ES2139443T3 - Latex hibridos de poliester/materiales acrilicos de pequeño tamaño de particulas. - Google Patents
Latex hibridos de poliester/materiales acrilicos de pequeño tamaño de particulas.Info
- Publication number
- ES2139443T3 ES2139443T3 ES97906468T ES97906468T ES2139443T3 ES 2139443 T3 ES2139443 T3 ES 2139443T3 ES 97906468 T ES97906468 T ES 97906468T ES 97906468 T ES97906468 T ES 97906468T ES 2139443 T3 ES2139443 T3 ES 2139443T3
- Authority
- ES
- Spain
- Prior art keywords
- latex
- stage
- polyester
- hybrids
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000004816 latex Substances 0.000 title abstract 4
- 239000002245 particle Substances 0.000 title abstract 3
- 229920000728 polyester Polymers 0.000 title abstract 3
- 239000000463 material Substances 0.000 title 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- 239000000178 monomer Substances 0.000 abstract 2
- DWHJJLTXBKSHJG-UHFFFAOYSA-N 5-hydroxy-2-methylpent-2-enoic acid Chemical compound OC(=O)C(C)=CCCO DWHJJLTXBKSHJG-UHFFFAOYSA-N 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 238000007720 emulsion polymerization reaction Methods 0.000 abstract 1
- 230000002209 hydrophobic effect Effects 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/02—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polycarbonates or saturated polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F257/00—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00
- C08F257/02—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00 on to polymers of styrene or alkyl-substituted styrenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Paints Or Removers (AREA)
- Graft Or Block Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
EN ESTA INVENCION SE PRESENTA LA PREPARACION DE HIBRIDOS DE POLIESTER/ACRILICOS DISPERSIBLES EN AGUA A TRAVES DE UN PROCESO DE POLIMERIZACION EN EMULSION DE DOS ETAPAS. POR EJEMPLO, SE COPOLIMERIZAN ACIDO METACRILICO Y/O METACRILATO DE 2 - HIDROXIETILO CON MONOMEROS DE ESTIRENO/ACRILICOS PARA OBTENER UNA PRIMERA ETAPA RELATIVAMENTE HIDROFILA E HIDROPLASTIFICADA. LAS ADICIONES SUBSIGUIENTES DE MONOMEROS HIDROFOBOS A ESTA "SEMILLA" DE LA PRIMERA ETAPA RESULTAN EN UNA INVERSION DEL LATEX TAL QUE LA PRIMERA ETAPA MAS HIDROFILA TIENE LUGAR EN LA SUPERFICIE DE LAS PARTICULAS. ESTO DA COMO RESULTADO NO SOLO UNA ESTABILIDAD MEJORADA DEL LATEX RESULTANTE SIN QUE SEA NECESARIA LA UTILIZACION DE TENSIOACTIVOS ADICIONALES, TAL Y COMO QUEDA PROBADO POR LA PRODUCCION DE CANTIDADES REDUCIDAS DE COAGULOS, SINO QUE TAMBIEN OFRECE UNAS TEMPERATURAS MINIMAS DE FORMACION DE PELICULAS RELATIVAMENTE BAJAS DEBIDO A LA HIDROPLASTIFICACION DE LA ENVOLTURA DE LA PARTICULAS. ADEMAS, CON EL USO DEL POLIESTER DISPERSIBLE EN AGUA SE OBTIENEN UNOS TAMAÑOS DE LAS PARTICULAS DE LATEX EXTREMADAMENTE FINOS LO QUE AUMENTA SIGNIFICATIVAMENTE LAS PROPIEDADES DEL REVESTIMIENTO AL COMO EL BRILLO Y CLARIDAD DE LA PELICULA.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US59456496A | 1996-01-31 | 1996-01-31 | |
| US2405496P | 1996-08-16 | 1996-08-16 | |
