ES2169016T3 - Proceso para la preparacion de polimeros estabilizados con poli(alcohol vinilico). - Google Patents

Proceso para la preparacion de polimeros estabilizados con poli(alcohol vinilico).

Info

Publication number
ES2169016T3
ES2169016T3 ES00111074T ES00111074T ES2169016T3 ES 2169016 T3 ES2169016 T3 ES 2169016T3 ES 00111074 T ES00111074 T ES 00111074T ES 00111074 T ES00111074 T ES 00111074T ES 2169016 T3 ES2169016 T3 ES 2169016T3
Authority
ES
Spain
Prior art keywords
optionally
monomers
weight
initiator
reducing agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES00111074T
Other languages
English (en)
Inventor
Hans-Peter Dr Weitzel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wacker Polymer Systems GmbH and Co KG
Original Assignee
Wacker Polymer Systems GmbH and Co KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wacker Polymer Systems GmbH and Co KG filed Critical Wacker Polymer Systems GmbH and Co KG
Application granted granted Critical
Publication of ES2169016T3 publication Critical patent/ES2169016T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • C09D151/003—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/24—Macromolecular compounds
    • C04B24/26—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B24/2641—Polyacrylates; Polymethacrylates
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/0028—Aspects relating to the mixing step of the mortar preparation
    • C04B40/0039—Premixtures of ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/20—Aqueous medium with the aid of macromolecular dispersing agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/22—Emulsion polymerisation
    • C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
    • C08F2/30—Emulsion polymerisation with the aid of emulsifying agents non-ionic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F261/00—Macromolecular compounds obtained by polymerising monomers on to polymers of oxygen-containing monomers as defined in group C08F16/00
    • C08F261/02—Macromolecular compounds obtained by polymerising monomers on to polymers of oxygen-containing monomers as defined in group C08F16/00 on to polymers of unsaturated alcohols
    • C08F261/04—Macromolecular compounds obtained by polymerising monomers on to polymers of oxygen-containing monomers as defined in group C08F16/00 on to polymers of unsaturated alcohols on to polymers of vinyl alcohol
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • C09J151/003—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/0045—Polymers chosen for their physico-chemical characteristics
    • C04B2103/0057—Polymers chosen for their physico-chemical characteristics added as redispersable powders
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Structural Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Polymerisation Methods In General (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

Proceso para la preparación de polímeros estabilizados con poli(alcoholes vinílicos) a base de monómeros de (met)acrilato en forma de sus dispersiones acuosas y polvos de redispersión redispersables en agua por medio de polimerización en emulsión o polimerización en suspensión iniciada por radicales libres de uno o varios monómeros del grupo de los ésteres de ácido acrílico o ácido metacrílico y opcionalmente otros monómeros copolimerizables con ellos, en presencia de uno o varios coloides protectores del grupo de los poli(alcoholes vinílicos), y opcionalmente secado de la dispersión acuosa obtenida de este modo, caracterizado porque a) la polimerización se efectúa en presencia de 0,001 a 0,02 % en peso de iniciador, y opcionalmente además 0,001 a 0,03 % en peso de agente reductor, referido en todos los casos al peso total de los monómeros, y b) se carga inicialmente 10 a 50 % en peso de los monómeros, referido al peso total de los monómeros, y el resto se dosifica, y c) el iniciador y opcionalmente el agente reductor se dosfican totalmente, en el cual hasta el transcurso de un período de tiempo que está comprendido entre 50 y 80 % del tiempo de polimerización total, se dosifican continuamente 25 a 60 % en peso de la cantidad total de iniciador y opcionalmente la cantidad de agente reductor, y d) en el tiempo de polimerización restante, la cantidad residual de iniciador y opcionalmente agente reductorse añade aceleradamente con una tasa de dosicación al menos dos veces mayor que en el paso c).
ES00111074T 1999-06-24 2000-06-02 Proceso para la preparacion de polimeros estabilizados con poli(alcohol vinilico). Expired - Lifetime ES2169016T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19928933A DE19928933A1 (de) 1999-06-24 1999-06-24 Verfahren zur Herstellung von Polyvinylalkohol-stabilisierten Polymerisaten

Publications (1)

Publication Number Publication Date
ES2169016T3 true ES2169016T3 (es) 2002-07-01

Family

ID=7912373

Family Applications (1)

Application Number Title Priority Date Filing Date
ES00111074T Expired - Lifetime ES2169016T3 (es) 1999-06-24 2000-06-02 Proceso para la preparacion de polimeros estabilizados con poli(alcohol vinilico).

