ES2150622T3 - Adhesivos de fusion en caliente a base de poliesteres sulfonados. - Google Patents
Adhesivos de fusion en caliente a base de poliesteres sulfonados.Info
- Publication number
- ES2150622T3 ES2150622T3 ES96113481T ES96113481T ES2150622T3 ES 2150622 T3 ES2150622 T3 ES 2150622T3 ES 96113481 T ES96113481 T ES 96113481T ES 96113481 T ES96113481 T ES 96113481T ES 2150622 T3 ES2150622 T3 ES 2150622T3
- Authority
- ES
- Spain
- Prior art keywords
- group
- weight
- reagent
- groups
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J191/00—Adhesives based on oils, fats or waxes; Adhesives based on derivatives thereof
- C09J191/06—Waxes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J167/00—Adhesives based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Adhesives based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Polyesters Or Polycarbonates (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
UNA COMPOSICION DE UN ADHESIVO TERMOFUSIBLE, QUE COMPRENDE (I) DEL 10 AL 90% EN PESO DE UN POLIESTER SULFONADO; POLIMERO DE CONDENSACION QUE COMPRENDE EL PRODUCTO DE REACCION DE A) AL MENOS UN ACIDO DICARBOXILICO DIFUNCIONAL, O EL CORRESPONDIENTE METIL ESTER, QUE NO ES UN SULFOMONOMERO; B) DE 2 A 25 MOLES POR CIENTO DE AL MENOS UN SULFOMONOMERO, CON AL MENOS UN GRUPO SULFONATO METALICO, O UN GRUPO SULFONATO NO METALICO QUE CONTIENE NITROGENO, UNIDO A UN NUCLEO AROMATICO O CICLOALIFATICO, Y AL MENOS UN GRUPO FUNCIONAL SELECCIONADO A PARTIR DEL GRUPO CONSISTENTE EN HIDROXILO, CARBOXILO, O AMINO; C) AL MENOS UN REACTIVO DIFUNCIONAL SELECCIONADO ENTRE UN GLICOL, O UNA MEZCLA DE GLICOL Y DIAMINA CON DOS GRUPOS -NRH, CONTENIENDO EL GLICOL DOS GRUPOS C(R{SUP,1}){SUB,2}-OH, DONDE R, EN EL REACTIVO, ES HIDROGENO O UN GRUPO ALQUILO DE 1 A 6 ATOMOS DE CARBONO, Y R{SUP,1}, EN EL REACTIVO, ES UN ATOMO DE HIDROGENO, UN ALQUILO DE 1 A 5 ATOMOS DE CARBONO, O UN GRUPO ARILO DE 6 A 10 ATOMOS DE CARBONO; D) DE 0 A 40 MOLES POR CIENTO DE UN REACTIVO DIFUNCIONAL SELECCIONADO ENTRE ACIDOS DICARBOXILICOS QUE TIENEN UN GRUPO C(R){SUB,2}-OH, ACIDOS AMINOCARBOXILICOS QUE TIENEN UN GRUPO NRH, O MEZCLAS DE DICHOS REACTIVOS DIFUNCIONALES, DONDE R, EN EL REACTIVO, ES HIDROGENO O UN GRUPO ALQUILO DE 1 A 6 ATOMOS DE CARBONO; Y E) DE 0 A 40 MOLES POR CIENTO DE UN REACTIVO MULTIFUNCIONAL, QUE CONTIENE AL MENOS TRES GRUPOS FUNCIONALES, SELECCIONADOS ENTRE HIDROXILO, CARBOXILO, Y MEZCLAS DE LOS MISMOS, DONDE AL MENOS UNA PORCION DEL REACTIVO MULTIFUNCIONAL, CONTIENE AL MENOS TRES GRUPOS HIDROXILO, DONDE TODOS LOS PORCENTAJES MOLARES CITADOS SE BASAN EN EL TOTAL DE TODOS LOS REACTIVOS QUE CONTIENEN GRUPOS ACIDOS, HIDROXILO, Y AMINO, QUE ES IGUAL A 200 MOLES POR CIENTO, Y DONDE EL POLIMERO CONTIENE PROPORCIONES ENTRE REACTIVOS CON GRUPOS ACIDOS (100 MOLES POR CIENTO DE ACIDO) Y LOS REACTIVOS QUE CONTIENEN GRUPOS HIDROXI- Y AMINO- (100 MOLES POR CIENTO DE BASE), TALES QUE EL VALOR DE LOS EQUIVALENTES DE BASE DIVIDIDO POR EL VALOR DE LOS EQUIVALENTES DE ACIDO, ES ENTRE 0,5 Y 2; (II) DEL 0 AL 80% EN PESO DE UN AGENTE ADHERENTE COMPATIBLE; (III) DEL 0 AL 40% EN PESO DE UN PLASTIFICANTE COMPATIBLE; (IV) AL MENOS UN MATERIAL CRISTALINO SELECCIONADO ENTRE EL GRUPO CONSISTENTE EN : (I) DEL 10 AL 40% EN PESO DE UN DILUYENTE DE PARAFINA DE PESO MOLECULAR INFERIOR A 500G/MOL, QUE CONTIENE AL MENOS UN GRUPO FUNCIONAL POLAR, ESTANDO PRESENTE DICHO GRUPO CON UNA CONCENTRACION MAYOR DE 3 X 10{SUP,3} EQUIVALENTES POR GRAMO, Y (II) DEL 5 AL 60% EN PESO DE UN POLIMERO TERMOPLASTICO CRISTALINO; Y (V) DEL 0 AL 3% EN PESO DE UN ESTABILIZADOR, AJUSTANDOSE EL TOTAL DE (I) - (V) HASTA ALCANZAR EL 100% EN PESO.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US52219095A | 1995-08-31 | 1995-08-31 | |