| US2405596P | 1996-08-16 | 1996-08-16 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2139443T3 true ES2139443T3 (es) | 2000-02-01 |
Family
ID=27362250
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES97906468T Expired - Lifetime ES2139443T3 (es) | 1996-01-31 | 1997-01-31 | Latex hibridos de poliester/materiales acrilicos de pequeño tamaño de particulas. |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US6001922A (es) |
| EP (1) | EP0877764B1 (es) |
| JP (1) | JP2000505830A (es) |
| CA (1) | CA2245146C (es) |
| DE (1) | DE69700831T2 (es) |
| ES (1) | ES2139443T3 (es) |
| MX (1) | MX206545B (es) |
| WO (1) | WO1997028198A1 (es) |
Families Citing this family (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6184287B1 (en) * | 1999-01-26 | 2001-02-06 | Omnova Solutions Inc. | Polymeric latexes prepared in the presence of 2-acrylamido-2-methylpropanesulfonate |
| JP4469966B2 (ja) * | 2000-03-30 | 2010-06-02 | 独立行政法人 国立印刷局 | 水性印刷インキと、これを用いた印刷物及びその製造方法 |
| US6531523B1 (en) * | 2000-10-10 | 2003-03-11 | Renal Tech International, Llc | Method of making biocompatible polymeric adsorbing material for purification of physiological fluids of organism |
| US7812079B2 (en) | 2001-02-22 | 2010-10-12 | Valspar Sourcing, Inc. | Coating compositions containing low VOC compounds |
| AU2002301310B2 (en) | 2001-10-17 | 2007-12-20 | Rohm And Haas Company | Polymer composition |
| AU2003204606A1 (en) * | 2002-06-14 | 2004-01-15 | Rohm And Haas Company | Water-based adhesives |
| US20050004272A1 (en) * | 2003-06-23 | 2005-01-06 | Thauming Kuo | Small-particle latex compositions based on waterborne alkyd seeds |
| US7173081B2 (en) * | 2003-08-12 | 2007-02-06 | Hexion Specialty Chemicals, Inc. | Processes to produce water-dispersible polyester stabilized fluoroalkyl compositions |
| US7189780B2 (en) * | 2003-08-12 | 2007-03-13 | Hexion Specialty Chemicals, Inc. | Processes to produce water-dispersible polyester stabilized, acid-treated, fluoroalkyl compositions |
| US7186769B2 (en) * | 2003-08-12 | 2007-03-06 | Hexion Specialty Chemicals, Inc. | Water-dispersible polyester stabilized fluoroalkyl compositions |
| US7179376B2 (en) * | 2003-11-24 | 2007-02-20 | Ppg Industries Ohio, Inc. | Method and system for removing residual water from excess washcoat by ultrafiltration |
| US7195820B2 (en) * | 2003-12-09 | 2007-03-27 | Arkema Inc. | Core-shell polymers having hydrophilic shells for improved shell coverage and anti-blocking properties |
| US7717992B2 (en) | 2004-11-03 | 2010-05-18 | Basf Corporation | Color enhancing emulsions |
| US7589158B2 (en) * | 2005-11-30 | 2009-09-15 | Columbia Insurance Company | Polymers with improved shelf stability |
| US20080057090A1 (en) * | 2006-09-01 | 2008-03-06 | Mcentire Edward Enns | Wrinkle masking film composition for skin |
| US7879942B2 (en) | 2006-10-05 | 2011-02-01 | Eastman Chemical Company | Switchable adhesive article for attachment to skin and method of using the same |
| US20080153980A1 (en) * | 2006-12-20 | 2008-06-26 | Xerox Corporation | Process for preparing nano-sized polymer particles |
