ES2131121T3 - Procedimiento de fabricacion de una espuma alquenilaromatica. - Google Patents

Procedimiento de fabricacion de una espuma alquenilaromatica.

Info

Publication number
ES2131121T3
ES2131121T3 ES93922243T ES93922243T ES2131121T3 ES 2131121 T3 ES2131121 T3 ES 2131121T3 ES 93922243 T ES93922243 T ES 93922243T ES 93922243 T ES93922243 T ES 93922243T ES 2131121 T3 ES2131121 T3 ES 2131121T3
Authority
ES
Spain
Prior art keywords
foam
bodies
polymer material
blowing agent
ethane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES93922243T
Other languages
English (en)
Inventor
Chung P Park
Kyung W Suh
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Application granted granted Critical
Publication of ES2131121T3 publication Critical patent/ES2131121T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/141—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
    • C08J9/08—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B9/00—Making granules
    • B29B9/02—Making granules by dividing preformed material
    • B29B9/06—Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B9/00—Making granules
    • B29B9/12—Making granules characterised by structure or composition
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/122—Hydrogen, oxygen, CO2, nitrogen or noble gases
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/127—Mixtures of organic and inorganic blowing agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/16—Making expandable particles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2201/00—Foams characterised by the foaming process
    • C08J2201/02—Foams characterised by the foaming process characterised by mechanical pre- or post-treatments
    • C08J2201/03—Extrusion of the foamable blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/06—CO2, N2 or noble gases
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2205/00—Foams characterised by their properties
    • C08J2205/04—Foams characterised by their properties characterised by the foam pores
    • C08J2205/052—Closed cells, i.e. more than 50% of the pores are closed
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
    • C08J2325/02—Homopolymers or copolymers of hydrocarbons
    • C08J2325/04—Homopolymers or copolymers of styrene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
  • Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)

Abstract

SE PRESENTA UN PROCESO PARA FABRICAR CUERPOS DE EMPAQUETADO DE ESPUMA O HEBRAS DE ESPUMA DE POLIMERO AROMATICO DE ALQUENILO, DE CELDA CERRADA. UN MATERIAL DE POLIMERO AROMATICO DE ALQUENILO SE CALIENTA PARA FORMAR UN MATERIAL DE POLIMERO FUNDIDO. SE INCORPORA UN AGENTE ESPUMANTE EN EL MATERIAL DE POLIMERO FUNDIDO A UNA TEMPERATURA Y UNA PRESION ELEVADAS PARA FORMAR UN GEL ESPUMABLE. EL AGENTE ESPUMANTE TIENE UN 20% DE SU PESO O MAS DE UN PRIMER AGENTE ESPUMANTE SELECCIONADO ENTRE EL GRUPO QUE CONSTA DE DIOXIDO DE CARBONO Y ETANO. EL GEL ESPUMABLE SE EXTRUYE A TRAVES DE UN TROQUEL PARA FORMAR UNA HEBRA ESPUMADA. LA HEBRA ESPUMADA SE CONVIERTE OPCIONALMENTE EN PASTILLAS PARA FORMAR UNA PLURALIDAD DE CUERPOS DE ESPUMA. LOS CUERPOS SON EXPANDIDOS ADICIONALMENTE EXPONIENDOLOS UNA O MAS VECES A AIRE O VAPOR CALIENTE. PREFERIBLEMENTE, LAS HEBRAS O CUERPOS SE DEJAN ENVEJECER DURANTE UN PERIODO DE TIEMPO PRESELECCIONADO ANTES Y ENTRE EXPANSIONES SUBSECUENTES. EL USO DE DIOXIDO DE CARBONO Y/O ETANO COMO AGENTES ESPUMANTES PERMITE LA REDUCCION O ELIMINACION DE CIERTOS AGENTES ESPUMANTES CLASIFICADOS COMO CONTAMINANTES ORGANICOS VOLATILES, QUE ACTUALMENTE SE EMPLEAN COMERCIALMENTE EN LA FABRICACION DE CUERPOS DE ESPUMA.
ES93922243T 1992-10-23 1993-09-17 Procedimiento de fabricacion de una espuma alquenilaromatica. Expired - Lifetime ES2131121T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US96591792A 1992-10-23 1992-10-23
US08/059,718 US5288740A (en) 1992-10-23 1993-05-11 Process for making alkenyl aromatic foam packing bodies with carbon dioxide and/or ethane blowing agent systems

Publications (1)

Publication Number Publication Date
ES2131121T3 true ES2131121T3 (es) 1999-07-16

Family

ID=26739099

Family Applications (1)

Application Number Title Priority Date Filing Date
ES93922243T Expired - Lifetime ES2131121T3 (es) 1992-10-23 1993-09-17 Procedimiento de fabricacion de una espuma alquenilaromatica.

