ES2112666T3 - Composiciones polimerizables a base de monomeros tio(met)acrilatos, polimeros de bajo indice de amarillo obtenidos a partir de tales composiciones y lentes oftalmicas correspondientes. - Google Patents
Composiciones polimerizables a base de monomeros tio(met)acrilatos, polimeros de bajo indice de amarillo obtenidos a partir de tales composiciones y lentes oftalmicas correspondientes.Info
- Publication number
- ES2112666T3 ES2112666T3 ES96401064T ES96401064T ES2112666T3 ES 2112666 T3 ES2112666 T3 ES 2112666T3 ES 96401064 T ES96401064 T ES 96401064T ES 96401064 T ES96401064 T ES 96401064T ES 2112666 T3 ES2112666 T3 ES 2112666T3
- Authority
- ES
- Spain
- Prior art keywords
- ophthalmic lenses
- compositions
- tio
- met
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000178 monomer Substances 0.000 title abstract 5
- 239000000203 mixture Substances 0.000 title abstract 4
- 229920000642 polymer Polymers 0.000 title abstract 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 title 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- -1 HYDROXY GROUP Chemical group 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
- ORGHESHFQPYLAO-UHFFFAOYSA-N vinyl radical Chemical class C=[CH] ORGHESHFQPYLAO-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F228/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a bond to sulfur or by a heterocyclic ring containing sulfur
- C08F228/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a bond to sulfur or by a heterocyclic ring containing sulfur by a bond to sulfur
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
- G02B1/041—Lenses
Landscapes
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
COMPOSICION POLIMERA TRANSPARENTE QUE COMPRENDE: UN COMPONENTE A QUE COMPRENDE: AL MENOS 10% EN PESO DE UN MONOMERO O DE UNA MEZCLA DE MONOMEROS (I), QUE LLEVA AL MENOS UNA FUNCION TIOACRILATO O TIOMETACRILATO; - 0 A 90% EN PESO DE UNO O VARIOS MONOMEROS (II) COPOLIMERIZABLES POR VIA RADICALICA, PREFERENTEMENTE VINILO, ACRILICO O METACRILICO MONO- O POLIFUNCIONALES; Y UN COMPONENTE B QUE COMPRENDE, RESPECTO DEL PESO DEL COMPONENTE A: - 0,1 A 15% EN PESO DE UNO O VARIOS MONOMEROS (III) QUE LLEVAN UNA INSATURACION ETILENICA QUE NO PERTENECE A UN SISTEMA AROMATICO Y QUE TIENE UN CARBONO EN POSICION {AL} RESPECTO DE LA INSATURACION ETILENICA QUE LLEVA UN GRUPO HIDROXI LIBRE. APLICACION EN LA FABRICACION DE LENTILLAS OFTALMICAS.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9506442A FR2734827B1 (fr) | 1995-05-31 | 1995-05-31 | Compositions polymerisables a base de monomeres thio (meth)acrylates, polymeres a faible indice de jaune obtenus a partir de telles compositions et lentilles ophtalmiques correspondantes |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2112666T3 true ES2112666T3 (es) | 1998-04-01 |
Family
ID=9479533
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES96401064T Expired - Lifetime ES2112666T3 (es) | 1995-05-31 | 1996-05-15 | Composiciones polimerizables a base de monomeros tio(met)acrilatos, polimeros de bajo indice de amarillo obtenidos a partir de tales composiciones y lentes oftalmicas correspondientes. |
Country Status (7)
Country | Link |
---|---|
US (1) | US5741831A (es) |
EP (1) | EP0745620B1 (es) |
JP (1) | JP3682117B2 (es) |
AU (1) | AU704328B2 (es) |
DE (1) | DE69600087T2 (es) |