| US7915327B2 (en) * | 2007-03-22 | 2011-03-29 | Xerox Corporation | Spherical silica core-shell particles |
| US20090163635A1 (en) * | 2007-12-19 | 2009-06-25 | Eastman Chemical Company | Aqueous dispersions of adhesion promoters |
| US8071037B2 (en) | 2008-06-25 | 2011-12-06 | Cummins Filtration Ip, Inc. | Catalytic devices for converting urea to ammonia |
| US20100056724A1 (en) * | 2008-09-04 | 2010-03-04 | Carmen Flosbach | Process for preparation of aqueous binder latices |
| EP2342245B1 (en) | 2008-10-09 | 2019-03-06 | Allnex Netherlands B.V. | Aqueous hybrid dispersions |
| JP4406468B1 (ja) * | 2009-04-03 | 2010-01-27 | 昭和高分子株式会社 | 水系速乾塗料組成物 |
| KR20140014366A (ko) * | 2009-04-15 | 2014-02-06 | 바스프 에스이 | 수성 복합-입자 분산액의 제조 방법 |
| WO2011086883A1 (ja) * | 2010-01-18 | 2011-07-21 | 星光Pmc株式会社 | 水性印刷インキ用水性分散液および水性印刷インキ |
| SG184275A1 (en) | 2010-03-31 | 2012-11-29 | Nuplex Resins Bv | Waterborne hybrid polymer dispersion |
| JP5490159B2 (ja) * | 2012-02-03 | 2014-05-14 | 富士フイルム株式会社 | インク組成物、画像形成方法及びそれを用いた印画物 |
| CA2966787A1 (en) * | 2014-11-03 | 2016-05-12 | Arkema Inc. | Latex comprising water-soluble acrylic modified alkyd dispersion and method of production thereof |
| EP3138867B1 (de) * | 2015-09-03 | 2019-10-02 | Evonik Degussa GmbH | Verwendung von eugenol-polyethern und eugenol-polyethersiloxanen als netzmittel |
| EP3294819A1 (en) * | 2015-09-15 | 2018-03-21 | Hewlett-Packard Development Company, L.P. | White inks |
| CN106715611B (zh) * | 2016-03-16 | 2018-11-27 | 互应化学工业株式会社 | 底漆组合物、层合材料和用于生产底漆组合物的方法 |
| US20180298224A1 (en) * | 2017-04-13 | 2018-10-18 | Eastman Chemical Company | Process for producing cellulose ester/acrylic composite latex particles |
| CN109705505B (zh) * | 2018-12-27 | 2022-04-08 | 科思创树脂制造(佛山)有限公司 | 一种具有互穿网络结构的水性双组分体系丙烯酸树脂的制备方法 |
| US20220064371A1 (en) | 2020-09-03 | 2022-03-03 | Jain-Chem, Ltd. | Non-sulfonated polyester acrylates and coatings employing same |
| CN112708335B (zh) * | 2020-12-27 | 2022-04-05 | 山东齐鲁漆业有限公司 | 一种基于纳米改性醇酸树脂的速干面漆及其制备工艺 |
| CN113603833B (zh) * | 2021-07-02 | 2024-09-03 | 珠海展辰新材料股份有限公司 | 醇酸-丙烯酸杂化乳液及其制备方法 |
| JP2025010045A (ja) * | 2023-06-30 | 2025-01-20 | サカタインクス株式会社 | 水性グラビア印刷インキ組成物 |
| WO2025071812A1 (en) * | 2023-09-29 | 2025-04-03 | Dow Global Technologies Llc | Silicone - acrylic binder for liquid applied thermal insulation coating compositions to resist corrosion under insulation |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4150005A (en) * | 1977-03-17 | 1979-04-17 | Rohm And Haas Company | Internally plasticized polymer latex |
| US4325856A (en) * | 1980-01-02 | 1982-04-20 | The Dow Chemical Company | Sequential emulsion polymerization process |
| FR2515657B1 (fr) * | 1981-11-03 | 1987-07-17 | Kendall & Co | Procede de polymerisation en emulsion et produit obtenu |
| US4916171A (en) * | 1984-07-25 | 1990-04-10 | Rohm And Haas Company | Polymers comprising alkali-insoluble core/alkali-soluble shell and copositions thereof |
