ES2108313T3 - Procedimiento de (co)polimerizacion de monomeros olefinicos fluorados en emulsion acuosa. - Google Patents
Procedimiento de (co)polimerizacion de monomeros olefinicos fluorados en emulsion acuosa.Info
- Publication number
- ES2108313T3 ES2108313T3 ES94103287T ES94103287T ES2108313T3 ES 2108313 T3 ES2108313 T3 ES 2108313T3 ES 94103287 T ES94103287 T ES 94103287T ES 94103287 T ES94103287 T ES 94103287T ES 2108313 T3 ES2108313 T3 ES 2108313T3
- Authority
- ES
- Spain
- Prior art keywords
- monomers
- olephinic
- polymerization
- fluorine
- procedure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000178 monomer Substances 0.000 title abstract 3
- 239000000839 emulsion Substances 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 238000006116 polymerization reaction Methods 0.000 title abstract 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 title 1
- 229910052731 fluorine Inorganic materials 0.000 title 1
- 239000011737 fluorine Substances 0.000 title 1
- -1 HYDROGEN CHAIN Chemical group 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical class [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/18—Monomers containing fluorine
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/18—Monomers containing fluorine
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F216/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
- C08F216/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an alcohol radical
- C08F216/04—Acyclic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2438/00—Living radical polymerisation
- C08F2438/01—Atom Transfer Radical Polymerization [ATRP] or reverse ATRP
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Abstract
SE PRESENTA UN PROCESO DE (CO)POLIMERIZACION RADICAL DE MONOMEROS OLEFINICOS CLORADOS, OPCIONALMENTE EN ASOCIACION CON UNA O MAS OLEFINAS NO FLUORADAS, EN EL QUE LOS MONOMEROS SE (CO)POLIMERIZAN EN UNA EMULSION ACUOSA, EN LA PRESENCIA DE UN AGENTE DE TRANSFERENCIA DE CADENA HIDROGENADO SELECCIONADO ENTRE HIDROGENO, HIDROCARBONOS ALIFATICOS Y FLUOROHIDROCARBONOS C1-C20 Y DE UN ALCOHOL ALIFATICO DE CADENA RAMIFICADA C3-C12 QUE SE CARACTERIZA POR LA PROPORCION ENTRE EL NUMERO DE GRUPOS DE HIDROXIL Y EL NUMERO DE GRUPOS DE METIL MENOR O IGUAL A 0.5.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ITMI930551A IT1271136B (it) | 1993-03-23 | 1993-03-23 | Processo di (co)polimerizzazione in emulsione acquosa di monomeri olefinici fluorurati |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2108313T3 true ES2108313T3 (es) | 1997-12-16 |
Family
ID=11365454
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES94103287T Expired - Lifetime ES2108313T3 (es) | 1993-03-23 | 1994-03-04 | Procedimiento de (co)polimerizacion de monomeros olefinicos fluorados en emulsion acuosa. |
Country Status (9)
Country | Link |
---|---|
US (1) | US5516863A (es) |
EP (1) | EP0617058B1 (es) |
JP (1) | JP3383064B2 (es) |
KR (1) | KR100296906B1 (es) |
AT (1) | ATE158310T1 (es) |
CA (1) | CA2119411A1 (es) |
DE (1) | DE69405618T2 (es) |
ES (1) | ES2108313T3 (es) |
IT (1) | IT1271136B (es) |
Families Citing this family (37)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5590654A (en) | 1993-06-07 | 1997-01-07 | Prince; Martin R. | Method and apparatus for magnetic resonance imaging of arteries using a magnetic resonance contrast agent |
US5579767A (en) * | 1993-06-07 | 1996-12-03 | Prince; Martin R. | Method for imaging abdominal aorta and aortic aneurysms |