US08/652,072 US5750605A (en) | 1995-08-31 | 1996-05-23 | Hot melt adhesives based on sulfonated polyesters |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2150622T3 true ES2150622T3 (es) | 2000-12-01 |
Family
ID=27060732
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES96113481T Expired - Lifetime ES2150622T3 (es) | 1995-08-31 | 1996-08-22 | Adhesivos de fusion en caliente a base de poliesteres sulfonados. |
Country Status (7)
Country | Link |
---|---|
US (1) | US5750605A (es) |
EP (1) | EP0761795B1 (es) |
JP (1) | JP3949755B2 (es) |
AU (1) | AU702877B2 (es) |
CA (1) | CA2184743A1 (es) |
DE (1) | DE69608624T2 (es) |
ES (1) | ES2150622T3 (es) |
Families Citing this family (58)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6162890A (en) * | 1994-10-24 | 2000-12-19 | Eastman Chemical Company | Water-dispersible block copolyesters useful as low-odor adhesive raw materials |
US5912076A (en) | 1996-12-31 | 1999-06-15 | Kimberly-Clark Worldwide, Inc. | Blends of polyethylene and peo having inverse phase morphology and method of making the blends |
NL1005174C2 (nl) * | 1997-02-04 | 1998-08-06 | Oce Tech Bv | Inktsamenstelling voor een smeltbare inkt. |
US5976694A (en) * | 1997-10-03 | 1999-11-02 | Kimberly-Clark Worldwide, Inc. | Water-sensitive compositions for improved processability |
DE69830010T2 (de) † | 1998-01-08 | 2006-03-09 | H.B. Fuller Licensing & Financing, Inc., St. Paul | Thermoplastische zusammensetzung mit kristallinen und amorphen polymeren |
US6348679B1 (en) | 1998-03-17 | 2002-02-19 | Ameritherm, Inc. | RF active compositions for use in adhesion, bonding and coating |
US6387528B1 (en) * | 1998-12-29 | 2002-05-14 | Kimberly-Clark Worldwide, Inc. | Compositions of ion-trigger polymer coatings on water-sensitive polymer films |
KR20010099995A (ko) * | 1998-12-29 | 2001-11-09 | 로날드 디. 맥크레이 | 열-활성화 접착제 |
US6423804B1 (en) | 1998-12-31 | 2002-07-23 | Kimberly-Clark Worldwide, Inc. | Ion-sensitive hard water dispersible polymers and applications therefor |
US6020420A (en) * | 1999-03-10 | 2000-02-01 | Eastman Chemical Company | Water-dispersible polyesters |
US6653522B1 (en) | 1999-04-09 | 2003-11-25 | National Starch And Chemical Investment Holding Corporation | Hot melt adhesives based on sulfonated polyesters comprising wetness indicator |
US6410627B1 (en) * | 1999-04-09 | 2002-06-25 | National Starch And Chemical Investment Holding Corporation | Use of high hydroxyl compounds for water sensitive hot melt adhesives |
US6001910A (en) * | 1999-04-09 | 1999-12-14 | National Starch And Chemical Investment Holding Corporation | Use of anionic or cationic plasticizers with sulfonated polyesters in hot melt formulations |
US6649888B2 (en) | 1999-09-23 | 2003-11-18 | Codaco, Inc. | Radio frequency (RF) heating system |
US6171685B1 (en) * | 1999-11-26 | 2001-01-09 | Eastman Chemical Company | Water-dispersible films and fibers based on sulfopolyesters |
