ES2099289T3 - Procedimiento para la ciclodimerizacion de 1,3-butadienos a 4-vinilciclohexenos. - Google Patents

Procedimiento para la ciclodimerizacion de 1,3-butadienos a 4-vinilciclohexenos.

Info

Publication number
ES2099289T3
ES2099289T3 ES92923294T ES92923294T ES2099289T3 ES 2099289 T3 ES2099289 T3 ES 2099289T3 ES 92923294 T ES92923294 T ES 92923294T ES 92923294 T ES92923294 T ES 92923294T ES 2099289 T3 ES2099289 T3 ES 2099289T3
Authority
ES
Spain
Prior art keywords
cyclodimerization
butadiene
copper
contact
vinyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES92923294T
Other languages
English (en)
Other versions
ES2099289T5 (es
Inventor
Ronald W Diesen
Kenneth A Burdett
Stanley S T King
Michael M Olken
Ravi S Dixit
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=42628532&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES2099289(T3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Priority claimed from US07/688,808 external-priority patent/US5196621A/en
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Application granted granted Critical
Publication of ES2099289T3 publication Critical patent/ES2099289T3/es
Publication of ES2099289T5 publication Critical patent/ES2099289T5/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/50—Diels-Alder conversion
    • C07C2/52—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/60—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

SE PRESENTA UN PROCESO PARA LA CICLODIMERIZACION DE 1,3-BUTADIENOS A 4-VINILOCICLIHEXENOS. EL PROCESO COMPRENDE LA PUESTA EN CONTACTO DE UN BUTADIENO CON UNA ZEOLITA DE ALUMINOSILICATO DE COBRE(I) PREPARADO MEDIANTE (A) UN METODO DE IMPREGNACION O (B) MEDIANTE EL CALENTAMIENTO DE UNA MEZCLA SOLIDA DE SAL DE COBRE Y ZEOLITA O (C) MEDIANTE LA PUESTA EN CONTACTO DE VAPORES DE UNA SAL DE COBRE CON LA ZEOLITA. LOS CATALIZADORES EXHIBEN UNA LARGA VIDA Y UNA BUENA ACTIVIDAD EN EL PROCESO PRESENTADO. SE REIVINDICA EL CATALIZADOR DE CU(I) IMPREGNADO. SE PRESENTA UN SEGUNDO PROCESO DE CICLODIMERIZACION DE 1,3-BUTENOS EN 4-VINILOCICLOHEXENOS. EL PROCESO COMPRENDE LA PUESTA EN CONTACTO DE UN BUTADIENO CON UN CATALIZADOR QUE COMPRENDE IONES DE COBRE(I) SOPORTADOS SOBRE UN PORTADOR EN LA PRESENCIA DE UN SOLVENTE HIDROXILICO.
ES92923294T 1991-04-19 1992-10-22 Procedimiento para la ciclodimerizacion de 1,3-butadienos a 4-vinilciclohexenos. Expired - Lifetime ES2099289T5 (es)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US07/688,808 US5196621A (en) 1991-04-19 1991-04-19 Process for the cyclodimerization of 1,3-butadienes to 4-vinylcyclohexenes
US07/954,710 US5329057A (en) 1991-04-19 1992-09-30 Process for the cyclodimerization of 1,3-butadienes to 4-vinylcyclohexenes
PCT/US1992/009147 WO1994008925A1 (en) 1991-04-19 1992-10-22 Process for the cyclodimerization of 1,3-butadienes to 4-vinylcyclohexenes
CN 92113004 CN1036453C (zh) 1991-04-19 1992-11-13 1，3-丁二烯转化成4-乙烯基环己烯的环化二聚方法

Publications (2)

Publication Number Publication Date
ES2099289T3 true ES2099289T3 (es) 1997-05-16
ES2099289T5 ES2099289T5 (es) 2001-03-16

Family

ID=42628532

Family Applications (1)

Application Number Title Priority Date Filing Date
ES92923294T Expired - Lifetime ES2099289T5 (es) 1991-04-19 1992-10-22 Procedimiento para la ciclodimerizacion de 1,3-butadienos a 4-vinilciclohexenos.

