ES2161429T3 - Procedimiento para la obtencion de empleo de capas o polvos estables al almacenaje de reactividad latente, a partir de poliisocianatos solidos desactivados superficialmente y polimeros en dispersion con grupos funcionales. - Google Patents
Procedimiento para la obtencion de empleo de capas o polvos estables al almacenaje de reactividad latente, a partir de poliisocianatos solidos desactivados superficialmente y polimeros en dispersion con grupos funcionales.Info
- Publication number
- ES2161429T3 ES2161429T3 ES97810969T ES97810969T ES2161429T3 ES 2161429 T3 ES2161429 T3 ES 2161429T3 ES 97810969 T ES97810969 T ES 97810969T ES 97810969 T ES97810969 T ES 97810969T ES 2161429 T3 ES2161429 T3 ES 2161429T3
- Authority
- ES
- Spain
- Prior art keywords
- polyisocyanate
- reaction temperature
- solid
- storage
- polyisocianates
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000006185 dispersion Substances 0.000 title abstract 4
- 229920000642 polymer Polymers 0.000 title abstract 4
- 239000000843 powder Substances 0.000 title abstract 4
- 239000007787 solid Substances 0.000 title abstract 3
- 230000009257 reactivity Effects 0.000 title abstract 2
- 238000000034 method Methods 0.000 title 1
- 229920001228 polyisocyanate Polymers 0.000 abstract 5
- 239000005056 polyisocyanate Substances 0.000 abstract 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 3
- 238000004519 manufacturing process Methods 0.000 abstract 2
- 239000000758 substrate Substances 0.000 abstract 2
- 239000007900 aqueous suspension Substances 0.000 abstract 1
- 239000012948 isocyanate Substances 0.000 abstract 1
- 150000002513 isocyanates Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/80—Masked polyisocyanates
- C08G18/8003—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen
- C08G18/8054—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/38
- C08G18/8058—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/38 with compounds of C08G18/3819
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/50—Polyethers having heteroatoms other than oxygen
- C08G18/5021—Polyethers having heteroatoms other than oxygen having nitrogen
- C08G18/5024—Polyethers having heteroatoms other than oxygen having nitrogen containing primary and/or secondary amino groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
- C08G18/6216—Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
- C08G18/622—Polymers of esters of alpha-beta ethylenically unsaturated carboxylic acids
- C08G18/6225—Polymers of esters of acrylic or methacrylic acid
- C08G18/6229—Polymers of hydroxy groups containing esters of acrylic or methacrylic acid with aliphatic polyalcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/703—Isocyanates or isothiocyanates transformed in a latent form by physical means
- C08G18/705—Dispersions of isocyanates or isothiocyanates in a liquid medium
- C08G18/706—Dispersions of isocyanates or isothiocyanates in a liquid medium the liquid medium being water
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2170/00—Compositions for adhesives
- C08G2170/80—Compositions for aqueous adhesives
