ES2109975T3 - Cermet de niquel y procedimiento para prepararlo. - Google Patents

Cermet de niquel y procedimiento para prepararlo.

Info

Publication number
ES2109975T3
ES2109975T3 ES92201698T ES92201698T ES2109975T3 ES 2109975 T3 ES2109975 T3 ES 2109975T3 ES 92201698 T ES92201698 T ES 92201698T ES 92201698 T ES92201698 T ES 92201698T ES 2109975 T3 ES2109975 T3 ES 2109975T3
Authority
ES
Spain
Prior art keywords
nickel
cermet
prepare
phase
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES92201698T
Other languages
English (en)
Inventor
Thomas Paul Lockhart
Giampietro Piro
Federica Gagliardi
Laura Zanibelli
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eni Tecnologie SpA
Snam SpA
Original Assignee
Snam SpA
Eniricerche SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Snam SpA, Eniricerche SpA filed Critical Snam SpA
Application granted granted Critical
Publication of ES2109975T3 publication Critical patent/ES2109975T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90—Selection of catalytic material
    • H01M4/9041—Metals or alloys
    • H01M4/905—Metals or alloys specially used in fuel cell operating at high temperature, e.g. SOFC
    • H01M4/9066—Metals or alloys specially used in fuel cell operating at high temperature, e.g. SOFC of metal-ceramic composites or mixtures, e.g. cermets
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C1/00—Making non-ferrous alloys
    • C22C1/10—Alloys containing non-metals
    • C22C1/1026—Alloys containing non-metals starting from a solution or a suspension of (a) compound(s) of at least one of the alloy constituents
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
    • C22C29/12—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on oxides
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C32/00—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ
    • C22C32/001—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with only oxides
    • C22C32/0015—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with only oxides with only single oxides as main non-metallic constituents
    • C22C32/0026—Matrix based on Ni, Co, Cr or alloys thereof
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Composite Materials (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Cutting Tools, Boring Holders, And Turrets (AREA)
  • Powder Metallurgy (AREA)
  • Chemically Coating (AREA)
  • Inert Electrodes (AREA)
  • Forging (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Fuel Cell (AREA)
  • Catalysts (AREA)

Abstract

CERMET DE NIQUEL QUE CONTIENE 35-70% EN PESO DE UNA FASE DEL NIQUEL METALICA Y 65-30% EN PESO DE UNA FASE DE CIRCONIO ESTABILIZADO EN LA FORMA CUBICA CON ITRIA, APARECIENDO, SOBRE ANALISIS DE DIFRACCION DE RAYOS X, DICHAS FASES COMO DISTINTAS Y HOMOGENEAMENTE DISTRIBUIDAS A UN NIVEL MENOR DE 1 MICRA. ESTE CERMET DE NIQUEL SE OBTIENE PREPARANDO UNA SOLUCION ACUOSA QUE CONTIENE CIRCONIL DESCOMPONIBLE AL CALOR, ITRIO Y SAL DE NIQUEL, Y UN HIDROXIACIDO ORGANICO O AMINOACIDO, O UN (ACIDO) POLI (ACRILICO); RETIRANDO EL AGUA DE LA SOLUCION RESULTANTE, BAJO CONDICIONES DE AUSENCIA, O AUSENCIA SUBSTANCIAL, DE FENOMENOS DE DESCOMPOSICION, PARA PREPARAR UN SOLIDO POROSO; CALCINAR EL SOLIDO POROSO, Y REDUCIR CON HIDROGENO EL PRODUCTO DE LA CALCINACION. EL CERMET DE NIQUEL OBTENIDO DE TAL MANERA ES UTIL COMO MATERIAL ANODICO PARA CELULAS DE COMBUSTIBLE DE OXIDO SOLIDO (SOFC).
ES92201698T 1991-06-28 1992-06-11 Cermet de niquel y procedimiento para prepararlo. Expired - Lifetime ES2109975T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ITMI911792A IT1248589B (it) 1991-06-28 1991-06-28 Cermet di nichel e procedimento per la sua preparazione

Publications (1)

Publication Number Publication Date
ES2109975T3 true ES2109975T3 (es) 1998-02-01

Family

ID=11360231

Family Applications (1)

Application Number Title Priority Date Filing Date
ES92201698T Expired - Lifetime ES2109975T3 (es) 1991-06-28 1992-06-11 Cermet de niquel y procedimiento para prepararlo.

