ES2113657T3 - Material en lamina para calcomanias retrorreflectoras. - Google Patents

Material en lamina para calcomanias retrorreflectoras.

Info

Publication number
ES2113657T3
ES2113657T3 ES94916514T ES94916514T ES2113657T3 ES 2113657 T3 ES2113657 T3 ES 2113657T3 ES 94916514 T ES94916514 T ES 94916514T ES 94916514 T ES94916514 T ES 94916514T ES 2113657 T3 ES2113657 T3 ES 2113657T3
Authority
ES
Spain
Prior art keywords
layer
reflective
sheet material
microspheres
color
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES94916514T
Other languages
English (en)
Inventor
Ulf N Olsen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Co
Original Assignee
Minnesota Mining and Manufacturing Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US08/058,155 external-priority patent/US5344705A/en
Application filed by Minnesota Mining and Manufacturing Co filed Critical Minnesota Mining and Manufacturing Co
Application granted granted Critical
Publication of ES2113657T3 publication Critical patent/ES2113657T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06Q—DECORATING TEXTILES
    • D06Q1/00—Decorating textiles
    • D06Q1/10—Decorating textiles by treatment with, or fixation of, a particulate material, e.g. mica, glass beads
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/16—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
    • B44C1/165—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
    • B44C1/17—Dry transfer
    • B44C1/1712—Decalcomanias applied under heat and pressure, e.g. provided with a heat activable adhesive
    • B44C1/1716—Decalcomanias provided with a particular decorative layer, e.g. specially adapted to allow the formation of a metallic or dyestuff layer on a substrate unsuitable for direct deposition
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44F—SPECIAL DESIGNS OR PICTURES
    • B44F1/00—Designs or pictures characterised by special or unusual light effects
    • B44F1/02—Designs or pictures characterised by special or unusual light effects produced by reflected light, e.g. matt surfaces, lustrous surfaces
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06Q—DECORATING TEXTILES
    • D06Q1/00—Decorating textiles
    • D06Q1/12—Decorating textiles by transferring a chemical agent or a metallic or non-metallic material in particulate or other form, from a solid temporary carrier to the textile
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/12—Reflex reflectors
    • G02B5/126—Reflex reflectors including curved refracting surface
    • G02B5/128—Reflex reflectors including curved refracting surface transparent spheres being embedded in matrix
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00—Stock material or miscellaneous articles
    • Y10S428/913—Material designed to be responsive to temperature, light, moisture
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00—Stock material or miscellaneous articles
    • Y10S428/914—Transfer or decalcomania
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24851—Intermediate layer is discontinuous or differential
    • Y10T428/24868—Translucent outer layer
    • Y10T428/24876—Intermediate layer contains particulate material [e.g., pigment, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24893—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including particulate material
    • Y10T428/24901—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including particulate material including coloring matter
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24893—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including particulate material
    • Y10T428/24909—Free metal or mineral containing
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
    • Y10T428/2991—Coated
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y10T428/31565—Next to polyester [polyethylene terephthalate, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y10T428/31609—Particulate metal or metal compound-containing
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31725—Of polyamide
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31786—Of polyester [e.g., alkyd, etc.]

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Decoration By Transfer Pictures (AREA)
  • Optical Elements Other Than Lenses (AREA)
  • Laminated Bodies (AREA)
  • Coloring (AREA)

