ES2130356T3 - Procedimiento para controlar la adsorcion de latex polimero sobre dioxido de titanio. - Google Patents
Procedimiento para controlar la adsorcion de latex polimero sobre dioxido de titanio.Info
- Publication number
- ES2130356T3 ES2130356T3 ES94303434T ES94303434T ES2130356T3 ES 2130356 T3 ES2130356 T3 ES 2130356T3 ES 94303434 T ES94303434 T ES 94303434T ES 94303434 T ES94303434 T ES 94303434T ES 2130356 T3 ES2130356 T3 ES 2130356T3
- Authority
- ES
- Spain
- Prior art keywords
- particles
- titanium dioxide
- adsorption
- procedure
- control
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/66—Additives characterised by particle size
- C09D7/67—Particle size smaller than 100 nm
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/08—Ingredients agglomerated by treatment with a binding agent
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/0081—Composite particulate pigments or fillers, i.e. containing at least two solid phases, except those consisting of coated particles of one compound
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/0081—Composite particulate pigments or fillers, i.e. containing at least two solid phases, except those consisting of coated particles of one compound
- C09C1/0084—Composite particulate pigments or fillers, i.e. containing at least two solid phases, except those consisting of coated particles of one compound containing titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/36—Compounds of titanium
- C09C1/3607—Titanium dioxide
- C09C1/3676—Treatment with macro-molecular organic compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D17/00—Pigment pastes, e.g. for mixing in paints
- C09D17/004—Pigment pastes, e.g. for mixing in paints containing an inorganic pigment
- C09D17/007—Metal oxide
- C09D17/008—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/024—Emulsion paints including aerosols characterised by the additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/66—Additives characterised by particle size
- C09D7/68—Particle size between 100-1000 nm
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/03—Particle morphology depicted by an image obtained by SEM
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/04—Particle morphology depicted by an image obtained by TEM, STEM, STM or AFM
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/30—Particle morphology extending in three dimensions
- C01P2004/32—Spheres
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/50—Agglomerated particles
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/51—Particles with a specific particle size distribution
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
- C01P2004/82—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases
- C01P2004/84—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases one phase coated with the other
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/19—Oil-absorption capacity, e.g. DBP values
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/22—Rheological behaviour as dispersion, e.g. viscosity, sedimentation stability
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/90—Other properties not specified above
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Nanotechnology (AREA)
- Composite Materials (AREA)
- Inorganic Chemistry (AREA)
- General Physics & Mathematics (AREA)
- Polymers & Plastics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Dispersion Chemistry (AREA)
- Paints Or Removers (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