Country Status (9)

Country Link
US (1) US5261944A (es)
EP (1) EP0525844B1 (es)
JP (1) JPH05255796A (es)
AT (1) ATE160591T1 (es)
DE (1) DE69223293T2 (es)
DK (1) DK0525844T3 (es)
ES (1) ES2109975T3 (es)
GR (1) GR3025662T3 (es)
IT (1) IT1248589B (es)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5388810A (en) * 1994-01-25 1995-02-14 The United States Of America As Represented By The United States Department Of Energy Cermet crucible for metallurgical processing
IT1277439B1 (it) 1995-08-04 1997-11-10 Eniricerche Spa Cernet di nichel e relativo procedimento di preparazione
ATE191815T1 (de) * 1996-02-02 2000-04-15 Sulzer Hexis Ag Hochtemperatur-brennstoffzelle mit einem dünnfilm-elektrolyten
DE19637261C2 (de) * 1996-09-13 1998-08-27 Forschungszentrum Juelich Gmbh Verfahren zur Herstellung einer Anode für Hochtemperatur-Brennstoffzellen mittels Sol-Gel-Methode
AU3110197A (en) * 1996-11-11 1998-06-03 Gorina, Liliya Fedorovna Method for manufacturing a single unit high temperature fuel cell and its components: a cathode, an electrolyte, an anode, a current conductor, and interface and insulating layers
US6099985A (en) * 1997-07-03 2000-08-08 Gas Research Institute SOFC anode for enhanced performance stability and method for manufacturing same
US6051330A (en) * 1998-01-15 2000-04-18 International Business Machines Corporation Solid oxide fuel cell having vias and a composite interconnect
US6074771A (en) * 1998-02-06 2000-06-13 Igr Enterprises, Inc. Ceramic composite electrolytic device and method for manufacture thereof
DE10031102C2 (de) * 2000-06-30 2003-03-06 Forschungszentrum Juelich Gmbh Verfahren zur Herstellung eines Verbundkörpers, insbesondere einer Elektrode mit temperaturbeständiger Leitfähigkeit
JP3720250B2 (ja) * 2000-09-26 2005-11-24 独立行政法人科学技術振興機構 高水素吸蔵合金とその製造方法
JP4605885B2 (ja) * 2000-10-23 2011-01-05 東邦瓦斯株式会社 支持膜式固体電解質型燃料電池
US8361295B2 (en) 2003-01-24 2013-01-29 Ezelleron Gmbh Method for producing metallic moulded bodies comprising a ceramic layer, metallic moulded body, and the use of the same
EP1702376A1 (en) * 2003-12-24 2006-09-20 Pirelli & C. S.p.A. Solid oxide fuel cell
US7527761B2 (en) * 2004-12-15 2009-05-05 Coorstek, Inc. Preparation of yttria-stabilized zirconia reaction sintered products
US7833469B2 (en) * 2004-12-15 2010-11-16 Coorstek, Inc. Preparation of yttria-stabilized zirconia reaction sintered products
ITMI20042468A1 (it) * 2004-12-23 2005-03-23 Eni Spa Metodo per la preparazione di un cermet di nichel per celle a combustibile ad ossidi solidi
JP2006318767A (ja) * 2005-05-12 2006-11-24 Shinko Electric Ind Co Ltd 電極材料及び燃料電池
JP2006318769A (ja) * 2005-05-12 2006-11-24 Shinko Electric Ind Co Ltd 電極材料及び燃料電池
US7842200B2 (en) * 2006-05-30 2010-11-30 University Of Maryland, College Park Solid oxide fuel cell (SOFC) anode materials
FR2940856B1 (fr) 2009-01-05 2012-05-18 Commissariat Energie Atomique Procede de fabrication d'une electrode cermet au nickel
CN102030368A (zh) * 2010-11-18 2011-04-27 西南科技大学 一种纯相高性能稀土锆酸盐材料的制备方法
KR101220586B1 (ko) * 2010-12-28 2013-01-11 주식회사 포스코 고체산화물 연료전지용 ＮｉＯ/ＹＳＺ 복합체 제조방법
FR3029937B1 (fr) * 2014-12-16 2017-01-20 Commissariat Energie Atomique Procede de preparation d'un materiau composite du type cermet mettant en œuvre une resine echangeuse d'ions
WO2018030691A1 (ko) * 2016-08-10 2018-02-15 대주전자재료 주식회사 고체산화물 연료전지용 코어-쉘 구조의 복합 분말의 제조 방법