Abstract

UN MATERIAL DE LAMINA DE TRANSFERENCIA PARA FORMAR IMAGENES GRAFICAS RETROREFLECTIVAS EN UN SUSTRATO. EL MATERIAL DE LAMINA CONSTA DE UNA MONOCAPA DE MICROESFERAS TRASPARENTES (12); UNA CAPA DE COLOR (22) IMPRESA SOBRE LAS MICROESFERAS EN UN PRIMER SEGMENTO GRAFICO DEL MATERIAL DE LAMINA EN UN DISEÑO EN FORMA DE IMAGEN, INCLUYENDO LA CAPA DE COLOR UN COLORANTE Y UNA RESINA TRANSPARENTE. UNA CAPA REFLECTIVA IMPRESA SOBRE LAS MICROESFERAS EN UN SEGUNDO SEGMENTO GRAFICO DEL MATERIAL DE LAMINA EN UN DISEÑO EN FORMA DE IMAGEN, CONSTANDO LA CAPA REFLECTIVA DE COPOS REFLECTIVOS EN UN AGLOMERANTE TRANSPARENTE, DONDE LAS MICROESFERAS SE ENCUENTRAN PARCIALMENTE HUNDIDAS EN AL MENOS UNA DE LOS DOS CAPAS DE COLOR Y REFLECTIVA, TENIENDO LAS MICROESFERAS INDIVIDUALES COPOS REFLECTIVOS COLOCADOS EN UNA FORMA A MODO DE TAZA ALREDEDOR DE LAS PARTES HUNDIDAS; Y UNA CAPA DE UNION (28) IMPRESA SOBRE LA CAPA DE COLOR Y LA REFLECTIVA, SIENDO ESTA SUFICIENTEMENTE GRUESA PARA ENTERRAR TODAS LAS CAPAS EXPUESTAS DELAS CAPAS REFLECTIVA Y DE COLOR Y ESTANDO ADAPTADA PARA SER ASEGURAR EL MATERIAL DE LAMINA A UN SUSTRATO (30). TAMBIEN SE DESCRIBE UN METODO PARA REALIZAR TAL MATERIAL DE LAMINA. ADEMAS DE UN MATERIAL DE LAMINA QUE TIENE LA CAPA DE COLOR Y LA CAPA REFLECTIVA COMBINADAS COMO UNA SOLA CAPA. TAMBIEN, UN MATERIAL DE LAMINA CON UN SEGMENTO GRAFICO EN EL QUE UNA CAPA DE METAL ESPECULARMENTE REFLECTIVO SE ENCUENTRA DEPOSITADA SOBRE LAS MICROESFERAS.
ES94916514T 1993-05-05 1994-03-30 Material en lamina para calcomanias retrorreflectoras. Expired - Lifetime ES2113657T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/058,155 US5344705A (en) 1993-05-05 1993-05-05 Retroreflective transfer sheet material
US08/181,619 US5503906A (en) 1993-05-05 1994-01-13 Retroreflective transfer sheet material

Publications (1)

Publication Number Publication Date
ES2113657T3 true ES2113657T3 (es) 1998-05-01

Family

ID=26737302

Family Applications (1)

Application Number Title Priority Date Filing Date
ES94916514T Expired - Lifetime ES2113657T3 (es) 1993-05-05 1994-03-30 Material en lamina para calcomanias retrorreflectoras.

Country Status (8)

Country Link
US (2) US5503906A (es)
EP (1) EP0697042B1 (es)
JP (1) JP3679116B2 (es)
CN (1) CN1076062C (es)
CA (1) CA2160361C (es)
DE (1) DE69408978T2 (es)
ES (1) ES2113657T3 (es)
WO (1) WO1994025666A1 (es)