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Paints Or Removers (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
LA INVENCION TRATA DE UN PROCEDIMIENTO PARA LA SINTESIS DE CAPAS Y POLVOS CON CAPACIDAD DE REACTIVIDAD LATENTE Y ESTABLES EN ALMACENAMIENTO A PARTIR DE POLIISOCIANATOS SOLIDOS DESACTIVADOS SUPERFICIALMENTE Y DISPERSIONES O SOLUCIONES ACUOSAS DE POLIMEROS QUE REACCIONAN CON LOS ISOCIANATOS, LOS CUALES SE PUEDEN UTILIZAR COMO ADHESIVOS Y REVESTIMIENTOS. ESTAS DISPERSIONES, SUSPENSIONES O SOLUCIONES ACUOSAS SE PUEDEN UTILIZAR SOBRE UN SUSTRATO DE MANERA APROPIADA, DESPUES EL AGUA SE QUITA A UNA TEMPERATURA POR DEBAJO DE LA TEMPERATURA DE REACCION DE LOS ISOCIANATOS, PUDIENDOSE REALIZAR ESTO POR ENCIMA DE LA TEMPERATURA DE REBLANDECIMIENTO DE LOS POLIMEROS. SE FORMAN A TEMPERATURA AMBIENTE CAPAS SECAS Y ANHIDRAS QUE A TEMPERATURAS POR DEBAJO DE LA TEMPERATURA DE REACCION DE LOS POLIISOCIANATOS CON LOS POLIMEROS SON ESTABLES EN ALMACENAMIENTO Y CAPACES DE REACCIONAR. MEDIANTE LA ACCION DE TEMPERATURAS POR ENCIMA DE LA TEMPERATURA DE REACCION DE LOS POLIISOCIANATOS SOLIDOS Y DESACTIVADOS SUPERFICIALMENTE SE FORMAN MEDIANTE REACCIONES CON LOS GRUPOS FUNCIONALES DEL POLIMERO CAPAS RETICULADAS CON ELEVADA RESISTENCIA AL CALOR Y ELEVADA RESISTENCIA A LOS PRODUCTOS QUIMICOS. LOS PRODUCTOS CON CAPACIDAD DE REACCION LATENTE EN FORMA DE CAPA O POLVO SE UTILIZAN PARA FABRICAR COMPUESTOS ADHESIVOS Y REVESTIMIENTOS.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP97810969A EP0922720B1 (de) | 1997-12-11 | 1997-12-11 | Verfahren zur Herstellung und Verwendung von lagerstabilen latentreaktiven Schichten oder Pulvern aus oberflächendesaktivierten festen Polyisocyanaten und Dispersionspolymeren mit funktionellen Gruppen |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2161429T3 true ES2161429T3 (es) | 2001-12-01 |
Family
ID=8230516
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES97810969T Expired - Lifetime ES2161429T3 (es) | 1997-12-11 | 1997-12-11 | Procedimiento para la obtencion de empleo de capas o polvos estables al almacenaje de reactividad latente, a partir de poliisocianatos solidos desactivados superficialmente y polimeros en dispersion con grupos funcionales. |
ES00109963T Expired - Lifetime ES2218026T3 (es) | 1997-12-11 | 1997-12-11 | Dispersion acuosa que contiene un poliisocianato de superficie desactivada. |
ES98956754T Expired - Lifetime ES2209221T3 (es) | 1997-12-11 | 1998-12-09 | Procedimiento para la fabricacion y uso de capas o polvos estables al almacenamiento y de reactividad latente formados por poliisocianatos solidos de superficie desactivada y polimeros de dispersion con grupos funcionales. |
Family Applications After (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES00109963T Expired - Lifetime ES2218026T3 (es) | 1997-12-11 | 1997-12-11 | Dispersion acuosa que contiene un poliisocianato de superficie desactivada. |
ES98956754T Expired - Lifetime ES2209221T3 (es) | 1997-12-11 | 1998-12-09 | Procedimiento para la fabricacion y uso de capas o polvos estables al almacenamiento y de reactividad latente formados por poliisocianatos solidos de superficie desactivada y polimeros de dispersion con grupos funcionales. |
Country Status (17)