US6444761B1 (en) | 1999-12-28 | 2002-09-03 | Kimberly-Clark Worldwide, Inc. | Water-soluble adhesive compositions |
US6428900B1 (en) | 2000-03-09 | 2002-08-06 | Ato Findley, Inc. | Sulfonated copolyester based water-dispersible hot melt adhesive |
US6444214B1 (en) | 2000-05-04 | 2002-09-03 | Kimberly-Clark Worldwide, Inc. | Ion-sensitive, water-dispersible polymers, a method of making same and items using same |
US6835678B2 (en) | 2000-05-04 | 2004-12-28 | Kimberly-Clark Worldwide, Inc. | Ion sensitive, water-dispersible fabrics, a method of making same and items using same |
US6706399B1 (en) * | 2000-08-29 | 2004-03-16 | Eastman Chemical Company | Non-blocking polymeric articles |
JP4965054B2 (ja) * | 2000-09-07 | 2012-07-04 | ミツビシ ポリエステル フィルム インク | ヒートシール塗膜および塗布フィルム |
US6767972B1 (en) * | 2000-09-15 | 2004-07-27 | Eastman Chemical Company | Methods for slowing the degradation rate of biodegradable polymers and biodegradable polymer compositions and compositions thereof |
US6586529B2 (en) | 2001-02-01 | 2003-07-01 | Kimberly-Clark Worldwide, Inc. | Water-dispersible polymers, a method of making same and items using same |
US6828014B2 (en) | 2001-03-22 | 2004-12-07 | Kimberly-Clark Worldwide, Inc. | Water-dispersible, cationic polymers, a method of making same and items using same |
US20040132922A1 (en) * | 2001-05-17 | 2004-07-08 | Hidetoshi Abe | Heat activated adhesive |
US7285587B2 (en) * | 2002-12-20 | 2007-10-23 | Eastman Chemical Company | Flame retardant polyester compositions for calendering |
US7892993B2 (en) | 2003-06-19 | 2011-02-22 | Eastman Chemical Company | Water-dispersible and multicomponent fibers from sulfopolyesters |
US20040260034A1 (en) | 2003-06-19 | 2004-12-23 | Haile William Alston | Water-dispersible fibers and fibrous articles |
US7687143B2 (en) * | 2003-06-19 | 2010-03-30 | Eastman Chemical Company | Water-dispersible and multicomponent fibers from sulfopolyesters |
US8513147B2 (en) | 2003-06-19 | 2013-08-20 | Eastman Chemical Company | Nonwovens produced from multicomponent fibers |
EP1493795A1 (de) * | 2003-07-04 | 2005-01-05 | Collano AG | Klebstoffzusammensetzung |
US20050065633A1 (en) * | 2003-11-14 | 2005-03-24 | Michael Wynblatt | Systems and methods for relative control of load motion actuators |
US7537840B2 (en) * | 2004-08-05 | 2009-05-26 | H.B. Licensing & Financing, Inc. | Polyamide adhesive and articles including the same |
CA2600416A1 (en) * | 2004-11-01 | 2006-05-11 | Basf Corporation | Radiofrequency activated inkjet inks and apparatus for inkjet printing |
US20060090250A1 (en) * | 2004-11-04 | 2006-05-04 | Bolles Properties, Llc | Dual purpose toilet paper and urinary aid |
US8071695B2 (en) | 2004-11-12 | 2011-12-06 | Eastman Chemical Company | Polyeste blends with improved stress whitening for film and sheet applications |
US20060258249A1 (en) * | 2005-05-11 | 2006-11-16 | Fairbanks Jason S | Elastic laminates and process for producing same |
DE102005042389A1 (de) * | 2005-06-17 | 2006-12-28 | Röhm Gmbh | Heißversiegelungsmasse für Aluminium- und Polyethylenterephthalatfolien gegen Polypropylen-Polyvinylchlorid- und Polystyrolbehälter |
KR101283847B1 (ko) * | 2005-07-26 | 2013-07-08 | 미츠비시 폴리에스테르 필름 인코포레이티드 | 중합체 필름에 금속화된 층을 부착하기 위한 코팅 조성물 |
US20070249771A1 (en) * | 2006-04-21 | 2007-10-25 | Paul Charles W | Hot melt adhesive for packaging applications |
US7879942B2 (en) * | 2006-10-05 | 2011-02-01 | Eastman Chemical Company | Switchable adhesive article for attachment to skin and method of using the same |
DE102006054196A1 (de) * | 2006-11-15 | 2008-05-21 | Henkel Kgaa | Schmelzhaftklebstoffe mit verbesserter Haftung |
PL2178953T3 (pl) * | 2007-08-09 | 2014-12-31 | Basf Se | Kompozycja powłokowa do spienialnych cząstek polimerów styrenowych |
JP5218411B2 (ja) * | 2007-09-06 | 2013-06-26 | コニカミノルタアドバンストレイヤー株式会社 | 光学フィルム、偏光板及び液晶表示装置 |
BRPI0912578A2 (pt) | 2008-05-06 | 2015-10-13 | Metabolix Inc | combinações de poliésteres biodegradáveis |
US8512519B2 (en) * | 2009-04-24 | 2013-08-20 | Eastman Chemical Company | Sulfopolyesters for paper strength and process |
US9273417B2 (en) | 2010-10-21 | 2016-03-01 | Eastman Chemical Company | Wet-Laid process to produce a bound nonwoven article |
US8840758B2 (en) | 2012-01-31 | 2014-09-23 | Eastman Chemical Company | Processes to produce short cut microfibers |
CN102585748B (zh) * | 2012-02-09 | 2014-05-07 | 北京联合大学生物化学工程学院 | 用于晶体加工过程中晶片粘接的水溶性热熔胶及其制备方法 |
US9475930B2 (en) | 2012-08-17 | 2016-10-25 | Metabolix, Inc. | Biobased rubber modifiers for polymer blends |
JP5925094B2 (ja) * | 2012-09-27 | 2016-05-25 | ヘンケルジャパン株式会社 | ラベル用ホットメルト粘着剤 |
US9617685B2 (en) | 2013-04-19 | 2017-04-11 | Eastman Chemical Company | Process for making paper and nonwoven articles comprising synthetic microfiber binders |
EP3004225A1 (en) | 2013-05-30 | 2016-04-13 | Metabolix, Inc. | Recyclate blends |
US9598802B2 (en) | 2013-12-17 | 2017-03-21 | Eastman Chemical Company | Ultrafiltration process for producing a sulfopolyester concentrate |
US9605126B2 (en) | 2013-12-17 | 2017-03-28 | Eastman Chemical Company | Ultrafiltration process for the recovery of concentrated sulfopolyester dispersion |
US10611903B2 (en) | 2014-03-27 | 2020-04-07 | Cj Cheiljedang Corporation | Highly filled polymer systems |
US11661537B2 (en) | 2018-09-07 | 2023-05-30 | Bostik, Inc. | Compostable hot melt adhesive |
CN115612430B (zh) * | 2022-12-19 | 2023-03-07 | 山东友谊胶粘科技有限公司 | 一种易剥离包装热熔胶及其制备方法 |
Family Cites Families (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3779993A (en) * | 1970-02-27 | 1973-12-18 | Eastman Kodak Co | Polyesters and polyesteramides containing ether groups and sulfonate groups in the form of a metallic salt |
US4073777A (en) * | 1975-01-17 | 1978-02-14 | Eastman Kodak Company | Radiation crosslinkable polyester and polyesteramide compositions containing sulfonate groups in the form of a metallic salt and unsaturated groups |
US4052368A (en) * | 1976-06-21 | 1977-10-04 | Minnesota Mining And Manufacturing Company | Water-dispellable hot melt polyester adhesives |
US4233196A (en) * | 1979-04-30 | 1980-11-11 | Eastman Kodak Company | Polyester and polyesteramide compositions |
US4257928A (en) * | 1980-01-28 | 1981-03-24 | Permabond International Corporation | Polyester adhesives |
US4304901A (en) * | 1980-04-28 | 1981-12-08 | Eastman Kodak Company | Water dissipatable polyesters |
US4525524A (en) * | 1984-04-16 | 1985-06-25 | The Goodyear Tire & Rubber Company | Polyester composition |
US4598142A (en) * | 1985-04-29 | 1986-07-01 | Eastman Kodak Company | Copolyester adhesives |
