ES2126041T3 - Poliisocianato basado en diisocianatos de 4,4'- y 2,4'-difenil-metano y su uso en un procedimiento de rim. - Google Patents
Poliisocianato basado en diisocianatos de 4,4'- y 2,4'-difenil-metano y su uso en un procedimiento de rim.Info
- Publication number
- ES2126041T3 ES2126041T3 ES94116393T ES94116393T ES2126041T3 ES 2126041 T3 ES2126041 T3 ES 2126041T3 ES 94116393 T ES94116393 T ES 94116393T ES 94116393 T ES94116393 T ES 94116393T ES 2126041 T3 ES2126041 T3 ES 2126041T3
- Authority
- ES
- Spain
- Prior art keywords
- isocyanate
- diphenyl
- functionality
- polyisocyanate based
- dizyzyanine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
- C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/02—Polymeric products of isocyanates or isothiocyanates of isocyanates or isothiocyanates only
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
- C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4804—Two or more polyethers of different physical or chemical nature
- C08G18/4812—Mixtures of polyetherdiols with polyetherpolyols having at least three hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2120/00—Compositions for reaction injection moulding processes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
UN NUEVO POLIISOCIANATO QUE ES LIQUIDO Y ESTABLE A TEMPERATURA AMBIENTE Y TIENE UN CONTENIDO DE GRUPO ISOCIANATO DEL 10 AL 30% DEL PESO, ES PREPARADO AL REACCIONAR: A) UNA MEZCLA DE ISOCIANATO DE DIISOCIANATO DE DIFENILMETANO-4,4 Y DIISOCIANATO DE DIFENILMETANO2,4 , Y UNA CANTIDAD DE UN ISOCIANATO QUE TIENE UN FUNCIONALIDAD DE ISOCIANATO DE MAS DE 2, SELECCIONADO DE HOMOLOGOS DE DIISOCIANATO DE DIFENILMETANO QUE TIENEN UNA FUNCIONALIDAD DE AL MENOS 3 Y DIISOCIANATO DE DIFENILMETANO MODIFICADO, TAL QUE LA MEZCLA DE ISOCIANATO TOTAL A) TIENE UNA FUNCIONALIDAD DE ISOCIANATO MEDIA DE 2.02 A 2.50, Y B) UNA MEZCLA DE POLIOL QUE COMPRENDE 1) UNO O MAS DIOLES QUE TIENE PESOS MOLECULARES DE 1000 A 5000 Y 2) UNO O MAS TRIOLES QUE TIENE PESOS MOLECULARES DE 1000 A 6000, EN DONDE EL COEFICIENTE DE PESO DE DIOLES A TRIOLES ES DE 10:1 A 1:10. CUANDO SE USA EN UN PROCESO RIM, LAS PARTES SON PRODUCIDAS CON EXCELENTES PROPIEDADES DE IMPACTO DE TEMPERATURA BAJA.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US14445893A | 1993-10-28 | 1993-10-28 |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2126041T3 true ES2126041T3 (es) | 1999-03-16 |
Family
ID=22508684
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES94116393T Expired - Lifetime ES2126041T3 (es) | 1993-10-28 | 1994-10-18 | Poliisocianato basado en diisocianatos de 4,4'- y 2,4'-difenil-metano y su uso en un procedimiento de rim. |
Country Status (8)
Country | Link |
---|---|
US (1) | US5585452A (es) |
EP (1) | EP0650989B1 (es) |
JP (1) | JPH07179550A (es) |
KR (1) | KR100330822B1 (es) |
BR (1) | BR9404275A (es) |
CA (1) | CA2117740A1 (es) |
DE (1) | DE69415921T2 (es) |
ES (1) | ES2126041T3 (es) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19648509A1 (de) * | 1996-11-22 | 1998-05-28 | Bayer Ag | Verwendung von Polyether-PUR für Sicherheitskleidung |
US6248856B1 (en) | 1999-12-10 | 2001-06-19 | Bayer Corporation | One-shot polyurethane elastomers with very low compression sets |