Country | Link |
---|---|
US (2) | US6348548B1 (es) |
EP (3) | EP0922720B1 (es) |
JP (1) | JP4099312B2 (es) |
KR (1) | KR100603781B1 (es) |
CN (1) | CN1137178C (es) |
AT (3) | ATE203035T1 (es) |
AU (1) | AU748817B2 (es) |
BR (1) | BR9813562A (es) |
CA (1) | CA2314320A1 (es) |
DE (2) | DE59705314D1 (es) |
DK (3) | DK0922720T3 (es) |
ES (3) | ES2161429T3 (es) |
GR (1) | GR3036520T3 (es) |
HK (1) | HK1034985A1 (es) |
ID (1) | ID24970A (es) |
PT (2) | PT922720E (es) |
WO (1) | WO1999029755A1 (es) |
Families Citing this family (67)
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DE19924138A1 (de) | 1999-05-26 | 2000-11-30 | Henkel Kgaa | Lösbare Klebeverbindungen |
DE19951599A1 (de) | 1999-10-27 | 2001-05-23 | Henkel Kgaa | Verfahren zur adhesiven Trennung von Klebeverbunden |
TWI279408B (en) | 2000-01-31 | 2007-04-21 | Vantico Ag | Epoxy resin composition |
DE10012826A1 (de) * | 2000-03-16 | 2001-09-20 | Bayer Ag | Klebstoffzubereitungen |
DE10020160A1 (de) * | 2000-04-25 | 2001-10-31 | Bayer Ag | Klebstoffzubereitungen |
EP1164154A1 (de) * | 2000-06-15 | 2001-12-19 | Ag Bayer | Haftklebstoffe mit verbesserter Scherfestigkeit bei erhöhten Temperaturen |
DE10034637B4 (de) * | 2000-07-15 | 2004-04-08 | Jowat Ag | Lagerstabile Isocyanatdispersionen |
DE10037884A1 (de) | 2000-08-03 | 2002-02-21 | Henkel Kgaa | Verfahren zur beschleunigten Klebstoffaushärtung |
DE10106630A1 (de) * | 2001-02-12 | 2002-08-22 | Jowat Lobers U Frank Gmbh & Co | Selbsttragendes reaktives Schmelzklebeelement und seine Verwendung |
DE10117198A1 (de) * | 2001-04-05 | 2002-10-17 | Ovd Kinegram Ag Zug | Sicherheitsfoliensystem mit reaktiven Klebstoffen |
DE10140206A1 (de) * | 2001-08-16 | 2003-03-06 | Bayer Ag | Einkomponentige isocyanatvernetzende Zweiphasen-Systeme |
US6956084B2 (en) * | 2001-10-04 | 2005-10-18 | Bridgestone Corporation | Nano-particle preparation and applications |
DE50309990D1 (de) | 2002-02-22 | 2008-07-31 | Jowat Ag | Polyurethan-Zusammensetzungen mit geringem Anteil an Diisocyanatmonomer(en) |
DE10208027B4 (de) * | 2002-02-26 | 2008-03-13 | Lord Germany Gmbh | Wässriger reaktiver Beflockungsklebstoff für polymere Substrate und seine Verwendung |
DE10210477A1 (de) * | 2002-03-11 | 2003-10-02 | Henkel Kgaa | Verfahren zum Herstellen von flächigen Formteilen |
US20040170855A1 (en) * | 2003-02-27 | 2004-09-02 | Shigeo Kawabata | Decorative film-like material and decorative sheet |
US20050170126A1 (en) * | 2003-02-27 | 2005-08-04 | Shigeo Kawabata | Decorative film |
GB2400104B (en) * | 2003-04-03 | 2007-10-10 | Bostik Findley Ltd | Storage stable adhesive paste compositions |
DE10353953A1 (de) | 2003-11-18 | 2005-06-09 | Basf Ag | Kaschierklebstoffe, enthaltend Polyurethan und Epoxidharz |
DE102004026118A1 (de) * | 2004-05-28 | 2005-12-15 | Bayer Materialscience Ag | Klebstoffe |
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US20070231577A1 (en) * | 2006-03-30 | 2007-10-04 | Basf Corporation | Coatings for polycarbonate windows |
DE102006058527A1 (de) * | 2006-12-12 | 2008-06-19 | Bayer Materialscience Ag | Klebstoffe |
DE102007031594A1 (de) | 2007-07-06 | 2009-01-08 | Basf Coatings Ag | Universeller Spotblender für Einkomponenten- und Zweikomponentenklarlacke |