Country Status (11)

Country Link
US (1) US5288740A (es)
EP (2) EP0665865B1 (es)
JP (1) JP3295759B2 (es)
KR (1) KR100284215B1 (es)
AT (1) ATE180002T1 (es)
CA (1) CA2145399A1 (es)
DE (1) DE69324927T2 (es)
ES (1) ES2131121T3 (es)
GR (1) GR3030691T3 (es)
HU (1) HU216543B (es)
WO (1) WO1994010232A1 (es)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5411683B1 (en) * 1993-08-20 2000-08-01 Sweetheart Cup Co Method for making thermoplastic foam with combined 1,1-difluoroethane and co2 blowing agent
DE4416863A1 (de) * 1994-05-13 1995-11-16 Basf Ag Expandierbare Styrolpolymerisate
DE4445140A1 (de) * 1994-12-17 1996-06-20 Basf Ag Mit Kohlendioxid getriebener Schaum aus Styrolpolymeren
US6245823B1 (en) 1995-10-20 2001-06-12 Free-Flow Packaging International, Inc. Composition and blowing agent for making foamed polyethylene material
US5670552A (en) * 1995-12-18 1997-09-23 W. R. Grace & Co.-Conn. Foam and process for producing foam using a carbon dioxide blowing agent
EP0921148A1 (en) 1997-12-08 1999-06-09 Dow Deutschland Inc. Low density strand foams
US6123881A (en) * 1998-09-16 2000-09-26 Owens Corning Fiberglas Technology, Inc. Process for producing extruded foam products having polystyrene blends with high levels of CO2 as a blowing agent
US6187831B1 (en) 1998-09-16 2001-02-13 Owens Corning Fiberglas Technology, Inc. Process for producing extruded foam products with higher levels of CO2 as a blowing agent
US6093352A (en) * 1998-09-16 2000-07-25 Owens Corning Fiberglas Technology, Inc. Process for producing foam by monitoring key process parameters
EP1124887B1 (en) 1998-10-21 2005-04-27 Owens Corning Process for producing extruded foam
US6428297B1 (en) 1998-10-28 2002-08-06 Dart Container Corporation Apparatus for making a corrugation-free foam
GB2388070B (en) * 1998-10-28 2003-12-10 Dart Container Thermoplastic corrugation-free foam
GB2385554B (en) * 1998-10-28 2003-10-15 Dart Container Process for making a corrugation-free foam
US6403663B1 (en) 1999-09-20 2002-06-11 North Carolina State University Method of making foamed materials using surfactants and carbon dioxide
CA2598387A1 (en) * 2005-03-18 2006-09-28 Dow Global Technology Inc. Extrusion die plate
US20110240904A1 (en) * 2008-05-28 2011-10-06 The Ohio State University Research Foundation Surfactant-free synthesis and foaming of liquid blowing agent-containing activated carbon-nano/microparticulate polymer composites
DE102015000393A1 (de) 2014-01-21 2015-07-23 Frank Becher Verfahren zur Herstellung von geschlossen-porigen Erzeugnissen mit hohlen Zellen, mittels dessen der Druck in den Zellen kontrolliert während des Aufschäumens erhöht oder reduziert werden kann, sowie Erzeugnisse, die nach diesem Verfahren hergestellt werden
RU2682609C2 (ru) 2015-01-30 2019-03-19 ВЕРСАЛИС С.п.А. Вспениваемые композиции из винилароматических полимеров

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DE1229722B (de) * 1957-11-29 1966-12-01 Dow Chemical Co Verfahren zum Herstellen verschaeumbarer Formmassen aus vinylaromatischen Polymerisaten
US3121132A (en) * 1961-12-18 1964-02-11 Koppers Co Inc Stress relieving expandable plastic particles
US3481455A (en) * 1968-10-10 1969-12-02 Free Flow Packaging Corp Free-flowing packing material of low bulk density
US3632705A (en) * 1970-06-04 1972-01-04 Free Flow Packaging Corp Method for manufacturing free flow packing materials of low bulk density
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US4455272A (en) * 1982-03-29 1984-06-19 Standard Oil Company (Indiana) Method of extruding a polystyrene foam using both a physical blowing agent and water
IT1163386B (it) * 1983-05-19 1987-04-08 Montedison Spa Procedimento per la produzione di granuli espandibili di polimeri termoplastici e relativa apparecchiatura
DE3435440A1 (de) * 1983-12-10 1985-06-20 Hoechst Ag, 6230 Frankfurt Aufschaeumbares kunststoffgranulat und daraus hergestelltes packmaterial
US4657715A (en) * 1984-12-31 1987-04-14 Mobil Oil Corporation Process for preparing smooth skinned extruded foams with water-organic blowing agent
DE3503057A1 (de) * 1985-01-30 1986-07-31 Hoechst Ag, 6230 Frankfurt Aufschaeumbares kunststoffgranulat und daraus hergestelltes packmaterial
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Also Published As

Publication number Publication date
DE69324927T2 (de) 1999-09-16
JP3295759B2 (ja) 2002-06-24
CA2145399A1 (en) 1994-05-11
HUT71504A (en) 1995-12-28
US5288740A (en) 1994-02-22
DE69324927D1 (de) 1999-06-17
HU9501134D0 (en) 1995-06-28
GR3030691T3 (en) 1999-11-30
JPH08502544A (ja) 1996-03-19
KR950704409A (ko) 1995-11-20
EP0665865A4 (en) 1996-05-29
ATE180002T1 (de) 1999-05-15
WO1994010232A1 (en) 1994-05-11
HU216543B (hu) 1999-07-28
EP0903369A1 (en) 1999-03-24
EP0665865B1 (en) 1999-05-12
EP0665865A1 (en) 1995-08-09
KR100284215B1 (ko) 2001-03-02

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