GB1488521A - Dimerisation of butadiene - Google Patents
Dimerisation of butadieneInfo
- Publication number
- GB1488521A GB1488521A GB4698874A GB4698874A GB1488521A GB 1488521 A GB1488521 A GB 1488521A GB 4698874 A GB4698874 A GB 4698874A GB 4698874 A GB4698874 A GB 4698874A GB 1488521 A GB1488521 A GB 1488521A
- Authority
- GB
- United Kingdom
- Prior art keywords
- butadiene
- zeolite
- oct
- reaction
- dimerisation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/76—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
- C07C2529/20—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type containing iron group metals, noble metals or copper
- C07C2529/24—Iron group metals or copper
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
1488521 Cyclodimerizing butadiene BURMAH OIL TRADING Ltd 29 Oct 1975 [30 Oct 1974] 46988/74 Heading C5E C 8 carbocyclic hydrocarbons are formed by the dimerization or dehydrodimerization of 1,3- butadiene by contact at elevated temperature with a catalyst comprising a zeolite which has been ion-exchanged with Ni, Cu, Zn and/or Co ions. The reaction may be carried out at 400- 600‹ C. using mordenite as the zeolite. The principal product of the reaction is ethylbenzene, but xylenes, toluene, benzene, vinylcyclohexene and ethylcyclohexene are also formed.
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB4698874A GB1488521A (en) | 1974-10-30 | 1974-10-30 | Dimerisation of butadiene |
JP12842875A JPS5912089B2 (en) | 1974-10-30 | 1975-10-27 | Butadienno Niriyoukahou |
DE19752548428 DE2548428A1 (en) | 1974-10-30 | 1975-10-29 | METHOD OF DIMERIZATION OF BUTADIENE |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB4698874A GB1488521A (en) | 1974-10-30 | 1974-10-30 | Dimerisation of butadiene |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1488521A true GB1488521A (en) | 1977-10-12 |
Family
ID=10443314
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB4698874A Expired GB1488521A (en) | 1974-10-30 | 1974-10-30 | Dimerisation of butadiene |
Country Status (3)
Country | Link |
---|---|
JP (1) | JPS5912089B2 (en) |
DE (1) | DE2548428A1 (en) |
GB (1) | GB1488521A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5196621A (en) * | 1991-04-19 | 1993-03-23 | The Dow Chemical Company | Process for the cyclodimerization of 1,3-butadienes to 4-vinylcyclohexenes |
US5329057A (en) * | 1991-04-19 | 1994-07-12 | The Dow Chemical Company | Process for the cyclodimerization of 1,3-butadienes to 4-vinylcyclohexenes |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4413154A (en) * | 1982-09-27 | 1983-11-01 | Mobil Oil Corporation | Diels-Alder cyclodimerization over a carbon molecular sieve catalyst |
US4665247A (en) * | 1985-11-15 | 1987-05-12 | Mobil Oil Corporation | Diels-Alder cyclization over copper-containing ZSM-12 |
US5300719A (en) * | 1992-07-09 | 1994-04-05 | The Dow Chemical Company | Dehydrocyclization of unsaturated hydrocarbons to aromatic products |
US5276257A (en) * | 1992-07-09 | 1994-01-04 | The Dow Chemical Company | Process for converting butadiene to styrene or ethylbenzene or both using catalysts containing molybdenum |
-
1974
- 1974-10-30 GB GB4698874A patent/GB1488521A/en not_active Expired
-
1975
- 1975-10-27 JP JP12842875A patent/JPS5912089B2/en not_active Expired
- 1975-10-29 DE DE19752548428 patent/DE2548428A1/en not_active Withdrawn
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5196621A (en) * | 1991-04-19 | 1993-03-23 | The Dow Chemical Company | Process for the cyclodimerization of 1,3-butadienes to 4-vinylcyclohexenes |
US5329057A (en) * | 1991-04-19 | 1994-07-12 | The Dow Chemical Company | Process for the cyclodimerization of 1,3-butadienes to 4-vinylcyclohexenes |
US5488020A (en) * | 1991-04-19 | 1996-01-30 | The Dow Chemical Company | Copper-impregnated zeolite composition |
Also Published As
Publication number | Publication date |
---|---|
JPS5912089B2 (en) | 1984-03-21 |
DE2548428A1 (en) | 1976-05-13 |
JPS5168538A (en) | 1976-06-14 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PCNP | Patent ceased through non-payment of renewal fee |