ES2118008T3 - Composiciones polimerizables a base de monomeros tio(met)acrilatos, composiciones polimeras transparentes obtenidas, y sus aplicaciones en optica. - Google Patents

Composiciones polimerizables a base de monomeros tio(met)acrilatos, composiciones polimeras transparentes obtenidas, y sus aplicaciones en optica.

Info

Publication number
ES2118008T3
ES2118008T3 ES96401065T ES96401065T ES2118008T3 ES 2118008 T3 ES2118008 T3 ES 2118008T3 ES 96401065 T ES96401065 T ES 96401065T ES 96401065 T ES96401065 T ES 96401065T ES 2118008 T3 ES2118008 T3 ES 2118008T3
Authority
ES
Spain
Prior art keywords
sub
met
weight
tio
optics
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES96401065T
Other languages
English (en)
Inventor
Peiqi Jiang
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EssilorLuxottica SA
Original Assignee
Essilor International Compagnie Generale dOptique SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Essilor International Compagnie Generale dOptique SA filed Critical Essilor International Compagnie Generale dOptique SA
Application granted granted Critical
Publication of ES2118008T3 publication Critical patent/ES2118008T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
    • C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
    • C08F290/06—Polymers provided for in subclass C08G
    • C08F290/062—Polyethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F228/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a bond to sulfur or by a heterocyclic ring containing sulfur
    • C08F228/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a bond to sulfur or by a heterocyclic ring containing sulfur by a bond to sulfur
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
    • C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
    • C08F290/06—Polymers provided for in subclass C08G
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
    • G02B1/041—Lenses

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Macromonomer-Based Addition Polymer (AREA)

Abstract

LA COMPOSICION COMPRENDE: A) 10 A 70% EN PESO DE UN MONOMERO TIO{(}MET{ACRILATO BIFUNCIONAL, DE FORMULA (I) EN LA QUE R{SUB,1} Y R{SUB,2} REPRESENTAN UN ATOMO DE HIDROGENO O UN RADICAL -CH{SUB,3}, O DE UNA MEZCLA DE AL MENOS UN MONOMERO DE FORMULA (I) CON AL MENOS UN MONOMERO DE FORMULA (II): EN LA QUE R''{SUB,1} Y R''{SUB,2} REPRESENTAN UN ATOMO DE HIDROGENO O UN RADICAL -CH{SUB,3}; B) 10 A 60% EN PESO DE AL MENOS UN MONOMERO DE FORMULA (III): EN LA QUE R{SUB,3} Y R{SUB,4} REPRESENTAN UN ATOMO DE HIDROGENO O UN RADICAL -CH{SUB,3} Y O INFERIOR O IGUAL A M+N INFERIOR O IGUAL A 10; C) 5 A 30% EN PESO DE AL MENOS UN MONOMERO MONO{(}MET{ACRILATO AROMATICO O POLICICLANICO; D) 0 A 15% EN PESO DE UN POLIALQUILENO GLICOLDI{(}MET{ACRILATO; Y E) 0 A 10% EN PESO DE UN POLITIOLR{(}SH{{SUB,N}, N ES UN NUMERO ENTERO QUE PUEDE TOMAR LOS VALORES DE 2 A 6, R ES UN GRUPO ORGANICO DE VALENCIA N, O DE UNA MEZCLA DE ESTOS POLITIOLES; RESPECTO DEL PESO TOTAL DE A) + B) + C) + D) + E). APLICACION EN LA FABRICACION DE LENTILLAS OFTALMICAS.
ES96401065T 1995-05-31 1996-05-15 Composiciones polimerizables a base de monomeros tio(met)acrilatos, composiciones polimeras transparentes obtenidas, y sus aplicaciones en optica. Expired - Lifetime ES2118008T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9506443A FR2734828B1 (fr) 1995-05-31 1995-05-31 Compositions polymerisables a base de monomeres thio(meth)acrylates, compositions polymeres transparentes obtenues, et leurs applications en optique

Publications (1)

Publication Number Publication Date
ES2118008T3 true ES2118008T3 (es) 1998-09-01

Family

ID=9479534

Family Applications (1)

Application Number Title Priority Date Filing Date
ES96401065T Expired - Lifetime ES2118008T3 (es) 1995-05-31 1996-05-15 Composiciones polimerizables a base de monomeros tio(met)acrilatos, composiciones polimeras transparentes obtenidas, y sus aplicaciones en optica.

