ES2172145T3 - Catalizador y procedimiento para la oxidacion catalitica de etano en acido acetico. - Google Patents

Catalizador y procedimiento para la oxidacion catalitica de etano en acido acetico.

Info

Publication number
ES2172145T3
ES2172145T3 ES98922688T ES98922688T ES2172145T3 ES 2172145 T3 ES2172145 T3 ES 2172145T3 ES 98922688 T ES98922688 T ES 98922688T ES 98922688 T ES98922688 T ES 98922688T ES 2172145 T3 ES2172145 T3 ES 2172145T3
Authority
ES
Spain
Prior art keywords
catalyst
acetic acid
etano
sub
procedure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES98922688T
Other languages
English (en)
Inventor
Holger Borchert
Uwe Dingerdissen
Rainer Roesky
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Celanese Sales Germany GmbH
Original Assignee
Celanese Chemicals Europe GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Celanese Chemicals Europe GmbH filed Critical Celanese Chemicals Europe GmbH
Application granted granted Critical
Publication of ES2172145T3 publication Critical patent/ES2172145T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/652—Chromium, molybdenum or tungsten
    • B01J23/6527—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/683—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten
    • B01J23/687—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten with tungsten
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Se describe un procedimiento para preparar de forma selectiva ácido acético a partir de una alimentación gaseosa de etano, etileno o mezclas de los mismos, así como oxígeno, a una temperatura elevada, sobre un catalizador que contiene los elementos W, X, Y y Z en la relación gramo-átomo a:b:c:d, asociados con oxígeno. En la fórmula W{sub,a}X{sub,b}Y{sub,c}Z{sub,d} (I), X representa uno o varios elementos seleccionados entre el grupo compuesto por Pd, Pt, Ag y/o Au; Y representa uno o varios elementos seleccionados entre el grupo V, Nb, Cr, Mn, Fe, Sn, Sb, Cu, Zn, U, Ni y/o Bi; Z representa uno o varios elementos seleccionados entre el grupo Li, Na, K, Rb, Cs, Br, Mg, Ca, Sr, Ba, Sc, Y, La, Ti, Zr, Hf, Ru, Os, Co, Rh, Ir, B, Al, Ga, In, Tl, Si, Ge, Pb, P, As y/o Te; a es igual a 1, b es un número mayor de 0, c es un número mayor de 0 y d es un número de 0 a 2. También se describe dicho catalizador.
ES98922688T 1997-04-23 1998-04-11 Catalizador y procedimiento para la oxidacion catalitica de etano en acido acetico. Expired - Lifetime ES2172145T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19717076A DE19717076A1 (de) 1997-04-23 1997-04-23 Katalysator und Verfahren zur katalytischen Oxidation von Ethan zu Essigsäure

Publications (1)

Publication Number Publication Date
ES2172145T3 true ES2172145T3 (es) 2002-09-16

Family

ID=7827456

Family Applications (1)

Application Number Title Priority Date Filing Date
ES98922688T Expired - Lifetime ES2172145T3 (es) 1997-04-23 1998-04-11 Catalizador y procedimiento para la oxidacion catalitica de etano en acido acetico.

Country Status (11)