ES (1) | ES2112666T3 (es) |
FR (1) | FR2734827B1 (es) |
Families Citing this family (50)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2734828B1 (fr) * | 1995-05-31 | 1997-07-11 | Essilor Int | Compositions polymerisables a base de monomeres thio(meth)acrylates, compositions polymeres transparentes obtenues, et leurs applications en optique |
US5916987A (en) * | 1996-05-29 | 1999-06-29 | Mitsui Chemicals, Inc. | Thiol and Sulfur-containing O-(meth) acrylate compounds and use thereof |
AUPO395896A0 (en) * | 1996-12-03 | 1997-01-02 | Sola International Holdings Ltd | Acrylic thio monomers |
FR2765879B1 (fr) * | 1997-07-11 | 2002-06-07 | Essilor Int | Nouvelles compositions polymerisables et lentilles optiques a haut indice de refraction obtenues a partir de ces compositions |
US5891931A (en) * | 1997-08-07 | 1999-04-06 | Alcon Laboratories, Inc. | Method of preparing foldable high refractive index acrylic ophthalmic device materials |
US6015842A (en) * | 1997-08-07 | 2000-01-18 | Alcon Laboratories, Inc. | Method of preparing foldable hydrophilic ophthalmic device materials |
FR2772302B1 (fr) | 1997-12-11 | 2000-01-21 | Essilor Int | Procede d'obtention d'une lentille ophtalmique comportant une microstructure utilitaire en surface et lentilles ophtalmiques ainsi obtenues |
FR2790264A1 (fr) * | 1999-02-26 | 2000-09-01 | Essilor Int | Procede de preparation d'un latex a proprietes photochromiques et ses applications, en particulier dans le domaine ophtalmique |
FR2828743B1 (fr) | 2001-08-14 | 2004-02-27 | Essilor Int | Procede de moulage d'une lentille presentant un insert |
WO2004009659A1 (ja) * | 2002-07-22 | 2004-01-29 | Mitsui Chemicals, Inc. | 無機超微粒子を含有する樹脂組成物 |
CN100504447C (zh) * | 2003-04-17 | 2009-06-24 | 埃西勒国际通用光学公司 | 可光固化粘合剂组合物及其在光学领域中的用途 |
FR2858691B1 (fr) | 2003-08-05 | 2005-11-11 | Essilor Int | Composition de revetement anti-rayures comportant des particules anisotropes, substrat revetu correspondant et son application en optique ophtalmique |
DE10342521A1 (de) * | 2003-09-12 | 2005-04-14 | Röhm GmbH & Co. KG | Mischungen zur Herstellung transparenter Kunststoffe, transparente Kunststoffe sowie Verfahren zu deren Herstellung und Verwendung |
US7820085B2 (en) * | 2003-10-29 | 2010-10-26 | Essilor International | Methods relating to molding optical lenses |
US7501229B2 (en) * | 2004-03-16 | 2009-03-10 | Nissan Chemical Industries, Ltd. | Anti-reflective coating containing sulfur atom |
USD527797S1 (en) * | 2004-12-23 | 2006-09-05 | Hickman David F | Sillock and handle |
JP4617207B2 (ja) * | 2005-06-03 | 2011-01-19 | 丸善石油化学株式会社 | 半導体リソグラフィー用共重合体、組成物及びチオール化合物 |
US8163354B2 (en) | 2006-05-29 | 2012-04-24 | Essilor International Compagnie Generale D'optique | Process for obtaining a hard coated article having anti-fouling properties |
FR2917416B1 (fr) | 2007-06-13 | 2012-08-10 | Essilor Int | Procede de traitement de la surface d'un substrat a base de polymere soufre destine a etre recouvert par un revetement |
FR2920431B1 (fr) | 2007-08-29 | 2010-03-12 | Essilor Int | Procede de preparation d'un materiau transparent de type alliage de polymere thermodurcissable/polymere thermoplastique et son application dans l'optique pour la fabrication de verres organiques. |
FR2920337B1 (fr) | 2007-08-29 | 2010-03-12 | Essilor Int | Procede de preparation d'un article moule transparent a base d'un alliage de polymere thermoplastique et de polymere thermodurcissable |