US6277943B1 (en) | 1999-12-10 | 2001-08-21 | Bayer Corporation | One-shot polyurethane elastomers with very low compression set |
US6586487B1 (en) * | 2000-07-12 | 2003-07-01 | Bayer Corporation | Low-density, water blown polyurethane foams for energy-absorbing applications |
US6376567B1 (en) | 2000-12-07 | 2002-04-23 | Bayer Corporation | Polyisocyanate compositions and a process for the production of low-density flexible foams with low humid aged compression sets from these polyisocyanate compositions |
DE50305488D1 (de) * | 2002-02-08 | 2006-12-07 | Henkel Kgaa | Farbneutraler 1K Polyurethan-Klebstoff |
US6797799B1 (en) * | 2003-04-02 | 2004-09-28 | Bayer Materialscience Llc | High 2,4′-diphenylmethane diisocyanate content prepolymers |
US7648933B2 (en) | 2006-01-13 | 2010-01-19 | Dynamic Abrasives Llc | Composition comprising spinel crystals, glass, and calcium iron silicate |
US7790907B2 (en) * | 2006-07-21 | 2010-09-07 | Basf Corporation | Method of producing a uretonimine-modified isocyanate composition |
US20080085987A1 (en) * | 2006-10-05 | 2008-04-10 | Thomas Savino | Method of producing a uretonimine-modified isocyanate composition |
WO2012169791A2 (ko) | 2011-06-07 | 2012-12-13 | 주식회사 엘지화학 | 락타이드 공중합체, 이의 제조 방법 및 이를 포함하는 수지 조성물 |
JP6746490B2 (ja) | 2013-04-19 | 2020-08-26 | コベストロ・エルエルシー | 成形された電子プリント回路基板における封入および組立体 |
CN113170586A (zh) | 2018-10-09 | 2021-07-23 | 科思创有限公司 | 使用导热聚碳酸酯的插入模制电子模块以及模制互锁特征件 |
Family Cites Families (49)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3152162A (en) * | 1959-07-29 | 1964-10-06 | Bayer Ag | Polyisocyanate-carbodiimide adducts and process for the production thereof |
US3384653A (en) * | 1965-03-31 | 1968-05-21 | Upjohn Co | Compositions of methylenebis (phenyl isocyanate) with trihydrocarbyl phosphates and preparation thereof |
US3394165A (en) * | 1965-10-24 | 1968-07-23 | Upjohn Co | Stabilized methylenebis-(phenyl isocyanate) compositions |
US3449256A (en) * | 1966-01-19 | 1969-06-10 | Upjohn Co | Methylenebis(phenyl isocyanate) compositions and preparation thereof |
DE1618380C3 (de) * | 1967-03-08 | 1975-09-11 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung eines bei Raumtemperatur flüssigen Diphenylmethan-diisocyanatpräparates |
GB1194050A (en) * | 1967-12-12 | 1970-06-10 | Ici Ltd | Liquid Diphenylmethane Diisocyanate Compositions |
GB1200432A (en) * | 1968-01-25 | 1970-07-29 | Bayer Ag | Process for the preparation of polyisocyanates which contain a carbodiimideisocyanate adduct |
GB1193401A (en) * | 1968-05-14 | 1970-06-03 | Ici Ltd | Liquid diphenylmethane diisocyanate compositions |
US3701796A (en) * | 1970-09-29 | 1972-10-31 | Upjohn Co | Storage stable methylenebis (phenyl isocyanate) compositions |
NL178871C (nl) * | 1972-09-26 | Ici Ltd | Werkwijze voor het bereiden van een vloeibaar difenylmethaandiisocyanaatproduct en voor het bereiden of vervaardigen van een polyurethaan onder toepassing van een dergelijk isocyanaatproduct. | |
GB1476088A (en) * | 1975-04-03 | 1977-06-10 | Ici Ltd | Carbodiimides |
GB1483957A (en) * | 1975-05-19 | 1977-08-24 | Ici Ltd | Diphenylmethane diisocyanate compositions |
DE2537685C2 (de) * | 1975-08-23 | 1989-04-06 | Bayer Ag, 5090 Leverkusen | Verfahren zur teilweisen Carbodiimidisierung der Isocyanatgruppen von organischen Polyisocyanaten |
