ES482903A1 - Procedimiento para la obtencion de triesteres de acido fos- forico - Google Patents
Procedimiento para la obtencion de triesteres de acido fos- foricoInfo
- Publication number
- ES482903A1 ES482903A1 ES482903A ES482903A ES482903A1 ES 482903 A1 ES482903 A1 ES 482903A1 ES 482903 A ES482903 A ES 482903A ES 482903 A ES482903 A ES 482903A ES 482903 A1 ES482903 A1 ES 482903A1
- Authority
- ES
- Spain
- Prior art keywords
- phosphoric acid
- preparation
- formula
- acid triesters
- compounds produced
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Substances OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 title abstract 5
- 229910000147 aluminium phosphate Inorganic materials 0.000 title abstract 4
- -1 phosphoric acid triesters Chemical class 0.000 title abstract 4
- 150000001875 compounds Chemical class 0.000 title 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 2
- 229910052698 phosphorus Inorganic materials 0.000 abstract 2
- 239000011574 phosphorus Substances 0.000 abstract 2
- 150000008044 alkali metal hydroxides Chemical class 0.000 abstract 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 1
- 150000001342 alkaline earth metals Chemical class 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/08—Esters of oxyacids of phosphorus
- C07F9/09—Esters of phosphoric acids
- C07F9/12—Esters of phosphoric acids with hydroxyaryl compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
Abstract
Según el procedimiento de la presente invención se hacen reaccionar en una reacción de dos ó de varias etapas compuestos hidroxi aromáticos con oxihaluros de fósforo, pentahaluros de fósforo, dihaluros de monoéster de ácido fosfórico y monohaluros de diésteres de ácido fosfórico, en presencia de soluciones acuosas de hidróxido de metal y cantidades suficientes de disolventes orgánicos a triésteres de ácido fosfórico. Preferentemente se emplea el procedimiento de la presente invención para la reacción de compuestos hidroxi aromáticos con oxicloruro de fósforo en presencia del lejía alcalina acuosa y disolventes orgánicos, no miscibles con agua. El valor pH se mantiene en el transcurso de la reacción preferentemente en un pH de 7,5 hasta 13,5. De ésta manera se evitan, contrario a los procedimientos usuales en la práctica, los problemas de corrosión originados por el cloruro de hidrógeno libre.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19782833341 DE2833341A1 (de) | 1978-07-29 | 1978-07-29 | Verfahren zur herstellung von phosphorsaeure-triestern |
Publications (1)
Publication Number | Publication Date |
---|---|
ES482903A1 true ES482903A1 (es) | 1980-04-16 |
Family
ID=6045708
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES482903A Expired ES482903A1 (es) | 1978-07-29 | 1979-07-27 | Procedimiento para la obtencion de triesteres de acido fos- forico |
Country Status (6)
Country | Link |
---|---|
US (1) | US4267127A (es) |
EP (1) | EP0008648B1 (es) |
JP (1) | JPS5520772A (es) |
BR (1) | BR7904847A (es) |
DE (2) | DE2833341A1 (es) |
ES (1) | ES482903A1 (es) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2926652A1 (de) * | 1979-07-02 | 1981-01-22 | Bayer Ag | Verfahren zur herstellung von phosphorsaeurepropargylestern |
US4440716A (en) * | 1981-01-30 | 1984-04-03 | Scandpower, Inc. | In-situ calibration of local power measuring devices for nuclear reactors |
JPH0529780Y2 (es) * | 1987-12-15 | 1993-07-29 | ||
WO1996017853A1 (en) * | 1994-12-07 | 1996-06-13 | Akzo Nobel N.V. | Process for making hydrocarbyl (dihydrocarbyl) phosphates |
KR100409049B1 (ko) * | 1996-07-01 | 2004-04-14 | 삼성아토피나주식회사 | 혼합 할로알킬-아릴포스페이트의 제조방법 |
CA2281106A1 (en) * | 1997-02-14 | 1998-08-20 | David W. Bartley | Process for making and using bisaryl diphosphates |
EP1004588B1 (en) * | 1997-06-06 | 2003-10-29 | Daihachi Chemical Industry Co., Ltd. | Process for producing phosphoric ester compounds |
US6388120B1 (en) | 1998-02-13 | 2002-05-14 | Pabu Services, Inc. | Continuous process for the manufacture of phosphoric acid esters |
US6031035A (en) * | 1998-02-13 | 2000-02-29 | Great Lakes Chemical Corporation | Process for making and using bisaryl diphosphates |
US20070254991A1 (en) * | 2006-04-28 | 2007-11-01 | Saadat Hussain | Phosphorus-containing tetrabromobisphenol A |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1837176A (en) * | 1928-06-19 | 1931-12-15 | Elko Chemical Company | Process of manufacturing triaryl phosphates |
US2653161A (en) * | 1950-12-02 | 1953-09-22 | Shell Dev | Sulfur and phosphorus-containing esters |
US3792132A (en) * | 1970-12-21 | 1974-02-12 | Stauffer Chemical Co | Process for preparing alkyl phenyl phosphate and phosphorothionate compounds |
BE790639A (fr) * | 1971-10-28 | 1973-04-27 | Bayer Ag | Chlorure de diester o-ethyl-o-(3-methyl-4- methylmercaptophenylique) d'acide phosphorique, son procede de preparation et son application commeproduit intermediaire pour la synthese de pesticides |
JPS5495133A (en) * | 1978-01-13 | 1979-07-27 | Mitsubishi Electric Corp | Input/output processing control system |
JPS597973B2 (ja) * | 1978-01-13 | 1984-02-22 | 三菱電機株式会社 | デ−タ処理装置 |
-
1978
- 1978-07-29 DE DE19782833341 patent/DE2833341A1/de not_active Withdrawn
-
1979
- 1979-07-18 DE DE7979102517T patent/DE2962624D1/de not_active Expired
- 1979-07-18 EP EP79102517A patent/EP0008648B1/de not_active Expired
- 1979-07-25 US US06/060,679 patent/US4267127A/en not_active Expired - Lifetime
- 1979-07-27 BR BR7904847A patent/BR7904847A/pt unknown
- 1979-07-27 ES ES482903A patent/ES482903A1/es not_active Expired
- 1979-07-27 JP JP9513479A patent/JPS5520772A/ja active Granted
Also Published As
Publication number | Publication date |
---|---|
JPH0120158B2 (es) | 1989-04-14 |
JPS5520772A (en) | 1980-02-14 |
EP0008648B1 (de) | 1982-04-28 |
BR7904847A (pt) | 1980-05-06 |
DE2962624D1 (en) | 1982-06-09 |
EP0008648A1 (de) | 1980-03-19 |
US4267127A (en) | 1981-05-12 |
DE2833341A1 (de) | 1980-02-14 |
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