ES2147829T3 - Perfluoroalquil sulfuro, sulfona, polisulfona y polisulfuro dioles. - Google Patents

Perfluoroalquil sulfuro, sulfona, polisulfona y polisulfuro dioles.

Info

Publication number
ES2147829T3
ES2147829T3 ES95810423T ES95810423T ES2147829T3 ES 2147829 T3 ES2147829 T3 ES 2147829T3 ES 95810423 T ES95810423 T ES 95810423T ES 95810423 T ES95810423 T ES 95810423T ES 2147829 T3 ES2147829 T3 ES 2147829T3
Authority
ES
Spain
Prior art keywords
carbon
sub
alkylene
atoms
carbon atoms
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES95810423T
Other languages
English (en)
Inventor
Ted Deisenroth
Marlon Haniff
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Schweiz AG
Ciba SC Holding AG
Original Assignee
Ciba Spezialitaetenchemie Holding AG
Ciba SC Holding AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Spezialitaetenchemie Holding AG, Ciba SC Holding AG filed Critical Ciba Spezialitaetenchemie Holding AG
Application granted granted Critical
Publication of ES2147829T3 publication Critical patent/ES2147829T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/16—Sizing or water-repelling agents
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C305/00—Esters of sulfuric acids
    • C07C305/02—Esters of sulfuric acids having oxygen atoms of sulfate groups bound to acyclic carbon atoms of a carbon skeleton
    • C07C305/04—Esters of sulfuric acids having oxygen atoms of sulfate groups bound to acyclic carbon atoms of a carbon skeleton being acyclic and saturated
    • C07C305/06—Hydrogenosulfates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C317/00—Sulfones; Sulfoxides
    • C07C317/16—Sulfones; Sulfoxides having sulfone or sulfoxide groups and singly-bound oxygen atoms bound to the same carbon skeleton
    • C07C317/18—Sulfones; Sulfoxides having sulfone or sulfoxide groups and singly-bound oxygen atoms bound to the same carbon skeleton with sulfone or sulfoxide groups bound to acyclic carbon atoms of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/10—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and singly-bound oxygen atoms bound to the same carbon skeleton
    • C07C323/11—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and singly-bound oxygen atoms bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton
    • C07C323/12—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and singly-bound oxygen atoms bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being acyclic and saturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/06—Phosphorus compounds without P—C bonds
    • C07F9/08—Esters of oxyacids of phosphorus
    • C07F9/09—Esters of phosphoric acids
    • C07F9/091—Esters of phosphoric acids with hydroxyalkyl compounds with further substituents on alkyl
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3855—Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur
    • C08G18/3863—Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur containing groups having sulfur atoms between two carbon atoms, the sulfur atoms being directly linked to carbon atoms or other sulfur atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3855—Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur
    • C08G18/3863—Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur containing groups having sulfur atoms between two carbon atoms, the sulfur atoms being directly linked to carbon atoms or other sulfur atoms
    • C08G18/3865—Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur containing groups having sulfur atoms between two carbon atoms, the sulfur atoms being directly linked to carbon atoms or other sulfur atoms containing groups having one sulfur atom between two carbon atoms
    • C08G18/3868—Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur containing groups having sulfur atoms between two carbon atoms, the sulfur atoms being directly linked to carbon atoms or other sulfur atoms containing groups having one sulfur atom between two carbon atoms the sulfur atom belonging to a sulfide group
    • C08G18/387—Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur containing groups having sulfur atoms between two carbon atoms, the sulfur atoms being directly linked to carbon atoms or other sulfur atoms containing groups having one sulfur atom between two carbon atoms the sulfur atom belonging to a sulfide group in addition to a perfluoroalkyl group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
    • C08G63/688—Polyesters containing atoms other than carbon, hydrogen and oxygen containing sulfur
    • C08G63/6884—Polyesters containing atoms other than carbon, hydrogen and oxygen containing sulfur derived from polycarboxylic acids and polyhydroxy compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D06M13/236—Esters of carboxylic acids; Esters of carbonic acid containing halogen atoms
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D06M13/265—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur containing halogen atoms
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
    • D06M13/292—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
    • D06M13/298—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof containing halogen atoms
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D06M13/425—Carbamic or thiocarbamic acids or derivatives thereof, e.g. urethanes
    • D06M13/428—Carbamic or thiocarbamic acids or derivatives thereof, e.g. urethanes containing fluorine atoms
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/507—Polyesters
    • D06M15/513—Polycarbonates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • D06M15/576—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them containing fluorine
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/54—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen
    • D21H17/57—Polyureas; Polyurethanes

