GB1442364A - Aromatization process - Google Patents

Aromatization process

Info

Publication number
GB1442364A
GB1442364A GB5853473A GB5853473A GB1442364A GB 1442364 A GB1442364 A GB 1442364A GB 5853473 A GB5853473 A GB 5853473A GB 5853473 A GB5853473 A GB 5853473A GB 1442364 A GB1442364 A GB 1442364A
Authority
GB
United Kingdom
Prior art keywords
zsm
catalyst
product
liquid product
aromatized
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5853473A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Oil Corp
Original Assignee
Mobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mobil Oil Corp filed Critical Mobil Oil Corp
Publication of GB1442364A publication Critical patent/GB1442364A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
    • C10L1/06—Liquid carbonaceous fuels essentially based on blends of hydrocarbons for spark ignition
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G35/00—Reforming naphtha
    • C10G35/04—Catalytic reforming
    • C10G35/06—Catalytic reforming characterised by the catalyst used
    • C10G35/095—Catalytic reforming characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1442364 Oligomerizing and aromatizing olefins MOBIL OIL CORP 18 Dec 1973 [11 Jan 1973] 58534/73 Heading C5E A C 2 -C 5 olefin-containing gas stream is aromatized in a two stage process comprising (a) oligomerizing the gas feed with a ZSM 5, 8 or 11 type catalyst in the absence of added H 2 at 560-850‹ F. and up to 800Àp.s.i.g. to give a product consisting of up to 50% gas and a C 5 -C 9 olefinic liquid, and contacting at least part of the liquid product of (a) with a second ZSM 5, 8 or 11 type zeolite at 800-1200‹ F. and 1-10 atmospheres in the absence of added H 2 so as to produce up to 50% of a second gaseous product and a second liquid product comprising at least 75% aromatics. In the examples propylene was oligomerized with a Ni exchanged HZSM 5 catalyst and the liquid product aromatized with Zn ZSM 5 catalyst. Gaseous products of the oligomerization maybe pyrolized to convert paraffins to olefins which are recycled to the oligomerization.
GB5853473A 1973-01-11 1973-12-18 Aromatization process Expired GB1442364A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US00322812A US3827968A (en) 1973-01-11 1973-01-11 Aromatization process

Publications (1)

Publication Number Publication Date
GB1442364A true GB1442364A (en) 1976-07-14

Family

ID=23256538

Family Applications (1)

Application Number Title Priority Date Filing Date
GB5853473A Expired GB1442364A (en) 1973-01-11 1973-12-18 Aromatization process

Country Status (8)

Country Link
US (1) US3827968A (en)
BE (1) BE809523A (en)
CA (1) CA1021357A (en)
DE (1) DE2400946A1 (en)
FR (1) FR2322917A1 (en)
GB (1) GB1442364A (en)
IT (1) IT1006710B (en)
NL (1) NL180833C (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2246141A (en) * 1990-07-19 1992-01-22 British Petroleum Co Plc Two stage process for conversion of hydrocarbons