US4735843A (en) * | 1986-12-18 | 1988-04-05 | The Procter & Gamble Company | Selectively surface-hydrophilic porous or perforated sheets |
US4990593A (en) * | 1988-10-14 | 1991-02-05 | Eastman Kodak Company | Water-dissipatable polyester resins and coatings prepared therefrom |
US4910292A (en) * | 1988-10-14 | 1990-03-20 | Eastman Kodak Company | Water-dissipatable polyester resins and coatings prepared therefrom |
US5098962A (en) * | 1990-06-25 | 1992-03-24 | Frank Bozich | Water dispersible hot melt adhesive composition and application |
WO1992000363A1 (en) * | 1990-06-25 | 1992-01-09 | Enbond Limited | Water dispersible hot melt adhesive composition and application |
US5382652A (en) * | 1991-04-01 | 1995-01-17 | Toyo Boseki Kabushiki Kaisha | Polyester resin, compositions thereof and sealant made therefrom |
US5387623A (en) * | 1991-07-30 | 1995-02-07 | H. B. Fuller Company | Biodegradable adhesive packaging |
US5169889A (en) * | 1992-01-27 | 1992-12-08 | National Starch And Chemical Investment Holding Corporation | Poly hydroxybutyrate/hydroxyvalerate based hot melt adhesive |
US5360845A (en) * | 1992-12-23 | 1994-11-01 | National Starch And Chemical Investment Holding Corporation | Starch ester based hot melt adhesive |
US5356963A (en) * | 1993-07-16 | 1994-10-18 | National Starch And Chemical Investment Holding Corporation | Hydrophilic hot melt adhesives |
EP0713503B1 (en) * | 1993-08-12 | 1998-05-06 | Eastman Chemical Company | Water-dispersible acrylic-modified polyester resins used in coatings and process for their preparation |
US5608000A (en) * | 1993-09-24 | 1997-03-04 | H. B. Fuller Licensing & Financing, Inc. | Aqueous polyurethane dispersion adhesive compositions with improved heat resistance |
DK0737233T3 (da) * | 1993-12-29 | 1998-09-28 | Eastman Chem Co | Vanddispergerbar klæbestofsammensætning og fremgangsmåde |
US5543488A (en) * | 1994-07-29 | 1996-08-06 | Eastman Chemical Company | Water-dispersible adhesive composition and process |
US5532306A (en) * | 1994-08-31 | 1996-07-02 | National Starch And Chemical Investment Holding Corporation | Water-sensitive rubber-based hot melt adhesives |
US5574076A (en) * | 1995-05-03 | 1996-11-12 | National Starch And Chemical Investment Holding Corporation | Sucrose benzoate as a tackifier for water sensitive or biodegradable hot melt adhesives |
-
1996
- 1996-05-23 US US08/652,072 patent/US5750605A/en not_active Expired - Lifetime
- 1996-08-16 AU AU62135/96A patent/AU702877B2/en not_active Ceased
- 1996-08-22 ES ES96113481T patent/ES2150622T3/es not_active Expired - Lifetime
- 1996-08-22 EP EP96113481A patent/EP0761795B1/en not_active Expired - Lifetime
- 1996-08-22 DE DE69608624T patent/DE69608624T2/de not_active Expired - Lifetime
- 1996-09-02 JP JP23192896A patent/JP3949755B2/ja not_active Expired - Fee Related
- 1996-09-03 CA CA002184743A patent/CA2184743A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
EP0761795A3 (en) | 1997-10-22 |
US5750605A (en) | 1998-05-12 |
AU702877B2 (en) | 1999-03-11 |
EP0761795B1 (en) | 2000-05-31 |
EP0761795A2 (en) | 1997-03-12 |
AU6213596A (en) | 1997-03-06 |
DE69608624T2 (de) | 2001-02-08 |
JP3949755B2 (ja) | 2007-07-25 |
JPH09118869A (ja) | 1997-05-06 |
CA2184743A1 (en) | 1997-03-01 |
DE69608624D1 (de) | 2000-07-06 |
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