Country Link
US (1) US6274765B1 (es)
EP (1) EP0979222B1 (es)
JP (1) JP4006029B2 (es)
CN (1) CN1090605C (es)
CA (1) CA2288276C (es)
DE (2) DE19717076A1 (es)
ES (1) ES2172145T3 (es)
MY (1) MY119225A (es)
NO (1) NO326454B1 (es)
SA (1) SA98190500B1 (es)
WO (1) WO1998047850A1 (es)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9807142D0 (en) 1998-04-02 1998-06-03 Bp Chem Int Ltd Catalyst and process utilising the catalyst
GB9819221D0 (en) 1998-09-04 1998-10-28 Bp Chem Int Ltd Process for the production of acetic acid
US6114278A (en) * 1998-11-16 2000-09-05 Saudi Basic Industries Corporation Catalysts for catalytic oxidation of propane to acrylic acid, methods of making and using the same
GB9907704D0 (en) 1999-04-01 1999-05-26 Bp Chem Int Ltd Catalyst and process utilising the catalyst
JP4486751B2 (ja) * 1999-06-25 2010-06-23 サウディ ベーシック インダストリーズ コーポレイション エチレンからの酢酸の一段気相製造用触媒システム
CN1153614C (zh) * 1999-10-05 2004-06-16 昭和电工株式会社 用于生产乙酸的催化剂、其生产方法和用其生产乙酸的方法
US6706919B1 (en) 1999-10-05 2004-03-16 Showa Denko K. K. Catalyst for use in producing acetic acid, process for producing the catalyst, and process for producing acetic acid using the catalyst
JP4809532B2 (ja) * 1999-11-15 2011-11-09 サウディ ベーシック インダストリーズ コーポレイション プロパンのアクリル酸への接触酸化用触媒、その製造法及び使用法
US6693059B2 (en) 2000-02-09 2004-02-17 Rohm And Haas Company Process for preparing a catalyst and catalytic oxidation therewith
US6531631B1 (en) 2000-04-28 2003-03-11 Saudi Basic Industries Corporation Oxidation of ethane to acetic acid and ethylene using molybdenum and vanadium based catalysts
US7368599B2 (en) * 2001-10-16 2008-05-06 Bp Chemicals Limited Ethane oxidation catalyst and process utilising the catalyst
US7318915B2 (en) * 2002-01-25 2008-01-15 United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration Oxidation-reduction catalyst and its process of use
US20040040890A1 (en) * 2002-08-30 2004-03-04 Morton Robert W. Desulfurization and novel compositions for same
ATE524234T1 (de) * 2004-03-29 2011-09-15 Showa Denko Kk Verfahren zur herstellung einer sauerstoffhaltigen verbindung unter verwendung eines katalysators auf basis von palladium, wolfram und zirkon
TWI311498B (en) * 2006-07-19 2009-07-01 Lg Chemical Ltd Catalyst for partial oxidation of methylbenzenes, method for preparing the same, and method for producing aromatic aldehydes using the same
DE102010001399A1 (de) 2010-01-29 2011-08-04 Wacker Chemie AG, 81737 Verfahren zur Herstellung von Carbonsäuren mit 1-3 Kohlenstoff-atomen aus nachwachsenden Rohstoffen
US20140275619A1 (en) 2013-03-15 2014-09-18 Celanese International Corporation Process for Producing Acetic Acid and/or Ethanol By Methane Oxidation

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB8915410D0 (en) * 1989-07-05 1989-08-23 Bp Chem Int Ltd Chemical process
GB9022127D0 (en) * 1990-10-11 1990-11-21 Bp Chem Int Ltd Process
US5300682A (en) * 1991-06-10 1994-04-05 The Standard Oil Co. Catalytic oxidation of ethane to acetic acid
TW295579B (es) * 1993-04-06 1997-01-11 Showa Denko Kk
DE4414981A1 (de) 1994-04-29 1995-11-02 Teves Gmbh Alfred Elektrisches Steuermodul mit Lichtleiter zur Aufnahme mindestens einer Glühlampe
JP3230427B2 (ja) * 1995-01-05 2001-11-19 株式会社日本触媒 燻蒸排ガス浄化用触媒および燻蒸排ガスの浄化方法

Also Published As

Publication number Publication date
NO326454B1 (no) 2008-12-08
JP2001524089A (ja) 2001-11-27
WO1998047850A1 (de) 1998-10-29
NO995085D0 (no) 1999-10-18
CA2288276C (en) 2007-06-19
CN1090605C (zh) 2002-09-11
EP0979222B1 (de) 2002-02-13
CA2288276A1 (en) 1998-10-29
EP0979222A1 (de) 2000-02-16
NO995085L (no) 1999-10-18
MY119225A (en) 2005-04-30
JP4006029B2 (ja) 2007-11-14
SA98190500B1 (ar) 2006-06-21
US6274765B1 (en) 2001-08-14
DE59803069D1 (de) 2002-03-21
CN1253542A (zh) 2000-05-17
DE19717076A1 (de) 1998-10-29

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