COMPOSICIONES DE REVESTIMIENTO INCLUYENDO PARTICULAS COMPUESTAS DE PIGMENTOS LATEX SE PREPARAN MEDIANTE LA DISPERSION DE PARTICULAS DE PIGMENTO DE BIOXIDO DE TITANIO, EN UNA DISPERSION DE PARTICULAS DE LATEX POLIMERICO SELECCIONADO, QUE TIENEN AL MENOS UN GRUPO FUNCIONAL DE FOSFATO BIACIDO. LAS PARTICULAS DE LATEX POLIMERICO SELECCIONADO ABSORBEN A LAS PARTICULAS DE BIOXIDO DE TITANIO. A CONTINUACION SE PROPORCIONA FOSFATO DIBASICO A LA MEZCLA PARA DETENER LA ABSORCION Y ESTABILIZAR LAS PARTICULAS COMPUESTAS. LA COMPOSICION DE REVESTIMIENTO PROPORCIONA UN REVESTIMIENTO CON UNA OPACIDAD MEJORADA.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/065,883 US5385960A (en) | 1991-12-03 | 1993-05-20 | Process for controlling adsorption of polymeric latex on titanium dioxide |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2130356T3 true ES2130356T3 (es) | 1999-07-01 |
Family
ID=22065788
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES94303434T Expired - Lifetime ES2130356T3 (es) | 1993-05-20 | 1994-05-13 | Procedimiento para controlar la adsorcion de latex polimero sobre dioxido de titanio. |
Country Status (15)
Country | Link |
---|---|
US (1) | US5385960A (es) |
EP (1) | EP0625541B1 (es) |
JP (1) | JP3527537B2 (es) |
KR (1) | KR100306740B1 (es) |
CN (1) | CN1054871C (es) |
AT (1) | ATE178081T1 (es) |
AU (1) | AU664967B2 (es) |
BR (1) | BR9402006A (es) |
CA (1) | CA2123389A1 (es) |
DE (1) | DE69417284T2 (es) |
ES (1) | ES2130356T3 (es) |
FI (1) | FI942336A (es) |
IL (1) | IL109676A0 (es) |
NZ (1) | NZ260532A (es) |
TW (1) | TW272227B (es) |
Families Citing this family (112)
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GB9127293D0 (en) * | 1991-12-23 | 1992-02-19 | Ici Plc | Coating pigment particles with polymers |
GB9500497D0 (en) * | 1995-01-11 | 1995-03-01 | Tioxide Group Services Ltd | Gloss emulsion paints |
GB9502982D0 (en) * | 1995-02-16 | 1995-04-05 | Tioxide Group Services Ltd | Composite pigmentary material |
EP0902731B1 (de) * | 1995-12-21 | 2002-04-03 | BASF Coatings Aktiengesellschaft | Verfahren zur herstellung von mehrschichtigen überzügen |
JP3294774B2 (ja) * | 1996-11-26 | 2002-06-24 | 関西ペイント株式会社 | 塗料組成物及びこれを用いた塗装金属板 |
US6127455A (en) * | 1997-04-14 | 2000-10-03 | Omnova Solutions Inc. | Process for forming a seed polymer |
US6214467B1 (en) | 1998-07-24 | 2001-04-10 | Rohm And Haas Company | Polymer-pigment composites |
DE19839856A1 (de) * | 1998-09-02 | 2000-04-20 | Metallgesellschaft Ag | Präparationsmittel |
WO2000049097A1 (en) * | 1999-02-19 | 2000-08-24 | Markem Corporation | Stable titanium dioxide containing ink jet ink composition |
JP2000309610A (ja) * | 1999-02-25 | 2000-11-07 | Mitsubishi Rayon Co Ltd | 共重合体、制振用部品及び共重合体用組成物 |
US6869996B1 (en) | 1999-06-08 | 2005-03-22 | The Sherwin-Williams Company | Waterborne coating having improved chemical resistance |
US20020165309A1 (en) * | 2000-05-25 | 2002-11-07 | Winterowd Jack G. | Labeling paint and method for the manufacture thereof |
US7026389B2 (en) | 2000-05-25 | 2006-04-11 | Weyerhaeuser Company | Labeling paint for use with metallic stencils on oriented strandboard finishing line |
JP4989839B2 (ja) * | 2000-08-07 | 2012-08-01 | エス ウント ツェー ポリマー ジリコーン ウント コンポジット シュペーツィアリテーテン ゲーエムベーハー | 接着性フッ化物バーニッシュ |
US6756459B2 (en) | 2000-09-28 | 2004-06-29 | Rohm And Haas Company | Binder compositions for direct-to-metal coatings |
AU782594B2 (en) * | 2000-11-21 | 2005-08-11 | Rohm And Haas Company | Polymer-pigment composites |
MXPA03004919A (es) * | 2000-12-01 | 2003-09-05 | Sherwin Williams Co | Composiciones de recubrimiento transportadas por agua.. |
US6638998B2 (en) | 2001-04-18 | 2003-10-28 | Basf Ag | Use of surfactants for improving the compatibility of inorganic pigments in aqueous coating compositions |
US8822569B2 (en) * | 2001-06-20 | 2014-09-02 | Rohm And Haas Company | Composite particles |
AU785282B2 (en) * | 2001-06-20 | 2006-12-21 | Rohm And Haas Company | Coating with improved hiding, compositions prepared therewith, and processes for the preparation thereof |
