ES2150295T3 - Procedimiento para la hidroxilacion de hidrocarburos aromaticos. - Google Patents

Procedimiento para la hidroxilacion de hidrocarburos aromaticos.

Info

Publication number
ES2150295T3
ES2150295T3 ES98102068T ES98102068T ES2150295T3 ES 2150295 T3 ES2150295 T3 ES 2150295T3 ES 98102068 T ES98102068 T ES 98102068T ES 98102068 T ES98102068 T ES 98102068T ES 2150295 T3 ES2150295 T3 ES 2150295T3
Authority
ES
Spain
Prior art keywords
procedure
hydroxylation
catalyst
iron
hydrogen peroxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES98102068T
Other languages
English (en)
Inventor
Rodolfo Vignola
Ezio Battistel
Daniele Bianchi
Rossella Bortolo
Roberto Tassinari
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Enichem SpA
Original Assignee
Enichem SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Enichem SpA filed Critical Enichem SpA
Application granted granted Critical
Publication of ES2150295T3 publication Critical patent/ES2150295T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/403—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/745—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B41/00—Formation or introduction of functional groups containing oxygen
    • C07B41/02—Formation or introduction of functional groups containing oxygen of hydroxy or O-metal groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/60—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by oxidation reactions introducing directly hydroxy groups on a =CH-group belonging to a six-membered aromatic ring with the aid of other oxidants than molecular oxygen or their mixtures with molecular oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/842—Iron
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

LA INVENCION TRATA DE UN PROCEDIMIENTO PARA LA HIDROXILACION DE HIDROCARBUROS AROMATICOS MEDIANTE LA OXIDACION DIRECTA CON PEROXIDO DE HIDROGENO. EL PROCEDIMIENTO SE LLEVA A CABO EN PRESENCIA DE UN CATALIZADOR QUE INCLUYE: - HIERRO, ADMINISTRADO COMO SAL INORGANICA; - UN LIGANDO DE HIERRO, QUE CONSISTE EN ACIDOS CARBOXILICOS DE COMPUESTOS DE ETER AROMATICOS QUE CONTIENEN NITROGENO, EN PARTICULAR EL ACIDO PIRAZIN - 2 - CARBOXILICO Y DERIVADOS; - UN AGENTE ACIDIFICANTE, EN ESPECIAL ACIDO TRIFLUOROACETICO, Y UN SISTEMA DISOLVENTE QUE INCLUYE UNA FASE ORGANICA QUE CONSISTE EN UN SUSTRATO Y ACETONITRILO, Y UNA FASE ACUOSA QUE CONTIENE EL CATALIZADOR Y PEROXIDO DE HIDROGENO.
ES98102068T 1997-02-27 1998-02-06 Procedimiento para la hidroxilacion de hidrocarburos aromaticos. Expired - Lifetime ES2150295T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT97MI000434A IT1289989B1 (it) 1997-02-27 1997-02-27 Processo per l'idrossilazione di idrocarburi aromatici

Publications (1)

Publication Number Publication Date
ES2150295T3 true ES2150295T3 (es) 2000-11-16

Family

ID=11376214

Family Applications (1)

Application Number Title Priority Date Filing Date
ES98102068T Expired - Lifetime ES2150295T3 (es) 1997-02-27 1998-02-06 Procedimiento para la hidroxilacion de hidrocarburos aromaticos.

Country Status (6)

Country Link
US (2) US6071848A (es)
EP (1) EP0861688B1 (es)
JP (1) JPH10251178A (es)
DE (1) DE69800265T2 (es)
ES (1) ES2150295T3 (es)
IT (1) IT1289989B1 (es)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19853491A1 (de) * 1998-11-19 2000-05-25 Bayer Ag Verfahren zur Hydroxylierung von Benzol mit Wasserstoffperoxid
US7148386B2 (en) 2004-07-30 2006-12-12 General Electric Company Processes for preparing benzoquinones and hydroquinones
ITMI20042169A1 (it) * 2004-11-12 2005-02-12 Polimeri Europa Spa Processo continuo per la preparazione di fenolo da benzene in reattore a letto fisso
US7858787B2 (en) * 2006-09-22 2010-12-28 Shell Oil Company Process for producing olefins
DE102010008393A1 (de) 2010-02-10 2011-10-06 Technische Universität Dresden Substrat zur Bodenverbesserung mit Wasser speichernder Eigenschaft, Verfahren zur Herstellung und dessen Verwendung
ES2373291B2 (es) 2010-07-20 2012-10-17 Universidad De Huelva Procedimiento para la oxidación catalítica de benceno a fenol.

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3692842A (en) * 1971-02-12 1972-09-19 Stephen N Massie Hydroxylation of aromatic compounds
US4786714A (en) * 1985-11-29 1988-11-22 Shell Oil Company Catalytic process for polymerizing carbon monoxide and olefin(s) with nitrogen bidentate ligand
GB8704338D0 (en) * 1987-02-24 1987-04-01 Shell Int Research Dimerization of olefins
KR0148012B1 (ko) * 1989-03-03 1998-08-17 오노 알버어스 신규한 포스핀으로 구성되는 촉매시스템 및 이를 이용한 아세틸렌형 또는 올레핀형 불포화화합물의 카르보닐화방법
RU2043331C1 (ru) * 1989-08-07 1995-09-10 Государственный российский научно-исследовательский институт органической химии и технологии Способ совместного получения пирокатехина и гидрохинона
US5149880A (en) * 1990-01-16 1992-09-22 The Texas A & M University System Nitrogen-containing aromatic heterocyclic ligand-metal complexes and their use for the activation of hydrogen peroxide and dioxygen in the reaction of organic compounds
GB9002521D0 (en) * 1990-02-05 1990-04-04 Shell Int Research Carbonylation catalyst system
RU2028287C1 (ru) * 1992-02-10 1995-02-09 Акционерное общество закрытого типа "Промышленно-финансовая группа "Ассоциация внедрения" Способ совместного получения пирокатехина и гидрохинона

Also Published As

Publication number Publication date
DE69800265D1 (de) 2000-09-28
EP0861688A1 (en) 1998-09-02
EP0861688B1 (en) 2000-08-23
US6156939A (en) 2000-12-05
US6071848A (en) 2000-06-06
JPH10251178A (ja) 1998-09-22
IT1289989B1 (it) 1998-10-19
ITMI970434A1 (it) 1998-08-27
DE69800265T2 (de) 2001-02-01

Similar Documents

Publication Publication Date Title
Finichiu et al. A mitochondria-targeted derivative of ascorbate: MitoC
ES2150295T3 (es) Procedimiento para la hidroxilacion de hidrocarburos aromaticos.
Walker et al. Palladium‐Catalyzed Direct C H Functionalization of Benzoquinone
Ohtake et al. Highly efficient oxidation of alkanes and alkyl alcohols with heteroaromatic N-oxides catalyzed by ruthenium porphyrins
Calvete et al. Hydrogen peroxide and metalloporphyrins in oxidation catalysis: old dogs with some new tricks
Hashimoto et al. Direct Synthesis of 1, 4‐Diols from Alkenes by Iron‐Catalyzed Aerobic Hydration and C H Hydroxylation
Kirihara et al. Selective synthesis of sulfoxides and sulfones by tantalum (V) catalyzed oxidation of sulfides with 30% hydrogen peroxide
Garza‐Sanchez et al. DMSO as a switchable alkylating agent in heteroarene C− H functionalization
Parvari et al. Applicable properties of cucurbiturils
AR083305A2 (es) Catalizador, proceso para prepararlo, proceso para la oxidacion de un sustrato organico y proceso para preparar una sal de acido carboxilico
ES2174141T3 (es) Procedimiento para la fabricacion en continuo de carbonatos de diarilo
BR9500294A (pt) Processo para a estabilização de um sistema catalítico para a produção de olefinas bem como processo para tal produção
AR246501A1 (es) Un procedimiento para la alquilacion en fase liquida de un substrato de hidrocarburo con un agente de alquilacion olefinico.
ES2095529T3 (es) Derivados de los acidos carboxilicos como inhibidores de la 5-alfa-reductasa.
DE60232325D1 (de) Gerichtete oxidative therapeutische formulierung
Lu et al. Copper‐Catalyzed Aerobic Decarboxylation/Ketooxygenation of Electron‐Deficient Alkenes
ES2097370T3 (es) Un metodo para preparar acidos carboxilicos o sus esteres por escision oxidativa de acidos grasos insaturados o sus esteres.
Schröder et al. Novel biomimetic iron-catalysts for environmentally benign epoxidations of olefins
ES2191943T3 (es) Procedimiento de epoxidacion empleando un compuesto de peroxowolframato estabilizado con fosfato como catalizador.
Nakagawa Photo‐Controlled Release of Small Signaling Molecules to Induce Biological Responses
D'Accolti et al. Continued Progress towards Efficient Functionalization of Natural and Non‐natural Targets under Mild Conditions: Oxygenation by C− H Bond Activation with Dioxirane
ES2137307T3 (es) Catalizador y procedimiento para la oxidacion selectiva de hidrocarburos.
Petronilli et al. Switch from inhibition to activation of the mitochondrial permeability transition during hematoporphyrin-mediated photooxidative stress.: Unmasking pore-regulating external thiols
ES2182148T3 (es) Metodo de epoxidacion de polimeros insaturados.
ES2101953T3 (es) Compuestos de cerio iv organicos y su preparacion y utilizacion.

Legal Events

Date Code Title Description
FG2A Definitive protection

Ref document number: 861688

Country of ref document: ES