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EP0795137B1 (en) * 1994-11-29 1998-08-26 Minnesota Mining And Manufacturing Company Transparent decorative article having an etched appearing/prismatic image thereon
US5631064A (en) * 1995-09-15 1997-05-20 Minnesota Mining And Manufacturing Company Retroreflective transfer sheet and applique
US5812317A (en) * 1995-10-26 1998-09-22 Minnesota Mining And Manufacturing Company Exposed lens retroreflective article having a polymeric intermediate layer disposed between microspheric and reflective layers
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DE19915713B4 (de) * 1999-04-08 2007-11-22 Harald Kaufmann Siebdruck-Reflexionstransfer und Verfahren zu dessen Herstellung
MXPA01003984A (es) * 1998-10-23 2003-03-10 Kaufmann Harald Producto de transfernecia de reflexion de serigrafia y metodo para producirlo.
US6376045B1 (en) * 1999-05-24 2002-04-23 Tyco Adhesives Lp Hand tearable patterned retroreflective material
DE69922849T2 (de) * 1999-06-17 2005-12-08 3M Innovative Properties Co., St. Paul Retroreflektierender gegenstand mit einer farbigen schicht, die reflektierende blättchen und einen kovalent an ein polymer gebundenen farbstoff enthält
US6361850B1 (en) * 1999-06-17 2002-03-26 3M Innovative Properties Company Retroreflective article having a colored layer containing a dye covalently bonded to a polymer
US6966660B1 (en) * 1999-10-15 2005-11-22 3M Innovative Properties Company Article exhibiting dry and wet retroreflectivity
US6958179B2 (en) * 1999-12-30 2005-10-25 3M Innovative Properties Company Segmented sheeting and methods of making and using same
US6691865B1 (en) * 2000-05-18 2004-02-17 Christopher E. Fischer Decorative tire cover and transfer pattern and method for use therewith
US20040222304A1 (en) * 2001-04-11 2004-11-11 Matthew Adams Method and apparatus for on-demand marking or etching of metal
US8002930B2 (en) 2001-05-18 2011-08-23 Boomerang Enterprises, Inc. Decorative tire cover and transfer pattern and method for use therewith
WO2002099475A1 (fr) * 2001-06-04 2002-12-12 Teijin Dupont Films Japan Limited Film reflechissant semi-permeable
GB0114738D0 (en) * 2001-06-16 2001-08-08 Reflec Plc Retroreflective fabric production
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US20050145122A1 (en) * 2003-09-24 2005-07-07 Matthew Adams Use of a UV-curable thermal ribbon in conjunction with a porous substrate to form a durable, on-demand electro-chemical stencil
US20060276565A1 (en) * 2003-09-25 2006-12-07 Craig Polta Retroflective polymeric compounds and articles made from them
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CN101380834B (zh) * 2007-12-18 2012-06-27 杭州星华反光材料有限公司 高亮彩色反光布
CN101369032B (zh) * 2008-09-11 2010-04-21 常州华日升反光材料有限公司 用于高强级反光膜生产的植珠工艺
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US8727550B2 (en) 2009-03-12 2014-05-20 Oryon Technologies, Llc Hybrid electroluminescent assembly
EP2405778B1 (en) * 2009-03-12 2013-07-17 3M Innovative Properties Company Garment with a retroreflective and electroluminescent article
PL2470931T3 (pl) 2009-08-25 2016-08-31 Avery Dennison Corp Wyrób retrorefleksyjny
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KR20130086299A (ko) 2010-05-25 2013-08-01 쓰리엠 이노베이티브 프로퍼티즈 컴파니 렌즈 노출형 재귀반사성 물품
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CN103048713B (zh) * 2013-01-07 2015-03-11 浙江方远夜视丽反光材料有限公司 一种彩色反光制品的制造方法
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GB201413130D0 (en) 2014-07-24 2014-09-10 Nkr Cheshire Ltd A method of manufacturing a combined photoluminescent and retroreflective sheet material
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JP6760929B2 (ja) 2014-09-30 2020-09-23 スリーエム イノベイティブ プロパティズ カンパニー 再帰反射性着色物品
JP6972006B2 (ja) 2016-03-30 2021-11-24 スリーエム イノベイティブ プロパティズ カンパニー ランダムに分散された微小球の所定のパターンを主とする物品及びその製造方法
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CN111344607B (zh) * 2017-10-27 2022-06-07 3M创新有限公司 包括具有双层结构的颜色层的外露透镜回射制品
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EP0697042B1 (en) 1998-03-11
JP3679116B2 (ja) 2005-08-03
US5620613A (en) 1997-04-15
CN1076062C (zh) 2001-12-12
US5503906A (en) 1996-04-02
EP0697042A1 (en) 1996-02-21
DE69408978D1 (de) 1998-04-16
JPH08509783A (ja) 1996-10-15
DE69408978T2 (de) 1998-10-29
CA2160361C (en) 2004-07-06
CA2160361A1 (en) 1994-11-10
CN1122621A (zh) 1996-05-15
WO1994025666A1 (en) 1994-11-10

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