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3085876A (en) * 1960-03-01 1963-04-16 Du Pont Process for dispersing a refractory metal oxide in another metal
GB919052A (en) * 1960-09-28 1963-02-20 Gen Electric Co Ltd Improvements in or relating to the manufacture of sintered metallic bodies
BE634204A (es) * 1962-06-27 1900-01-01
JPS53100890A (en) * 1977-02-16 1978-09-02 Ngk Insulators Ltd Oxygen concentration cell and its manufacture

Also Published As

Publication number Publication date
EP0525844B1 (en) 1997-11-26
GR3025662T3 (en) 1998-03-31
ITMI911792A0 (it) 1991-06-28
ITMI911792A1 (it) 1992-12-28
EP0525844A3 (en) 1994-05-25
DE69223293D1 (de) 1998-01-08
US5261944A (en) 1993-11-16
EP0525844A2 (en) 1993-02-03
DK0525844T3 (da) 1998-05-18
IT1248589B (it) 1995-01-19
JPH05255796A (ja) 1993-10-05
ATE160591T1 (de) 1997-12-15
DE69223293T2 (de) 1998-04-09

Similar Documents

Publication Publication Date Title
ES2109975T3 (es) Cermet de niquel y procedimiento para prepararlo.
Liu New high pressure phases of ZrO2 and HfO2
Cohen Electrochemical studies of plutonium ions in perchloric acid solution
BR0014994A (pt) Vidro metálico para uso em processos eletroquìmicos, eletrodo para uso em uma célula eletroquìmica, e, processo para a produção eletroquìmica de oxigênio e hidrogênio a partir de uma solução aquosa em uma célula eletroquìmica
ES2026622T3 (es) Procedimiento para la preparacion de polvo de oxido de zirconio.
ATE205812T1 (de) Lamo 3-typ verbindung, wobei m aluminium, gallium oder indium ist, in pulver- oder sinterform zu dessen herstellung und dessen verwendung als sauerstoffleiter
Wiggins Intracellular pH and the structure of cell water
Ussui et al. Synthesis of ZrO 2-based ceramics for applications in SOFC.
Juhera et al. Operating modes of electrochemical H-concentration probes for tritium sensors
Lockhart et al. Nickel Cermet, and Process for Preparing It
Ferry et al. Oxidation of Titanium in LiCl--KCl Eutectic With Oxide Ions at 470 deg C
Hammerich et al. Stabilisation of organic cation-radicals; a novel anodic synthesis of cation-radical salts
Usui et al. Operating temperature of a limiting-current oxygen sensor using a zirconia electrolyte
Smolenskii et al. Behavior of UO 2 in a room-temperature ionic liquid in the presence of AlCl 3
ES2090281T3 (es) Procedimiento de fabricacion de pastillas combustibles nucleares calcinadas a partir de soluciones precipitadas con la ayuda de peroxido de hidrogeno en medio acido.
Uedaira The Free Energy of Transfer from a Binary to a Ternary Solution by the Isopiestic Measurements
Liu et al. An oxygen pumping anode for electrowinning aluminium
Muddle et al. Structural Analysis in MgO-PSZ Using Electron Microdiffraction and HREM.(Retroactive Coverage)
ATE96765T1 (de) Zirkondioxidpulver, verfahren zu seiner herstellung sowie dessen verwendung zur herstellung von sinterkoerpern.
Leonov INFLUENCE OF PHASE TRANSITIONS ON ELECTRICAL PROPERTIES IN THE SYSTEM ZRO 2-CAO
Ganesan et al. ELECTRODEPOSITION OF YTTRIA STABILISED ZIRCONIA SOLID ELECTROLYTE
SU535221A1 (ru) Электролит дл электрохимического окислени америци до
Zhou et al. Thermodynamics of Fe-Nb-Ce liquid solutions containing trace O, S and C.
GB1196930A (en) Oxide Cathode Material for Primary Fuel Cells for High Temperatures
Tananaev et al. Solubility of Al 2 O 3 in ZrO 2

Legal Events

Date Code Title Description
FG2A Definitive protection

Ref document number: 525844

Country of ref document: ES