US5417213A (en) * | 1993-06-07 | 1995-05-23 | Prince; Martin R. | Magnetic resonance arteriography with dynamic intravenous contrast agents |
IT1266647B1 (it) * | 1993-10-29 | 1997-01-09 | Ausimont Spa | Processo di (co)polimerizzazione di monomeri olefinici fluorurati in emulsione acquosa |
IT1271621B (it) * | 1994-03-21 | 1997-06-04 | Ausimont Spa | Processo per la preparazione di fluoropolimeri termoplastici contenenti idrogeno |
IT1274711B (it) | 1994-08-04 | 1997-07-24 | Ausimont Spa | Processo per la preparazione di fluoropolimeri contenenti idrogeno tramite (co)polimerizzazione in sospensione |
IT1270703B (it) * | 1994-11-17 | 1997-05-07 | Ausimont Spa | Microemulsioni di fluoropoliossialchileni in miscela con idrocarburi, e loro uso in processi di (co)polimerizzazione di monomeri fluorurati |
EP1141047B1 (en) | 1998-11-30 | 2009-03-11 | E.I. Du Pont De Nemours And Company | Fluoromonomer polymerization |
FR2804438A1 (fr) * | 2000-01-31 | 2001-08-03 | Atofina | Procede de preparation d'un polymere fluore par polymerisation radicalaire d'une emulsion aqueuse |
IT1317847B1 (it) | 2000-02-22 | 2003-07-15 | Ausimont Spa | Processo per la preparazione di dispersioni acquose di fluoropolimeri. |
IT1318596B1 (it) * | 2000-06-23 | 2003-08-27 | Ausimont Spa | Copolimeri termoprocessbili del tfe. |
IT1318594B1 (it) * | 2000-06-23 | 2003-08-27 | Ausimont Spa | Processo di polimerizzazione di monomeri solfonici. |
US6649720B2 (en) | 2001-02-14 | 2003-11-18 | Atofina Chemicals, Inc. | Ethane as a chain transfer agent for vinylidene fluoride polymerization |
US7125941B2 (en) | 2001-03-26 | 2006-10-24 | 3M Innovative Properties Company | Aqueous emulsion polymerization process for producing fluoropolymers |
ATE332316T1 (de) * | 2001-03-26 | 2006-07-15 | 3M Innovative Properties Co | Verbessertes verfahren zur polymerisation von fluor enthaltenden monomeren in wässriger emulsion |
US6734264B1 (en) * | 2002-12-16 | 2004-05-11 | Atofina Chemicals, Inc. | Chain transfer agent |
FR2850387B1 (fr) * | 2003-01-23 | 2005-03-04 | Atofina | Procede de fabrication de pvdf |
EP1533325B1 (en) | 2003-11-17 | 2011-10-19 | 3M Innovative Properties Company | Aqueous dispersions of polytetrafluoroethylene having a low amount of fluorinated surfactant |
AU2008234382A1 (en) * | 2007-04-02 | 2008-10-09 | Cfs Concrete Forming Systems Inc. | Methods and apparatus for providing linings on concrete structures |
AU2008324734B2 (en) | 2007-11-09 | 2015-05-07 | Cfs Concrete Forming Systems Inc. | Pivotally activated connector components for form-work systems and methods for use of same |
CA2712533C (en) * | 2008-01-21 | 2016-06-21 | Octaform Systems Inc. | Stay-in-place form systems for windows and other building openings |
US8943774B2 (en) | 2009-04-27 | 2015-02-03 | Cfs Concrete Forming Systems Inc. | Methods and apparatus for restoring, repairing, reinforcing and/or protecting structures using concrete |
AU2010204442B2 (en) | 2009-01-07 | 2016-01-07 | Cfs Concrete Forming Systems Inc. | Methods and apparatus for restoring, repairing, reinforcing and/or protecting structures using concrete |
EP2398974B1 (en) | 2009-02-18 | 2017-08-02 | CFS Concrete Forming Systems Inc. | Clip-on connection system for stay-in-place form-work |
CA2804361C (en) | 2010-07-06 | 2014-04-08 | Cfs Concrete Forming Systems Inc. | Push on system for restoring, repairing, reinforcing, protecting, insulating and/or cladding structures |