Abstract

SE PRESENTAN DIOLES SUSTITUIDOS CON BISPERFLUOROALQUIL DE LA FORMULA (I) EN LA CUAL R{SUB, 1} ES UN ENLACE DIRECTO, UN ALQUILENO LINEAL O RAMIFICADO DE HASTA 6 ATOMOS DE CARBONO, ALQUILENOXIDO-ALQUILENO HASTA 6 ATOMOS DE CARBONO, ALQUILENOTIOALQUILENO DE HASTA 6 ATOMOS DE CARBONO, ALQUILENOXIDO DE HASTA 6 ATOMOS DE CARBONO, ALQUILENOOXIALQUILENO DE HASTA 6 ATOMOS DE CARBONO, ALQUILENOTIOALQUILENOOXIALQUILENO DE HASTA 9 ATOMOS DE CARBONO, CARBONAMIDOALQUILENO EN DONDE LA MOLECULA DE ALQUILENO CONTIENE HASTA 6 ATOMOS DE CARBONO Y EL NITROGENO DEL AMIDO ESTA SUSTITUIDO O ADICIONALMENTE SUSTITUIDO POR ALQUIL, SULFONAMIDOALQUILENO EN DONDE LA MOLECULA DE ALQUILENO CONTIENE HASTA 6 ATOMOS DE CARBONO Y EL NITROGENO DEL AMIDO ESTA INSUSTITUIDO O ADICIONALMENTE SUSTITUIDO POR ALQUIL INFERIOR; CARBONAMIDOALQUILENOTIOALQUILENO EN DONDE LA MOLECULA DE CARBONAMIDOALQUILENO ES SEGUN SE DEFINE Y LA MOLECULA DE TIOALQUILENO CONTIENE HASTA 6 ATOMOS DE CARBONO, O SULFONAMIDOALQUILENOTIOALQUILENO EN DONDE LAMOLECULA DE SULFONAMIDOALQUILENO ES SEGUN SE DEFINE Y LA MOLECULA DE TIOALQUILENO CONTIENE HASTA 6 ATOMOS DE CARBONO, R{SUB, X}, R{SUB, Y} Y R{SUB, Z} SON INDEPENDIENTEMENTE UNA DE LAS OTRAS HIDROGENO O UN GRUPO DE ALQUIL CON ENTRE 1 Y 5 ATOMOS DE CARBONO, H ES 1 O 2, X ES 0, 1 O 2, CON LA CONDICION DE QUE CUANDO H ES 2, X ES 0, D ES 0 O 1, D ES UN GRUPO DE ALQUILENO CON ENTRE 2 Y 10 ATOMOS DE CARBONO, UN GRUPO DE ETER DE DIALQUILENO CON ENTRE 4 Y 10 ATOMOS DE CARBONO O DIACETATO O DIPROPIONATO DE PENTAERITRITOL, Y R{SUB, F} ES UN RADICAL ORGANICO, RECTO, RAMIFICADO O CICLICO, DE ALQUIL O ALQUENIL, PERFLUORADO, MONOVALENTE QUE TIENE ENTRE 3 Y 20 ATOMOS DE CARBONO COMPLETAMENTE FLUORADOS, CUYO RADICAL PUEDE ESTAR INTERRUMPIDO POR UNO O MAS ATOMOS DE AZUFRE O DE OXIGENO DIVALENTE, Y CADA RADICAL R{SUB, F} ES IGUAL O DIFERENTE, TAMBIEN SE PRESENTA UN METODO PARA FABRICAR LOS DIOLES. ESTOS DIOLES PUEDEN REACCIONAR CON ISOCIANATOS PARA FORMAR URETANOS; CON DIISOCIANATOS PARA FORMAR POLIURETANOS;CON CLOROFORMATOS PARA FORMAR CARBONATOS; CON ACIDOS CARBOXILICO, SULFURICO O FOSFORICO O DERIVADOS DE LOS MISMOS PARA FORMAR ESTERES DE CARBOXILATO, ESTERES DE SULFATO Y ESTERES DE FOSFATO, RESPECTIVAMENTE. LOS COMPUESTOS DE DIOL Y SUS DERIVADOS SON UTILES PARA IMPARTIR REPELENCIA AL ACEITE Y AL AGUA A SUBSTRATOS TALES COMO CRISTAL, MADERA, PAPEL, PIEL, LANA, ALGODON, POLIESTER Y OTROS SUBSTRATOS.
ES95810423T 1994-07-01 1995-06-22 Perfluoroalquil sulfuro, sulfona, polisulfona y polisulfuro dioles. Expired - Lifetime ES2147829T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US27006794A 1994-07-01 1994-07-01

Publications (1)

Publication Number Publication Date
ES2147829T3 true ES2147829T3 (es) 2000-10-01

Family

ID=23029757

Family Applications (1)

Application Number Title Priority Date Filing Date
ES95810423T Expired - Lifetime ES2147829T3 (es) 1994-07-01 1995-06-22 Perfluoroalquil sulfuro, sulfona, polisulfona y polisulfuro dioles.