EP2018948A1 (de) | 2007-07-27 | 2009-01-28 | Sika Technology AG | Verfahren zur Herstellung eines Sandwichelements |
DE102007054046A1 (de) * | 2007-11-13 | 2009-06-18 | Bayer Materialscience Ag | Latentreaktive Klebstoffe für Identifikations-Dokumente |
DE102007060240B4 (de) * | 2007-12-14 | 2015-03-26 | Lisa Dräxlmaier GmbH | Verfahren zur Verklebung von zwei Schichten von flächigen Materialien |
DE102008052572A1 (de) | 2008-10-21 | 2010-04-29 | Bayer Materialscience Ag | Latent-reaktiv verklebte TPU/PC-Schichtstoffe |
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EP2284919A1 (de) | 2009-08-07 | 2011-02-16 | Bayer MaterialScience AG | Verfahren zur Herstellung eines elektromechanischen Wandlers |
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EP2368957A1 (de) | 2010-03-26 | 2011-09-28 | Sika Technology AG | Verstärkungselement zur Verstärkung in Hohlräumen von strukturellen Bauteilen |
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EP2423247A1 (de) * | 2010-08-30 | 2012-02-29 | Rhein Chemie Rheinau GmbH | Neuartige wässrige Resorcin-Formaldehyd-Latex-Dispersionen, ein Verfahren zu deren Herstellung und deren Verwendung |
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JP5697955B2 (ja) | 2010-11-19 | 2015-04-08 | 住化バイエルウレタン株式会社 | 多層加飾フィルム |
DE102012203249A1 (de) | 2012-03-01 | 2013-09-05 | Tesa Se | Verwendung eines latentreaktiven Klebefilms zur Verklebung von eloxiertem Aluminium mit Kunststoff |
EP2712879B1 (de) | 2012-09-28 | 2018-02-14 | Collano Adhesives AG | Latent reaktive Schmelzklebstoffzusammensetzung |
CN107603501B (zh) * | 2013-07-30 | 2021-05-28 | H.B.富乐公司 | 聚氨酯粘合膜 |
DE102013217880A1 (de) | 2013-09-06 | 2015-03-12 | Tesa Se | Latentreaktive Klebeprodukte mit verbesserter Stanzbarkeit und latentreaktive Klebfolienstanzlinge |
EP3110898B2 (en) | 2014-02-26 | 2022-06-15 | H. B. Fuller Company | Tacky, heat curable multi-layer adhesive films |
US20160046775A1 (en) * | 2014-08-12 | 2016-02-18 | H.B. Fuller Company | Heat curable adhesive film |
DE102014222259A1 (de) | 2014-10-31 | 2016-05-04 | Tesa Se | Verklebung zweier Substrate mittels latentreaktiver Klebefilme |
WO2016100344A1 (en) | 2014-12-15 | 2016-06-23 | H.B. Fuller Company | Reactive film adhesives with enhanced adhesion to metallic surfaces |
DE102015204018A1 (de) | 2015-03-05 | 2016-09-08 | Bundesdruckerei Gmbh | Wert- oder Sicherheitsdokument mit einer elektronischen Schaltung und Verfahren zum Herstellen des Wert- oder Sicherheitsdokuments |
CN106753000A (zh) | 2015-11-25 | 2017-05-31 | 德莎欧洲公司 | 具有改善的耐湿热性的粘合 |
DE102016117674A1 (de) | 2016-09-20 | 2018-03-22 | Bundesdruckerei Gmbh | Verfahren zur Herstellung eines Sicherheits- oder Wertprodukts mit einem diffraktiven Sicherheitselement |
US20190337278A1 (en) | 2016-12-14 | 2019-11-07 | Sika Technology Ag | Instant pre-fixation of adhesive bonded insert parts which is preferably made of plastic with the help of chemical screws |
EP3418322A1 (de) * | 2017-06-21 | 2018-12-26 | Nolax AG | Flächiges halbfertigprodukt mit einer kunststoffmatrix |