Country Status (9)

Country Link
US (2) US5329057A (es)
EP (1) EP0665826B2 (es)
JP (1) JPH08504758A (es)
CN (1) CN1036453C (es)
AU (1) AU2920992A (es)
CA (1) CA2147604A1 (es)
DE (1) DE69218798T3 (es)
ES (1) ES2099289T5 (es)
WO (1) WO1994008925A1 (es)

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JP2836706B2 (ja) * 1995-05-25 1998-12-14 クンホ セオキュ ホアハク ジュシクヘサ ４−ビニルシクロヘキセンからエチルベンゼンを製造する方法
US5625101A (en) * 1995-06-30 1997-04-29 Phillips Petroleum Company Cyclodimerization of butadiene
DE19609947A1 (de) * 1995-11-22 1997-05-28 Degussa Siliciumreicher Zeolith
US6780806B1 (en) 1998-12-30 2004-08-24 The Regents Of The University Of Michigan Lithium-based zeolites containing silver and copper and use thereof for selective absorption
DE102005003879A1 (de) * 2005-01-24 2006-08-03 INSTITUT FüR ANGEWANDTE CHEMIE BERLIN-ADLERSHOF E.V. Katalysator zur Synthese von Dimethylcarbonat in der Gasphase
EP2072124A1 (en) * 2007-12-19 2009-06-24 BP Chemicals Limited Regeneration of zeolite carbonylation catalysts
US8395008B2 (en) 2008-01-14 2013-03-12 Catalytic Distillation Technologies Process and catalyst for cracking of ethers and alcohols
FR2931704B1 (fr) * 2008-05-28 2012-05-04 Inst Francais Du Petrole Procede de neutralisation d'une zeolithe cationique
ES2684169T3 (es) * 2009-01-23 2018-10-01 Pacific Scientific Energetic Materials Company Preparación de un explosivo primario exento de plomo
TWI434921B (zh) * 2009-06-17 2014-04-21 Danisco Us Inc 從生物異戊二烯組合物製造燃料成分之方法及系統
US8933282B2 (en) 2010-06-17 2015-01-13 Danisco Us Inc. Fuel compositions comprising isoprene derivatives
US9278984B2 (en) 2012-08-08 2016-03-08 Pacific Scientific Energetic Materials Company Method for preparation of a lead-free primary explosive
EP3129141B1 (en) 2014-04-07 2020-04-15 Haldor Topsøe A/S Method for producing metal exchanged metallo-aluminophosphates by solid-state ion exchange at low temperatures
KR102101335B1 (ko) 2014-04-07 2020-04-17 할도르 토프쉐 에이/에스 고체-상태 이온 교환에 의한 금속 교환된 미소다공성 물질의 제조 방법
US9452414B2 (en) 2014-04-30 2016-09-27 Uop Llc Metal impregnated zeolite adsorbents, methods of making, and systems for using the same
WO2018204796A1 (en) * 2017-05-04 2018-11-08 The Johns Hopkins University Methods of removing and recovering phosphorus from aqueous solutions
CN111909727B (zh) * 2020-09-22 2022-02-01 中国海洋大学 一种异戊二烯制备饱和烃类燃料的绿色合成方法

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Also Published As

Publication number Publication date
ES2099289T5 (es) 2001-03-16
US5488020A (en) 1996-01-30
EP0665826B1 (en) 1997-04-02
AU2920992A (en) 1994-05-09
JPH08504758A (ja) 1996-05-21
EP0665826B2 (en) 2000-11-29
DE69218798T3 (de) 2001-03-29
CN1036453C (zh) 1997-11-19
DE69218798T2 (de) 1997-07-17
US5329057A (en) 1994-07-12
EP0665826A1 (en) 1995-08-09
CN1087074A (zh) 1994-05-25
CA2147604A1 (en) 1994-04-28
DE69218798D1 (de) 1997-05-07
WO1994008925A1 (en) 1994-04-28

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