Country Status (4)

Country Link
US (2) US5708119A (es)
EP (1) EP0694532B1 (es)
DE (1) DE69517252T2 (es)
ES (1) ES2147829T3 (es)

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Publication number Priority date Publication date Assignee Title
US5859126A (en) * 1995-09-18 1999-01-12 E. I. Du Pont De Nemours And Company Coatings containing fluorinated esters
US5670573A (en) * 1996-08-07 1997-09-23 E. I. Du Pont De Nemours And Company Coatings containing fluorinated esters
US5789513A (en) * 1997-02-26 1998-08-04 E. I. Du Pont De Nemours And Company Polyfluorourethane additives for curable coating compositions
DE29720200U1 (de) * 1997-11-14 1998-01-02 Kwade Betonwerk Gmbh & Co Kg Betonelement in Gestalt eines Pflastersteins
US6479612B1 (en) 1999-08-10 2002-11-12 E. I. Du Pont De Nemours And Company Fluorochemical water and oil repellents
EP1088867A1 (de) 1999-09-30 2001-04-04 Ciba Spezialitätenchemie Pfersee GmbH Zusammensetzungen für die öl- und wasserabweisende Ausrüstung von Fasermaterialien
JP2003050068A (ja) * 2001-05-30 2003-02-21 Permelec Electrode Ltd 過酸化水素を含有する氷組成物及び生鮮食品の保存方法
US6835860B2 (en) * 2002-02-01 2004-12-28 Merck & Co., Inc. Iodohydroxylation of olefins
WO2005116099A1 (en) * 2004-05-25 2005-12-08 Ciba Specialty Chemicals Holding Inc. Perfluorinated esters, polyester, ethers and carbonates
US7326506B2 (en) * 2004-05-28 2008-02-05 Samsung Electronics Co., Ltd. Bridged charge transport materials having a central sulfur atom linkage
US7205431B2 (en) * 2004-07-26 2007-04-17 Air Products And Chemicals, Inc. Bis(3-alkoxyalkan-2-ol) sulfides, sulfones, and sulfoxides: new surface active agents
US7160480B2 (en) * 2005-02-22 2007-01-09 E. I. Du Pont De Nemours And Company Leather treated with fluorochemicals
US20060188729A1 (en) * 2005-02-22 2006-08-24 Kai-Volker Schubert Washable leather with repellency
JP2008536023A (ja) * 2005-04-12 2008-09-04 インヴィスタ テクノロジー エスアエルエル 耐久性のある防汚および汚れ除去仕上げ剤で処理された布ならびに仕上げ剤の耐久性を維持するための業務用洗濯の方法
CN101935449B (zh) * 2010-07-28 2012-09-05 丽水市优耐克水性树脂科技有限公司 一种水性聚氨酯树脂的制备方法和水性聚氨酯树脂
CN103726308A (zh) * 2013-12-17 2014-04-16 江苏金太阳纺织科技有限公司 一种羊毛衫拒油整理液及其制备方法
CN103741459B (zh) * 2013-12-17 2016-08-31 南通市通州区家纺产业发展服务中心 一种涤纶织物拒油整理剂及其制备方法
US9120899B1 (en) * 2014-06-02 2015-09-01 International Business Machines Corporation Preparation of functional polysulfones
US9656239B2 (en) 2014-06-16 2017-05-23 International Business Machines Corporation Apparatus for controlling metals in liquids
US10080806B2 (en) 2015-08-19 2018-09-25 International Business Machines Corporation Sulfur-containing polymers from hexahydrotriazine and dithiol precursors as a carrier for active agents
CN111479900B (zh) * 2017-12-13 2022-03-29 3M创新有限公司 全氟化1-烷氧基丙烯、组合物、及其使用方法和设备
CN113130953B (zh) * 2021-04-09 2022-06-17 陕西国防工业职业技术学院 一种交联型聚砜阴离子交换膜及其制备方法

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US3759874A (en) * 1971-08-30 1973-09-18 Fmc Corp Fluorinated polyurethanes as soil release agents
US3828098A (en) * 1972-10-02 1974-08-06 Allied Chem Sulfur substituted bis(polyfluoroalkoxyalkyl carboxylic acids)and derivatives thereof
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US4098742A (en) * 1977-01-24 1978-07-04 Ciba-Geigy Corporation Fluorine and silicone containing polymers
US4898981A (en) * 1988-06-20 1990-02-06 Ciba-Geigy Corporation Heteroatom containing perfluoroalkyl terminated neopentyl glycols and compositions therefrom
US4946992A (en) * 1988-06-20 1990-08-07 Ciba-Geigy Corporation Heteroatom containing perfluoroalkyl terminated neopentyl glycols and compositions therefrom
US5200493A (en) * 1989-11-30 1993-04-06 Ciba-Geigy Corporation Heteroatom containing perfluoralkyl terminated neopentyl mercapto-alcohols and compositions therefrom
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US5132445A (en) * 1990-04-20 1992-07-21 Ciba-Geigy Corporation 5,5-bis (perfluoroalkylheteromethyl)-2-hydroxy-2-oxo-1,3,2-dioxaphosphorinanes, and salts or esters thereof
US5120364A (en) * 1990-10-10 1992-06-09 Ciba-Geigy Corporation Heteroatom containing perfluoroalkyl terminated neopentyl sulfates and salts thereof

Also Published As

Publication number Publication date
EP0694532A1 (en) 1996-01-31
DE69517252T2 (de) 2001-01-25
DE69517252D1 (de) 2000-07-06
US5708119A (en) 1998-01-13
US5693747A (en) 1997-12-02
EP0694532B1 (en) 2000-05-31

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