US8268907B2 (en) * | 2008-06-13 | 2012-09-18 | Essilor International (Compagnie Generale D'optique) | Photocurable acrylic coating compositions having good adhesion properties to a subsequent coating and corresponding coated substrates |
FR2938255B1 (fr) | 2008-11-13 | 2011-04-01 | Essilor Int | Procede de traitement au moyen d'un film adhesif d'une lentille optique comportant un revetement antisalissure en vue de son debordage |
FR2938931B1 (fr) | 2008-11-27 | 2011-03-18 | Essilor Int | Procede de fabrication d'un article d'optique a proprietes antireflets |
EP2534108B1 (en) | 2010-02-08 | 2021-12-22 | Essilor International | Optical article comprising an anti-reflecting coating having anti-fogging properties |
FR2968774B1 (fr) | 2010-12-10 | 2013-02-08 | Essilor Int | Article d'optique comportant un revetement antireflet a faible reflexion dans le domaine ultraviolet et le domaine visible |
TW201400916A (zh) | 2012-05-16 | 2014-01-01 | Essilor Int | 眼用鏡片 |
BR112016000120B1 (pt) | 2013-07-05 | 2022-02-08 | Essilor International | Artigo óptico compreendendo um revestimento anti-reflexo com uma reflexão muito reduzida no domínio visível |
DE102014214273A1 (de) | 2013-07-22 | 2015-01-22 | Ceramtec-Etec Gmbh | Transparenter Klebstoff mit einem Brechungsindex im Bereich von 1,7 bis 1,73 |
EP3027396B1 (en) | 2013-07-31 | 2023-06-14 | Essilor International | Additive manufacturing processes for transparent ophthalmic lens |
FR3021110B1 (fr) | 2014-05-19 | 2016-06-10 | Essilor Int | Procede de determination de caracteristiques colorimetriques en reflexion d'un filtre interferentiel, procede de depot d'un tel filtre interferentiel et ensemble forme d'un filtre interferentiel et d'un objet |
WO2016108077A1 (en) | 2014-12-31 | 2016-07-07 | Essilor International (Compagnie Generale D'optique) | Method of mirror coating an optical article and article thereby obtained |
CN107430211B (zh) | 2015-03-25 | 2020-04-28 | 依视路国际公司 | 具有低Rv和低Ruv的减反射溅射叠层 |
WO2017103177A1 (en) | 2015-12-17 | 2017-06-22 | Essilor International (Compagnie Générale d'Optique) | Hard muli-coat on optical article |
EP3185050A1 (en) | 2015-12-23 | 2017-06-28 | Essilor International (Compagnie Générale D'Optique) | Optical article comprising a multilayered interferential coating obtained from an organic precursor or a mixture of organic precursors |
EP3287818B1 (en) | 2016-08-23 | 2020-11-11 | Corporation de L'Ecole Polytechnique de Montreal | Ophthalmic lens having increased resistance to hot and humid environment |
EP3306354B1 (en) | 2016-10-07 | 2021-12-22 | Corporation de L'Ecole Polytechnique de Montreal | Article comprising a nanolaminate coating |
EP3346023A1 (en) | 2017-01-05 | 2018-07-11 | Essilor International | Method for layer by layer optimization of a thin film |
EP3345684B1 (en) | 2017-01-10 | 2021-03-31 | Essilor International | Spin coating system and method |
EP3396423A1 (en) | 2017-04-27 | 2018-10-31 | Essilor International | A nir-absorbing hard coat formulation and its method of preparation |
JP7027519B2 (ja) * | 2017-07-28 | 2022-03-01 | 株式会社ニコン | 光硬化性組成物、3次元造形物の製造方法 |
EP3693401B1 (en) | 2017-10-03 | 2023-10-18 | Nikon Corporation | Compound, resin precursor, cured product, optical element, optical system, interchangeable lens for camera, optical device, cemented lens, and production method for cemented lens |