US4048105A (en) * | 1975-12-19 | 1977-09-13 | Mccord Corporation | High density urethane foam for rim |
US4218543A (en) * | 1976-05-21 | 1980-08-19 | Bayer Aktiengesellschaft | Rim process for the production of elastic moldings |
US4055548A (en) * | 1976-09-17 | 1977-10-25 | The Upjohn Company | Storage-stable liquid polyisocyanate composition |
US4118411A (en) * | 1977-02-09 | 1978-10-03 | Mobay Chemical Corporation | Low-temperature storage stable liquid diphenylmethane diisocyanates |
US4115429A (en) * | 1977-03-18 | 1978-09-19 | Mobay Chemical Corporation | Low-temperature storage stable liquid diphenylmethane diisocyanates |
GB1596469A (en) * | 1978-04-11 | 1981-08-26 | Ici Ltd | Liquid isocyanate compositions based on diphenylmethane diisocyanate |
US4154752A (en) * | 1978-05-05 | 1979-05-15 | Mobay Chemical Corporation | Preparation of partially carbodiimidized methylenebis (phenyl isocyanate) |
EP0010850B2 (en) * | 1978-10-03 | 1990-01-31 | Imperial Chemical Industries Plc | Liquid polyisocyanate compositions |
US4177205A (en) * | 1978-11-20 | 1979-12-04 | Basf Wyandotte Corporation | Process for the preparation of highly stable liquid carbodiimide-containing polyisocyanate compositions |
US4321333A (en) * | 1981-04-16 | 1982-03-23 | The Upjohn Company | Polyurethane prepared from polyisocyanate blend |
US4332742A (en) * | 1981-06-22 | 1982-06-01 | Mobay Chemical Corporation | Low temperature storage stable liquid diphenylmethane diisocyanates |
US4374210A (en) * | 1981-09-18 | 1983-02-15 | The Upjohn Company | Polyurea-polyurethane from a mixture of a polyol, an aromatic diamine, and an isocyanate-terminated prepolymer |
DE3147736A1 (de) * | 1981-12-02 | 1983-06-09 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung von elastischen formkoerpern |
US4433067A (en) * | 1982-04-23 | 1984-02-21 | Texaco Inc. | Reaction injection molded elastomers prepared from amine terminated polyethers, amine terminated chain extender and aromatic polyisocyanate |
US4444910A (en) * | 1982-04-23 | 1984-04-24 | Texaco Inc. | Reaction injection molded elastomers made using a polyurethane organometallic catalyst amine terminated polyethers amine terminated chain extender and aromatic polyisocyanate |
DE3241450A1 (de) * | 1982-11-10 | 1984-05-10 | Basf Ag, 6700 Ludwigshafen | Fluessige urethangruppen enthaltende polyisocyanatmischungen auf diphenylmethan-diisocyanat-basis, verfahren zu deren herstellung und deren verwendung zur herstellung von polyurethan-weichschaumstoffen |
US4530941A (en) * | 1983-01-26 | 1985-07-23 | The Dow Chemical Company | Reaction injection molded polyurethanes employing high molecular weight polyols |
US4442235A (en) * | 1983-05-09 | 1984-04-10 | Mobay Chemical Corporation | Process and composition for the production of polyurethane elastomer moldings |
US4448904A (en) * | 1983-06-08 | 1984-05-15 | Texaco Inc. | Reaction injection molded elastomer using a methylene bis(phenyliscoyanate) containing 2,4' isomer in amounts greater than about 10 percent |
US4490301A (en) * | 1983-09-30 | 1984-12-25 | Mobay Chemical Corporation | Liquid diphenylmethane diisocyanate compositions |
US4490300A (en) * | 1983-09-30 | 1984-12-25 | Mobay Chemical Corporation | Liquid diphenylmethane diisocyanate compositions |
