ES2168799T3 - Procedimiento para la obtencion de compuestos de fosfabenceno. - Google Patents

Procedimiento para la obtencion de compuestos de fosfabenceno.

Info

Publication number
ES2168799T3
ES2168799T3 ES98952673T ES98952673T ES2168799T3 ES 2168799 T3 ES2168799 T3 ES 2168799T3 ES 98952673 T ES98952673 T ES 98952673T ES 98952673 T ES98952673 T ES 98952673T ES 2168799 T3 ES2168799 T3 ES 2168799T3
Authority
ES
Spain
Prior art keywords
linked
hydrogen
group
procedure
obtaining
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES98952673T
Other languages
English (en)
Inventor
Rocco Paciello
Edgar Zeller
Bernhard Breit
Michael Roper
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Application granted granted Critical
Publication of ES2168799T3 publication Critical patent/ES2168799T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6568—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2419—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising P as ring member
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2442—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems
    • B01J31/2461—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as ring members in the condensed ring system or in a further ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Procedimiento para la obtención de compuestos de fosfabenceno de las fórmulas generales I y II **fórmula** en las que R 1 a R 6 , independientes entre sí, representan hidrógeno, COOM, SO3M, NR3X, NR2, OR, COOR o SR con M = hidrógeno, NH4 o metal alcalino, X = anión, R = hidrógeno o alquilo C1-6, o representan alquilo C1-12, arilo C6-12, aralquilo C7-12, o heterocicloalquilo C3-6,con1 a3 heteroátomos, que pueden estar substituidos con los restos anteriores o pueden estar unidos para formar ciclos anillados, y (W) significa un puente formado por un enlace covalente, un grupo oxo, un grupo azufre, un grupo amino, un grupo di-alquilosilicio C1-6, o un resto C1-16, que puede ser parte integrante de uno o varios núcleos cíclicos o aromáticos enlazados y puede estar interrumpido por 1 a 3 heteroátomos, pudiendo portar la posición o- o m-, no enlazada con el puente de los núcleos de fosfabenceno, respectivamente, uno de los restos R 1 a R 6, con la excepción de bis-3,3''(3-metil-2,4,6-trifenilfosfabenceno)-1,1''-difenilo, mediante conversión de sales de pirilio correspondientes con PH3 en presencia de una cantidad catalítica de ácido y en presencia o ausencia de un disolvente o diluyente, caracterizado porque las sales de pirilio se combinan con PH3 a una temperatura por encima de 0º C y se hacen reaccionar a una temperatura de 0º C hasta 200º C y a una presión por encima de 1 bar.
ES98952673T 1997-09-30 1998-09-30 Procedimiento para la obtencion de compuestos de fosfabenceno. Expired - Lifetime ES2168799T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19743197A DE19743197A1 (de) 1997-09-30 1997-09-30 Verfahren zur Herstellung von Phosphabenzolverbindungen

Publications (1)

Publication Number Publication Date
ES2168799T3 true ES2168799T3 (es) 2002-06-16

Family

ID=7844153

Family Applications (1)

Application Number Title Priority Date Filing Date
ES98952673T Expired - Lifetime ES2168799T3 (es) 1997-09-30 1998-09-30 Procedimiento para la obtencion de compuestos de fosfabenceno.

Country Status (9)

Country Link
US (1) US6255532B1 (es)
EP (1) EP1025111B1 (es)
JP (1) JP2001518474A (es)
KR (1) KR20010015673A (es)
CN (1) CN1140533C (es)
DE (2) DE19743197A1 (es)
ES (1) ES2168799T3 (es)
MY (1) MY118852A (es)
WO (1) WO1999016774A1 (es)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19743197A1 (de) 1997-09-30 1999-04-01 Basf Ag Verfahren zur Herstellung von Phosphabenzolverbindungen
DE19911922A1 (de) 1999-03-17 2000-09-21 Basf Ag Verfahren zur Herstellung von Phosphabenzolverbindungen
DE19911920A1 (de) * 1999-03-17 2000-09-21 Basf Ag Phosphabenzolverbindungen und ihre Verwendung in der Hydroformylierung
CN1444590A (zh) * 2000-06-26 2003-09-24 巴斯福股份公司 磷杂环已烷类化合物及其在烯烃醛化中的用途
WO2005003719A2 (en) * 2003-06-04 2005-01-13 American National Red Cross Decontamination of biological fluids using diphenylpyrilium compounds

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE704785A (es) 1966-10-14 1968-04-08
DE1618668A1 (de) 1967-03-18 1971-02-25 Gottfried Prof Dr Maerkl Verfahren zur Herstellung von Phosphabenzolen
DE1668416A1 (de) * 1967-10-18 1971-08-05 Gottfried Prof Dr Maerkl Phosphabenzole und Verfahren zu ihrer Herstellung
DE19621967A1 (de) * 1996-05-31 1997-12-04 Basf Ag Verfahren zur Hydroformylierung und dafür geeignete Katalysatoren die Phosphorverbindungen als Liganden enthalten
DE19743197A1 (de) 1997-09-30 1999-04-01 Basf Ag Verfahren zur Herstellung von Phosphabenzolverbindungen

Also Published As

Publication number Publication date
MY118852A (en) 2005-01-31
JP2001518474A (ja) 2001-10-16
CN1272847A (zh) 2000-11-08
WO1999016774A1 (de) 1999-04-08
EP1025111A1 (de) 2000-08-09
EP1025111B1 (de) 2001-11-21
DE59802764D1 (de) 2002-02-21
US6255532B1 (en) 2001-07-03
CN1140533C (zh) 2004-03-03
DE19743197A1 (de) 1999-04-01
KR20010015673A (ko) 2001-02-26

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