Country Status (7)

Country Link
US (1) US6184323B1 (es)
EP (1) EP0745621B1 (es)
JP (1) JP3682118B2 (es)
AU (1) AU705542B2 (es)
DE (1) DE69600238T2 (es)
ES (1) ES2118008T3 (es)
FR (1) FR2734828B1 (es)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6437918B1 (en) 1996-07-22 2002-08-20 Nippon Sheet Glass Co., Ltd. Method of manufacturing flat plate microlens and flat plate microlens
FR2799470B1 (fr) * 1999-10-06 2002-01-11 Essilor Int Compositions polymerisables pour la fabrication de substrats polymeres transparents, substrats polymeres transparents obtenus et leurs applications dans l'optique
ATE384275T1 (de) * 2000-09-07 2008-02-15 Seed Co Ltd Aus synthetischem harz hergestellte linse und verfahren zur herstellung derselben
US6541591B2 (en) * 2000-12-21 2003-04-01 3M Innovative Properties Company High refractive index microreplication resin from naphthyloxyalkylmethacrylates or naphthyloxyacrylates polymers
FR2828743B1 (fr) 2001-08-14 2004-02-27 Essilor Int Procede de moulage d'une lentille presentant un insert
FR2832717B1 (fr) 2001-11-26 2004-07-09 Essilor Int Composition polymerisable par voie radicalaire conduisant a des verres organiques resistants au choc
US6872333B2 (en) * 2002-02-07 2005-03-29 Mitsubishi Gas Chemical Company, Ltd. Enic compounds, sulfur-containing polyenic compound, sulfur-containing polythiol compound, high refractive index photocurable composition and cured product thereof
EP1629308B1 (en) * 2003-04-17 2008-10-08 Essilor International Compagnie Generale D'optique Photocurable adhesive composition and its use in the optical field
DE10342521A1 (de) * 2003-09-12 2005-04-14 Röhm GmbH & Co. KG Mischungen zur Herstellung transparenter Kunststoffe, transparente Kunststoffe sowie Verfahren zu deren Herstellung und Verwendung
JP2010186979A (ja) 2008-12-03 2010-08-26 Fujifilm Corp インプリント用硬化性組成物、パターン形成方法およびパターン
US8470948B2 (en) 2009-08-28 2013-06-25 Florida State University Research Foundation, Inc. High refractive index polymers
KR101246684B1 (ko) * 2009-12-23 2013-03-21 제일모직주식회사 광학필름용 수지 조성물, 이를 이용한 광학필름 및 그 제조 방법
WO2015074080A1 (en) 2013-11-18 2015-05-21 Florida State Research Foundation, Inc. Thiol-ene polymer metal oxide nanoparticle high refractive index composites
EP3898734A1 (en) * 2018-12-18 2021-10-27 PPG Industries Ohio Inc. High refractive index compositions and uses thereof
KR102060272B1 (ko) * 2019-03-29 2019-12-27 주식회사 네모엘텍 양자점을 포함하는 도료 조성물 또는 이의 제조방법

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0273661B1 (en) * 1986-12-26 1990-07-25 Nippon Shokubai Kagaku Kogyo Co., Ltd Thiolcarboxylic acid esters
DE3784152T3 (de) * 1986-12-26 1997-03-20 Nippon Catalytic Chem Ind Harz mit hohem Brechungsindex, Verfahren zu seiner Herstellung und optische Materialien aus diesem Harz.
EP0394495B1 (en) 1988-10-20 1994-08-31 Sumitomo Seika Chemicals Co., Ltd. 4,4'-bis(methacryloylthio)diphenyl sulfide and curable composition containing same
DE4010783C2 (de) * 1990-04-04 1994-11-03 Bayer Ag Duromere transparente Terpolymerisate und ihre Verwendung zur Herstellung von optischen Formteilen
US5545828A (en) * 1992-12-22 1996-08-13 Essilor International Compagnie Generale D'optique Low yellow index polymer compositions, polymerizable compositions and lenses using said compositions
FR2699541B1 (fr) * 1992-12-22 1995-04-28 Essilor Int Compositions polymères à faible indice de jaune, compositions polymérisables et lentilles les mettant en Óoeuvre.
FR2734827B1 (fr) * 1995-05-31 1997-07-11 Essilor Int Compositions polymerisables a base de monomeres thio (meth)acrylates, polymeres a faible indice de jaune obtenus a partir de telles compositions et lentilles ophtalmiques correspondantes

Also Published As

Publication number Publication date
EP0745621B1 (fr) 1998-04-15
DE69600238T2 (de) 1998-12-03
EP0745621A1 (fr) 1996-12-04
AU705542B2 (en) 1999-05-27
DE69600238D1 (de) 1998-05-20
FR2734828A1 (fr) 1996-12-06
JPH0925321A (ja) 1997-01-28
US6184323B1 (en) 2001-02-06
JP3682118B2 (ja) 2005-08-10
FR2734828B1 (fr) 1997-07-11
AU5456396A (en) 1996-12-12

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