| US4704309A (en) * | 1985-06-07 | 1987-11-03 | Eastman Kodak Company | Printing processes employing water dispersible inks |
| CA1268294A (en) * | 1985-10-31 | 1990-04-24 | Johnson (S. C.) & Son, Inc. | Anticorrosive copolymer emulsions and methods of using and preparing them |
| US4839413A (en) * | 1986-08-22 | 1989-06-13 | S.C. Johnson & Son, Inc. | Resin-fortified emulsion polymers and methods of preparing the same |
| FR2628431B1 (fr) * | 1988-03-11 | 1992-01-10 | Rhone Poulenc Chimie | Nouveaux polyesters sulfones greffes, leur procede de preparation et leur application a l'encollage des fils et fibres textiles |
| US4996252A (en) * | 1988-07-28 | 1991-02-26 | Eastman Kodak Company | Ink composition containing a blend of a polyester and an acrylic polymer |
| US4946932A (en) * | 1988-12-05 | 1990-08-07 | Eastman Kodak Company | Water-dispersible polyester blends |
| US4939233A (en) * | 1988-12-05 | 1990-07-03 | Eastman Kodak Company | Aqueous polymer compositions and methods for their preparation |
| DE3939918A1 (de) * | 1989-12-02 | 1991-06-06 | Henkel Kgaa | Polymere stabilisatoren fuer die emulsionspolymerisation |
| US5147937A (en) * | 1990-03-22 | 1992-09-15 | Rohm And Haas Company | Process for making controlled, uniform-sized particles in the 1 to 50 micrometer range |
| US5218032A (en) * | 1991-01-09 | 1993-06-08 | Eastman Kodak Company | Process for preparing blends of polyesters and acrylic polymers |
| DE4136657A1 (de) * | 1991-11-07 | 1993-05-13 | Basf Ag | Emulsionspolymerisate mit niedrigem restmonomerengehalt |
| US5342877A (en) * | 1992-07-06 | 1994-08-30 | Eastman Chemical Company | Blends of polyesters and alkylhydroxy (meth)acrylate compounds |
| WO1995001381A1 (en) * | 1993-06-29 | 1995-01-12 | Eastman Chemical Company | Polymer blends comprising sulfonate group-containing surfactants |
| US5326843A (en) * | 1993-10-04 | 1994-07-05 | Rohm And Haas Company | Method for making an alkali-soluble emulsion copolymer |
-
1997
- 1997-01-31 CA CA002245146A patent/CA2245146C/en not_active Expired - Fee Related
- 1997-01-31 ES ES97906468T patent/ES2139443T3/es not_active Expired - Lifetime
- 1997-01-31 DE DE69700831T patent/DE69700831T2/de not_active Expired - Fee Related
- 1997-01-31 MX MX9806146A patent/MX206545B/es not_active IP Right Cessation
- 1997-01-31 WO PCT/US1997/001684 patent/WO1997028198A1/en not_active Ceased
- 1997-01-31 JP JP9527878A patent/JP2000505830A/ja active Pending
- 1997-01-31 EP EP97906468A patent/EP0877764B1/en not_active Expired - Lifetime
- 1997-08-15 US US08/911,702 patent/US6001922A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| MX9806146A (es) | 1999-02-28 |
| DE69700831D1 (de) | 1999-12-30 |
| CA2245146C (en) | 2003-04-08 |
| DE69700831T2 (de) | 2000-05-18 |
| EP0877764A1 (en) | 1998-11-18 |
| US6001922A (en) | 1999-12-14 |
| CA2245146A1 (en) | 1997-08-07 |
| JP2000505830A (ja) | 2000-05-16 |
| WO1997028198A1 (en) | 1997-08-07 |
| EP0877764B1 (en) | 1999-11-24 |
| MX206545B (es) | 2002-02-08 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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