EP3502768A1 (en) | 2017-12-20 | 2019-06-26 | Essilor International | Polarized eyewear with selective blocking |
EP3546122B1 (en) | 2018-03-30 | 2020-10-21 | Essilor International | Lens holding block and method for blocking and unblocking an optical lens component |
EP3581675A1 (en) | 2018-06-15 | 2019-12-18 | Corporation de L'Ecole Polytechnique de Montreal | Optical article having directional micro- or nanostructured thin film coating, and its process |
WO2020131786A1 (en) | 2018-12-18 | 2020-06-25 | Ppg Industries Ohio, Inc. | High refractive index compositions and uses thereof |
JP7519533B2 (ja) * | 2021-03-18 | 2024-07-19 | 三井化学株式会社 | 硬化性組成物、及び当該組成物から得られる光学材料 |
EP4091805A1 (en) | 2021-05-18 | 2022-11-23 | Essilor International | A method for improved coating of an optical article comprising optical elements |
KR20240116549A (ko) | 2022-03-28 | 2024-07-29 | 미쓰이 가가쿠 가부시키가이샤 | 다작용 (메트)아크릴산 싸이오에스터 조성물, 경화성 조성물, 경화물, 성형체, 광학 재료 및 다작용 (메트)아크릴산 싸이오에스터 조성물의 제조 방법 |
JPWO2023188978A1 (es) | 2022-03-28 | 2023-10-05 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4606864A (en) * | 1985-02-01 | 1986-08-19 | Eastman Kodak Company | Thiophenyl thioacrylate and thiomethacrylate monomers |
EP0273710B2 (en) * | 1986-12-26 | 1996-10-16 | Nippon Shokubai Kagaku Kogyo Co., Ltd | Resin having high refractive index, process for producing said resin and optical materials composed of said resin |
US4810812A (en) * | 1986-12-26 | 1989-03-07 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Thiolcarboxylic acid esters |
JPH0737437B2 (ja) * | 1987-06-19 | 1995-04-26 | 三井東圧化学株式会社 | 新規な含硫芳香族(メタ)アクリレ−ト |
WO1990004587A1 (en) * | 1988-10-20 | 1990-05-03 | Showa Denko Kabushiki Kaisha | 4,4'-bis(methacryloylthio)diphenyl sulfide and curable composition containing same |
JP2546887B2 (ja) * | 1989-02-07 | 1996-10-23 | 株式会社トクヤマ | チオカルボン酸エステル化合物及びその製造方法 |
CA2010364C (en) * | 1989-02-22 | 1998-10-20 | Yuichiro Iguchi | Thiol methacrylate or acrylate and resin made therefrom |
FR2699541B1 (fr) * | 1992-12-22 | 1995-04-28 | Essilor Int | Compositions polymères à faible indice de jaune, compositions polymérisables et lentilles les mettant en Óoeuvre. |
-
1995
- 1995-05-31 FR FR9506442A patent/FR2734827B1/fr not_active Expired - Fee Related
-
1996
- 1996-05-15 DE DE69600087T patent/DE69600087T2/de not_active Expired - Fee Related
- 1996-05-15 EP EP96401064A patent/EP0745620B1/fr not_active Expired - Lifetime
- 1996-05-15 ES ES96401064T patent/ES2112666T3/es not_active Expired - Lifetime
- 1996-05-23 US US08/652,244 patent/US5741831A/en not_active Expired - Fee Related
- 1996-05-28 JP JP13339096A patent/JP3682117B2/ja not_active Expired - Fee Related
- 1996-05-29 AU AU54562/96A patent/AU704328B2/en not_active Ceased
Also Published As
Publication number | Publication date |
---|---|
DE69600087D1 (de) | 1997-12-04 |
EP0745620B1 (fr) | 1997-10-29 |
JPH08325337A (ja) | 1996-12-10 |
AU5456296A (en) | 1996-12-12 |
EP0745620A1 (fr) | 1996-12-04 |
FR2734827B1 (fr) | 1997-07-11 |
JP3682117B2 (ja) | 2005-08-10 |
DE69600087T2 (de) | 1998-06-10 |
FR2734827A1 (fr) | 1996-12-06 |
AU704328B2 (en) | 1999-04-22 |
US5741831A (en) | 1998-04-21 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
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