US4490302A (en) * | 1983-11-25 | 1984-12-25 | Mobay Chemical Corporation | Liquid diphenylmethane diisocyanate compositions |
US4585850A (en) * | 1984-08-30 | 1986-04-29 | Texaco Inc. | Flakeglass with sizing, amino, chloro, isocyanate agents coated directly onto the glass in RRIM elastomers |
US4546114A (en) * | 1984-10-25 | 1985-10-08 | The Upjohn Company | Process for the preparation of polyurea elastomers |
US4539156A (en) * | 1984-12-14 | 1985-09-03 | Mobay Chemical Corporation | Liquid diphenylmethane diisocyanate compositions |
US4539158A (en) * | 1984-12-14 | 1985-09-03 | Mobay Chemical Corporation | Liquid diphenylmethane diisocyanate compositions |
US4539157A (en) * | 1984-12-14 | 1985-09-03 | Mobay Chemical Corporation | Liquid diphenylmethane diisocyanate compositions |
US4910333A (en) * | 1987-06-03 | 1990-03-20 | Mobay Corporation | Liquid diphenylmethane diisocyanate compositions |
GB8725217D0 (en) * | 1987-10-28 | 1987-12-02 | Ici Plc | Polyisocyanate prepolymer |
US4883909A (en) * | 1988-05-11 | 1989-11-28 | Mobay Corporation | Liquid diphenylmetane diisocyanate compositions |
DE3818769A1 (de) * | 1988-06-02 | 1989-12-07 | Bayer Ag | Fluessige polyisocyanatmischungen, ein verfahren zu ihrer herstellung und ihre verwendung zur herstellung von polyurethan-weichschaumstoffen |
GB8908490D0 (en) * | 1989-04-14 | 1989-06-01 | Ici Plc | Prepolymers |
US5246977A (en) * | 1990-05-04 | 1993-09-21 | The Dow Chemical Company | Microcellular polyurethane polymers prepared from isocyanate-terminated poly(oxytetramethylene) glycol prepolymers |
DE4026474A1 (de) * | 1990-08-22 | 1992-02-27 | Bayer Ag | Neue isocyanuratgruppen aufweisende polyisocyanatmischungen, ein verfahren zu ihrer herstellung und ihre verwendung zur herstellung von polyurethanschaumstoffen |
DE4115037A1 (de) * | 1991-05-08 | 1992-11-12 | Bayer Ag | Verfahren zur herstellung von urethangruppen aufweisenden polyharnstoff-elastomeren |
US5240635A (en) * | 1992-02-06 | 1993-08-31 | The Dow Chemical Company | Composition of flexible polyurethane foams blown using reduced amounts of chlorofluorocarbon blowing agents and method for preparation |
-
1994
- 1994-10-07 CA CA002117740A patent/CA2117740A1/en not_active Abandoned
- 1994-10-18 ES ES94116393T patent/ES2126041T3/es not_active Expired - Lifetime
- 1994-10-18 DE DE69415921T patent/DE69415921T2/de not_active Expired - Fee Related
- 1994-10-18 EP EP94116393A patent/EP0650989B1/en not_active Expired - Lifetime
- 1994-10-27 KR KR1019940027606A patent/KR100330822B1/ko not_active IP Right Cessation
- 1994-10-27 JP JP6263553A patent/JPH07179550A/ja active Pending
- 1994-10-27 BR BR9404275A patent/BR9404275A/pt not_active IP Right Cessation
-
1995
- 1995-06-06 US US08/469,963 patent/US5585452A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
DE69415921T2 (de) | 1999-05-27 |
DE69415921D1 (de) | 1999-02-25 |
KR950011492A (ko) | 1995-05-15 |
JPH07179550A (ja) | 1995-07-18 |
US5585452A (en) | 1996-12-17 |
KR100330822B1 (ko) | 2002-10-12 |
BR9404275A (pt) | 1995-07-04 |
EP0650989A1 (en) | 1995-05-03 |
EP0650989B1 (en) | 1999-01-13 |
CA2117740A1 (en) | 1995-04-29 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
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