Country Status (6)

Country Link
US (1) US6605663B1 (es)
EP (1) EP1065224B1 (es)
BR (1) BR0002847B1 (es)
CA (1) CA2311805C (es)
DE (2) DE19928933A1 (es)
ES (1) ES2169016T3 (es)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10062176A1 (de) * 2000-12-14 2002-07-04 Wacker Polymer Systems Gmbh Polyvinylacetal-gepfropfte Polymerisate
US7981958B1 (en) * 2002-09-17 2011-07-19 Kuraray Co., Ltd. Synthetic resin emulsion powder
DE10249636A1 (de) * 2002-10-24 2004-05-13 Wacker Polymer Systems Gmbh & Co. Kg Verwendung von in Wasser redispergierbaren Polymerpulvern als Bindemittel für Fugensand
DE10253046A1 (de) 2002-11-14 2004-06-03 Wacker Polymer Systems Gmbh & Co. Kg Schutzkolloidstabilisierte Polymerisate in Form deren wässrigen Dispersionen und in Wasser redispergierbaren Pulver
DE10316079A1 (de) 2003-04-08 2004-11-11 Wacker Polymer Systems Gmbh & Co. Kg Polyvinylalkohol-stabilisierte Redispersionspulver mit verflüssigenden Eigenschaften
DE10333623A1 (de) * 2003-07-24 2005-02-24 Celanese Emulsions Gmbh Beschichtungszusammensetzung und Verfahren zu deren Herstellung
DE10346973A1 (de) * 2003-10-09 2005-05-04 Wacker Polymer Systems Gmbh Modifizierte Polyvinylalkohole enthaltende Polymerzusammensetzungen
DE102006007282A1 (de) † 2006-02-16 2007-08-23 Wacker Polymer Systems Gmbh & Co. Kg Verfahren zur Herstellung von kationisch stabilisierten und in Wasser redispergierbaren Polymerpulverzusammensetzungen
KR100830909B1 (ko) * 2007-04-27 2008-05-22 (주)영우켐텍 아크릴산 에스테르 공중합체 조성물 및 재분산성 분말
WO2009051577A1 (en) * 2007-10-15 2009-04-23 Celanese International Corporation Paper coating composition
DE102011076407A1 (de) * 2011-05-24 2012-11-29 Wacker Chemie Ag Verfahren zur Herstellung von Schutzkolloid-stabilisierten Polymerisaten
JP6501761B2 (ja) 2013-05-21 2019-04-17 サン ケミカル コーポレイション アセタール化したポリビニルアルコールのバリアコーティング材
ES2958403T3 (es) 2015-12-31 2024-02-08 Kemira Oyj Revestimientos de barrera de base acuosa
EP4146714A1 (de) * 2020-05-05 2023-03-15 Wacker Chemie AG Polyvinylalkohol-stabilisierte (meth)acrylsäureesterpolymere

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2830470A1 (de) 1978-07-11 1980-01-31 Bayer Ag Verfahren zur herstellung von emulgatorfreien kautschuklatices
DE2842719A1 (de) * 1978-09-30 1980-04-10 Basf Ag Verfahren zur herstellung von waessrigen polyacrylat-dispersionen mit verbessertem fliessverhalten
CA1138596A (en) 1979-05-18 1982-12-28 Gary L. Burroway Method of preparing resin
US5240771A (en) * 1990-04-02 1993-08-31 Basf Aktiengesellschaft Copolymers based on C1 -C8 -alkyl acrylates and/or methacrylates and preparation and use thereof
DE4306808A1 (de) 1993-03-04 1994-09-08 Wacker Chemie Gmbh Vernetzbare Dispersionspulver als Bindemittel für Fasern
DE4316200A1 (de) * 1993-05-14 1994-11-17 Roehm Gmbh Verfahren zur Herstellung niedrigviskoser, wasserlöslicher Polymerdispersionen
US5705553A (en) * 1993-05-29 1998-01-06 Hoechst Aktiengesellschaft Copolymers containing carboxyl groups in aqueous dispersion form or redispersible powder form and their water-soluble salts, processes for their preparation and their use as thickeners in aqueous formulations
DE4407842A1 (de) 1994-03-09 1995-09-14 Huels Chemische Werke Ag Schutzkolloid-stabilisierte Polyacrylat-Dispersionen
DE4446539A1 (de) 1994-12-24 1996-06-27 Hoechst Ag Verfahren zur Herstellung von Kunststoffdispersionen
US5741871A (en) 1996-06-14 1998-04-21 Air Products And Chemicals, Inc. Acrylic emulsions prepared in the presence of fully hydrolyzed poly (vinyl alcohol)
DE19629948A1 (de) 1996-07-25 1998-01-29 Polymer Latex Gmbh & Co Kg Verfahren zur Herstellung von sterisch stabilisierten, emulgatorfreien, wäßrigen Polymer-Dispersionen und daraus hergestellten Pulvern zum Einsatz in Baustoffen
US5753036A (en) * 1997-04-21 1998-05-19 Air Products And Chemicals, Inc. Poly(vinyl alcohol) stabilized acrylic polymer modified hydraulic cement systems
DE19733133A1 (de) 1997-07-31 1999-02-04 Wacker Chemie Gmbh Pulverförmige, vernetzbare Textilbinder-Zusammensetzung
DE19735736A1 (de) * 1997-08-18 1999-02-25 Wacker Chemie Gmbh Verdickungsmittel auf der Basis von Carboxylgruppen- und Carboxylamidgruppenhaltigen Polymerisaten

Also Published As

Publication number Publication date
BR0002847A (pt) 2001-01-30
CA2311805C (en) 2006-03-28
US6605663B1 (en) 2003-08-12
EP1065224A1 (de) 2001-01-03
DE50000042D1 (de) 2002-01-10
DE19928933A1 (de) 2000-12-28
BR0002847B1 (pt) 2009-08-11
EP1065224B1 (de) 2001-11-28
CA2311805A1 (en) 2000-12-24

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