US9206614B2 (en) | 2011-11-24 | 2015-12-08 | Cfs Concrete Forming Systems Inc. | Stay-in-place formwork with engaging and abutting connections |
CA2855739C (en) | 2011-11-24 | 2016-10-11 | Cfs Concrete Forming Systems Inc. | Stay-in-place formwork with anti-deformation panels |
JP2012082438A (ja) * | 2011-12-22 | 2012-04-26 | Daikin Industries Ltd | 含フッ素オレフィン重合体粒子 |
US9315987B2 (en) | 2012-01-05 | 2016-04-19 | Cfs Concrete Forming Systems Inc. | Systems for restoring, repairing, reinforcing, protecting, insulating and/or cladding structures with locatable stand-off components |
US10151119B2 (en) | 2012-01-05 | 2018-12-11 | Cfs Concrete Forming Systems Inc. | Tool for making panel-to-panel connections for stay-in-place liners used to repair structures and methods for using same |
CA2859607C (en) | 2012-01-05 | 2016-10-11 | Cfs Concrete Forming Systems Inc. | Panel-to-panel connections for stay-in-place liners used to repair structures |
CN105940165B (zh) | 2013-12-06 | 2019-01-15 | Cfs 混凝土模板系统公司 | 结构件覆层装饰部件、制造及使用该结构件覆层装饰部件的方法 |
US9982444B2 (en) | 2014-04-04 | 2018-05-29 | Cfs Concrete Forming Systems Inc. | Liquid and gas-impermeable connections for panels of stay-in-place form-work systems |
CA3008915A1 (en) | 2015-12-31 | 2017-07-06 | Cfs Concrete Forming Systems Inc. | Structure-lining apparatus with adjustable width and tool for same |
CN115262848A (zh) | 2017-04-03 | 2022-11-01 | Cfs 混凝土模板系统公司 | 结构件衬里装置和对结构件加衬里表面的方法 |
EP3728763A4 (en) | 2017-12-22 | 2021-10-13 | CFS Concrete Forming Systems Inc. | LOCKING CONNECTOR SPACER FOR THE RESTORATION, REPAIR, REINFORCEMENT, PROTECTION, INSULATION AND / OR COVERING OF STRUCTURES |
WO2020160684A1 (en) | 2019-02-08 | 2020-08-13 | Cfs Concrete Forming Systems Inc. | Retainers for restoring, repairing, reinforcing, protecting, insulating and/or cladding structures |
Family Cites Families (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE471894A (es) * | 1946-03-16 | |||
US2520388A (en) * | 1946-11-21 | 1950-08-29 | Power Jets Res & Dev Ltd | Apparatus for supporting combustion in fast-moving air streams |
DE1072810B (de) * | 1955-12-05 | 1960-01-07 | E. I. Du Pont De Nemours And Company, Wilmington, Del. (V. St. A.) | Verfahren zur Polymerisation oder Mischpolymerisation von perfluorierten olefinisch ungesättigten Verbindungen, besonders von Tetrafluoräthylen |
US2968649A (en) * | 1958-12-04 | 1961-01-17 | Du Pont | Elastomeric terpolymers |
US3467635A (en) * | 1964-10-30 | 1969-09-16 | Du Pont | Copolymers of tetrafluoroethylene and olefins curable to elastomers |
US3635926A (en) * | 1969-10-27 | 1972-01-18 | Du Pont | Aqueous process for making improved tetrafluoroethylene / fluoroalkyl perfluorovinyl ether copolymers |
US3624250A (en) * | 1970-01-20 | 1971-11-30 | Du Pont | Copolymers of ethylene/tetrafluoroethylene and of ethylene/chlorotrifluoroethylene |
US3865845A (en) * | 1971-02-24 | 1975-02-11 | Paul Raphael Resnick | Fluorinated dioxoles |
US3978030A (en) * | 1973-08-01 | 1976-08-31 | E. I. Du Pont De Nemours And Company | Polymers of fluorinated dioxoles |
JPS53125491A (en) * | 1977-04-08 | 1978-11-01 | Daikin Ind Ltd | Fluorine-containing polymer easily curable and its curable composition |
JPS5645911A (en) * | 1979-09-25 | 1981-04-25 | Asahi Glass Co Ltd | Production of ion-exchangeable fluorinated polymer |