DE102017221670A1 (de) | 2017-11-28 | 2019-05-29 | Tesa Se | Latent reaktiver Klebefilm enthaltend mindestens eine Substanz / einen Stoff / eine Komponente, der / die die Oberflächenspannung einer Flüssigkeit und / oder die Grenzflächenspannung zwischen zwei Phasen herabsetzen kann |
DE102018102916A1 (de) * | 2018-02-09 | 2019-08-14 | Delo Industrie Klebstoffe Gmbh & Co. Kgaa | Mit aktinischer Strahlung fixierbare Masse und ihre Verwendung |
CN110576593B (zh) * | 2018-08-01 | 2021-07-06 | 蓝思科技(长沙)有限公司 | 贴膜方法及其用途与玻璃面板 |
EP3628696A1 (en) | 2018-09-27 | 2020-04-01 | Covestro Deutschland AG | An adhesive and application thereof |
EP3837298A1 (en) | 2018-08-15 | 2021-06-23 | Covestro Intellectual Property GmbH & Co. KG | An adhesive and application thereof |
CN110835511A (zh) * | 2018-08-15 | 2020-02-25 | 科思创德国股份有限公司 | 一种粘着剂及其应用 |
EP3730528A1 (de) | 2019-04-24 | 2020-10-28 | Covestro Deutschland AG | Latent-reaktive klebstoffzubereitungen |
EP3882317A1 (de) | 2020-03-17 | 2021-09-22 | Covestro Deutschland AG | Polyurethandispersionen |
US20230398715A1 (en) * | 2020-10-25 | 2023-12-14 | Smartech The Industry Pivot Ltd. | Improved use of mdi in engineered wood products |
KR102390345B1 (ko) | 2020-11-10 | 2022-04-22 | 테사 소시에타스 유로파에아 | 잠재 반응성 접착 화합물을 제조하기 위한 제제 |
DE102021200580A1 (de) | 2020-11-10 | 2022-05-12 | Tesa Se | Zubereitung zur Herstellung latentreaktiver Klebmassen |
DE102021000890A1 (de) | 2021-02-19 | 2022-08-25 | Giesecke+Devrient Currency Technology Gmbh | Sicherheitselement und Verfahren zu seiner Herstellung |
EP4089126A1 (de) | 2021-05-12 | 2022-11-16 | Covestro Deutschland AG | Klebstoffe |
EP4317266A1 (de) | 2022-08-02 | 2024-02-07 | Nolax AG | Flächiges halbfertigprodukt mit einer kunststoffmatrix und einer thermoplastischen folie |
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-
1997
- 1997-12-11 DK DK97810969T patent/DK0922720T3/da active
- 1997-12-11 ES ES97810969T patent/ES2161429T3/es not_active Expired - Lifetime
- 1997-12-11 EP EP97810969A patent/EP0922720B1/de not_active Expired - Lifetime
- 1997-12-11 AT AT97810969T patent/ATE203035T1/de not_active IP Right Cessation
- 1997-12-11 EP EP00109963A patent/EP1029879B1/de not_active Expired - Lifetime
- 1997-12-11 PT PT97810969T patent/PT922720E/pt unknown
- 1997-12-11 AT AT00109963T patent/ATE264351T1/de active
- 1997-12-11 DE DE59705314T patent/DE59705314D1/de not_active Expired - Fee Related
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- 1997-12-11 DK DK00109963T patent/DK1029879T3/da active
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1998
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- 1998-12-09 CN CNB988135787A patent/CN1137178C/zh not_active Expired - Lifetime
- 1998-12-09 EP EP98956754A patent/EP1037935B1/de not_active Expired - Lifetime
- 1998-12-09 JP JP2000524342A patent/JP4099312B2/ja not_active Expired - Lifetime
- 1998-12-09 WO PCT/CH1998/000519 patent/WO1999029755A1/de active IP Right Grant
- 1998-12-09 US US09/581,139 patent/US6348548B1/en not_active Expired - Lifetime
- 1998-12-09 DK DK98956754T patent/DK1037935T3/da active
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2001
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2002
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