AU785239B2 (en) * | 2001-06-20 | 2006-11-23 | Rohm And Haas Company | Aqueous composite particle composition |
US7285162B2 (en) * | 2001-07-30 | 2007-10-23 | Millennium Inorganic Chemicals, Inc. | Titanium dioxide pigment having improved light stability |
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US7026368B2 (en) * | 2002-07-31 | 2006-04-11 | Dainippon Ink And Chemicals, Inc. | Ultraviolet-curable ink composition for ink jet recording |
US7056449B2 (en) * | 2002-08-14 | 2006-06-06 | Rohm And Haas Company | Aqueous silica dispersion |
US7179531B2 (en) * | 2002-09-12 | 2007-02-20 | Rohm And Haas Company | Polymer particles having select pendant groups and composition prepared therefrom |
DE10256265A1 (de) * | 2002-12-03 | 2004-06-24 | Basf Coatings Ag | Beschichtungsstoff, Verfahren zu seiner Herstellung und seine Verwendung zur Herstellung haftfester, korrosionshemmender Beschichtungen |
DE60319202T2 (de) * | 2002-12-19 | 2009-02-12 | Rohm & Haas Company | Pigmentationspolymerzusammensetzung |
EP1445288B1 (en) * | 2003-01-24 | 2017-03-08 | Rohm And Haas Company | Organic-inorganic composite particle and process for preparation thereof |
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US8309615B2 (en) * | 2003-08-04 | 2012-11-13 | Rohm And Haas Company | Aqueous silica dispersion |
US20050137291A1 (en) * | 2003-12-17 | 2005-06-23 | Schneider John R. | Coating compositions with enhanced corrosion resistance and appearance |
US7482054B2 (en) * | 2004-08-09 | 2009-01-27 | Behr Process Corporation | Pigment spacing |
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US7947763B2 (en) * | 2004-08-09 | 2011-05-24 | Behr Process Corporation | Exterior deep base paint formulation |
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-
1993
- 1993-05-20 US US08/065,883 patent/US5385960A/en not_active Expired - Lifetime
-
1994
- 1994-05-11 CA CA002123389A patent/CA2123389A1/en not_active Abandoned
- 1994-05-11 CN CN94105714A patent/CN1054871C/zh not_active Expired - Lifetime
- 1994-05-13 ES ES94303434T patent/ES2130356T3/es not_active Expired - Lifetime
- 1994-05-13 EP EP94303434A patent/EP0625541B1/en not_active Expired - Lifetime
- 1994-05-13 DE DE69417284T patent/DE69417284T2/de not_active Expired - Lifetime
- 1994-05-13 AT AT94303434T patent/ATE178081T1/de active
- 1994-05-16 NZ NZ260532A patent/NZ260532A/en unknown
- 1994-05-17 AU AU63128/94A patent/AU664967B2/en not_active Expired
- 1994-05-18 IL IL10967694A patent/IL109676A0/xx unknown
- 1994-05-18 BR BR9402006A patent/BR9402006A/pt not_active IP Right Cessation
- 1994-05-19 FI FI942336A patent/FI942336A/fi not_active Application Discontinuation
- 1994-05-20 KR KR1019940011092A patent/KR100306740B1/ko not_active IP Right Cessation
- 1994-05-20 JP JP13096794A patent/JP3527537B2/ja not_active Expired - Fee Related
- 1994-05-25 TW TW083104726A patent/TW272227B/zh active
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IL109676A0 (en) | 1994-08-26 |
AU6312894A (en) | 1994-11-24 |
TW272227B (es) | 1996-03-11 |
JPH0770505A (ja) | 1995-03-14 |
EP0625541B1 (en) | 1999-03-24 |
EP0625541A2 (en) | 1994-11-23 |
BR9402006A (pt) | 1994-12-13 |
KR100306740B1 (ko) | 2001-12-28 |
EP0625541A3 (en) | 1996-08-28 |
NZ260532A (en) | 1995-11-27 |
JP3527537B2 (ja) | 2004-05-17 |
FI942336A0 (fi) | 1994-05-19 |
ATE178081T1 (de) | 1999-04-15 |
CN1102427A (zh) | 1995-05-10 |
US5385960A (en) | 1995-01-31 |
FI942336A (fi) | 1994-11-21 |
CA2123389A1 (en) | 1994-11-21 |
DE69417284D1 (de) | 1999-04-29 |
CN1054871C (zh) | 2000-07-26 |
AU664967B2 (en) | 1995-12-07 |
DE69417284T2 (de) | 1999-12-09 |
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