JPS5838707A (ja) * | 1981-08-20 | 1983-03-07 | イ−・アイ・デユポン・デ・ニモアス・アンド・カンパニ− | パ−フルオロ−2,2−ジメチル−1,3−ジオキソ−ルの無定形共重合体 |
US4360652A (en) * | 1981-08-31 | 1982-11-23 | Pennwalt Corporation | Method of preparing high quality vinylidene fluoride polymer in aqueous emulsion |
US4429143A (en) * | 1981-09-28 | 1984-01-31 | E. I. Du Pont De Nemours & Co. | Cyclic monomers derived from trifluoropyruvate esters |
US4399264A (en) * | 1981-11-19 | 1983-08-16 | E. I. Du Pont De Nemours & Co. | Perfluorodioxole and its polymers |
US4426501A (en) * | 1983-01-17 | 1984-01-17 | E. I. Du Pont De Nemours And Company | Emulsion copolymerization process using comonomer solubility affecting additives |
JPS59197411A (ja) * | 1983-04-25 | 1984-11-09 | Daikin Ind Ltd | エチレン−テトラフルオロエチレンまたはクロロトリフルオロエチレン系共重合体 |
US4694045A (en) * | 1985-12-11 | 1987-09-15 | E. I. Du Pont De Nemours And Company | Base resistant fluoroelastomers |
US4675380A (en) * | 1985-10-25 | 1987-06-23 | E. I. Du Pont De Nemours And Company | Melt-processible tetrafluoroethylene/perfluoroolefin copolymer granules and processes for preparing them |
IT1189092B (it) * | 1986-04-29 | 1988-01-28 | Ausimont Spa | Processo di polimerizzazione in dispersione acquosa di monomeri fluorurati |
JPS62285907A (ja) * | 1986-06-03 | 1987-12-11 | Asahi Glass Co Ltd | テトラフルオロエチレン−フルオロビニルエ−テル共重合体の製造方法 |
IT1204903B (it) * | 1986-06-26 | 1989-03-10 | Ausimont Spa | Processo di polimerizzazione in dispersione acquosa di monomeri florati |
IT1230650B (it) * | 1988-11-17 | 1991-10-28 | Ausimont Srl | Procedimento per la preparazione di copolimeri tetrafluoroetilene etilene |
JP2773215B2 (ja) * | 1989-04-07 | 1998-07-09 | ダイキン工業株式会社 | 高分子誘電体材料 |
US4973633A (en) * | 1989-05-15 | 1990-11-27 | E. I. Du Pont De Nemours And Company | Peroxide-curable fluoroelastomers having bromine an iodine curesites and the preparation thereof |
IT1235545B (it) * | 1989-07-10 | 1992-09-09 | Ausimont Srl | Fluoroelastomeri dotati di migliore processabilita' e procedimento di preparazione |
IT1247934B (it) * | 1991-05-15 | 1995-01-05 | Ausimont Spa | Fluoroelastomeri a base di vinilidenfluoruro, dotati di superiore resistenza alle basi |
-
1993
- 1993-03-23 IT ITMI930551A patent/IT1271136B/it active IP Right Grant
-
1994
- 1994-03-04 DE DE69405618T patent/DE69405618T2/de not_active Expired - Fee Related
- 1994-03-04 AT AT94103287T patent/ATE158310T1/de not_active IP Right Cessation
- 1994-03-04 ES ES94103287T patent/ES2108313T3/es not_active Expired - Lifetime
- 1994-03-04 EP EP94103287A patent/EP0617058B1/en not_active Expired - Lifetime
- 1994-03-18 CA CA002119411A patent/CA2119411A1/en not_active Abandoned
- 1994-03-22 KR KR1019940005722A patent/KR100296906B1/ko not_active IP Right Cessation
- 1994-03-23 JP JP07643494A patent/JP3383064B2/ja not_active Expired - Fee Related
-
1995
- 1995-08-18 US US08/516,685 patent/US5516863A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
DE69405618D1 (de) | 1997-10-23 |
DE69405618T2 (de) | 1998-04-23 |
ITMI930551A0 (it) | 1993-03-23 |
EP0617058B1 (en) | 1997-09-17 |
US5516863A (en) | 1996-05-14 |
JPH0790008A (ja) | 1995-04-04 |
EP0617058A1 (en) | 1994-09-28 |
ITMI930551A1 (it) | 1994-09-23 |
KR940021592A (ko) | 1994-10-19 |
KR100296906B1 (ko) | 2001-10-24 |
CA2119411A1 (en) | 1994-09-24 |
JP3383064B2 (ja) | 2003-03-04 |
ATE158310T1 (de) | 1997-10-15 |
IT1271136B (it) | 1997-05-27 |
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