Families Citing this family (48)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3960978A (en) * 1974-09-05 1976-06-01 Mobil Oil Corporation Converting low molecular weight olefins over zeolites
US4070411A (en) * 1975-03-26 1978-01-24 Mobil Oil Corporation Conversion of lower olefins to isobutane
US4359378A (en) * 1979-04-16 1982-11-16 Chevron Research Company Catalytic cracking process for improved octane
US4227992A (en) * 1979-05-24 1980-10-14 Mobil Oil Corporation Process for separating ethylene from light olefin mixtures while producing both gasoline and fuel oil
US4347394A (en) * 1980-12-10 1982-08-31 Chevron Research Company Benzene synthesis
US4417088A (en) * 1981-09-25 1983-11-22 Chevron Research Company Oligomerization of liquid olefins
US4511746A (en) * 1981-09-25 1985-04-16 Chevron Research Company Low activity catalyst oligomerization process
US4414423A (en) * 1981-09-25 1983-11-08 Chevron Research Company Multistep oligomerization process
US4423269A (en) * 1981-09-25 1983-12-27 Chevron Research Company Oligomerization of gaseous olefins
US4458097A (en) * 1982-04-30 1984-07-03 Union Carbide Corporation Conversion of certain hydrocarbons using divalent-copper-containing ZSM-5 type catalyst
US4444988A (en) * 1982-07-22 1984-04-24 Mobil Oil Corporation Use of liquefied propane and butane or butane recycle to control heat of reaction of converting olefins to gasoline and distillate
US4433185A (en) * 1983-04-04 1984-02-21 Mobil Oil Corporation Two stage system for catalytic conversion of olefins with distillate and gasoline modes
US4483760A (en) * 1983-06-30 1984-11-20 Mobil Oil Corporation Process for dewaxing middle distillates
NZ209388A (en) * 1983-09-19 1987-02-20 Mobil Oil Corp Two-stage process for converting olefinic components in feedstock to high viscosity index lubricating oils using zeolite catalyst
US4528414A (en) * 1983-11-15 1985-07-09 Union Carbide Corporation Olefin oligomerization
US4527001A (en) * 1983-11-15 1985-07-02 Union Carbide Corporation Small olefin interconversions
US4613721A (en) * 1983-11-15 1986-09-23 Union Carbide Corporation Small olefin interconversions
US4612406A (en) * 1983-11-15 1986-09-16 Union Carbide Corporation Olefin oligomerization
US4897245A (en) * 1984-02-01 1990-01-30 Mobil Oil Corp. Catalytic reactor system for conversion of light olefin to heavier hydrocarbons with sorption recovery of unreacted olefin vapor
US4511747A (en) * 1984-02-01 1985-04-16 Mobil Oil Corporation Light olefin conversion to heavier hydrocarbons with sorption recovery of unreacted olefin vapor
US4605807A (en) * 1984-04-27 1986-08-12 Atlantic Richfield Company Process for catalytic conversion of ethylene to higher hydrocarbons
CA1227497A (en) * 1984-05-18 1987-09-29 Eduard P. Kieffer Process for the preparation of an aromatic hydrocarbon mixture
JP2617291B2 (en) * 1984-08-15 1997-06-04 智行 乾 Method for converting lower paraffinic hydrocarbons to aromatic hydrocarbons
US4740645A (en) * 1984-09-14 1988-04-26 Mobil Oil Corporation Multistage conversion of lower olefins with interreactor quenching
US4740648A (en) * 1985-03-11 1988-04-26 Union Carbide Corporation Conversion of olefins to liquid motor fuels
US4717782A (en) * 1985-09-13 1988-01-05 Mobil Oil Corporation Catalytic process for oligomerizing ethene
US4891457A (en) * 1985-09-13 1990-01-02 Hartley Owen Multistage process for converting olefins to heavier hydrocarbons
US4788370A (en) * 1986-05-13 1988-11-29 Mobil Oil Corporation Catalytic conversion
US4746763A (en) * 1987-04-22 1988-05-24 Uop Inc. Process for producing aromatic compounds from C2 -C6 aliphatic hydrocarbons
US4788364A (en) * 1987-12-22 1988-11-29 Mobil Oil Corporation Conversion of paraffins to gasoline
USRE34189E (en) * 1987-12-22 1993-03-02 Mobil Oil Corporation Conversion of paraffins to gasoline
US4827069A (en) * 1988-02-19 1989-05-02 Mobil Oil Corporation Upgrading light olefin fuel gas and catalytic reformate in a turbulent fluidized bed catalyst reactor
AU3346689A (en) * 1988-02-19 1989-09-06 Mobil Oil Corporation Process for the production of gasoline from fuel gas and catalytic reformate
US4851602A (en) * 1988-04-11 1989-07-25 Mobil Oil Corporation Alkanes and alkenes conversion to high octane gasoline
US4879424A (en) * 1988-09-19 1989-11-07 Mobil Oil Corporation Conversion of alkanes to gasoline
US4885420A (en) * 1988-10-31 1989-12-05 Uop Process for the production of aromatic hydrocarbons from olefinic hydrocarbons
US4992607A (en) * 1989-03-20 1991-02-12 Mobil Oil Corporation Petroleum refinery process and apparatus for the production of alkyl aromatic hydrocarbons from fuel gas and catalytic reformate
US5004852A (en) * 1989-08-24 1991-04-02 Mobil Oil Corp. Two-stage process for conversion of olefins to high octane gasoline
US5773676A (en) * 1996-08-06 1998-06-30 Phillips Petroleum Company Process for producing olefins and aromatics from non-aromatics
US5932777A (en) * 1997-07-23 1999-08-03 Phillips Petroleum Company Hydrocarbon conversion
KR20050102766A (en) * 2004-04-22 2005-10-27 주식회사 엘지화학 Hydrocarbon cracking catalyst and method for preparing the same
CN101952398B (en) 2007-12-03 2014-05-21 格沃股份有限公司 Renewable compositions
US8193402B2 (en) * 2007-12-03 2012-06-05 Gevo, Inc. Renewable compositions
EA022457B1 (en) 2009-11-02 2016-01-29 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Process for the conversion of mixed lower alkanes to aromatic hydrocarbons
CA2786607A1 (en) 2010-01-08 2011-07-14 Gevo, Inc. Integrated methods of preparing renewable chemicals
US8373012B2 (en) 2010-05-07 2013-02-12 Gevo, Inc. Renewable jet fuel blendstock from isobutanol
US8742187B2 (en) 2011-04-19 2014-06-03 Gevo, Inc. Variations on prins-like chemistry to produce 2,5-dimethylhexadiene from isobutanol
CN103834437B (en) * 2012-11-27 2015-09-23 中国石油天然气股份有限公司 A kind of processing method of lower carbon number hydrocarbons hydroaromatization

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA822162A (en) * 1969-09-02 B. Weisz Paul Hydrocarbon conversion process
DE1518745A1 (en) * 1957-05-01 1969-05-22 Exxon Research Engineering Co Use of crystalline zeolitic metal aluminum silicates as catalysts for aromatizing hydrocarbons
US3374282A (en) * 1967-02-01 1968-03-19 Dow Chemical Co Method of preparing aromatic hydrocarbons from propylene hydrocarbons

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2246141A (en) * 1990-07-19 1992-01-22 British Petroleum Co Plc Two stage process for conversion of hydrocarbons

Also Published As

Publication number Publication date
BE809523A (en) 1974-07-08
NL180833C (en) 1987-05-04
FR2322917B1 (en) 1978-02-17
NL7400438A (en) 1974-07-15
DE2400946A1 (en) 1974-07-25
DE2400946C2 (en) 1989-05-03
CA1021357A (en) 1977-11-22
US3827968A (en) 1974-08-06
NL180833B (en) 1986-12-01
FR2322917A1 (en) 1977-04-01
IT1006710B (en) 1976-10-20

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee