1994-02-12

Family

ID=6396314

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019900020650A KR940001061B1 (ko) 1989-12-23 1990-12-14 가수분해에 대해 안정한 유기포스파이트의 제조방법

Country Status (10)

Country Link
US (1) US5126475A (ko)
EP (1) EP0435071B1 (ko)
JP (1) JPH07110868B2 (ko)
KR (1) KR940001061B1 (ko)
AT (1) ATE114314T1 (ko)
AU (1) AU629079B2 (ko)
BR (1) BR9006501A (ko)
CA (1) CA2032371C (ko)
DE (2) DE3942787A1 (ko)
ES (1) ES2066945T3 (ko)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5292785A (en) * 1992-05-05 1994-03-08 Ciba-Geigy Corporation Bis-phosphite stabilized compositions
US5391799A (en) * 1992-05-05 1995-02-21 Ciba-Geigy Corporation Process for the preparation 6-chloro-2,4,8,10-tetra-butyldibenzo[d,f][1,3,2]dioxaphoshepin
US5786497A (en) * 1997-08-29 1998-07-28 General Electric Company Process for the preparation of phosphites
US5919966A (en) * 1998-03-26 1999-07-06 General Electric Company Process for the preparation of spiro bis-phosphites
US5917076A (en) * 1998-04-16 1999-06-29 General Electric Company Process for the preparation of spiro bis-phosphites using finely ground pentaerythritol
US6426429B1 (en) 2000-08-11 2002-07-30 General Electric Company Process for the preparation of hindered phosphites
US6504065B1 (en) 2000-09-29 2003-01-07 General Electric Company Method of making metal salts of 2,4,6-tri-t-butylphenol
DE10240050B3 (de) * 2002-08-30 2004-01-22 Bayer Ag Verfahren zur kombinierten Herstellung von Diethylphosphit und Ethylchlorid
EP2014752A1 (en) 2007-06-23 2009-01-14 Cognis IP Management GmbH Process for the manufacture of saturated fatty acid esters in the presence of a homogeneous complex of a Group VIII metal and a sulfonated phosphite

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2860898D1 (en) * 1977-08-08 1981-11-05 Ciba Geigy Ag Process for the preparation of triarylphosphites
FR2465740A1 (fr) * 1978-05-31 1981-03-27 Cellophane Sa Nouveaux derives du naphtalene diol-2,3

Also Published As

Publication number Publication date
US5126475A (en) 1992-06-30
AU629079B2 (en) 1992-09-24
AU6836890A (en) 1991-06-27
KR940001061B1 (ko) 1994-02-12
BR9006501A (pt) 1991-10-01
CA2032371C (en) 1995-04-04
EP0435071A3 (en) 1991-09-18
DE3942787A1 (de) 1991-06-27
ATE114314T1 (de) 1994-12-15
DE59007762D1 (de) 1995-01-05
JPH06239878A (ja) 1994-08-30
EP0435071A2 (de) 1991-07-03
JPH07110868B2 (ja) 1995-11-29
ES2066945T3 (es) 1995-03-16
EP0435071B1 (de) 1994-11-23

Similar Documents

Publication Publication Date Title
Cadogan Oxidation of tervalent organic compounds of phosphorus
EP1805107B1 (en) Process for the preparation of highly purified, dialkyl phosphinic acids
KR910011873A (ko) 가수분해에 대해 안정한 유기포스 파이트의 제조방법
US3899528A (en) Substituted ethane diphosphonic acids and salts and esters thereof
GB1440847A (en) Carboxyethyl ester of n-phosphonomethyl glycine salts thereof and their use as herbicides
US3812193A (en) Preparation of 3,3',5,5'-tetra-isopropyl-4,4'-hydroxydiphenyl
Beckwith Phosphorous and hypophosphorous acid derived radicals and their reactionsùan EPR study
Kargin et al. Electrochemical synthesis of organophosphorus compounds with P O, P N and P C bonds from white phosphorus
US3032500A (en) Sequestration of metal ions
Warren et al. The acid-catalysed decarboxylation of phosphonoformic acid
US3453301A (en) Tris-betahydroxyethyl phosphonomethylene ammonium compounds
ES482903A1 (es) Procedimiento para la obtencion de triesteres de acido fos- forico
US3962318A (en) Substituted ethane diphosphonic acids and salts and esters thereof
US3734954A (en) Polyphosphinic acids and salts thereof
JPH08193089A (ja) リン酸エステルの製造法
US3627842A (en) Process for the preparation of monohalogenated methylenediphosphonate esters, and phosphonoacetate esters
US3363032A (en) Long chain aliphatic benzylphosphonic acids, esters and salts
Michalski et al. 963. Anhydrides of organophosphorus acids. Part II. The synthesis of tri-and tetra-alkyl esters of phosphorous phosphoric anhydride
KR910018333A (ko) 1,4-부탄디올의 제조법
US3548040A (en) Process for the preparation of bis(beta-chloroethyl)vinyl phosphonates
CA1229621A (en) Metal ion control agents based on dicyclopentadiene derivatives
US3625999A (en) Process for the preparation of phosphonium sulfonate salts
Chenault et al. Side Reactions in the Phase Transfer Catalysed Wittig-Horner Synthesis. A Convenient Method of Preparation of Hydroxycinnamic Acids
DE2461906C3 (de) Phosphinoxide mit polyfluorierter Kette und Verfahren zu ihrer Herstellung
Brandsma et al. A convenient synthesis of tertiary phosphines from red phosphorus and aryl-or heteroarylethenes

Legal Events

Date Code Title Description
A201 Request for examination
E902 Notification of reason for refusal
G160 Decision to publish patent application
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 20000113

Year of fee payment: 7

LAPS Lapse due to unpaid annual fee